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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Potassium permanganate for mercury vapor environmental control

Potassium permanganate (KMnO4) was evaluated for application in removing mercury vapor from exhaust air systems. The KMnO4 may be used in water solution with a liquid spray scrubber system or as a solid adsorber bed material when impregnated onto a zeolite. Air samples contaminated with as much as 112 mg/cu m of mercury were scrubbed to 0.06mg/cum with the KMnO4-impregnated zeolite (molecular sieve material). The water spray solution of permanganate was also found to be as effective as the impregnated zeolite. The KMnO4-impregnated zeolite was applied as a solid adsorber material to (1) a hardware decontamination system, (2) a model incinerator, and (3) a high vacuum chamber for ion engine testing with mercury as the propellant. A liquid scrubber system was also applied in an incinerator system. Based on the results of these experiments, it is concluded that the use of KMnO4 can be an effective method for controlling noxious mercury vapor.

Kuivinen, D. E.↗
NASA NTRS1972

Rubidium-strontium and potassium-argon age of lunar sample 15555.

The lunar mare basalt 15555 from the edge of Hadley Rille has been dated at 3.3 b.y. by both rubidium-strontium and potassium-argon techniques. Age and trace element abundances closely resemble those of the Apollo 12 mare basalts. Data from lunar basalts obtained thus far indicate that they cannot be derived by simple fractionation from a homogeneous source.

Murthy, V. R.↗
NASA NTRS1972

Vapor chamber fin radiator study for the potassium Rankine cycle.

A structurally integrated vapor chamber fin (heat pipe) radiator is defined and evaluated as a potential candidate for rejecting waste heat from the potassium Rankine cycle powerplant. Several vapor chamber fin geometries, using stainless steel construction, are evaluated and an optimum is selected. A comparison is made with an operationally equivalent conduction fin radiator. Both radiators employ NaK-78 in the primary coolant loop. In addition, the Vapor Chamber Fin (VCF) radiator utilizes sodium in the vapor chambers. Preliminary designs are developed for the conduction fin and VCF concepts. Performance tests on a single vapor chamber were conducted to verify the VCF design.

Gerrels, E. E.↗
NASA NTRS1975

Oxygen reduction of several gold alloys in 1-molar potassium hydroxide

With rotated disk-and-ring equipment, polarograms and other electrochemical measurements were made of oxygen reduction in 1-molar potassium hydroxide on an equiatomic gold-copper (Au-Cu) alloy and a Au-Cu alloy doped with either indium (In) or cobalt (Co) and on Au doped with either nickel (Ni) or platinum (Pt). The results were compared with those for pure Au and pure Pt. The two-electron reaction dominated on all Au alloys as it did on Au. The polarographic results at lower polarization potentials were compared, assuming exclusively a two-step reduction. A qualified ranking of cathodic electrocatalytic activity on the freshly polished reduced disks was indicated: anodized Au Au-Cu-In Au-Cu Au-Cu-Co is equivalent or equal to Au-Pt Au-Ni. Aging in distilled water improved the electrocatalytic efficiency of Au-Cu-Co, Au-Cu, and (to a lesser extent) Au-Cu-In.

Miller, R. O.↗
NASA NTRS1978

Lithium and potassium heat pipes for thermionic converters

A prototypic heat pipe system for an out-of-core thermionic reactor was built and tested. The emitter of the concentric thermionic converter consists of the condenser of a tungsten heat pipe utilizing a lithium working fluid. The evaporator section of the emitter heat pipe is radiation heated to simulate the thermal input from the nuclear reactor. The emitter heat pipe thermal transport is matched to the thermionic converter input requirement. The collector heat pipe of niobium, 1% zirconium alloy uses potassium as the working fluid. The thermionic collector is coupled to the heat pipe by a tapered conical joint designed to minimize the temperature drop. The collector heat flux matches the design requirements of the thermionic converter.

Miskolczy, G.↗
NASA NTRS1978

Reflectance spectra for sodium and potassium doped ammonia frosts - Implications for Io's surface

This paper reports measurements of the reflection spectra of sodium- and potassium-doped ammonia frosts as a function of alkali metal concentration for the wavelength range 0.35-2.5 microns. The purpose of the measurements was to determine whether or not the reflection spectra for such a solid was compatible with the spectra albedo of Io. The data show that, with a sufficiently large alkali metal concentration, the reflection spectra of the doped ammonia frosts do not display the characteristic ammonia features at 2.0 and 2.25 micron. The high reflectance of the more concentrated samples and the character of the observed reflection spectrum make it difficult to rule out sodium-doped ammonia frost as a surface constituent on Io on the basis of existing data.

