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Low global warming potential (GWP) refrigerant supermarket refrigeration system modeling and its application

As an environmentally friendly low global warming potential (GWP) refrigerant, Carbon dioxide (CO 2 ) has continuously gained popularity and research attention as alternative refrigerant for supermarket refrigeration system. In this paper, to fulfill the increasing need of accurate Low-GWP supermarket refrigeration models for development of supervisory level control and optimization strategies, a high fidelity model is developed for CO 2 transcritical supermarket refrigeration system which includes compressor rack of low temperature (LT) compressors and medium temperature (MT) compressors, air-cooled gas cooler, evaporator, expansion valves and other auxiliary equipment. A resistance-capacity model structure is proposed to simulate the display cases. Semi-thermodynamic models are proposed to estimate reciprocating compressors volumetric efficiency and power consumption. Furthermore the zone modeling approach is used for evaporator simulation, and air-cooled gas cooler is modeled with distributed modeling method. The expansion valve simulation is based on orifice flow model. To calibrate these models, both manufacture performance data and experimental data are used. The experiments are conducted with a full instrumental CO 2 supermarket refrigeration system installed in Oak Ridge National Lab Flexible Research Platform (FRP). The simulation model can predict the system performance, including power consumption, cooling capacity, mass flow rate, temperature, and pressure, with high accuracy (within ±4%) compared to experimental data. In addition, this developed model has been used to create the system optimum high side pressure for high side expansion valve control, and to generate wide operating range simulation data for developing the batter-equivalent commercial refrigeration system model which can be used in grid interactive control development.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The Star Formation History of Orion and its Environs

During the period of performance, we have obtained the following observations and carried out the analysis of the Orion associations itemized below. Optical Photometry: The Quest camera that had been damaged by lightning on Sept. 2001 was reconfigured to use 10 chips and only 3 filters instead of the original 4 but retaining its spatial coverage of 2.3deg wide in declination. During the Winter and Fall 2002 observing campaigns, we obtained multifilter photometry using the Quest camera on the 1mt Schmidt of the Venezuelan National Observatory, to continue the survey of the Orion clouds. In the Winter 2002 season, we obtained photometry for 10 scans at DEC=+5, 7 scans at DEC=-5. Several additional scans at DEC=-3 were obtained during the Fall 2002 observing campaign. Slit spectroscopy of bright candidates: During 2002 spectra for some 235 candidate PMS stars were obtained with the FAST spectrograph at the SAO 1.5m telescope in Mt. Hopkins. These objects, all brighter than V=16, are located in two strips centered at DEC=+l and -5, and spanning from RA=5h-6h. The spectra are being analyzed. Multifiber spectroscopy: Spectroscopy for our fainter (V less than or equal to 16) candidates has not kept pace with our spectroscopy of brighter candidates, because of the delay in the commissioning of the Hectospec and Hectoechelle multi-object spectrographs at the new 6.5m MMT. We obtained some data with the Hydra spectrograph on the WIYN telescope: Feb 1-4, 2002. Time granted to the project: "A Large Scale Survey of the Low-Mass Young Population in the Orion OB1 Association" (P.I.: C. Briceno). Three half-nights (we used the first half of the night, the second half of the night was used with the Mini-Mosaic imager by another team). Only the first half night was clear. We observed 3 fields centered in a 2.3 deg wide strip centered at DEC=-1 and spanning RA=Sh to 6h. A total of 250 spectra were obtained for the same number of candidate PMS stars. Nov. 13-15, 2002. Time granted to the project "Cluster survey of protoplanetary disk evolution", (P.I.: A. Sicilia-Aguilar). Clear weather throughout. We obtained spectra for some 200 candidate PMS stars in 3 fields located in a 2.3 deg wide strip centered at DEC=+l and spanning from RA=5h20m to 5h35m. Data for both observing runs is partially reduced and is being analyzed. U photometry: During Nov.29-Dec.4, 2002 we were granted time with the 4-shooter CCD Mosaic Camera at the SAO 1.2m telescope, to obtain U-band photometry of a subset of the newly identified T Tauri stars in the strip centered at DEC=-1. This sample is composed of strong H(alpha) emitting PMS stars (Classical T Tauri stars) located mostly in the Orion OB lb association, around the Orion Belt area. Our data will be combined with our calibration of the U-band excess (Gullbring et al. 1998) to derive mass accretion rates. Because of bad weather we observed only 20 stars during 1.5 clear nights. Near IR photometry: During Dec. 14-19, 2002 we used the IR Camera on the SAO 1.2m telescope, to obtain L-band photometry of a set of 17 the newly identified Orion OB 1a and 1b stars, in order to look for IR excess emission coming from the hotter inner parts of circumstellar disks. Again, mediocre weather prevented a larger set to be observed. These stars were also observed with the OSCIR mid-IR camera on Gemini North during later 2001. Our goal is to construct SEDs from the visual out to the mid-IR (by combining our optical/IR data with 2MASS JHK magnitudes) in order to explore disk dissipation at the critical ages of 5-10 Myr spanned by these stars.

