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At least 361 records · Page 20

Selected Studies in High Temperature Chemistry at the NASA Glenn Research Center

Several high temperature chemistry studies, which support NASA missions in both Aeronautics and Space, will be discussed. As will be discussed, collaboration with partners both within NASA and outside of NASA was essential to attaining the goals of each study. The following studies will be presented: 1. Oxidation of the reinforced carbon/carbon on the wing leading edge of the Space Shuttle Orbiter. This was conducted for the Leading Edge Subsystem Problem Resolution Team and involved experts in mass transport, non-destructive evaluation, and mechanical properties. 2. Thermodynamic activity measurement in rare earth silicates for coatings of ceramic hot stage parts in aircraft combustors. This was conducted with colleagues at NASA in support of a larger project involving NASA and the major engine companies. 3. Planetary Science in conjunction with universities a. Thermochemical modeling to describe parts of the Venus atmosphere. b. High temperature vapor studies to describe the possible atmospheres of hot, rocky exoplanets. c. High temperature mass spectrometry for K/Ar dating of minerals. These problems are all addressed with basic laboratory studies and collaboration across multiple disciplines is necessary.

Mass spectrometry, thermodynamics, high temperatur↗

Outbursts by low-mass white dwarfs in symbiotic variables

The high-resolution IUE spectra of the symbiotic variables BF Cygni and EG Andromedae are studied in order to describe the P Cygni-like features of these objects. The 10 high-dispersion IUE spectra are examined for orbital phase-dependent variations in the C IV resonance doublet in terms of velocity and/or structure. One image is found to have a strong He-II absorption feature that coincides in velocity with the C-IV absorption component in P Cygni. The absorbing material for both lines is related to outflow and P Cygni self-absorption near the hot component. The P Cygni profiles do not appear to be related to a red-giant wind nor an expanding circumbinary shell in the in both BF Cyg and EG And. Quasi-static evolutionary model calculations demonstrate an unexpected outburst behavior in response to the assumed accretion. These data are shown to be important for the study of symbiotic systems that contain low-mass white dwarfs.

Sion, Edward M.↗

Center for Isotope Cosmochemistry and Geochronology at NASA Johnson Space Center

The Center for Isotope Cosmochemistry and Geochronology (CICG) at the NASA Johnson Space Center, led by Justin Simon, applies novel elemental and isotopic analytical techniques to understand solar system formation, from processes occurring during the earliest Solar Nebula, to the evolution of planetary bodies during planet formation and differentiation. CICG consists of an integrated suite of labs including dedicated spaces for specialized handling and preparation of meteorites and planetary return samples, metal-free clean chemistry, and mass spectrometry. In addition to a Thermo-Scientific Triton thermal ionization mass spectrometer (TIMS) for high precision isotopic analyses in processed samples, CICG houses two additional mass spectrometry instruments with added laser ablation capabilities for high spatial resolution in-situ measurements: (1) a Thermo-Scientific Element-XR inductively coupled mass spectrometer (ICP-MS) with a Teledyne Photon Machines Analyte Excite+ laser ablation system, and (2) a Nu Sapphire 1700 multi-collector ICP-MS, a large geometry instrument with a multi-pole collision cell for interference removal, with an Applied Spectra J200 tandem laser induced breakdown spectroscopy (LIBS) femto-second laser ablation system. We detail the analytical capabilities of CICG in the context of current and future research projects related to the studies of protoplanetary disk evolution via early-formed Solar System solids, volatile abundances and distribution within the inner solar system, and geochemical and temporal investigations related to planet formation and differentiation. We also highlight opportunities through the relationship with the Center of the Advancement of Space Safety and Mission Assurance Research (CASSMAR) at the University of Texas at El Paso. CICG is open to collaborations and participates in the NASA Facility for Astromaterials Research (NFAR) program, which accepts research proposals for access to the unique facility capabilities.

Jacob B. Setera↗

Analysis of data from the Pioneer Venus Sounder Probe mass spectrometer

The composition of the lower atmosphere of the planet Venus from 62 km to the surface was measured by a neutral gas mass spectrometer onboard of the Pioneer Venus Sounder Probe. Fifty-one mass spectra were obtained with an average altitude resolution of approximately 1 km. The instrument measured the composition of the gases relative to CO2, the dominant gas, that is sampled from the Venus atmosphere through a special leak. The mass range extended from 1 to 208 amu with a sensitivity of the order of 1 ppm relative to CO2, but for the noble gases it was nearly 100 times better. A description of the instrument and the initial results are reported.