Rosen, M. D. A.↗
NASA NTRS1978

Lithium and potassium heat pipes for thermionic converters

A prototypic heat pipe system for an out-of-core thermionic reactor has been built and tested. The emitter of the concentric thermionic converter consists of the condenser of a tungsten heat pipe utilizing a lithium working fluid. The evaporator section of the emitter heat pipe is radiation heated to simulate the thermal input from the nuclear reactor. The emitter heat pipe thermal transport is matched to the thermionic converter input requirement. The collector heat pipe of niobium, 1%-zirconium alloy uses potassium as the working fluid. The thermionic collector is coupled to the heat pipe by a tapered conical joint designed to minimize the temperature drop. The area ratio of the evaporator to condenser is 16:1, which increases the radiation area. The composite wick structure consists of seven arteries and cylindrical wraps. The collector heat flux matches the design requirements of the thermionic converter.

Miskolczy, G.↗
NASA NTRS1979

Electron impact study of potassium hydroxide

An attempt is made to measure the sum of the elastic, rotational and vibrational scattering of electrons by KOH at low impact energies (5 to 20 eV) at angles from 10 to 120 deg. Energy loss spectra taken in the 0 to 18 eV range using an electron impact spectrometer are used to identify the species contributing to electric scattering. At temperatures between 300 and 500 C, only inelastic spectral features belonging to water are detected, while at temperatures from 500 to 800 C strong atomic K lines, indicative of molecular dissociation, and H2 energy loss features become prominent. No features attributable to KOH, the KOH dimer, O2 or potassium oxides were observed, due to the effects of the dissociation products, and it is concluded that another technique will have to be developed in order to measure electron scattering by KOH.

Vuskovic, L.↗
NASA NTRS1981

A meteor-ablation model of the sodium and potassium layers

Recent results on meteor ablation are used as input to a model in which ablation (or evaporation) is the source and deposition on dust particles is the sink. The dust comes from recondensation of the rest of the meteor vapor. An excellent match is found to the observed characteristics of the sodium layer. It is argued that the high-latitude winter maximum of abundance (and layer height) is due to the much lower rate of ionization there and over the polar cap. The computations show the required factor of 4-5 and also match the height variation. To keep the ion density from being too large, downward electrodynamic transport at about 50 cm/sec must be invoked. The different behavior and low abundance of potassium require an additional sink. The one proposed is Penning ionization by metastable excited O2. Inherent in the model is that sodium and its compounds reside almost entirely on dust particles below 80 km. Large abundances in the free form at stratospheric heights are very unlikely and are not a good explanation of observed ambient ions.

Hunten, D. M.↗
NASA NTRS1981

High-resolution extreme-ultraviolet spectroscopy of potassium using anti-Stokes radiation

The use of a new extreme-ultraviolet radiation source based on spontaneous anti-Stokes scattering for high-resolution absorption spectroscopy of transition originating from the 3p6 shell of potassium is reported. The region from 546.6 to 536.8 A is scanned at a resolution of about 1.2 Kayser. Within this region, four previously unreported lines are observed.

Rothenberg, J. E.↗
NASA NTRS1981

Water vapor resistance of plasma-polymerized coatings on potassium bromide windows

Plasma-polymerized tetrafluoroethylene (PPTFE) coated potassium bromide IR window are shown to possess better resistance to moisture than either ethylene or chlorotrifluoroethylene. The PPTFE-coated windows tolerated an upper limit relative humidity of about 80% at 297 K, without visible damage to either window or coating, over a period of 24 hours. Elemental analysis of the bulk, and photoelectron spectroscopy of the coating surface, showed that PPTFE coatings deposited downstream of the internal plasma reactor electrodes contained less atmospheric oxygen than coatings deposited between the electrodes; perhaps accounting for the improved moisture resistance.

Wydeven, T.↗
NASA NTRS1982

A flow-system comparison of the reactivities of calcium superoxide and potassium superoxide with carbon dioxide and water vapor

A single pass flow system was used to test the reactivity of calcium superoxide with respiratory gases and the performance was compared to that of potassium superoxide. The KO2 system is used by coal miners as a self-contained unit in rescue operations. Particular attention was given to the reactivity with carbon dioxide and water vapor at different temperatures and partial pressures of oxygen, carbon dioxide, and water vapor. The calcium superoxide beds were found to absorb CO2 and H2O vapor, releasing O2. The KO2 bed, however, released O2 at twice the rate of CO2 absorption at 37 C. It is concluded that the calcium superoxide material is not a suitable replacement for the KO2 bed, although Ca(O2)2 may be added to the KO2 bed to enhance the CO2 absorption.