Calvet, Nuria↗

Stratigraphic Change from Ca-Sulfate to Mg-Sulfate in the Sedimentary Bedrock of Gale Crater, Mars: Recent Results from Curiosity’s APXS

Curiosity’s APXS instrument has been quantifying sulfates over >30 km of traverse in Gale crater. The rover recently arrived at sedimentary strata where orbital data predicted hydrated Mg-sulfates that may record a change to a drier paleoenvironment. The sequence of strata is in the Marker Band Valley (MBV), the ~10-m-thick, metal-rich Marker Band (MB), and strata above the MB. Here, we report recent sulfate observations by the APXS and provide constraints on the occurrence of Mg-sulfate and the implications for paleoenvironment interpretations. In sedimentary strata below the MBV, Mg-sulfate enrichment (~5-10 wt%) is generally limited to larger diagenetic nodules (~1-3 cm). Ca is positively correlated with S at proportions consistent with Ca-sulfate addition to the bedrock matrix. S variation is thus controlled primarily by Ca-sulfate, which increases ~30% in transitional units below the MBV. The MBV contains the first evidence of Mg-sulfate enrichment in the bedrock matrix, confirmed by the detection of crystalline Mg-sulfate by CheMin. The MBV bedrock has the same overall bulk composition as the underlying Mt. Sharp gp. strata, but with an additional ~5-15 wt% Mg-sulfate. The MB has contrasting sulfate content: (1) targets with very high concentrations of MnO (1.5 wt%), FeO (47 wt%), and Zn (2.2 wt%) are depleted in S and (2) targets with lower metal content have evidence of Mg-sulfate addition. Strata above the MB have a bulk composition that is distinct from other rocks in Gale. For example, the bedrock has molar Fe/Mn (50-60) and Cr/Ti (0.4-0.7) similar to basaltic soil, but ~3X higher Zn and high Ge (50 ppm). Median SO3 above the MB (15 wt%) is higher than the MBV (14 wt%) as well as strata below the MBV (~8 wt%). S does not correlate with Ca or Mg above the MBV. MgO (~9 wt%) is higher than below the MBV (~5 wt%) and the SO3/MgO (1.7) is in the same range as the Mg-sulfate-bearing MBV, suggesting Mg-sulfate enrichment. APXS data indicate that the MBV and above the MB preserve a relatively sharp vertical transition (~5-10 m) from Ca-sulfate to Mg-sulfate in the rock matrix. The sharp contacts with the sulfate-depleted MB and the notable change in bulk composition above the MB may indicate a complex depositional and/or diagenetic history under conditions where enrichments in the highly soluble Mg-sulfates were ultimately preserved.

