Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Performance Gap”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Surface-Enhanced Raman Scattering (SERS) Studies of Disc-on-Pillar (DOP) Arrays: Contrasting Enhancement Factor with Analytical Performance

The use of nanomachining methods capable of reproducible construction of nano-arrayed devices have revolutionized the field of plasmonic sensing by the introduction of a diversity of rationally engineered designs. Significant strides have been made to fabricate plasmonic platforms with tailored interparticle gaps to improve their performance for surface-enhanced Raman scattering (SERS) applications. Over time, a dichotomy has emerged in the implementation of SERS for analytical applications, the construction of substrates, optimization of interparticle spacing as a means to optimize electromagnetic field enhancement at the localized surface plasmon level, and the substrate sensitivity over extended areas to achieve quantitative performance. Here, we assessed the enhancement factor of plasmonic Ag/SiO 2 /Si disc-on-pillar (DOP) arrays of variable pitch with its analytical performance for quantitative applications. Experimental data were compared with those from finite-difference time-domain (FDTD) simulations used in the optimization of the array dimensions. A self-assembled monolayer (SAM) of benzenethiol rendered highly reproducible signals (RSD ~4–10%) and SERS substrate enhancement factor (SSEF) values in the orders of 10 6 –10 8 for all pitches. Furthermore, spectra corresponding to rhodamine 6G (R6G) and 4-aminobenzoic acid demonstrated the advantages of using the more densely packed DOP arrays with a 160 nm pitch (gap= 40 nm) for quantitation in spite of the strongest SSEF was attained for a pitch of 520 nm corresponding to a 400 nm gap.

36 MATERIALS SCIENCE↗
NASA NTRS2019

Modeling Quiet Solar Luminosity Variability from TSI Satellite Measurements and Proxy Models During 1980–2018

A continuous record of direct total solar irradiance (TSI) observations began with a series of satellite experiments in 1978. This record requires comparisons of overlapping satellite observations with adequate relative precisions to provide useful long term TSI trend information. Herein we briefly review the active cavity radiometer irradiance monitor physikalisch-meteorologisches observatorium davos (ACRIM-PMOD) TSI composite controversy regarding how the total solar irradiance (TSI) has evolved since 1978 and about whether TSI significantly increased or slightly decreased from 1980 to 2000. The main question is whether TSI increased or decreased during the so-called ACRIM-gap period from 1989 to 1992. There is significant discrepancy between TSI proxy models and observations before and after the gap, which requires a careful revisit of the data analysis and modeling performed during the ACRIM-gap period. In this study, we use three recently proposed TSI proxy models that do not present any TSI increase during the ACRIM-gap, and show that they agree with the TSI data only from 1996 to 2016. However, these same models significantly diverge from the observations from 1981 and 1996. Thus, the scaling errors must be different between the two periods, which suggests errors in these models. By adjusting the TSI proxy models to agree with the data patterns before and after the ACRIM-gap, we found that these models miss a slowly varying TSI component. The adjusted models suggest that the quiet solar luminosity increased from the 1986 to the 1996 TSI minimum by about 0.45 W/sq.m reaching a peak near 2000 and decreased by about 0.15 W/sq.m from the 1996 to the 2008 TSI cycle minimum. This pattern is found to be compatible with the ACRIM TSI composite and confirms the ACRIM TSI increasing trend from 1980 to 2000, followed by a long-term decreasing trend since.

Scafetta, Nicola↗
NASA NTRS2019

Modeling Quiet Solar Luminosity Variability from TSI Satellite Measurements and Proxy Models during 1980-2018