Hoffman, J. H.↗

Ion composition experiment

An investigation using a novel ion mass spectrometer for measuring the ionic composition of the solar wind from the ISEE-C spacecraft is described. The resolution and dynamic range of the instrument are sufficient to be able to resolve up to twelve individual ions or groups of ions. This will permit the solution of a number of fundamental problems related to solar abundances and the formation of the solar wind. The spectrometer is composed of a stigmatic Wien filter and hemispherical electrostatic energy analyzer. The use of curved electric field plates in the filter results in a substantial saving of weight with respect to a conventional filter of the same resolution and angular acceptance. The spectrometer is controlled by a microprocessor based on a special purpose computer which has three modes of operations: full and partial survey modes and a search mode. In the search mode, the instrument locks on to the solar wind. This allows four times the time resolution of the full survey mode and yields a full mass spectrum every 12.6 min.

Coplan, M. A.↗

Total Dust Deposition Flux During Precipitation in Toyama, Japan, in the Spring of 2009: A Sensitivity Analysis with the NASA GEOS-5 Model

We compared the observed total dust deposition fluxes during precipitation (TDP) mainly at Toyama in Japan during the period January - April 2009 with results available from four NASA GEOS-5 global model experiments. The modeled results were obtained from three previous experiments and carried out in one experiment, which were all driven by assimilated meteorology and simulating aerosol distributions for the time period. We focus mainly on the observations of two distinct TDP events, which were reported in Osada et al. (2011), at Toyama, Japan, in February (Event B) and March 2009 (Event C). Although all of our GEOS-5 simulations captured aspects of the observed TDP, we found that our low horizontal spatial resolution control experiment performed generally the worst. The other three experiments were run at a higher spatial resolution, with the first differing only in that respect from the control, the second adding imposed a prescribed corrected precipitation product, and the final experiment adding as well assimilation of aerosol optical depth based on MODIS observations. During Event C, the increased horizontal resolution could increase TDP with precipitation increase. There was no significant improvement, however, due to the imposition of the corrected precipitation product. The simulation that incorporated aerosol data assimilation performed was by far the best for this event, but even so could only reproduce less than half of the observed TDP despite the significantly increased atmospheric dust mass concentrations. All three of the high spatial resolution experiments had higher simulated precipitation at Toyama than was observed and that in the lower resolution control run. During Event B, the aerosol data assimilation run did not perform appreciably better than the other higher resolution simulations, suggesting that upstream conditions (i.e., upstream cloudiness), or vertical or horizontal misplacement of the dust plume did not allow for significant improvement in the simulated aerosol distributions. Furthermore, a detailed comparison of observed hourly precipitation and surface particulate mass concentration data suggests that the observed TDP during Event B was highly dependent on short periods of weak precipitation correlated with elevated dust surface concentrations, important details possibly not captured well in a current global model.

Dust; Wet deposition; Numerical modeling; Japan; P↗

Dust counter and mass analyser (DUCMA) measurements of comet Halley's coma from Vega spacecraft

Measurements of dust particles in comet Halley's coma from Vega spacecraft made with instruments using a new principle of dust detection and having a high time resolution over a large range of dust fluxes and masses are reported. The dust coma, whether quiescent (as seen by Vega 2) or containing a major jet structure, (as seen by Vega 1) displays large, short-term variations throughout which are at times quasi-periodic. The integral mass spectra increase in intensity to the lowest masses measured, and the flux levels lie approximately in the ranges estimated previously from ground-based observations. The coma is highly dynamical on all spatial and temporal scales, suggesting a complex structure of localized regions of dust emission from the nucleus.