Jeffrey Allan Berger↗

Check-Up of Planet Earth at the Turn of the Millennium Anticipated New Phase in Earth Sciences

Langley's remarkable solar and lunar spectra collected from mt. Whitney inspired Arrhenius to develop the first quantitative climate model in 1896. In 1999, NASA's Earth Observing AM Satellite named recently "Terra" (by Ms. Sasha Jones, a 17 year old student in St. Louis, MO) will repeat Langley's experiment, but for the entire planet, thus pioneering calibrated spectral observations from space. Conceived in response to real environmental problems, EOS-AM, in conjunction with other international satellite efforts, will fill a major gap in current efforts by providing quantitative global data sets with a resolution of few kilometers on the physical, chemical and biological elements of the earth system. Thus, like Langley's data, EOS-AM can revolutionize climate research by inspiring a new generation of climate system models and enable us to assess the human impact on the environment. In this talk I shall a give a historical perspective for the need for this expensive mission, give examples of the science that we anticipate to achieve using Terra measurements and describe this exciting mission.

Kaufman, Yoram↗

The Earth Observing System Terra Mission

Langley's remarkable solar and lunar spectra collected from Mt. Whitney inspired Arrhenius to develop the first quantitative climate model in 1896. After the launch in Dec. 16 1999, NASA's Earth Observing AM Satellite (EOS-Terra) will repeat Langley's experiment, but for the entire planet, thus pioneering a wide array of calibrated spectral observations from space of the Earth System. Conceived in response to real environmental problems, EOS-Terra, in conjunction with other international satellite efforts, will fill a major gap in current efforts by providing quantitative global data sets with a resolution smaller than 1 km on the physical, chemical and biological elements of the earth system. Thus, like Langley's data, EOS-Terra can revolutionize climate research by inspiring a new generation of climate system models and enable us to assess the human impact on the environment. In the talk I shall review the historical perspective of the Terra mission and the key new elements of the mission. We expect to have some first images that demonstrate the most innovative capability from EOS Terra: MODIS - 1.37 microns cirrus channel; 250 m daily cover for clouds and vegetation change; 7 solar channels for land and aerosol; new fire channels; Chlorophyll fluorescence; MISR - 9 multi angle views of clouds and vegetation; MOPITT - Global CO maps and CH4 maps; ASTER - Thermal channels for geological studies with 15-90 m resolution.

Kaufman, Yoram J.↗

The Earth Observing System Terra Mission

Langley's remarkable solar and lunar spectra collected from Mt. Whitney inspired Arrhenius to develop the first quantitative climate model in 1896. After the launch in Dec. 16 1999, NASA's Earth Observing AM Satellite (EOS-Terra) will repeat Langley's experiment, but for the entire planet, thus pioneering a wide array of calibrated spectral observations from space of the Earth System. Conceived in response to real environmental problems, EOS-Terra, in conjunction with other international satellite efforts, will fill a major gap in current efforts by providing quantitative global data sets with a resolution better than 1 km on the physical, chemical and biological elements of the earth system. Thus, like Langley's data, EOS-Terra can revolutionize climate research by inspiring a new generation of climate system models and enable us to assess the human impact on the environment. In the talk I shall review the historical perspective of the Terra mission and the key new elements of the mission. We expect to have first images that demonstrate the most innovative capability from EOS Terra 5 instruments: MODIS - 1.37 micron cirrus cloud channel; 250m daily coverage for clouds and vegetation change; 7 solar channels for land and aerosol studies; new fire channels; Chlorophyll fluorescence; MISR - first 9 multi angle views of clouds and vegetation; MOPITT - first global CO maps and C114 maps; ASTER - Thermal channels for geological studies with 15-90 m resolution.

Kaufman, Yoram J.↗

Data from Technical and Economic Feasibility of an Integrated Ethanol and Anthocyanin Coproduction Process Using Purple Corn Stover

