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At least 361 records · Page 20

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NASA NTRS1986

Channel specific rate constants for reactions of O(1D) with HCl and HBr

The absolute rate coefficients and product yields for reactions of O(1D) with HCl(1) and HBr(2) at 287 K are presently determined by means of the time-resolved resonance fluorescence detection of O(3P) and H(2S) in conjunction with pulsed laser photolysis of O3/HX/He mixtures. Total rate coefficients for O(1D) removal are found to be, in units of 10 to the -10th cu cm/molecule per sec, k(1) = 1.50 + or - 0.18 and k(2) 1.48 + or - 0.16; the absolute accuracy of these rate coefficients is estimated to be + or - 20 percent.

Wine, P. H.↗

NASA NTRS1986

The microwave and far-infrared spectra of the O-(18)H radical

Far-infrared laser magnetic resonance (LMR) spectroscopy was used to calculate the frequencies, wavelengths, and line strengths for transitions of O-(18)H molecules at microwave and far-infrared frequencies. In this experiment, a molecular transition frequency is tuned into coincidence with that of a fixed frequency laser by the application of a variable magnetic field. The O-(18)H radicals, detected in natural abundance (0.20 percent), were produced by the reaction of hydrogen atoms with nitrogen dioxide. These data together with microwave frequencies ascertained by Gottlieb, Redford, and Smith (1974) were used to determine the parameters of an effective Hamiltonian. Rotational levels up to J = 5.5 were involved. Results are indicated schematically and the low-lying energy levels of O-(18)H are shown. It is concluded that the frequencies of transitions between levels studied directly in the LMR experiment are reliable.

Comben, E. R.↗

NASA NTRS1986

Rate constant for the reaction of O(3P) with diacetylene from 210 to 423 K

The absolute rate constant for the reaction of O(3P) with diacetylene (C4H2) has been measured as a function of pressure and temperature by the flash-photolysis/resonance-fluorescence method. At 298 K and below, no pressure dependence of the rate constant was observed, but at 423 K a moderate (factor-of-2) increase was detected in the range 3 to 75 torr Ar.Results at or near the high-pressure limit are represented by an Arrhenius expression over the temperature range 210 to 423 K. The results are compared with previous determinations, all of which employed the discharge-flow/mass-spectrometry technique. The mechanism of the reaction is considered, including both primary and secondary processes. The heats of formation of the reactants, adducts, and products for the O(3P) + C4H2 reaction are discussed and contrasted with those for O(3P) + C2H2.

Mitchell, M. B.↗

NASA NTRS1986

Preferential O(+) heating in the topside ionosphere

Observations of preferential heating of the ionospheric majority ion species O(+), are reported. The heating took the form of a hot (few electron volts) tail in the upgoing thermal O(+). No such hot tail was observed in the light ion distributions. An event observed at 700-800 km altitude was highly anisotropic with a much hotter tail transverse to the local magnetic field. A series of events observed at 250-375 km were more nearly isotropic with respect to the local magnetic field. Broadband plasma wave emission near the lower hybrid resonance was observed in conjunction with the high altitude event. The low altitude events were tightly correlated with auroral electron precipitation, but broadband lower hybrid emission was much reduced. The observed hot tail formation is sufficient to produce significant O(+) ion transport to higher altitude auroral acceleration regions.

Moore, T. E.↗

NASA NTRS1986

Thermospheric production of O(1S) by dissociative recombination of vibrationally excited O2(+)

High spectral resolution line profiles at 5577 A of the nighttime, F-region O(1S) emission measured by the Fabry-Perot interferometer on board the Dynamics Explorer satellite are analyzed using a continuous O(1S) relaxation model. The model is an improvement over the previous model of Killeen and Hays (1981) in that energy loss via elastic collision is considered in addition to the single collision, excitation exchange thermalization process. The results show that the active channel for O(1S) production is capture into the 1Sigma(+)u repulsive state of O2 and that the main contributor to its production is the dissociative recombination of O2(+) ions in vibrational levels v = 1 and 2 in agreement with the quantal calculations of Guberman (1983).

Yee, Jeng-Hwa↗

NASA NTRS1987

O 7774 A diagnostic for quiescent prominences

Results are reported from photometric observations and statistical analyses of the O 7774 A (3/5/P yields 3/5/S) transition in quiescent solar prominences. The goal of the study was to derive accurate values for the ratio between the population density of the upper level of the observed transition relative to the total O population. The data were collected with the 25 cm coronagraph/3 m spectrograph at the Mees Solar Observatory. A strong temperature dependence was found for the transition, indicating that the O 7774 A/Na 5890 A ratio is of use for diagnostic studies of quiescent prominences. The possibility of applying the ratio as a diagnostic for spicules is discussed.