A continuous record of direct total solar irradiance (TSI) observations began with a series of satellite experiments in 1978. This record requires comparisons of overlapping satellite observations with adequate relative precisions to provide useful long term TSI trend information. Herein we briefly review the active cavity radiometer irradiance monitor physikalisch-meteorologisches observatorium davos (ACRIM-PMOD) TSI composite controversy regarding how the total solar irradiance (TSI) has evolved since 1978 and about whether TSI significantly increased or slightly decreased from 1980 to 2000. The main question is whether TSI increased or decreased during the so-called ACRIM-gap period from 1989 to 1992. There is significant discrepancy between TSI proxy models and observations before and after the gap, which requires a careful revisit of the data analysis and modeling performed during the ACRIM-gap period. In this study, we use three recently proposed TSI proxy models that do not present any TSI increase during the ACRIM-gap, and show that they agree with the TSI data only from 1996 to 2016. However, these same models significantly diverge from the observations from 1981 and 1996. Thus, the scaling errors must be different between the two periods, which suggests errors in these models. By adjusting the TSI proxy models to agree with the data patterns before and after the ACRIM-gap, we found that these models miss a slowly varying TSI component. The adjusted models suggest that the quiet solar luminosity increased from the 1986 to the 1996 TSI minimum by about 0.45 W/m2 reaching a peak near 2000 and decreased by about 0.15 W/m2 from the 1996 to the 2008 TSI cycle minimum. This pattern is found to be compatible with the ACRIM TSI composite and confirms the ACRIM TSI increasing trend from 1980 to 2000, followed by a long-term decreasing trend since.

total solar irradiance↗
NASA NTRS1988

VLA telemetry performance with concatenated coding for Voyager at Neptune

Current plans for supporting the Voyager encounter at Neptune include the arraying of the Deep Space Network (DSN) antennas at Goldstone, California, with the National Radio Astronomy Observatory's Very Large Array (VLA) in New Mexico. Not designed as a communications antenna, the VLA signal transmission facility suffers a disadvantage in that the received signal is subjected to a gap or blackout period of approximately 1.6 msec once every 5/96 sec control cycle. Previous analyses showed that the VLA data gaps could cause disastrous performance degradation in a VLA stand-alone system and modest degradation when the VLA is arrayed equally with Goldstone. New analysis indicates that the earlier predictions for concatenated code performance were overly pessimistic for most combinations of system parameters, including those of Voyager-VLA. The periodicity of the VLA gap cycle tends to guarantee that all Reed-Solomon codewords will receive an average share of erroneous symbols from the gaps. However, large deterministic fluctuations in the number of gapped symbols from codeword to codeword may occur for certain combinations of code parameters, gap cycle parameters, and data rates. Several mechanisms for causing these fluctuations are identified and analyzed. Even though graceful degradation is predicted for the Voyager-VLA parameters, catastrophic degradation greater than 2 dB can occur for a VLA stand-alone system at certain non-Voyager data rates inside the range of the actual Voyager rates. Thus, it is imperative that all of the Voyager-VLA parameters be very accurately known and precisely controlled.

Dolinar, S. J., Jr.↗
DOE OSTI2019

High lifetime and mobility CdTe alloys by co-sublimation

The focus of this project was to understand controlled doping of CdTe and CdSe x Te 1-x films using group V element dopants such as nitrogen and arsenic. Using methods such as metal organic precursor injection as well as deposition of absorber with source charge incorporated with desired group V dopant. Using characterization methods such as Secondary Ion Mass Spectroscopy and capacitance vs voltage measurement dopant incorporation and activation was verified. Since our deposition system had CuCl deposition source, this source was permanently removed from the system and vacuum chamber was thoroughly cleaned out. CdSe x Te 1-x grading into CdTe has led to higher device efficiency owing to an improvement in short-circuit current (J SC ) due to its lower band-gap. More device fabrication and characterization was performed in an effort to optimize the lower band-gap CdSe x Te 1-x . This optimization was performed using different co-sublimation method where CdTe and Se were co-sublimated in varying proportion to sweep the band-gap of CdSe x Te 1-x that deposited on the substrate.

14 SOLAR ENERGY↗
DOE OSTI2019

Performance Improvements to the Prototype Design of the AGU

The existing design for the Magnet Structure of the prototype multi-segment AGU (Adaptive- Gap Undulator) has undergone analysis (see TN #298). To optimize performance, after review of said analysis, certain design modifications are proposed herein. A primary constraint of this proposed design is to use the existing fabricated parts from initial assembly SR-ID-SAGU-4300 with three pairs of feed-throughs spaced along the platen length of a single segment, but with foresight for the eventual multi-segment prototype. Measurements of the center segment are to be conducted on the frame and gap-drive system of the NSLS X9 MGU with its single driven axis. The eventual multi-segment prototype will also use the sister devices (X13, X27) for simultaneous measurement of both central and outboard segments at various segment gaps. Criteria effecting IVU performance like Gap Tolerance, Taper Error, and the critical Planarity of pole plane as in Figure 1 are used to evaluate the design. The error in planarity to be minimized is the deviation of vertical displacement (Y direction) with Platen length (beam Z direction).