The coproduction of high-value anthocyanin extract in the cellulosic ethanol process would diversify the co-product market, increase revenue, and potentially improve the economics of the process. The high anthocyanin concentration in the cob and structural carbohydrates in residual stover make purple corn stover an attractive source for anthocyanin and ethanol coproduction. This study aimed to develop simulation models for processes integrating ethanol production and anthocyanin extraction using purple corn stover, to evaluate their techno-economic feasibility, and to compare their performance with the conventional ethanol production process using corn stover. The annual ethanol production for plants processing 2000 MT dry feedstock / day was 148.6 million L/year for the integrated processes compared with 222.6 million L/year for the conventional process. Anthocyanin production in the modified processes using dilute acid-based and water-based anthocyanin extraction processes was 1779 and 1099 MT/year, respectively. Capital investments for the integrated processes ($448.1 to $443.8 million) were higher than the conventional process ($371.9 million). Due to high revenue from anthocyanin extract, the ethanol production cost for the integrated process using acid-based anthocyanin extraction ($0.36/L) was 34.5% lower than conventional ethanol production ($0.55/L). The ethanol production cost for the integrated process using water-based anthocyanin extraction ($0.68/L) was higher than conventional ethanol production due to low ethanol and anthocyanin yields. The minimum ethanol selling price for the integrated process using acid-based anthocyanin extraction ($0.65/L) was also lower than the conventional process ($0.72/L), indicating an improvement in economic performance.

Conversion↗

Investigating Sources of Ozone over California Using AJAX Airborne Measurements and Models: Assessing the Contribution from Long Range Transport

High ozone (O3) concentrations at low altitudes (1.5e4 km) were detected from airborne Alpha Jet Atmospheric eXperiment (AJAX) measurements on 30 May 2012 off the coast of California (CA). We investigate the causes of those elevated O3 concentrations using airborne measurements and various models. GEOS-Chem simulation shows that the contribution from local sources is likely small. A back trajectory model was used to determine the air mass origins and how much they contributed to the O3 over CA. Low-level potential vorticity (PV) from Modern Era Retrospective analysis for Research and Applications 2 (MERRA-2) reanalysis data appears to be a result of the diabatic heating and mixing of airs in the lower altitudes, rather than be a result of direct transport from stratospheric intrusion. The Q diagnostic, which is a measure of the mixing of the air masses, indicates that there is sufficient mixing along the trajectory to indicate that O3 from the different origins is mixed and transported to the western U.S.The back-trajectory model simulation demonstrates the air masses of interest came mostly from the mid troposphere (MT, 76), but the contribution of the lower troposphere (LT, 19) is also significant compared to those from the upper troposphere/lower stratosphere (UTLS, 5). Air coming from the LT appears to be mostly originating over Asia. The possible surface impact of the high O3 transported aloft on the surface O3 concentration through vertical and horizontal transport within a few days is substantiated by the influence maps determined from the Weather Research and Forecasting Stochastic Time Inverted Lagrangian Transport (WRF-STILT) model and the observed increases in surface ozone mixing ratios. Contrasting this complex case with a stratospheric-dominant event emphasizes the contribution of each source to the high O3 concentration in the lower altitudes over CA. Integrated analyses using models, reanalysis, and diagnostic tools, allows high ozone values detected by in-situ measurements to be attributed to multiple source processes.

Ryoo, Ju-Mee↗

MastCam Multispectral Examination of Rocks in the Sulfate-Bearing Terrain of Marker Band Valley, Gale Crater, Mars

A primary objective of the 4th extended mission of the Mars Science Laboratory rover Curiosity is to characterize the sulfate-bearing beds exposed on the slopes of Mt. Sharp (Aeolis Mons) above the clay-bearing beds of the Glen Torridon region characterized in the 3rd extended mission. Orbital reflectance spectroscopy from CRISM has indicated the presence of polyhydrated Mg sulfates in the portion of Mt. Sharp dubbed “Marker Band Valley” (MBV). The Marker Band is a darker toned, high-Ca pyroxene bearing unit that extends around much of Mt. Sharp above the first exposures of sulfate-bearing beds. Standoff imaging of the Marker Band indicates that it is not monolithic, but contains at least two subunits. Curiosity measures multispectral reflectance in the 430 to 1012 nm range with its Mastcam. While diagnostic spectral features of Mg-sulfates are not present in the Mastcam spectral range, a water overtone feature of some polyhydrated sulfates can be observed as a drop in reflectance in the longest wavelength one to three bands of Mastcam multispectral data. Other minerals associated with sulfate-generating alteration processes, most notably Fe-bearing minerals, are more readily detectable in Mastcam multispectral data.

