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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Effects of Coating on the Electrochemical Performance of a Nickel-Rich Cathode Active Material

Due to their safety and high power density, one of the most promising types of all-solid-state lithium batteries is the one made with the argyrodite solid electrolyte (ASE). Although substantial efforts have been made toward the commercialization of this battery, it is still challenged by some technical issues. One of these issues is to prevent the side reactions at the interface of the ASE and the cathode active material (CAM). A solution to address this issue is to coat the CAM particles with a material that is compatible with both ASE and CAM. Prior studies show that the lithium niobate, LiNbO 3 , (LNO) is a promising material for coating CAM particles to reduce the interfacial side reactions. However, no systematic study is available in the literature to show the effect of coating LNO on CAM performance. This paper aims to quantify the effect of LNO coating on the electrochemical performance of a nickel-rich CAM. The electrochemical performance parameters that are studied are the capacity, cycling performance, and rate performance of the coated-CAM; and the effectiveness of the coating to prevent the side reactions at the ASE and CAM interface is out of the scope of this study. To eliminate the effect of side reactions at the ASE and CAM interface, we conduct all tests in the organic liquid electrolyte (OLE) cells to solely present the effect of coating on the CAM performance. For this purpose, 0.5 wt.% and 1 wt.% LNO are used to coat the LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC-60) CAM through two synthesizing methods. Consequently, the effects of the synthesizing method and the coating weight percentage on the NMC-60 performance are presented.

10 SYNTHETIC FUELS↗

Noncured Graphene Thermal Interface Materials for High-Power Electronics: Minimizing the Thermal Contact Resistance

We report on experimental investigation of thermal contact resistance, RC, of the noncuring graphene thermal interface materials with the surfaces characterized by different degree of roughness, Sq. It is found that the thermal contact resistance depends on the graphene loading, ξ, non-monotonically, achieving its minimum at the loading fraction of ξ ~15 wt%. Decreasing the surface roughness by Sq~1 μm results in approximately the factor of ×2 decrease in the thermal contact resistance for this graphene loading. The obtained dependences of the thermal conductivity, KTIM, thermal contact resistance, RC, and the total thermal resistance of the thermal interface material layer on ξ and Sq can be utilized for optimization of the loading fraction of graphene for specific materials and roughness of the connecting surfaces. Our results are important for the thermal management of high-power-density electronics implemented with diamond and other wide-band-gap semiconductors.

36 MATERIALS SCIENCE↗

Knock Mitigation Effectiveness of EGR across the Pressure-Temperature Domain

Exhaust gas recirculation (EGR) has been shown to enable efficiency improvements in SI engines through multiple different mechanisms, including decreasing the knock propensity at high load, which allows higher compression ratio. While many of the benefits of EGR are applicable to both low and high power density engines, including reductions in pumping work and improved specific heat ratio, the knock benefits and corresponding compression ratio increases have been limited to low power density naturally aspirated engines primarily intended for hybrid vehicle architectures. An earlier study [1] indicated that there may be a kinetic limitation for the ability of EGR to mitigate knock under these conditions, but that study only considered a small number of conditions. In this investigation, we expand on that study while also providing data for model validation for the new light-duty combustion consortium from the U.S. Department of Energy: Partnership for Advancing Combustion Engines (PACE). In this investigation, the effectiveness of EGR to mitigate knock is studied with regards to the effect of engine speed (1,500 and 3,000 rpm), changing trajectory in the pressure-temperature domain by varying the intake manifold temperature (35, 60, and 90 deg C), and by considering the effect of minor species by studying the effect of untreated EGR vs. EGR that has been treated by an automotive three-way catalyst. Additionally, to increase the relevance of these data for future modeling studies, the performance of the full boiling range gasoline was compared relative to a surrogate formulation. The study found that the fuel surrogate performs well, confirmed the kinetic limitations of EGR to mitigate knock under boost, and showed improvements in EGR performance with catalyzed EGR.

