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At least 361 records · Page 20

Nonequilibrium boundary layer at a stagnation point for a hydrogen-helium stream over ablating graphite

The nonequilibrium axisymmetric stagnation point boundary layer over an ablating graphite surface is considered. The external stream is a high temperature mixture of hydrogen and helium. Variable thermodynamic and transport properties are assumed. Lennard-Jones potential model is used to calculate the transport coefficients of each species. Although the mixture rules for viscosity of the gas mixture are used, the weighting functions are more sophisticated than those commonly employed. For the conductivity of the mixture, generalized Wassiljewa coefficients are used. Seven species with 28 dissociation/recombination reactions are considered. Hansen's model for the dissociation rate constants is employed. The recombination rate constants are obtained by invoking detailed balance principles assisted by the JANAF thermodynamic data and the Hansen-Pearson thermodynamic data for C3.

Liu, T.-M.↗

Hazards Induced by Breach of Liquid Rocket Fuel Tanks: Conditions and Risks of Cryogenic Liquid Hydrogen-Oxygen Mixture Explosions

We analyze the data of purposeful rupture experiments with LOx and LH2 tanks, the Hydrogen-Oxygen Vertical Impact (HOVI) tests that were performed to clarify the ignition mechanisms, the explosive power of cryogenic H2/Ox mixtures under different conditions, and to elucidate the puzzling source of the initial formation of flames near the intertank section during the Challenger disaster. We carry out a physics-based analysis of general explosions scenarios for cryogenic gaseous H2/Ox mixtures and determine their realizability conditions, using the well-established simplified models from the detonation and deflagration theory. We study the features of aerosol H2/Ox mixture combustion and show, in particular, that aerosols intensify the deflagration flames and can induce detonation for any ignition mechanism. We propose a cavitation-induced mechanism of self-ignition of cryogenic H2/Ox mixtures that may be realized when gaseous H2 and Ox flows are mixed with a liquid Ox turbulent stream, as occurred in all HOVI tests. We present an overview of the HOVI tests to make conclusion on the risk of strong explosions in possible liquid rocket incidents and provide a semi-quantitative interpretation of the HOVI data based on aerosol combustion. We uncover the most dangerous situations and discuss the foreseeable risks which can arise in space missions and lead to tragic outcomes. Our analysis relates to only unconfined mixtures that are likely to arise as a result of liquid propellant space vehicle incidents.

Osipov, Viatcheslav↗

Infrared Emission from Comets

A brief discussion of the infrared observations from 4 to 20 micrometers of seven comets is presented. The observed infrared emission from comets depends primarily on their heliocentric distance. A model based on grain populations composed of a mixture of silicate and amorphous carbon particles in the mass ratio of about 40 to 1, with a power-law size distribution similar to that inferred for comet Halley, is applied to the observations. The model provides a good match to the observed heliocentric variation of both the 10 micrometers feature and the overall thermal emission from comets West and Halley. Matches to the observations of comet IRAS-Araki-Alcock and the antitail of comet Kohoutek require slightly larger grains. While the model does not match the exact profile and position of the 3.4 micrometers feature discovered in comet Halley, it does produce a qualitative fit to the observed variation of the feature's strength as a function of heliocentric distance. The calculations predict that the continuum under the 3.4 micrometers feature is due primarily to thermal emission from the comet dust when the comet is close to the Sun and to scattered solar radiation at large heliocentric distances, as is observed. A brief discussion of the determination of cometary grain temperatures from the observed infrared emission is presented. It is found that the observed shape of the emission curve from about 4 to 8 micrometers provides the best spectral region for estimating the cometary grain temperature distribution.