W H Farrand↗

Exploration of a Combined LIBS and LA-ICP-MS Approach for Apatite Characterisation

A combined laser‐induced breakdown spectroscopy (LIBS) and laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) method is demonstrated for comprehensive apatite analysis. These measurements provide elemental imaging that can be used as a screening technique for chemical selection of grains for subsequent analysis (e.g., U‐Pb geochronology) or can be used to understand elemental distributions within a single grain that would have direct textural‐chemical implications (e.g., zoning patterns). Adding LIBS as a simultaneous measurement, to LA‐ICP‐MS U‐Pb geochronology, allowed for the direct determination of F (H and O show promise for future applications) in addition to major and trace elements of interest. Here, the quantitative measurements were validated against a series of apatites with known values and used to characterise a wide range of samples. Fluorine detection limits were determined to be as low as 70 μg g ‐1 F (broadband CMOS detector) and 4.2 μg g ‐1 F (ICCD detector). U‐Pb age dating was simultaneously collected by LA‐ICP‐MS with the quantitative elemental data from LIBS, providing a comprehensive method for geochronology.

Apatite↗

Paying it Forward: How an Emerging Unconventional Play can Hit the Ground Running

While every tight oil play is unique, there are lessons that can be transferred from one play to another to improve the efficiency and pace of production operations and development. These improvements may not fit precisely in every basin or play but generally hold to themes that can be tested against and built upon. Themes such as the quantity of proppant, longer lateral length, or the number of stages can be directly tied to increased productivity. However, there are diminishing returns on these investment activities for which each operator, within a given play, will be required to identify and mitigate against. This is especially true as the industry steps in and begins developing new tight oil plays. In their nascent stages, these plays may have limited well penetrations and, as a result, limited geological and performance data from which to extrapolate. Pulling together an understanding of where the industry currently resides in terms of how to exploit these resources can provide a boost in terms of working towards greatly improved well completions. In 2019, the US EIA estimated that nearly 8 million barrels of oil per day were produced from tight oil reservoirs in the United States (US EIA, 2020). This represents over 60% of the domestic crude production, originating from multiple reservoirs in the Permian Basin (TX) as well as the Bakken (MT, ND), Eagle Ford (TX), Niobrara (CO, WY), and Anadarko Basin (OK) formations, among others. As such, there are 1,000s of wells across these numerous tight oil plays that can relate an informative story. To build this story, the interplay of geology, well spacing, lateral length, and stimulation, all critical to economic success, will be explored. This paper proposes to look back at these mature tight oil (and gas) basins and bring forth an understanding of what lessons can be applied to the emerging Powder River Basin tight oil reservoirs (Mowry and the Turner/Frontier). The authors will delve into the four broad topics of geology, well spacing, lateral length, and stimulation, highlighting case studies to demonstrate those lessons from established tight oil plays that will underpin planned activities at a Field Laboratory Test Site in the southern Powder River Basin.

02 PETROLEUM↗

Lunar rover technology demonstrations with Dante and Ratler

Carnegie Mellon University has undertaken a research, development, and demonstration program to enable a robotic lunar mission. The two-year mission scenario is to traverse 1,000 kilometers, revisiting the historic sites of Apollo 11, Surveyor 5, Ranger 8, Apollo 17, and Lunokhod 2, and to return continuous live video amounting to more than 11 terabytes of data. Our vision blends autonomously safeguarded user driving with autonomous operation augmented with rich visual feedback, in order to enable facile interaction and exploration. The resulting experience is intended to attract mass participation and evoke strong public interest in lunar exploration. The encompassing program that forwards this work is the Lunar Rover Initiative (LRI). Two concrete technology demonstration projects currently advancing the Lunar Rover Initiative are: (1) The Dante/Mt. Spurr project, which, at the time of this writing, is sending the walking robot Dante to explore the Mt. Spurr volcano, in rough terrain that is a realistic planetary analogue. This project will generate insights into robot system robustness in harsh environments, and into remote operation by novices; and (2) The Lunar Rover Demonstration project, which is developing and evaluating key technologies for navigation, teleoperation, and user interfaces in terrestrial demonstrations. The project timetable calls for a number of terrestrial traverses incorporating teleoperation and autonomy including natural terrain this year, 10 km in 1995. and 100 km in 1996. This paper will discuss the goals of the Lunar Rover Initiative and then focus on the present state of the Dante/Mt. Spurr and Lunar Rover Demonstration projects.

