Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “GAS DISCHARGE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Divertor detachment characterization in negative triangularity discharges in DIII-D via 2D edge-plasma transport modeling

Edge fluid modeling of the first divertor-plasma detachment experiments in negative triangularity (NT) discharges in the DIII-D tokamak is presented using the 2D multifluid edge transport code UEDGE, including cross-field particle drifts. Experiments were performed where the lower single-null magnetic equilibrium had a strong NT (δ≈−0.5), that is, where the magnetic X-point is at a larger major radius than the core magnetic axis. Divertor-plasma detachment was induced by increasing the core plasma density in DIII-D via intrinsic gas puffing. Here density scans are performed with UEDGE to reach a detached plasma and to quantitatively recover the experimental rollover of the ion saturation current on the outer divertor target plate. The simulations cover experiments with both signs of the toroidal magnetic field, B T , where the ion magnetic Grad-B drifts are directed into (forward B T ) and out of (reverse B T ) the divertor region. Consistent with experiments with neutral beam power injection, the NT simulations reproduce: 40% higher density is needed to reach detachment onset with forward B T compared with reverse B T , and the absence of deep detachment is found with reverse B T . Similarly, comparison between Ohmic discharges in NT and positive triangularity (PT) shaping confirms that a substantially higher density is needed to achieve detachment in NT than in PT, with NT requiring an line-average density of at least the Greenwald density or higher. Simulation results suggest that higher densities are needed to reach detachment in negative compared to PT because these discharges have a shorter midplane-to-target distance along the total magnetic field B, a shorter outer divertor poloidal leg length (0.06 m vs 0.2 m), and reduced radial transport [near-scrape-off layer (SOL) D ⊥ /χ ⊥ =0.3/0.5 vs D ⊥ /χ ⊥ =1.0/1.0, all in (m 2 /s)].

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Electrical breakdown dynamics in an argon bubble submerged in conductive liquid for nanosecond pulsed discharges

Abstract This study delves into the dynamics of cold atmospheric plasma and their interaction within conductive solutions under the unique conditions of nanosecond pulsed discharges (22 kV peak voltage, 10 ns FWHM, 4.5 kV ns −1 rate-of-rise). The research focuses on the electrical response, breakdown, and discharge propagation in an argon bubble, submerged in a NaCl solution of varying conductivity. Full or partial discharges were observed at conductivities of 1.5 µ S cm −1 (deionized water) to 1.6 mS cm −1 , but no breakdown was observed at 11.0 mS cm −1 when reducing the electrode gap. It is demonstrated that at higher conductivity electric breakdown is observed only when the gas bubble comes into direct contact with the electrode and multiple emission nodes were observed at different timescales. These nodes expanded in the central region of the bubble over timescales longer than the initial high-voltage pulse. This work offers a temporal resolution of 2 ns exposure times over the first 30 ns of the initial voltage pulse, and insight into plasma formation over decaying reflected voltage oscillations over 200 ns.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Overview of physics results from the ADITYA-U tokamak and future experiments

The ADITYA upgrade (ADITYA-U), a medium-sized (R 0 = 75 cm, a = 25 cm) conventional tokamak facility in India, has been consistently producing experiments findings by usingcircular and shaped-plasmas. Recognizing the plasma parameters aligning closely with the design parameters of circular limited plasmas, ADITYA-U shifted its focus toward exploring the operational regime for experimentation on saw-tooth and MHD phenomena. Moreover, ADITYA-U has made consistent advancements toward conducting preliminary plasma shaping experiments through the activation of top and bottom divertor coils utilizing hydrogen as well as deuterium fuels. Confinement is improved by a factor of ~1.5 in D 2 plasmas when compared to H 2 plasmas of ADITYA-U. Further, ADITYA-U operations emphasize preventing disruptions and runaway electrons (REs) to ensure safe operations for future fusion devices. Significant suppression of REs has been achieved in ADITYA-U with the application of pulsed localized vertical magnetic field (LVF) perturbation, thereby establishing the technique's independence from the tokamak device. The successful RE mitigation requires a critical threshold of LVF pulse magnitude, which is approximately 1% of the toroidal magnetic field, and a minimum duration of ~5 ms. Apart from this, several novel findings have been achieved in the ADITYA-U experiments, including the modification of sawtooth duration through gas-puff, the emergence of MHD-induced geodesic acoustic mode-like oscillations, the propagation of fast heat pulses induced by MHD activity, the control of RE dynamics through Gas-puffs, the propagation of pinch-driven cold-pulses, the transport and core accumulations of argon impurities, the mass dependency of plasma toroidal rotation and the detection of 'RICE' scaling, as well as the characterization of edge plasma using wall conditioning methods, such as glow discharge cleaning using a combination of Ar-H 2 mixture, localized wall cleaning by electron cyclotron resonant plasma, and the development of machine learning-based disruption predictions, will be discussed in this paper.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Rapid depletion analysis of flowing-pebble reactor systems at equilibrium using SCALE