36 MATERIALS SCIENCE↗
DOE OSTI2018

Unit mechanisms of fission gas release: Current understanding and future needs

Gaseous fission product transport and release has a large impact on fuel performance, degrading fuel properties and, once the gas is released into the gap between the fuel and cladding, lowering gap thermal conductivity and increasing gap pressure. While gaseous fission product behavior has been investigated with bulk reactor experiments and simplified analytical models, recent improvements in experimental and modeling approaches at the atomistic and mesoscales are being applied to provide unprecedented understanding of the unit mechanisms that define the fission product behavior. In this article, existing research on the basic mechanisms behind the various stages of fission gas release during normal reactor operation are summarized and critical areas where experimental and simulation work is needed are identified. This basic understanding of the fission gas behavior mechanisms has the potential to revolutionize our ability to predict fission product behavior during reactor operation and to design fuels that have improved fission product retention. In addition, this work can serve as a model on how a coupled experimental and modeling approach can be applied to understand the unit mechanisms behind other critical behaviors in reactor materials.

computer simulation↗
DOE OSTI2014

Improvement in the statistical operation of a Blumlein pulse forming line in bipolar pulse mode

The paper presents the results of studies on shot-to-shot performance of a water Blumlein pulse forming line of 1–1.2 kJ of stored energy. The experiments were carried using the TEMP-4M pulsed ion beam accelerator during its operation in both unipolar pulse mode (150 ns, 250–300 kV) and bipolar-pulse mode with the first negative (300–600 ns, 100–150 kV) followed by a second positive (120 ns, 250–300 kV) pulse. The analysis was carried out for two cases when the Blumlein was terminated with a resistive load and with a self-magnetically insulated ion diode. It was found that in bipolar pulse mode the shot-to-shot variation in breakdown voltage of a preliminary spark gap is small, the standard deviation (1σ) does not exceed 2%. At the same time, the shot-to-shot variation in the breakdown voltage of the main spark gap in both bipolar-pulse and unipolar pulse mode is 3–4 times higher than that for the preliminary spark gap. To improve the statistical performance of the main spark gap we changed the regime of its operation from a self-triggered mode to an externally triggered mode. In the new arrangement the first voltage pulse at the output of Blumlein was used to trigger the main spark gap. The new trigatron-type regime of the main spark gap operation showed a good stability of breakdown voltage and thus allowed to stabilize the duration of the first pulse. The standard deviation of the breakdown voltage and duration of the first pulse did not exceed 2% for a set of 50 pulses. The externally triggered mode of the main gap operation also allowed for a decrease in the charging voltage of the Blumlein to a 0.9–0.95 of self-breakdown voltage of the main spark gap while the energy stored in Marx generator was decreased from 4 kJ to 2.5 kJ. At the same time the energy stored in Blumlein remained the same.

43 PARTICLE ACCELERATORS↗
NASA NTRS2011

Mu-Spec - A High Performance Ultra-Compact Photon Counting spectrometer for Space Submillimeter Astronomy

We have designed and are testing elements of a fully integrated submillimeter spectrometer based on superconducting microstrip technology. The instrument can offer resolving power R approximately 1500, and its high frequency cutoff is set by the gap of available high performance superconductors. All functions of the spectrometer are integrated - light is coupled to the microstrip circuit with a planar antenna, the spectra discrimination is achieved using a synthetic grating, orders are separated using planar filter, and detected using photon counting MKID detector. This spectrometer promises to revolutionize submillimeter spectroscopy from space. It replaces instruments with the scale of 1m with a spectrometer on a 10 cm Si wafer. The reduction in mass and volume promises a much higher performance system within available resource in a space mission. We will describe the system and the performance of the components that have been fabricated and tested.