Krotkov, Eric↗

Fermi surface topology and magnetotransport properties of superconducting Pd 3 Bi 2 Se 2

Pd 3 Bi 2 Se 2 is a rare realization of a superconducting metal with a non-zero topological invariant. Here, in this study, we report the growth of high-quality single crystals of layered Pd 3 Bi 2 Se 2 with a superconducting transition at T c ≈ 0.80 K and upper critical fields of ~10 mT and ~5 mT for the in plane and out-of-plane directions, respectively. Our density functional theory (DFT) calculations reveal three pairs of doubly degenerate bands crossing the Fermi level all displaying clear three dimensional dispersion consistent with the overall low electronic anisotropy (<2). The multiband electronic nature of Pd 3 Bi 2 Se 2 is evident in magneto-transport measurements, yielding a sign changing Hall resistivity at low temperatures. The magnetoresistance is non-saturating and follows Kohler’s scaling rule. We interpret the magneto-transport data in terms of open orbits that are revealed in the DFT calculated Fermi surface. de Haas-van Alphen (dHvA) oscillation measurements using torque magnetometry on single crystals yield four frequencies for out-of-plane fields: F α = (150 ± 26) T, F β = (293 ± 10) T, F γ = (375 ± 20) T and F η = (1017 ± 12) T, with the low frequency dominating the spectrum. Through the measurement of angular dependent dHvA oscillations and DFT calculations we identify the F α frequency with an approximately ellipsoidal electron pocket centered on the L 2 point of the Brillouin zone. Lifshitz-Kosevich analysis of the dHvA oscillations reveals a small cyclotron effective mass m* = (0.11 ± 0.02)m 0 and a nontrivial Berry phase for the dominant orbit. The presence of nontrivial topology in a bulk superconductor positions Pd 3 Bi 2 Se 2 as a potential candidate for exploring topological superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Temperature Dependence of the Langmuir Adsorption Model for a Single-Site Metal–Organic Framework

The single-site Langmuir adsorption model, also known as the Langmuir isotherm equation, is one of the simplest possible descriptions of adsorption phenomena, and yet finds widespread applicability across a range of disciplines. In its simplest form, it is deployed to treat adsorption equilibria at constant temperature (i.e., along isotherms); however, at the heart of its derivation is a more general class of models that each incorporate an explicit temperature dependence, subject to assumptions about the spatial/translational degrees of freedom of the adsorbed species. In this work, measurements of the temperature dependence of supercritical adsorption of H 2 on a single-site metal-organic framework (MOF) are presented, and fitted using a range of Langmuir models with distinct treatments of degrees of freedom in the adsorbed phase. Surprisingly, all of the models can be used to adequately represent the measured data, despite yielding significantly different values for binding energy and the temperature dependence of the isosteric enthalpy of adsorption (i.e., the isosteric heat, qst). Furthermore, a critical finding is that the mean-temperature isosteric enthalpy of adsorption remains consistent across all models within experimental error, highlighting its reliability for evaluating adsorption thermodynamics.

08 HYDROGEN↗

Lidar observation of ozone over Tsukuba (36 deg N, 140 deg E)

An ozone lidar system was installed at the National Institute for Environmental Studies (NIES) in Tsukuba, Japan in March 1988 and has been measuring vertical profiles of ozone (15 - 45 km) since September 1988. The lidar system consists of a XeCl (308 nm) excimer laser, its deuterium Raman shifter (339 nm), a XeF excimer laser (351 nm), a 2 m telescope, a receiving system and a data processing system. The precision of the derived ozone concentration is about 10 percent of an altitude of 40 km for a 4 hr observation. Temperature profiles (30 - 80 km) are also obtained from the Rayleigh scattering signals at 351 nm. Approximate 50 ozone measurements are carried out in a year and variations of vertical profiles of ozone such as seasonal variations and shorter-term variations are observed. Systematic errors due to aerosols had been negligible until the arrival of the stratospheric aerosols injected by the eruption of Mt. Pinatubo. Effects of the volcanic aerosols on ozone measurements depend on the differences between wavelengths used as the on- and off-resonance.

