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At least 361 records · Page 20

Evidence for Extrusive Mg-Suite Magmatism on the Moon? Fine-Grained Magnesian Clasts in an Apollo 16 Impact Melt Breccia

The magnesian suite (Mg-suite) of rocks record some of the earliest intrusive magmatism on the Moon. Studies of these Mg-suite rocks find they are plutonic or hypabyssal, formed typically kilometers under the lunar surface. Several models exist to explain the formation and evolution of the Mg-suite but distinguishing between hypotheses can be difficult given the limited sample availability. The global extent of Mg-suite magmatism remains in debate and is key to constraining models of early secondary crust building. In this study, we present magnesian clasts within Apollo impact melt rock 68815. These clasts contain olivine, plagioclase, with minor amounts of Mg-Al-spinel and pyroxene similar to spinel troctolites of the Mg-suite, but they lack plutonic textures. We provide evidence that some of the clasts may be of extrusive volcanic origin akin to terrestrial komatiites while others might represent crystalline impact melts. There exists a large breadth of evidence for Mg-suite intrusives, whereas here, we present possible evidence of Mg-rich volcanic counterparts. If valid, this would broaden the known diversity of lunar volcanism during the initial stages of secondary crust building. We anticipate this finding to provide a greater constraint onto models of Mg-suite ascent and emplacement, which only currently consider intrusive magmatism, as well as renewed motivation to examine impact melt breccias for rare and understudied lithologies. Future trace element studies or radiometric dating could be used to further interrogate the connections of these clasts to the Mg-suite.

Moon↗

Application of Energy-efficient Electromagnetic Melt-Processing for the Upcycling of Recycled Polyphenylene Sulfide into Multifunctional Segregated Nanocomposites

Polyphenylene sulfide (PPS) is widely used in structural and functional composites because of its thermal stability, chemical resistance, and mechanical strength. As circular manufacturing becomes increasingly important, extending the service life of recycled PPS (rPPS) is essential. However, conventional high-temperature reprocessing accelerates thermo-oxidative degradation, reducing recycled composite performance. This study proposes a rapid and potentially energy-saving upcycling strategy for rPPS using electromagnetic (EM) melt-processing to form segregated carbon nanotube (CNT) networks and produce EM-responsive nanocomposites. The aim was to determine whether CNT-assisted EM heating could reduce polymer degradation while improving multifunctional properties at ultralow filler loadings. rPPS micropellets were coated with CNTs by ball milling to create conductive shells, then compacted into green bodies (GBs) and selectively melted by rapid EM irradiation. Structural, electrical, mechanical, rheological, and electromagnetic interference (EMI) shielding properties were evaluated. Electrical percolation occurred at an ultralow CNT loading of 0.08 wt%, with conductivity reaching (1.24 ± 0.74) × 10 -5 S⋅m -1 at 0.1 wt%. At this concentration, tensile strength and modulus increased by 72% and 99%, respectively. At ~ 0.7 mm thickness, X-band EMI shielding effectiveness reached 6 dB for GBs and 3 dB after EM processing. This shows that EM melt-processing upcycles rPPS into high-performance multifunctional nanocomposites with minimum thermal degradation.

recycled↗

Determination of work functions near melting points of refractory metals by using a direct-current arc

Effective work functions of refractory metals at temperatures near their melting points were determined by using a direct-current arc. A metal wire connected as the cathode was melted by striking an arc discharge in an argon atmosphere. A melted sphere was formed with a definite emitting area which was calculated from the sphere diameter measured after terminating the arc. Effective work functions were calculated from the Richardson-Dushman equation by using this emission area. The procedure is experimentally advantageous because surface cleanliness of the specimen is not critical, high vacuum is not required, and the anode-cathode spacing is not critical.

Gordon, W. A.↗

Shock melting and vaporization of lunar rocks and minerals.

The entropy associated with the thermodynamic states produced by hypervelocity meteoroid impacts at various velocities are calculated for a series of lunar rocks and minerals and compared with the entropy values required for melting and vaporization. Taking into account shock-induced phase changes in the silicates, we calculate that iron meteorites impacting at speeds varying from 4 to 6 km/sec will produce shock melting in quartz, plagioclase, olivine, and pyroxene. Although calculated with less certainty, impact speeds required for incipient vaporization vary from 7 to 11 km/sec for the range of minerals going from quartz to periclase for aluminum (silicate-like) projectiles. The impact velocities, which are required to induce melting in a soil, are calculated to be in the range of 3 to 4 km/sec, provided thermal equilibrium is achieved in the shock state.