Simpson, J. A.↗

HD 191939: Three Sub-Neptunes Transiting a Sun-like Star Only 54 pc Away

We present the discovery of three sub-Neptune-sized planets transiting the nearby and bright Sun-like star HD 191939 (TIC 269701147, TOI 1339), a Ks = 7.18 mag G8 V dwarf at a distance of only 54 pc. We validate the planetary nature of the transit signals by combining 5 months of data from the Transiting Exoplanet Survey Satellite with follow-up ground-based photometry, archival optical images, radial velocities, and high angular resolution observations. The three sub-Neptunes have similar radii (R(b)=3.42(+0.11,-0.11), R(c)=3.23(+0.11,-0.11), and R(d)=3.16(+0.11,-0.11 Rꚛ), and their orbits are consistent with a stable, circular, and coplanar architecture near mean-motion resonances of 1:3 and 3:4 (P(b) = 8.88, P(c) = 28.58, and P(d) = 38.35 days). The HD 191939 system is an excellent candidate for precise mass determinations of the planets with high-resolution spectroscopy due to the host star's brightness and low chromospheric activity. Moreover, the system's compact and near-resonant nature can provide an independent way to measure planetary masses via transit timing variations while also enabling dynamical and evolutionary studies. Finally, as a promising target for multiwavelength transmission spectroscopy of all three planets' atmospheres, HD 191939 can offer valuable insight into multiple sub-Neptunes born from a protoplanetary disk that may have resembled that of the early Sun.

Mariona Badenas-Agusti↗

Observation of mass loading in the Io plasma torus

Ground-based high-resolution spectra of emission from the Io plasma torus obtained during 53 nights of observation over a seven month period are used to measure the torus rotation speed and discern regions of the torus that are slowed by mass loading of newly ionized materials. The amount of torus slowing implies that between 2000 and 3000 kg/sec are being ionized by the torus. The slowing is spread azimuthally throughout the orbit of Io, suggesting that neutral materials emanating from Io are distributed around Jupiter much more uniformly than currently believed.

Brown, Michael E.↗

On the mass of nova DQ Hercules (1934)

Time-resolved high-resolution CCD spectroscopy covering two 4.6-hr orbits of DQ Her are presented. Analysis of the Na I 8183,8195 A absorption doublet yields estimates of the secondary star's projected orbital velocity and rotational broadening. The estimate of the projected orbital velocity is refined using models of the effects of irradiation on the secondary star, producing a final value of 227 +/- 10 km/s. The stellar masses are estimated at M1 = 0.60 +/- 0.07 and M2 = 0.40 +/- 0.05 solar mass.

Horne, Keith↗

Mass spectrometric analysis of organic compounds, water and volatile constituents in the atmosphere and surface of Mars - The Viking Mars Lander.

An experiment centering around a mass spectrometer is described, which is aimed at the identification of organic substances present in the top 10 cm of the surface of Mars and an analysis of the atmosphere for major and minor constituents as well as isotopic abundances. In addition, an indication of the abundance of water in the surface and some information concerning the mineralogy can be obtained by monitoring the gases produced upon heating the soil sample. The organic material will simply be expelled by heating to 150, 300, and 500 C into the carrier gas stream of a gas chromatograph interfaced to the mass spectrometer or by slowly heating the sample in direct communication with the spectrometer. It is planned to analyze a total of up to nine soil samples in order to study diurnal and seasonal variations. The system is designed to give useful data even for minor constituents if the total of organics should be as low as 5 ppm. The spectrometer covers the mass range of 12-200 with adequate resolution.

Anderson, D. M.↗

The ultraviolet variability of HD 45166 (qWR + B8 V) - Evidence for stellar wind radiative instabilities

High-resolution IUE spectroscopy of the low-mass qWR star HD 45166, obtained at several epochs during 1980-1988, reveals a complex pattern of variability in its stellar wind emission lines, P Cygni profiles, and highly ionized photospheric absorption spectrum. The most intensive observations, obtained during a 36 hr continuous run in February 1988, show the presence of discrete absorption components (DACs) in the C IV 1550 resonance doublet. These DACs can blend to give the appearance of a well-developed P Cygni absorption profile seen at some other times, roughly doubling the column density of the ground state C(3+) ions in the wind. In the 1988 spectra, two principal features are seen, at about -950 km/s and -750 km/s, with column densities of about 14.0 and 14.7 dex/sq cm, respectively. Both features migrate in velocity with accelerations of about 140 cm/sq sec, implying a recurrence time scale of about 1.6 days and a lifetime of about 3 days for the DACs. A striking characteristic of the acceleration is its slowness. The pattern of DAC variability in HD 45166 is similar to that found for O-type stars and provides further evidence that the DACs are not mass-conserving features but rather that a given feature is formed by different material at different times. It is concluded that the C IV DAC variability observed in HD 45166 results from structural changes in the wind arising from radiative instabilities.