Brickhouse, Nancy S.↗

NASA NTRS1987

Molecular gas within 2 deg of the Galactic center. I - Survey of (C-13)O emission

The emission from the Galactic center at 2.72 mm from (C-13)O has been surveyed, and the results are reported. Data from 488 spectra taken in the region of l between -2.0 deg and +2.0 deg and b between -0.467 deg and +0.467 deg, and with a spectral resolution of 2.7 km/s over the V(LSR) range of -300 km/s to +300 km/s, are presented in eight l-v diagrams and in 123 maps in the plane of the sky. An averaged l-v diagram shows that virtually all of the (C-13)O emission falls within a roughly symmetrical parallelogram in l-v space; the center of symmetry is near l = +0.25 deg, V(LSR) = +30 km/s. A map of the integrated (C-13)O is presented which is very similar to maps of the far-IR continuum in which Sgr A, B2, C, and D are prominent. Maps of the emission at absolute value of V(LSR) above 100 km/s show that most of the high-velocity gas is tilted out of the Galactic plane by 7 deg; the nuclear disk appears to be inclined to the line of sight by about 85 deg.

Heiligman, Gary M.↗

NASA NTRS1988

An O(N squared) method for computing the eigensystem of N by N symmetric tridiagonal matrices by the divide and conquer approach

An efficient method is proposed to solve the eigenproblem of N by N Symmetric Tridiagonal (ST) matrices. Unlike the standard eigensolvers which necessitate O(N cubed) operations to compute the eigenvectors of such ST matrices, the proposed method computes both the eigenvalues and eigenvectors with only O(N squared) operations. The method is based on serial implementation of the recently introduced Divide and Conquer (DC) algorithm. It exploits the fact that by O(N squared) of DC operations, one can compute the eigenvalues of N by N ST matrix and a finite number of pairs of successive rows of its eigenvector matrix. The rest of the eigenvectors--all of them or one at a time--are computed by linear three-term recurrence relations. Numerical examples are presented which demonstrate the superiority of the proposed method by saving an order of magnitude in execution time at the expense of sacrificing a few orders of accuracy.

Gill, Doron↗

NASA NTRS1987

Spatial distribution of O(supra 1D) from Comet Halley

Images of Comet Halley in (OI)6300A emission obtained using a 150 mm Fabry-Perot spectrometer in the imaging mode were combined with spectra taken in the scanning mode to deduce the distribution of cometary O(1D) within a 10 arc min field of view centered on the comet head. The 10 km/sec bandpass of the system allows the distribution to be measured with little contamination from airglow O(1D) and cometary NH2 lines in the nearby spectrum. The results are modeled to provide photodestruction scale lengths for cometary H2O and OH, the predominant parents of O(1D). Results are compared with other experimental and theoretical results.

Roesler, F. L.↗

NASA NTRS1988

Temporal and spatial relationships between O V and Fe XXI emissions in solar flares

The temporal-spatial structure of simple solar flares observed with the Ultraviolet Spectrometer and Polarimeter of the Solar Maximum mission satellite has been studied in order to investigate the relationships between the impulsive O V and the gradual Fe XXI emissions. The point-like flares are characterized by the cotemporal evolution of the O V and Fe XXI emissions. The simple loop flares have a much larger spatial extent and show two distinctive phases: an initial impulsive phase with its emission localized in loop footpoints, and a gradual phase with its emission distributed in the loop. The temporal evolution of the Fe XXI and O V emissions in a flare is found to be closely related to its spatial structure.

Cheng, Chung-Chieh↗

NASA NTRS1988

Indirect IUE observation of O VI from photoexcited fluorescence lines of Fe II, present in the spectrum of RR Telescopii

A new, highly excited level of Fe II at 13.7 eV has been established by means of six lines in the laboratory spectrum below 2000 A. Confirming transitions appear in the infrared region. Four of the ultraviolet lines coincide with previously unidentified lines in the IUE spectrum of RR Tel reported by Penston et al. in 1983. One of the remaining UV lines coincides with the resonance line of O VI at 1032 A, outside the range of the IUE. This suggests that the new FE II level is selectively photoexcited by O VI in RR Tel, resulting in the strong fluorescence lines observed. This case of a Bowen mechanism provides an indirect observation of O VI, important for diagnostics of, e.g., symbiotic stars.