Moseley, H.↗
DOE OSTI2018

A modular synthetic approach for band-gap engineering of armchair graphene nanoribbons

Despite the great promise of armchair graphene nanoribbons (aGNRs) as high-performance semiconductors, practical band-gap engineering of aGNRs remains an unmet challenge. Given that width and edge structures are the two key factors for modulating band-gaps of aGNRs, a reliable synthetic method that allows control of both factors would be highly desirable. We report a simple modular strategy for efficient preparation of N = 6 aGNR, the narrowest member in the N = 3p (p: natural number) aGNR family, and two unsymmetrically edge-functionalized GNRs that contain benzothiadiazole and benzotriazole moieties. The trend of band-gap transitions among these GNRs parallels those in donor-acceptor alternating conjugated polymers. In addition, post-functionalization of the unsymmetrical heterocyclic edge via C-H borylation permits further band-gap tuning. Therefore, this method opens the door for convenient band-gap engineering of aGNRs through modifying the heteroarenes on the edge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1976

Effect of a surface-to-gap temperature discontinuity on the heat transfer to reusable surface insulation tile gaps

An experimental investigation is presented that was performed to determine the effect of a surface-to-gap wall temperature discontinuity on the heat transfer within space shuttle, reusable surface insulation, tile gaps submerged in a thick turbulent boundary layer. Heat-transfer measurements were obtained on a flat-plate, single-gap model submerged in a turbulent tunnel wall boundary layer at a nominal free-stream Mach number of 10.3 and free-stream Reynolds numbers per meter of 1.5 million, 3.3 million and 7.8 million. Surface-to-gap wall temperature discontinuities of varying degree were created by heating the surface of the model upstream of the instrumented gap. The sweep angle of the gap was varied between 0 deg and 60 deg; gap width and depth were held constant. A surface-to-gap wall temperature discontinuity (surface temperature greater than gap wall temperature) results in increased heat transfer to the near-surface portion of the gap, as compared with the heat transfer under isothermal conditions, while decreasing the heat transfer to the deeper portions of the gap. The nondimensionalized heat transfer to the near-surface portion of the gap is shown to decrease with increasing Reynolds number; in the deeper portion of the gap, the heat transfer increases with Reynolds number.

Throckmorton, D. A.↗
NASA NTRS2003

Evaluation of Cache-based Superscalar and Cacheless Vector Architectures for Scientific Computations

The growing gap between sustained and peak performance for scientific applications has become a well-known problem in high performance computing. The recent development of parallel vector systems offers the potential to bridge this gap for a significant number of computational science codes and deliver a substantial increase in computing capabilities. This paper examines the intranode performance of the NEC SX6 vector processor and the cache-based IBM Power3/4 superscalar architectures across a number of key scientific computing areas. First, we present the performance of a microbenchmark suite that examines a full spectrum of low-level machine characteristics. Next, we study the behavior of the NAS Parallel Benchmarks using some simple optimizations. Finally, we evaluate the perfor- mance of several numerical codes from key scientific computing domains. Overall results demonstrate that the SX6 achieves high performance on a large fraction of our application suite and in many cases significantly outperforms the RISC-based architectures. However, certain classes of applications are not easily amenable to vectorization and would likely require extensive reengineering of both algorithm and implementation to utilize the SX6 effectively.

Oliker, Leonid↗
DOE OSTI2014

Resonant indirect excitation of Gd{sup 3+} in AlN thin films

We studied the efficient indirect excitation of Gd{sup 3+} ions in AlN thin films. C-axis oriented polycrystalline thin films of Al{sub 0.997}Gd{sub 0.003}N/AlN were grown on fused silica substrates using a reactive radio-frequency magnetron sputtering technique. The intra-orbital electron transition in Gd{sup 3+} showed a narrow luminescence line at 3.9 eV. The photoluminescence (PL) excitation (PLE) spectrum exhibited a peak originating from efficient indirect energy transfer from the band edge of AlN to Gd{sup 3+} ions. The PLE peak shifted and the PL intensity showed a dramatic change when the AlN band gap was varied by changing the temperature. Energy scanning performed by changing the band-gap energy of AlN with temperature revealed several resonant channels of energy transfer into the higher excited states of Gd{sup 3+}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1998

Low-Loss NbTiN Films for THz SIS Mixer Tuning Circuits

Recent results at 1 THz using normal-metal tuning circuits have shown that SIS mixers can work well up to twice the gap frequency of the junction material (niobium). However, the performance at 1 THz is limited by the substantial loss in the normal metal films. For better performance superconducting films with a higher gap frequency than niobium and with low RF loss are needed. Niobium nitride has long been considered a good candidate material, but typical NbN films suffer from high RF loss. To circumvent this problem we are currently investigating the RF loss in NbTiN films, a 15 K Tc compound superconductor, by incorporating them into quasi-optical slot antenna SIS devices.