Willis, Allan J.↗

Color-coded global topographic map of Mars

A Digital Terrain Model (DTM) was derived with both Mercator and Sinusoidal Equal-area projections from the global topographic map of Mars at a scale of 1:15 million and a contour interval of 1 km. Elevations on the map are referred to the Mars topographic datum that is defined by the gravity field at a 6.1-millibar pressure surface with respect to the center of mass of Mars. The DTM has a resolution at the equator of 1/59.226 degrees (exactly 1 km) per pixel. By using the DTM, color-coded global maps of Mars' topography were generated in both the Mercator projection and the Sinusoidal Equal-Area projection. On both maps, colors indicate 1 km increments of height. From the equal-are dataset, the positive and negative elevation distributions are calculated to be 67 and 33 percent, respectively.

Wu, Sherman S. C.↗

Mars elevation distribution

A Digital Terrain Model (DTM) of Mars was derived with both Mercator and Sinusoidal Equal-Area projections from the global topographic map of Mars (scale 1:15 million, contour interval 1 km). Elevations on the map are referred to Mars' topographic datum that is defined by the gravity field at a 6.1-millibar pressure surface with respect to the center of mass of Mars. The DTM has a resolution at the equator of 1/59.226 degrees (exactly 1 km) per pixel. By using the DTM, the volumetric distribution of Mars topography above and below the datum has previously been calculated. Three types of elevation distributions of Mars' topography were calculated from the same DTM: (1) the frequency distribution of elevations at the pixel resolution; (2) average elevations in increments of 6 degrees in both longitude and latitude; and (3) average elevations in 36 separate blocks, each covering 30 degrees of latitude and 60 degrees of longitude.

Wu, Sherman S. C.↗

The quasi-periodic oscillations and very low frequency noise of Scorpius X-1 as transient chaos - A dripping handrail?

We present evidence that the quasi-periodic oscillations (QPO) and very low frequency noise (VLFN) characteristic of many accretion sources are different aspects of the same physical process. We analyzed a long, high time resolution EXOSAT observation of the low-mass X-ray binary (LMXB) Sco X-1. The X-ray luminosity varies stochastically on time scales from milliseconds to hours. The nature of this variability - as quantified with both power spectrum analysis and a new wavelet technique, the scalegram - agrees well with the dripping handrail accretion model, a simple dynamical system which exhibits transient chaos. In this model both the QPO and VLFN are produced by radiation from blobs with a wide size distribution, resulting from accretion and subsequent diffusion of hot gas, the density of which is limited by an unspecified instability to lie below a threshold.

Scargle, Jeffrey D.↗

On Al-26 and other short-lived interstellar radioactivity

Several authors have shown that massive stars exploding at a rate of about three per century can account for a large portion, if not all, of the observed interstellar Al-26. In a separate argument using models of Galactic chemical evolution, Clayton (1984) showed that the Al-26/Al-27 production ratio was not large enough to maintain enough Al-26 in the Galactic disk gas of about 10 exp 10 solar masses having solar composition. We present a resolution of those conflicting arguments. A past history of Galactic infall growing the Galactic disk so dilutes the stable Al-27 concentration that the two approaches can be brought into near agreement. If massive stars dominate the production of Al-26, we suggest that the apparent shortfall of their Al-26/Al-27 yield ratio is to be interpreted as evidence for significant growth of the Galactic disk. We also discuss the implications of these arguments for other extinct radioactivities in meteorites, using I-129 and Sm-146 as examples.

Clayton, Donald D.↗

Characterization of Metalorganic Chemical Vapor Deposition

A series of experimental and numerical investigations to develop a more complete understanding of the reactive fluid dynamics of chemical vapor deposition were conducted. In the experimental phases of the effort, a horizontal CVD reactor configuration was used for the growth of InP at UVA and for laser velocimetry measurements of the flow fields in the reactor at LaRC. This horizontal reactor configuration was developed for the growth of III-V semiconductors and has been used by our research group in the past to study the deposition of both GaAs and InP. While the ultimate resolution of many of the heat and mass transport issues will require access to a reduced-gravity environment, the series of groundbased research makes direct contributions to this area while attempting to answer the design questions for future experiments of how low must gravity be reduced and for how long must this gravity level be maintained to make the necessary measurements. It is hoped that the terrestrial experiments will be useful for the design of future microgravity experiments which likely will be designed to employ a core set of measurements for applications in the microgravity environment such as HOLOC, the Fluid Physics/Dynamics Facility, or the Schlieren photography, the Laser Imaging Velocimetry and the Laser Doppler Velocimetry instruments under development for the Advanced Fluids Experiment Module.

Jesser, W. A.↗