Nakane, H.↗

Well-Log Derived Geomechanical Analysis of Microseismicity in the Mt. Simon Saline Aquifers (Illinois Basin - Decatur Project)

The Illinois Basin Decatur Project (IBDP) successfully demonstrated the safe geologic storage of carbon dioxide at a commercial scale. Within the IBDP project three deep wells (injection (CCS1), monitoring (VW1), geophysical (GM1)) were competed and geophysical logs were recorded. During injection and post-injection periods microseismic monitoring was conducted to create a miscoseismic catalog. The correlations between microseimic attributes and geomechanical well logs define major geomechanical drivers of microseismic expression to understand a reservoir response to CO2 injection in geological context. Utilizing standard sonic and density well logs, the dynamic elastic moduli were calculated and employed to correlate with microseismic pseudo-logs. A multi-dimensional Mu-rho and Lambda-rho (MRLR) hyperdimensional plots display of meaningful data and uncovered subtle relationships between elastic properties of sandstones and the seismological attributes of recorded microseismicity.

Myshakin, Evgeniy↗

Evaluation of Containment and Geomechanical Risks at Integrated Mid-Content Stacked Carbon Storage Hub Sites

The U.S. Department of Energy is leading the development of CCS through collaborative projects and programs to not only develop and demonstrate the technology but to also quantify the risks and provide tools that site operators can use to develop a site-specific understanding of their risk to enable successful project operations. This report summarizes results and findings from the application of risk-assessment tools to an industrial-scale Geologic Carbon Storage (GCS) project. Specifically, we applied the National Risk Assessment Partnership’s (NRAP) Open Integrated Assessment Model (NRAP-Open-IAM) and State of Stress Assessment Tool (SOSAT) to two candidate sites being considered for storage by the Integrated Midcontinent Stacked Carbon Storage Hub (IMSCS-Hub) project team. These sites, Sleepy Hollow Field in Nebraska and Patterson Field in Kansas, have historical oil and gas production and thus are attractive candidates to store the 50 million metric tons (Mt), which is the CarbonSAFE objective. Because these sites have historical operations, they have a significant number of existing wells that pose a risk for well leakage. Additionally, the storage formations will undergo significant pore pressure perturbation (i.e., increase due to CO 2 injection). Hence, we have selected the two NRAP tools best suited to study the risks associated with well leakage and geomechanical risks. The objective of the study was not only to assess the risk at the site, but to also improve the NRAP tools through application using real site data on an ongoing project.

54 ENVIRONMENTAL SCIENCES↗

X-Ray and TeV Gamma-Ray Observations of the Strong TeV Gamma-Ray Blazars Mrk 501 and 1ES 1959+650

In June 2003, the blazar 1ES 1959+650 showed a very high level of X-ray activity. The 2-12 keV flux measured with the RXTE All Sky Monitor exceeded 10 mCrab for a prolonged time. We therefore invoked RXTE multiwavelength observations of the source. It was observed with RXTE between May 2,2003 and June 7,2003 with a total integration time of 33 ksec. We complemented the RXTE observations with TeV gamma- ray observations with the Whipple 10 m Cherenkov telescope (Mt. Hopkins, &.). In addition, we invoked radio observations with the UMRAO radio telescope (Aller et al.) and with the Bordeaux optical observatory (P. Charlot et al.). The RXTE observations revealed several X-ray flares with large amplitude variations of the 3 keV - 15 keV spectral index. While the X-ray flares were of intermediate amplitude - some of them comparable to the high X-ray fluxes measured in 2002 - the source remained unexpectedly quiet at TeV gamma-rays. The analysis of the Whipple 10 m TeV gamma-ray data did not result in a firm detection.

Krawczynski, Henric↗