42 ENGINEERING↗

Development of a carbon cloth heat post module for thermal vacuum testing of a spinning spacecraft

Development of a high temperature, high power density, isothermal, rapid transient, infrared thermal module is described. The investigation of various alternative approaches is discussed, as well as the rationale leading to the choice of a carbon cloth concept. Evolution of module design configurations and a summary of the development test results are included, along with a detailed description of the final design, which incorporated a black plate emitter radiantly heated by the carbon cloth. The final module configuration met design criteria during a 200-hour thermal vacuum performance test at 1000 F operating temperature without contaminating a solar cell array.

Levine, M. B.↗

Study, selection, and preparation of solid cationic conductors

Crystal chemical principles and transport theory were used to predict structures and specific compounds which might find application as solid electrolytes in rechargeable high energy and high power density batteries operating at temperatures less than 200 C. More than twenty compounds were synthesized or obtained and screened by nuclear magnetic resonance and conductivity. Many were densified by sintering or hot pressing. Encouraging results were obtained for nine of these materials but none have yet been good ionic conductors at low temperature.

Roth, W. L.↗

Study, selection, and preparation of solid cationic conductors

Crystal chemical principles and transport theory have been used to predict structures and specific compounds which might find application as solid electrolytes in rechargeable high energy and high power density batteries operating at temperatures less than 200 C. Structures with 1-, 2-, and 3-dimensional channels were synthesized and screened by nuclear magnetic resonance, dielectric loss, and conductivity. There is significant conductivity at room temperature in some of the materials but none attain a level that is comparable to beta-alumina. Microwave and fast pulse methods were developed to measure conductivity in powders and in small crystals.

Roth, W. L.↗

Dual membrane hollow fiber fuel cell and method of operating same

A gaseous fuel cell is described which includes a pair of electrodes formed by open-ended, ion-exchange hollow fibers, each having a layer of metal catalyst deposited on the inner surface and large surface area current collectors such as braided metal mesh in contact with the metal catalyst layer. A fuel cell results when the electrodes are immersed in electrolytes and electrically connected. As hydrogen and oxygen flow through the bore of the fibers, oxidation and reduction reactions develop an electrical potential. Since the hollow fiber configuration provides large electrode area per unit volume and intimate contact between fuel and oxidizer at the interface, and due to the low internal resistance of the electrolyte, high power densities can be obtained.

Ingham, J. D.↗

Research on radiation induced laser plasmas

The development of high power nuclear pumped lasers is discussed. The excitation mechanism of continuous wave (CW) HeNe nuclear pumped lasers is studied and a CO2 nuclear pumped laser is used to demonstrate the CW output in the order of watts. The assumption that high power densities are only achievable by volume fission fragment sources is used to identify laser gases which are compatible with UF6 by excited states lifetime measurements. The examination of Xe2, XeF, and KrF under nuclear irradiation to determine if they are good candidates for nuclear-pumped lasers is described.

Schneider, R. T.↗

Potentialities of TEC topping: A simplified view of parametric effects

An examination of the benefits of thermionic-energy-conversion (TEC)-topped power plants and methods of increasing conversion efficiency are discussed. Reductions in the cost of TEC modules yield direct decreases in the cost of electricity (COE) from TEC-topped central station power plants. Simplified COE, overall-efficiency charts presented illustrate this trend. Additional capital-cost diminution results from designing more compact furnaces with considerably increased heat transfer rates allowable and desirable for high temperature TEC and heat pipes. Such improvements can evolve of the protection from hot corrosion and slag as well as the thermal expansion compatibilities offered by silicon-carbide clads on TEC-heating surfaces. Greater efficiencies and far fewer modules are possible with high-temperature, high-power-density TEC: This decreases capital and fuel costs much more and substantially increases electric power outputs for fixed fuel inputs. In addition to more electricity, less pollution, and lower costs, TEC topping used directly in coal-combustion products contributes balance-of-payment gains.