Swamy, K. S. Krishna↗

Strain-Rate-Free Diffusion Flames: Initiation, Properties, and Quenching

For about a half century, the stabilization of a steady planar deflagration on a heat-sink-type flat-flame burner has been of extraordinary service for the theoretical modeling and diagnostic probing of combusting gaseous mixtures. However, most engineering devices and most unwanted fire involve the burning of initially unmixed reactants. The most vigorous burning of initially separated gaseous fuel and oxidizer is the diffusion flame. In this useful idealization (limiting case), the reactants are converted to product at a mathematically thin interface, so no interpenetration of fuel and oxidizer occurs. This limit is of practical importance because it often characterizes the condition of optimal performance (and sometimes environmentally objectionable operation) of a combustor. A steady planar diffusion flame is most closely approached in the laboratory in the counterflow apparatus. The utility of this simple-strain-rate flow for the modeling and probing of diffusion flames was noted by Pandya and Weinberg 35 years ago, though only in the last decade or so has its use become internationally common place. However, typically, as the strain rate a is reduced below about 20 cm(exp -1), and the diffusion-flame limit (reaction rate much faster than the flow rate) is approached, the burning is observed to become unstable in earth gravity. The advantageous steady planar flow is not available in the diffusion-flame limit in earth gravity. This is unfortunate because the typical spatial scale in a counterflow is (k/a)(sup 1/2), where k denotes a characteristic diffusion coefficient; thus, the length scale becomes large, and the reacting flow is particularly amenable to diagnostic probing, as the diffusion-flame limit is approached. The disruption of planar symmetry is owing the fact that, as the strain rate a decreases, the residence time (l/a) of the throughput in the counterflow burner increases. Observationally, when the residence time exceeds about 50 msec, the inevitably present convective (Rayleigh-Benard) instabilities, associated with hot-under-cold (flame-under-fresh-reactant) stratification of fluid in a gravitational field, have time to grow to finite amplitude during transit of the burner.

Fendell, Francis↗

Mixing levels, the Apennine Front soil component, and compositional trends in the Apollo 15 soils

New compositional data (by INAA) for 29 samples of Apollo 15 soil fractions are presented along with data for six depth intervals of the bottom half of the double drive tube at station 2 on the Apennine Front. The compositional trends in the Apollo 15 soils are discussed in terms of four techniques used to determine the important components of the regolith: graphical techniques, factor analysis, chemical analysis of individual soil particles, and mixing models. The concept of 'mixing levels' is introduced, which states that a sample of lunar regolith can be considered as a mixture on several different compositional levels (I, igneous rock types; II, local rock types; III, soils), and it is shown that most attempts at modeling lunar soils as mixtures have been directed at level II. It is argued that only four components are required to account for the variation in concentrations of lithophile elements in the Apollo 15 samples: mare basalt, KREEP basalt, green glass, and Apennine front soil (best represented by the station 2 samples).

Korotev, Randy L.↗

Simplified Structure Models for Premixed n-Alkane Cool Flames

The chemical kinetics of cool flames in mixtures of normal alkanes, oxygen, and nitrogen recently have been reduced to obtain simplified asymptotic flame-structure models that can be used to compare theoretical predictions with experimental measurements. A key step that affects flame structures strongly, namely the abstraction of a hydrogen atom from the alkyl radical by an oxygen molecule, had not been taken into account in those models. This deficiency has now been remedied for diffusion flames. The present contribution reports the corresponding remedy for premixed-flame analyses. In the new model, non-zero chemical reaction rates are restricted to narrow regions in the vicinity of the maximum temperature, whereas previously they extended throughout the preheat zone. Comparisons of the new predictions with experimental burning-velocity measurements seem favorable.

premixed cool flames↗

Theoretical models for Mars and their seismic properties

Theoretical seismic properties of the planet Mars are investigated on the basis of the various models which have been proposed for the internal composition of the planet. The latest interpretation of gravity-field data, assuming a lower value of the moment of inertia, would require a less dense mantle and a larger core than previous models. If Mars is chondritic in composition, the most reasonable models are an incompletely differentiated H-chondrite or a mixture of H-chondrites and carbonaceous chondrites. Seismic profiles, travel times, and free oscillation periods are computed for various models, with the aim of establishing which seismic data is crucial for deciding among the alternatives. A detailed discussion is given of the seismic properties which could - in principle - help answer the questions of whether Mars' core is liquid or solid and whether Mars has a partially molten asthenosphere in its upper mantle.