Wood, P. C.↗
NASA NTRS1985

Very high potassium (VHK) basalt - Complications in mare basalt petrogenesis

The first comprehensive report on the petrology and geochemistry of Apollo 14 VHK (Very High Potassium) basalts and their implications for lunar evolution is presented. The reported data are most consistent with the hypothesis that VHK basalts formed through the partial assimilation of granite by a normal low-Ti, high-Al mare basalt magma. Assimilation was preceded by the diffusion-controlled exchange of alkalis and Ba between basalt magma and the low-temperature melt fraction of the granite. Hypotheses involving volatile/nonvolatile fractionations or long-term enrichment of the source regions in K are inconsistent with the suprachondritic Ba/La ratios and low initial Sr-87/Sr-86 ratios of VHK basalt. An important implication of this conclusion is that granite should be a significant component of the lunar crust at the Apollo 14 site.

Shervais, J. W.↗
NASA NTRS1986

Geochronology and petrogenesis of Apollo 14 very high potassium mare basalts

Rb-Sr, K-Ar, and Sm-Nd isotopic studies were undertaken for two Apollo 14 very high potassium (VHK) highly radiogenic mare basaltic clasts from breccias 14305 and 14168. Rb-Sr data indicate ages of 3.83 + or - 0.08 b.y., and 3.82 + or - 0.12 b.y. for samples 14305 and 14168 respectively, for lambda(Rb-87) = 0.0 139/b.y. Their corresponding initial Sr-87/Sr-86 ratios are nearly identical, as well as their Ar-39 to Ar-40 age spectra, and it is proposed that they were derived from the same flow. The Sm-Nd isotopic data of whole rock and mineral separates for the two VHK basalts define an internal isochrone age of 3.94 + or - 0.16 b.y. for lambda (Sm-147) = 0.00654/b.y. and an initial Nd-143/Nd-144 of 0.50673 + or - 21. The similarity in isotopic ages suggests that VHK basalts crystallized from a melt about 3.85 b.y. ago. VHK basalts show very large Rb/Sr fractionation but no significant Sm/Nd fractionation at the time of crystallization. The source material had a Rb/Sr ratio similar to those of Apollo 14 high-Al mare basalts and a nearly chrondritic Sm/Nd ratio. Basalt/granite interaction was found to be responsible for the extreme enrichments of Rb/Sr and K/La during the formation of VHK basalts. It is concluded that K, Rb-rich components of granitic wall rocks in the highland crust were selectively introduced into ascending hot high-Al mare basaltic magma upon contact.

Shih, C.-Y.↗
NASA NTRS1987

Ultraviolet quantum detection efficiency of potassium bromide as an opaque photocathode applied to microchannel plates

The quantum detection efficiency (QDE) of potassium bromide as a photocathode applied directly to the surface of a microchannel plate over the 250-1600 A wavelength range has been measured. The contributions of the photocathode material in the channels and on the interchannel web to the QDE have been determined. Two broad peaks in the QDE centered at about 450 and about 1050 A are apparent, the former with about 50 percent peak QDE and the latter with about 40 percent peak QDE. The photoelectric threshold is observed at about 1600 A, and there is a narrow QDE minimum at about 750 A which correlates with 2X the band gap energy for KBr. The angular variation of the QDE from 0 to 40 deg to the channnel axis has also been examined. The stability of Kbr with time is shown to be good with no significant degradation of QDE at wavelengths below 1216 A over a 15-day period in air.

Siegmund, Oswald H. W.↗
NASA NTRS1988

Importance of lunar granite and KREEP in very high potassium (VHK) basalt petrogenesis

Analysis of five very high potassium (VHK) basalts from Apollo 14 breccia 14303 shows the presence of a KREEP component. An assimilation and fractional crystallization model is presented to describe the basalt evolution. The influence of granite assimilation on the basalt evolution is discussed. The presence of VHK basalts containing only a granite signature and those with both granite and KREEP signatures suggests that there are at least two different VHK basalt flows at the Apollo 14 site.

Neal, Clive R.↗