Ahrens, T. J.↗

Effects of additives on volume change on melting, surface tension, and viscosity of liquid aluminum oxide

The effects of various oxide additives on the volume change on melting, the surface tension, and the viscosity of liquid Al2O3 were studied. Additives of Sm2O3, MgO, and Y2O3 which form solid solutions, compounds, and multiphase solids with Al2O3 were studied. A review of the property data for Al2O3 and Al2O3 containing oxide additives is presented. Oxide additives to Al2O3 reduce the volume change on melting and with the exception of SiO2 lower the viscosity; surface tensions change with oxide additives, but changes vary with different container material. Viscosity and volume change on melting appeared to be significantly more important for studying the properties of liquid oxides than surface tension. Supercooling of 270 K of yttrium aluminum garnet was observed.

Bates, J. L.↗

Segregation effects during solidification in weightless melts

Two types of melt segregation effects were studied: (1) evaporative segregation, or segregation due to surface evaporation; and (2) freezing segregation, or segregation due to liquid-solid phase transformation. These segregation effects are closely related. In fact, evaporative segregation always precedes freezing segregation to some degree and must often be studied prior to performing meaningful solidification experiments. This is particularly true since evaporation may cause the melt composition, at least at the critical surface regions or layers to be affected manyfold within seconds so that the surface region or layer melting point and other thermophysical properties, nucleation characteristics, base for undercooling, and critical velocity to avoid constitutional supercooling, may be completely unexpected. An important objective was, therefore, to develop the necessary normal evaporation equations for predicting the compositional changes within specified times at temperature and to correlate these equations with actual experimental data collected from the literature.

Li, C.↗

Rock melting technology and geothermal drilling

National awareness of the potential future shortages in energy resources has heightened interest in exploration and utilization of a variety of geothermal energy (GTE) reservoirs. The status of conventional drilling of GTE wells is reviewed briefly and problem areas which lead to higher drilling costs are identified and R and D directions toward solution are suggested. In the immediate future, an expanded program of drilling in GTE formations can benefit from improvements in drilling equipment and technology normally associated with oil or gas wells. Over a longer time period, the new rock-melting drill bits being developed as a part of the Los Alamos Scientific Laboratory's Subterrene Program offer new solutions to a number of problems which frequently hamper GTE drilling, including the most basic problem - high temperature. Two of the most favorable characteristics of rock-melting penetrators are their ability to operate effectively in hot rock and produce glass linings around the hole as an integral part of the drilling process. The technical advantages to be gained by use of rock-melting penetrators are discussed in relation to the basic needs for GTE wells.

Rowley, J. C.↗

Flows of impact melt at lunar craters

Lavalike materials that were emplaced in a fluid state occur in and around lunar impact craters whose diameters range from 3 km to more than 200 km and whose ages span a time interval of at least 3.5 billion years. The distribution of the lavalike deposits conforms to asymmetries of other ejecta from the same craters, and the material is concentrated downrange to distances as great as a crater radius. The character and distribution of the lavalike materials support the idea that they formed by impact melting rather than by volcanism. Returned samples indicate that materials with appropriate physical characteristics are generated by partial melting of feldspathic rocks by impact. The geologic evidence at lunar craters suggests that there is more melt rock in and near the craters than is predicted by experiment and theory.

Howard, K. A.↗

Effect of double vacuum melting and retained austenite on rolling-element fatigue life of AMS 5749 bearing steel

AMS 5749 steel combines the tempering, hot hardness, and hardness retention characteristics of AISI M-50 steel with the corrosion and oxidation resistance of AISI 440C stainless steel. The five-ball fatigue tester was used to evaluate the rolling-element fatigue life of AMS 5749. Double vacuum melting (vacuum induction melting plus vacuum arc remelting, VIM-VAR) produced AMS 5749 material with a rolling-element fatigue life at least 14 times that of vacuum induction melting alone. The VIM-VAR AMS 5749 steel balls gave lives from 6 to 12 times greater than VIM-VAR AISI M-50 steel balls. The highest level of retained austenite, 14.6 percent, was significantly detrimental to rolling-element fatigue life relative to the intermediate level of 11.1 percent.

Parker, R. J.↗

Thermal regimes in cratered terrain with emphasis on the role of impact melt

The distribution of bombardment energy in the moon's crust and the types of phase transformation resulting from this energy input are investigated. It is seen that the major significance of impact melts in the period of intense cratering is that they transfer most of the high-temperature heat following cratering and thus take part in many of the phase transformations on planetary surfaces. Energy partitioning studies suggest that of the projectiles' total kinetic energy, 23 to 35% is converted into heat by passage of the shock fronts, 43 to 53% transports ejecta and then is dissipated at modest temperature increases over a broad area, 8 to 24% is consumed comminuting country rock, and less than 1% becomes seismic and radiant energy. Subsequent to its formation, the melt is violently mixed with much colder debris to form the sheets of impact melt and the breccias.