Kooi, J. W.↗
DOE OSTI2017

Measuring CO 2 and N 2 O Mass Transfer into GAP-1 CO 2 –Capture Solvents at Varied Water Loadings

This paper investigates the CO 2 and N 2 O absorption behavior in the water-lean gamma amino propyl (GAP)-1/TEG solvent system using a wetted-wall contactor. Testing was performed on a blend of GAP-1 aminosilicone in triethylene glycol at varied water loadings in the solvent. Measurements were made with CO 2 and N 2 O at representative lean (0.04 mol CO 2 /mol alkalinity), middle (0.13 mol CO 2 /mol alkalinity) and rich (0.46 mol CO 2 /mol alkalinity) solvent loadings at 0, 5, 10 and 15 wt% water loadings at 40, 60 and 80C° and N 2 O at (0.08-0.09 mol CO 2 /mol alkalinity) at 5 wt% water at 40, 60 and 80C°. CO 2 flux was found to be non-linear with respect to log mean pressure driving force (LMPD). Liquid-film mass transfer coefficients (k'g) were calculated by subtracting the gas film resistance (determined from a correlation from literature) from the overall mass transfer measurement. The resulting k'g values for CO 2 and N 2 O in GAP-1/TEG mixtures were found to be higher than that of 5M aqueous monoethanolamine under comparable driving force albeit at higher solvent viscosities. The k'g values for CO 2 were also found to decrease with increasing solvent water content and increase with a decrease in temperature. These observations indicate that mass transfer of CO 2 in GAP-1/TEG is linked to the physical solubility of CO 2 , which is higher in organic solvents compared to water. This paper expands on the understanding of the unique mass transfer behavior and kinetics of CO 2 capture in water-lean solvents.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

A large area 100-channel PICOSEC Micromegas detector with time resolution at the 20 ps level

Abstract The PICOSEC Micromegas precise timing detector is based on a Cherenkov radiator coupled to a photocathode operating in a semi-transparent mode and a Micromegas amplification structure. The first proof of concept single-channel prototype was able to achieve a time resolution below 25 ps. One of the crucial aspects in the development of precise timing gaseous detectors applicable in high-energy physics experiments is a modular design that enables large area coverage. The first 19-channel multi-pad prototype with an active area of approximately 10 cm 2 suffered from degraded timing resolution due to the non-uniformity of the preamplification gap thickness. A new 100 cm 2 detector module with 100 channels based on a rigid hybrid ceramic/FR4 Micromegas board for improved drift gap uniformity was developed. Initial measurements with 80 GeV/c muons showed improvements in timing response over the measured pads and a time resolution below 25 ps. More recent measurements with a thinner drift gap detector module and newly developed RF pulse amplifiers show that the pad centre resolution can be enhanced to the level of 17 ps. This work will present the development of the detector from structural simulations, design, and beam test commissioning with a focus on the timing performance of a thinner drift gap detector module in combination with new electronics using an automated timing scan method.

Utrobicic, A.↗
DOE OSTI2021

A Comparison of Time Series Gap-Filling Methods to Impute Solar Radiation Data

Complete solar resource datasets play a critical role at every stage of solar project phases. However, measured or modeled solar resource data come with significant uncertainties and usually suffer from several issues, including but not limited to, data gaps, data quality issue, etc. In order to mitigate these issues an appropriate data imputation method should be implemented to build a complete and reliable temporal (and spatial) database. Being motivated by this, in this study we compare the performances of eight different gap filling methods extensively by creating random and artificial data gaps in (i) hourly irradiance data for one year using a few locations of the National Solar Radiation Database (NSRDB) and (ii) one-minute ground measurement dataset from Surface Radiation Budget Network (SURFRAD) stations.

clearness index↗