Morris, J. F.↗

Goals of thermionic program for space power

The considered investigation has the two objectives to assess the feasibility of operating a Brayton power-generating system at 1500 K and to explore the manner in which changing goals for the thermionic program may have resulted in the rise in specific mass that has been observed. Concerning the first objective, it is pointed out that to date no components have been built and evaluated for use in a Brayton space-power system to operate at 1500 K. On the other hand, the principles in design were successfully demonstrated at 1150 K with materials appropriate to that temperature. Long-time creep data for both the tantalum alloy ASTAR-811 C and the molybdenum alloy TZM support the performance predictions made by Harper (1979) with respect to a Brayton system providing a specific mass value of 21 kg/kWe at 1500 K. For the thermionics program, it is recommended to conduct an investigation of the original goals of high emitter temperature (1800-2000 K) and high power density.

English, R. E.↗

Laser power beaming for rocket propulsion and airbreathing propulsion

The developing technology of laser power beaming is introduced, and two systems are used as examples of the capabilities of the laser for beamed energy. In the first system, the potential of the laser to power flight systems ranging from hypersonic air-breathing launch vehicles to commercial jet transports is examined. Attention is given to the possibility of an air-breathing propulsion which offers the promise of a global air transportation network independent of kerosene and powered by solar energy. In addition, consideration is given to a new type of rocket propulsion based on the laser's ability to concentrate coherent laser energy to high power densities. Focused laser beams would heat the propellants directly to produce specific impulses approaching ion and MHD rocket levels, and would do so without the burden of a heavy electrical power supply.

Hertzberg, A.↗

Preliminary Investigation of Cyclic De-Icing of an Airfoil Using an External Electric Heater

An investigation was conducted in the NACA Lewis icing research tunnel to determine the characteristics and requirements of cyclic deicing of a 65,2-216 airfoil by use of an external electric heater. The present investigation was limited to an airspeed of 175 miles per hour. Data are presented to show the effects of variations in heat-on and heat-off periods, ambient air temperature, liquid-water content, angle of attack, and. heating distribution on the requirements for cyclic deicing. The external heat flow at various icing and heating conditions is also presented. A continuously heated parting strip at the airfoil leading edge was found necessary for quick, complete, and consistent ice removal. The cyclic power requirements were found to be primarily a function of the datum temperature and heat-on time, with the other operating and meteorological variables having a second-order effect. Short heat-on periods and high power densities resulted in the most efficient ice removal, the minimum energy input, and the minimum runback ice formations. The optimum chordwise heating distribution pattern was found to consist of a uniform distribution of cycled power density in the impingement region. Downstream of the impingement region the power density decreased to the limits of heating which, for the conditions investigated, extended from 5.7 percent chord on the upper surface of the airfoil to 8.9 percent chord on the lower surface. Ice removal did not take place at a heater surface temperature of 32 F; surface temperatures of approximately 50 to 100 F were required to effect removal. Better de-icing performance and greater energy savings would be possible with a heater having a higher thermal efficiency.

Lewis, James P.↗

Modified reference SPS with solid state transmitting antenna

The motivations for considering solid state microwave power amplifiers for the solar power satellite transmitting antenna are the possibilities of greatly increased system reliability due to elimination of electron tube cathodes, a lower mass per unit power and transmitting array area due to the high power densities obtainable in semiconductors, and, probably, cost savings due to development of small hardware items that can be handled by individuals instead of organizations. In order to provide a fair assessment where we stand today with regard to solid state SPS technology, the design described here is close to that of the NASA/DOE reference and is implemented using today's solid state technology with only a small "push". The small push is raising the efficiency of DC-RF conversion from the .68 obtained by RCA in 1975 to somewhat over .8 of the solid state SPS. This is generally considered feasible by semiconductor industry representatives. Other solid state SPS configurations can yield somewhat better performance. However, these generally do not provide as fair a vehicle for comparison with the reference and usually also incorporate somewhat more advanced technologies.

