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At least 361 records · Page 20

Determining Individual Phase Flow Properties in a Quench and Partitioning Steel with In Situ High-Energy X-Ray Diffraction and Multiphase Elasto-Plastic Self-Consistent Method

The micromechanical properties of the constituent phases were characterized for an advanced high strength steels (AHSS) produced by a quenching and partitioning (Q&P) process with in-situ tensile loading under Synchrotron-based high energy X-ray diffraction. The constituent phases present are retained austenite and three martensites (tempered, untempered and freshly formed martensites). For the material investigated, the 200 and 220 lattice strains of the retained austenite phase were calculated by examining the changes of the X-ray diffraction peak positions during deformation. The 200 and 211 lattice strains of the various martensitic phases with similar crystal structures were determined by separating their overlapped diffraction peaks. Apart from tempered and untempered martensite, the diffraction peaks of freshly formed martensite as a result of austenite to martensite transformation can also be able separated due to high initial austenite volume fraction. The phase stresses are first estimated with an empirical relationship through the X-ray diffraction elastic constants (XREC). A multi-phase elasto-plastic self constant model (EPSC) is next used for more accurate determination of the constitutive behaviors of the various phases by comparing the predicted lattice strain distributions and global stress-strain curves with the measured ones. The determined constitutive laws will be used for microstructure-based modeling for sheet formability of the Q&P AHSS steel.

Hu, Xiaohua↗

Microstructure and Mechanical Properties of a Multiphase FeCrCuMnNi High-Entropy Alloy

A FeCrCuMnNi high-entropy alloy was produced using vacuum induction melting, starting from high-purity raw materials. The microstructure and mechanical properties of the as-cast FeCrCuMnNi alloy were studied, considering x-ray diffraction (XRD), scanning electron microscopy, and hardness and tensile tests. XRD results revealed the existence of two FCC phases and one BCC phase. Microstructural evaluation illustrated that the as-cast alloy has a typical cast dendritic structure, where dendrite regions (BCC) were enriched in Cr and Fe. Interdendritic regions were saturated with Cu and Ni and revealed G/B(T) {110} 〈111〉 and Brass {110} 〈112〉 as the major texture components. The produced alloy revealed an excellent compromise in mechanical properties due to the mixture of solid solution phases with different structures: 300 HV hardness, 950 MPa ultimate tensile strength and 14% elongation. Microhardness test results also revealed that the BCC phase was the hardest phase. The fracture surface evidenced a typical ductile failure. Furthermore, heat treatment results revealed that phase composition remained stable after annealing up to 650 °C. Phase transformation occurred at higher temperatures in order to form more stable phases; therefore, FCC2 phase grew at the expense of the BCC phase.

36 MATERIALS SCIENCE↗

Multiphase computational fluid dynamics modeling of reacting flows in absorption columns for carbon capture

First-principles derived computational fluid dynamics (CFD) simulations have been proposed as a fundamental tool for investigating solvent-based CO 2 absorption in packed columns due to their ability to accurately represent the underlying nonlinear, multiscale dynamics. Numerous studies have previously utilized such CFD simulations to investigate hydrodynamics of columns with structured and random packings by assessing the key hydrodynamic metrics such as the interfacial and wetted areas. While mapping such metrics for different conditions is essential to the optimization of absorption columns, it is not sufficient, as the CO 2 capture rate depends also on the coupled, nonlinear dynamics from the underlying chemical reaction kinetics, thermodynamics, and heat-transfer rates. In this work, we present detailed CFD simulation results augmented by incorporating the effects of interfacial physical mass transfer of CO 2 , heat release from chemical reaction kinetics, and thermophysical property variations from resulting temperature gradients. We demonstrate the applicability of the proposed approach in numerically assessing the performance of packed columns by evaluating key hydrodynamic quantities, CO 2 absorption rates, and temperature rise in a reference column with packings that are structurally similar to the Sulzer Mellapak™ 250.Y packing, for different solvent inflow velocities and temperatures. Predictions from simulation results are found to be consistent with the trends in experimental observations from the literature, suggesting that the predictive capabilities of the simulation framework can be leveraged to guide the future development of absorber-column designs and optimized process flowsheets.

Absorption columns↗

Feasibility of X-ray scattering for tracer-free liquid-phase thermometry for multiphase flows

The feasibility of liquid temperature measurements using X-ray scattering is investigated for liquids with varying properties (water, ethanol, and n-dodecane) on beamline 7-BM at the Advanced Photon Source at Argonne National Laboratory. The temperature is inferred through the change in the scattering pattern from the liquid as a function of temperature using partial least squares regression. An accuracy of ~98% or higher was achieved enabling measurements for a wide range of applications.

42 ENGINEERING↗