Johansson, Sveneric↗

NASA NTRS1988

Observations of the 63 micron forbidden O I line in Herbig-Haro objects

The paper presents observations of the 63 micron forbidden O I line from Herbig-Haro objects and their exciting stars. Forbidden O I 63 micron emission is detected toward the HH-exciting stars T Tau, DG Tau, L1551 IRS 5, and toward the HH objects HH 7-11, HH 42A, and HH 43 which are displaced from their exciting stars. The forbidden O I emission is associated with these flows on the basis of its spatial coincidence and its negative radial velocities. If the exciting stars drive bipolar flows in which the 63 micron emission follows that at 6300 A, the absence of redshifted 63 micron lines from the three exciting stars might indicate that the disks hypothesized to overlie the receding lobes of these flows are still optically thick in the far-infrared.

Cohen, Martin↗

NASA NTRS1988

High temperature transport properties of air - N-O interaction energies and collision integrals

Potential curves for the higher-lying states of NO are used together with a general scattering code to compute accurate values of transport collision integrals for N(4S/0/)-O(3P) interactions. It is found that the major contribution to the collision integrals comes from these higher-lying states of NO. New values of the collision integrals for N(4S/0/)-N(4S/0/) and O(3P)-O(3P) interactions are computed as well. The tabulations of the collision integrals cover a broad range of temperatures from 250 to 100,000 K and can be used to determine transport properties such as viscosity, thermal conductivity, and the diffusion coefficient to the second order.

Levin, E.↗

NASA NTRS1988

O(+) and H(+) escape fluxes from the polar regions

The hydrodynamic transport equations are solved for H(+) and O(+) with allowance made for the important dynamic, collisional, and chemical effects that operate in the F region ionosphere below regions of ion acceleration. It is found that the total ion flux demand imposed on the ionosphere by the higher altitude acceleration region is an important parameter controlling the amount of O(+) in plasma outflows. As solar activity increases, there is an increase in the limiting O(+) escape flux and a decrease in the limiting H(+) escape flux.

Barakat, A. R.↗

NASA NTRS1988

Spatial distribution of O(1D) from Comet Halley

Images of comet Halley in forbidden OI 6300-A emission obtained using a 150 mm Fabry-Perot spectrometer in the imaging mode were combined with spectra taken in the scanning mode to deduce the distribution of cometary O(1D) within a 10-arcmin field of view centered on the comet head. The 10-km/sec bandpass of the system allows the distribution to be measured with little contamination from airglow O(1D) and cometary NH2 lines in the nearby spectrum. The results are modeled to provide photodestruction scale lengths for cometary H2O and OH, the predominant parents of O(1D). Results are compared with other experimental and theoretical results.

Magee-Sauer, K.↗

NASA NTRS1989

Atomic data for opacity calculations. X - Oscillator strengths and photoionisation cross sections for O III

Energy levels and electric dipole radiative transitions were determined for O III. The wavefunctions for the bound and continuum states were derived by solving coupled integrodifferential equations in the close-coupling approximation with the aid of two methods, the R-matrix and linear algebraic methods. Configuration interaction wavefunctions are presented for eight states of the O IV target with configurations of 2s(x)sp(y) (x + y = 3). Oscillator strengths are calculated for the transitions between, and photoionization cross sections from, bound states of O III with configurations of 2s(x)2p(y)nl (for n of not greater than 10 and l of not greater than 3).

Luo, D.↗

NASA NTRS1990

Measuring Gaps In O-Ring Seals

Technique enables measurement of leakage areas created by small obstructions in O-ring seals. With simple fixture, gaps measured directly. Compresses piece of O-ring by amount determined by spacers. Camera aimed through clear plastic top plate records depression made in O-ring by obstruction. Faster, easier, more accurate than conventional estimation.

Johnson, Scott E.↗

NASA NTRS1991

O-Ring-Testing Fixture

Fixture tests O-rings for sealing ability under dynamic conditions after extended periods of compression. Hydraulic cylinder moves plug in housing. Taper of 15 degrees on plug and cavity of housing ensures that gap created between O-ring under test and wall of cavity. Secondary O-rings above and below test ring maintain pressure applied to test ring. Evaluates effects of variety of parameters, including temperature, pressure, rate of pressurization, rate and magnitude of radial gap movement, and pretest compression time.

Turner, James E.↗