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Feasibility of Methane Oxidation on SSZ-13 Bridged Pd 2 O x Sites: A Theoretical Study
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Experimental and Theoretical Studies of Pd Cation Reduction and Oxidation During NO Adsorption on and Desorption from Pd/H–CHA
Not Available
Stabilization of Super Electrophilic Pd[superscript +2] Cations in Small-Pore SSZ-13 Zeolite
Abstract not provided
Synthesis of End-Functionalized Poly(norbornenes) and Poly(ethylidene norbornenes) Using a Pd(II) Catalyst in Combination with Chain Transfer Agents
Synthesis of end-functionalized poly(norbornene)s (PNBs) and poly(ethylidenenorbornene)s (PENBs) were prepared using the palladium catalyst t Bu 3 PPdMeCl/NaBAr f in combination with chain transfer agents (CTAs) 4-penten-1-ol and 10-undecenal. These CTAs produce polymers end-capped with -OH and -CHO groups, respectively, in high yields with M n values in the range of 6K to 17K, depending on the molar ratio of the CTA: monomer. End-functionalized PNBs and PENBs with precisely controlled Mn values and very narrow molecular weight distributions were accessed by using 4-penten-1-ol and 10-undecenal as chain-terminating agents following living polymerizations in which monomer is completely consumed. The utility of the aldehyde-functionalized polymers is illustrated via coupling to a dye molecule and by synthesis of ambiphilic diblock copolymers, PNB-b-PEG and PENB-b-PEG.
Unmasking the Latent Passivating Roles of Ni(OH)2 on the Performance of Pd-Ni Electrocatalysts for Alkaline Ethanol Fuel Cells
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