Okal, E. A.↗

A Holistic DSMC Transport Database for Re-Entry and Ablation Modeling

Hybrid simulation frameworks combining Computational Fluid Dynamics (CFD) and Direct Simulation Monte Carlo (DSMC) are frequently employed to efficiently perform high-fidelity solutions of environments containing combined continuum/rarified flow. The use of DSMC, a stochastic, particle-based method, is necessary for high-Knudsen flow where continuum-based assumptions governing CFD break down. However, the DSMC methodology is generally very computationally inefficient to model the continuum regime. In a CFD/DSMC hybrid approach, obtaining an accurate, high-fidelity solution hinges on the consistent treatment of transport properties and the used thermo-chemical models employed within the two solvers. In principle, in regions where CFD and DSMC are both employed, the same gas mixture under the same conditions should have the same properties, regardless of simulation type. Observed differences should be due to non-equilibrium processes, rather than differences in physical models. While the transport models governing CFD and DSMC simulations are starkly different, they can effectively be linked via their use of reduced Chapman-Enskog collision integrals. In CFD, these integrals are typically stored as fitted polynomial expressions and used to directly compute gas transport properties via mixing rules or the full Chapman-Enskog formulation. In DSMC, they can be used to derive the collision parameters needed for the phenomenological collision cross-section models that govern particle interactions, via a Nelder-Mead optimization scheme. The goal of this work is to provide a unified DSMC transport database encompassing the vast majority of known gas species encountered during atmospheric entry, on Earth or any other Solar body. This goal is largely possible due to recently performed ab-initio quantum chemistry calculations. Combined with other high-fidelity literature sources, the planned database will consist of collision integral data for over 200 neutral and ionized species and over 17000 binary collisions. From these collision integrals, Nelder-Mead optimization is used to compute Variable Soft Sphere (VSS) collision model parameters for DSMC, fitted from 300 K to 20000 K. Initial comparisons of transport properties of relevant equilibrium gas mixtures show great agreement between CFD and DSMC-derived results. The completed database will be able to be readily applied to model binary collisions of any gas mixture containing the included species over the specified temperature range, making it a valuable tool for future planetary probe modeling efforts. An example is shown below. Equilibrium mixture transport properties for a 19-species Titan atmospheric model [4] are computed using both fitted VSS parameters and the original CFD collision integral values. Deviations in computed properties between the two approaches is less than 5% for the entire temperature range.

M R Gosma↗

A semiempirical method for analysis of the reflectance spectra of binary mineral mixtures

A simple semiempirical method is presented for determination of the spectral reflectance of a powdered binary mineral mixture. This technique uses a two-stream radiative transfer model (a modified Kubelka-Munk model) on a particulate medium of isotroic scatterers The particles are assumed to be much larger than the wavelength of light under consideration. This same method can be used to determine the relative proportion of components in a mixture for which the spectral reflectance is known. Binary mixtures of olivine, two pyroxenes, and magnetite are used to test this model. The theoretical and empirical results agree approximately within experimental errors.

Johnson, P. E.↗

Freezable Radiator Model Correlation and Full Scale Design

Freezable radiators offer an attractive solution to the issue of thermal control system scalability. As thermal environments change, a freezable radiator will effectively scale the total heat rejection it is capable of as a function of the thermal environment and flow rate through the radiator. Scalable thermal control systems are a critical technology for spacecraft that will endure missions with widely varying thermal requirements. These changing requirements are a result of the space craft s surroundings and because of different thermal loads during different mission phases. However, freezing and thawing (recovering) a radiator is a process that has historically proven very difficult to predict through modeling, resulting in highly inaccurate predictions of recovery time. This paper summarizes efforts made to correlate a Thermal Desktop (TM) model with empirical testing data from two test articles. A 50-50 mixture of DowFrost HD and water is used as the working fluid. Efforts to scale this model to a full scale design, as well as efforts to characterize various thermal control fluids at low temperatures are also discussed.

Lillibridge, Sean T.↗

RL10A-3-3B high mixture ratio qualification program

The results of the high mixture ratio qualification testing of the RL10 engine for the Shuttle/Centaur program are presented. The objective of the engine qualification test was to demonstrate the suitability of the RL10A-3-3B engine for space vehicle flight by subjecting it to the testing specified in RL10A-3-3B Model Specification Number 2295 dated February 1986. The applicable section of the specification is presented. Due to payload volume advantages which can be achieved by increasing the operating mixture ratio of the RL10, a decision was made to qualify the engine to run at a higher mixture ratio. A program was created to qualify the RL10 engine for operation at 15,000 pounds thrust and a nominal 6.0 to 1 mixture ratio. This model of the engine was designated the RL10A-3-3B. The qualification program included three test series as follows: (1) hardware durability and limits test in which the engine completed 23 firings and 4605.7 seconds with 1588.7 seconds at less than 6.6 mixture ratio; (2) preliminary qualification test in which the engine completed 26 firings and 5750 seconds; and (3) qualification test in which the engine completed 26 hot firings and 5693.4 seconds with 905.9 seconds at 6.7 mixture ratio. Several changes in engine hardware were required for operation of the RL10A-3-3B engine in the Space Shuttle which include a duel pressure switch ignition, an oxidizer flow control, and helium plumbing changes.

Vogel, T.↗

Constraints on astronomical silicate dust

Numerical radiative-transfer models are used to discuss the properties of circumstellar dust grains around the premain-sequence star AB Aur (HD 31293). It is assumed that the dust consists of a silicate-graphite mixture with Draine and Lee (1984) optical properties. The modeling technique is to match the observed FUV through FIR energy distribution with the spectral energy distribution predicted for a spherical dust shell around a luminous hot star. Special attention is given to matching the observed 10-micron silicate emission feature and the observed circumstellar absorption curve at UV wavelengths, making it possible to strengthen constraints on dust-grain opacity and chemical composition. It is concluded that, although silicate grains can explain the observed 10-micron emission feature, the Draine and Lee silicate-graphite mixture cannot explain the observed FUV circumstellar absorption at the same time. The dust shell around AB Aur contains an additional population of small particles, the most likely candidate being amorphous carbon grains in a nonhydrogenated form.