Woodcock, G. R.↗

Meteorological effects on laser propagation for power transmission

An examination of possible laser operating parameters for power transmission to earth from solar power satellites is presented, with particular attention paid to assuring optimal delivery at midlatitudes. The degradation of beam efficiency due to molecular scattering, molecular absorption, aerosol scattering, and aerosol absorption during beam propagation through the atmosphere can be alleviated by judicious choice of wavelength windows, elevating the receptor sites, using a vertical propagation path, or by hole boring, i.e., vaporizing the aerosol particles in the beam path. Analyses are given for the beam propagation through fog, haze, clouds, and snow using various transitions. Only weapons-quality lasers are seen as being capable of boring through clouds and aerosols, employing a CW beam with superimposed pulses at high power densities. It is concluded that further short wavelength transmission experiments be performed to demonstrate transmission feasibility with the CW/pulsed mode of beam propagation.

Beverly, R. E., III↗

Method and apparatus for coating substrates using a laser

Metal substrates, preferably of titanium and titanium alloys, are coated by alloying or forming TiN on a substrate surface. A laser beam strikes the surface of a moving substrate in the presence of purified nitrogen gas. A small area of the substrate surface is quickly heated without melting. This heated area reacts with the nitrogen to form a solid solution. The alloying or formation of TiN occurs by diffusion of nitrogen into the titanium. Only the surface layer of the substrate is heated because of the high power density of the laser beam and short exposure time. The bulk of the substrate is not affected, and melting of the substrate is avoided because it would be detrimental.

Zaplatynsky, I.↗

NASA electrothermal auxiliary propulsion technology

Electrothermal auxiliary propulsion systems provide high performance options which can have major mission benefits. There are several electrothermal concepts which offer a range of characteristics and benefits. Resistojets are the highest thrust to power option and are currently operational at mission average values of specific impulse, I sub sp approximately 295 sec. Long life, multipropellant resistojets are being developed for the space station, and resistojet technology advancements are being pursued to improve the I sub sp by more than 20 percent for resistojets used in satellite applications. Direct current arcjets have the potential of I sub sp over 400 sec with storable propellants and should provide over 1000 sec with hydrogen. Advanced concepts are being investigated to provide high power density options and possible growth to primary propulsion applications. Broad based experimental and analytical research and technology programs of NASA are summarized and recent significant advances are reviewed.

Stone, J. R.↗

Preliminary evaluation of a compound cycle engine for shipboard gensets

The results of a thermodynamic cycle (SFC) and weight analysis performed to establish engine configuration, size, weight and performance are reported. Baseline design configuration was a 2,000 hour MTBO Compound Cycle Engine (CCE) for a helicopter application. The CCE configuration was extrapolated out to a 10,000 MTBO for a shipboard genset application. The study showed that an advanced diesel engine design (CCE) could be substantially lighter and smaller (79% and 82% respectively) than todays contemporary genset diesel engine. Although the CCE was not optimized, it had about a 7% reduction in mission fuel consumption over today's genset diesels. The CCE is a turbocharged, power-compounded, high power density, low-compression ratio diesel engine. Major technology development areas are presented.

Castor, J. G.↗

A tandem mirror plasma source for a hybrid plume plasma propulsion concept

This paper describes a tandem mirror magnetic plasma confinement device to be considered as a hot plasma source for the hybrid plume rocket concept. The hot plasma from this device is injected into an exhaust duct, which will interact with an annular layer of hypersonic neutral gas. Such a device can be used to study the dynamics of the hybrid plume and to experimentally verify the numerical predictions obtained with computer codes. The basic system design is also geared toward being lightweight and compact, as well as having high power density (i.e., several kW/sq cm) at the exhaust. This feature is aimed toward the feasibility of 'space testing'. The plasma is heated by microwaves. A 50 percent heating efficiency can be obtained by using two half-circle antennas. The preliminary Monte Carlo modeling of test particles result reported here indicates that interaction does take place in the exhaust duct. Neutrals gain energy from the ion, which confirms the hybrid plume concept.

Yang, T. F.↗