Simonds, C. H.↗

Poikilitic KREEP impact melts in the Apollo 14 white rocks

A KREEP-rich fragment-laden melt series in the Apollo 14 white rocks is interpreted to be the result of impact into a source region possibly consisting of KREEP volcanic rock flows, underlain and surrounded by anorthositic-troctolitic highlands rocks. The melt groundmass is a high-alumina, high-K2O Fra Mauro basalt, enriched in plagioclase. A poikilitic texture is developed in the coarser members of the series, possibly as a result of the impact melt being seeded with relict plagioclase nuclei.

Ryder, G.↗

Manicouagan impact melt, Quebec. II - Chemical interrelations with basement and formational processes

The basement rocks of Manicouagan exhibit a wide compositional range (40-72% SiO2). Least squares mixing calculations indicate that the average composition of the Manicouagan melt sheet can be modeled for 9 major and 11 trace elements by a mixture of 4.5% anorthosite, 55.5% mafic gneiss, and 40.0% tan gneiss with a granitic-granodioritic composition. The underrepresentation of anorthosite relative to its present distribution is considered. The homogeneous composition of the melt (57.75 + or - 1.21% SiO2) relative to that of the postulated target is explained in a model outlining the dynamic conditions existing during the formation of the melt and its accompanying movement into the excavated cavity.

Grieve, R. A. F.↗

Rb-Sr isochron age of the Manicouagan melt sheet, Quebec, Canada

Rb-Sr isotopic data for mineral separates from a rock of the Manicouagan impact melt sheet define an isochron of age T = 214 + or - 5 (2 sigma) m.y. which agrees with the K-Ar age of 210 + or - 8 (2 sigma) calculated by Wolfe (1971). The initial Sr-87/Sr-86 ratio I is found to be 0.70991 + or - 0.00007 (2 sigma); four whole rock samples yield age-corrected I values ranging from 0.70965 to 0.71006. These high I values support the hypothesis that the melt sheet was derived by total melting of Grenville basement rocks during the impact event 214 m.y. ago.

Jahn, B.↗

Petrology of Apollo 15 black-and-white rocks 15445 and 15455 - Fragments of the Imbrium impact melt sheet

The paper describes two macroscopically similar black-and-white rocks, 15445 and 15455, which were collected from the rim of Spur Crater on the Apennine Front. The two Apollo 15 rocks are very similar in chemistry and clast population, but the matrix of 15455 is finer grained than that of 15445. The 15445 sample contains a lithic clast assemblage of plutonic/metamorphic spinel troctolite, troctolite, norite, and anorthosite, and its fine-grained vesicular black coherent matrix consists of a melt-bonded aggregate of small mineral clasts which are mainly olivine, plagioclase, and pink spinel. The two rocks are distinct from any other large samples from the Apollo 15 site. It is suggested that the rocks are samples of an impact melt sheet which forms a bedrock unit of the Apennine Front, and that this melt sheet did not form in a local small-scale event but was produced during the Imbrium impact event.

Ryder, G.↗

Impact conditions required for formation of melt by jetting in silicates

It is demonstrated that the process of jetting which occurs when particles collide at oblique angles may produce melt at much lower velocities than are required for melt production in head-on collisions. The minimum velocities of impact required for jetting in aluminum, bronzitite, dunite, and quartz are calculated by the method of shock polars. The analysis, which depends on stated assumptions about attained pressures and the occurrence of jetting, uses shock-velocity particle-velocity equations of state with three shock regimes. The treatment indicates that jetting should arise in bronzitite, dunite, and quartz at relative velocities as low as 1-2 km/sec. At such velocities material which passes near the stagnation point in the jet-forming region is subjected to sufficiently high pressures so that it is probably melted.

Kieffer, S. W.↗

Thermal regimes in impact melts and the petrology of the Apollo 17 Station 6 boulder

A progress report is presented on the petrologic study of the Station 6 boulder, taking into account the implications of its petrographic and geochemical studies to the understanding of the processes of formation and crystallization of impact melts. The interpretation of the data from the boulder suggests processes that appear reasonable for a petrogenetic model of impact events large enough to produce a layer of melt a kilometer or more wide and at most a few tens of meters thick. A summary of the model is presented. The primary difference between the new model and the previous models of Warner et al. (1973, 1974) and Simonds et al. (1973, 1974) is that melt and clasts are derived from distinctly different parts of the cratering regime. The cooling is modeled in two steps, first the rapid equilibration between clasts and matrix, and second, the much slower loss of heat to the surroundings.

Simonds, C. H.↗

Thermodynamic and melting properties of RDX at elevated pressures

The laboratory set up for determination of melting and thermodynamic properties of RDX using a diamond anvil cell apparatus capable of pressures exceeding 10 kbar and 250 C is described. The slope of the melting temperature versus applied pressure curve for RDX, as determined in the diamond cell, was found to equal 4.09 + or - 0.6 C (kbar). The density of liquid RDX at its melting point was calculated from this slope to be approximately 1.63 gm/cu cm. Practical and theoretical considerations in using the diamond anvil cell to generate thermodynamic data on RDX are discussed.

Carlson, D. W.↗