Sorrell, Wilfred H.↗

Combustion effects on film cooling

The effects of: (1) a reactive environment on film cooling effectiveness, and (2) film cooling on rocket engine performance were determined experimentally in a rocket thrust chamber assembly operating with hydrogen and oxygen propellants at 300 psi chamber pressure. Tests were conducted using hydrogen, helium, and nitrogen film coolants in an instrumented, thin walled, steel thrust chamber. The film cooling, performance loss, and heat transfer coefficient data were correlated with the ALRC entrainment film cooling model which relates film coolant effectiveness and mixture ratio at the wall to the amount of mainstream gases entrained with the film coolant in a mixing layer. In addition, a comprehensive thermal analysis computer program, HOCOOL, was prepared from previously existing ALRC computer programs and analytical techniques.

Rousar, D. C.↗

Effect of fuel nitrogen and hydrogen content on emissions in hydrocarbon combustion

How the emissions of nitrogen oxides and carbon monoxide are affected by: (1) the decreased hydrogen content and (2) the increased organic nitrogen content of coal derived fuels is investigated. Previous CRT experimental work in a two stage flame tube has shown the effectiveness of rich lean two stage combustion in reducing fuel nitrogen conversion to nitrogen oxides. Previous theoretical work gave preliminary indications that emissions trends from the flame tube experiment could be predicted by a two stage, well stirred reactor combustor model using a detailed chemical mechanism for propane oxidation and nitrogen oxide formation. Additional computations are reported and comparisons with experimental results for two additional fuels and a wide range of operating conditions are given. Fuels used in the modeling are pure propane, a propane toluene mixture and pure toluene. These give hydrogen contents 18, 11 and 9 percent by weight, respectively. Fuel bound nitrogen contents of 0.5 and 1.0 percent were used. Results are presented for oxides of nitrogen and also carbon monoxide concentrations as a function of primary equivalence ratio, hydrogen content and fuel bound nitrogen content.

Bittker, D. A.↗

Statistical mechanics of dilute liquid mixtures of He3 in He4

The Woo-Tan-Massey quantum-mechanical theory of dilute mixtures of He-3 in liquid He-4 is extended to incorporate superfluid flow. Then statistical-mechanical principles are employed to find explicit formulas for thermodyanmic and hydrodynamic properties of mixtures, such as internal energy, free energy, entropy, pressure, chemical potential, and normal-fluid and superfluid densities. This paper is the first in a planned series that applies methods originally developed for pure liquid He-4 to dilute mixtures as a means of establishing a comprehensive theory that includes a theoretical bridge between a microscopic description of the mixtures and a hydrodynamic two-fluid model. Ultimately effects of applied electric and magnetic fields on dilute solutions are also planned to be treated.

Jackson, H. W.↗

Geochemical studies of feldspathic fragmental breccias and the nature of North Ray Crater ejecta

Wide variations in clast assemblages and bulk compositions are found in the matrix and clasts from feldspathic fragmental breccias by means of major and trace element analyses. The major components are found to be anorthosites, ferroan anorthositic norites, magnesian granulites, feldspathic melt rocks, and very high alumina impact melts. The compositional characteristics of bulk breccias and feldspathic melt rocks are quantitatively modeled as two- to five-component mixtures. Breccia 67455 is unique in consisting entirely of ferroan, KREEP-free components.

Lindstrom, M. M.↗

Microwave radiances from precipitating clouds containing aspherical ice, combined phase, and liquid hydrometeors

A numerical algorithm based on Eddington's second approximation to the equation of radiative transfer has been developed in order to compute the radiances with horizontal and vertical polarization that emerge from precipitating clouds. This algorithm yields a rapid solution to problems pertaining to clouds with vertically inhomogeneous structure. Precipitating clouds containing liquid, mixtures of phases, and ice hydrometeors are modelled. It is shown that the lower-frequency radiances are sensitive to liquid precipitation at low altitudes while the higher-frequency radiances are more sensitive to the ice hydrometeors at the cloud tops. The extinction coefficients of aspherical hydrometeors are presented as a function of rainfall rates. The fact that vertically polarized radiances are warmer than horizontally polarized ones at high rainfall rates, with the difference diminishing at lower frequencies, is due to aspherical ice hydrometeors in the upper regions of precipitating clouds.

Wu, R.↗