Several high-temperature gas-cooled reactor concepts (and more recently, salt-cooled designs such as the fluoride salt-cooled high-temperature reactor) feature core designs employing continuously circulating fuel pebbles. These reactor designs permit both continuous online refueling of fuel elements as well as higher overall achievable discharge burnups. However, rapid calculation of time-dependent fuel isotopic inventories proves challenging for this class of dynamic systems with current analysis tools. While iterative approaches employing coupled neutron transport have been developed to solve this issue, rapid depletion analysis techniques are needed to calculate time-dependent inventories for individual pebbles and batches (and thus the construction of full- core inventory at equilibrium). We propose a depletion analysis strategy for this type of system for cores at equilibrium. Drawing upon previous neutronic analysis of the PBMR-400 equilibrium core, we demonstrate the viability of developing collapsed one-group cross section libraries suitable for performing rapid depletion analyses with SCALE. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2022

Design Considerations for the Implementation of a High-Field-Side Transient CHI System on QUEST

Transient coaxial helicity injection (T-CHI), a method first developed on the small helicity injected torus (HIT-II) experiment and then validated on the much larger National Spherical Torus Experiment (NSTX) device, is a method to initiate an inductive-like tokamak plasma discharge without reliance on the central solenoid. A CHI discharge is initiated by driving current along magnetic flux that connects the inner and outer divertor plates on one end of the tokamak. To permit this, on both HIT-II and NSTX, toroidal ceramic insulators were used to electrically separate the inner and outer vessel components. The use of such large toroidal vacuum insulators may not be easy to implement in reactors. To address this issue, the Q-shu University experiments with steady-state spherical tokamak (ST) (QUEST) is developing a reactor-relevant CHI configuration in which one of the divertor plates is electrically insulated from the rest of the vessel. The first application of T-CHI on QUEST biased the CHI electrode to the outer vessel. While the CHI discharges could be easily generated, it was found that as the discharge filled the vessel, the separation distance between the injector magnetic flux footprints widened, a condition that is not favorable for the generation of closed flux surfaces. Biasing the electrode to the inner wall is a configuration similar to that used on NSTX and HIT-II, but initial testing in this configuration has proved to be challenging. The design described here overcomes the present limitation by locating the CHI electrode much closer to the CHI injector flux coil and using an NSTX-like gas injection manifold to enable high-field-side T-CHI startup on QUEST. Finally, the concepts described in this article should also benefit the future implementation of T-CHI systems in other tokamaks and spherical tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

A surface mechanism for O 3 production with N 2 addition in dielectric barrier discharges

Ozone, O 3 , is a strong oxidizing agent often used for water purification. O 3 is typically produced in dielectric barrier discharges (DBDs) by electron-impact dissociation of O 2 , followed by three-body association reactions between O and O 2 . Previous studies on O 3 formation in low-temperature plasma DBDs have shown that O 3 concentrations can drop to nearly zero after continued operation, termed the ozone-zero phenomenon (OZP). Including small (<4%) admixtures of N 2 can suppress this phenomenon and increase the O 3 production relative to using pure O 2 in spite of power deposition being diverted from O 2 to N 2 and the production of nitrogen oxides, N x O y . The OZP is hypothesized to occur because O 3 is destroyed on the surfaces in contact with the plasma. Including N 2 in the gas mixture enables N atoms to occupy surface sites that would otherwise participate in O 3 destruction. The effect of N 2 in ozone-producing DBDs was computationally investigated using a global plasma chemistry model. A general surface reaction mechanism is proposed to explain the increase in O 3 production with N 2 admixtures. The mechanism includes O 3 formation and destruction on the surfaces, adsorption and recombination of O and N, desorption of O 2 and N 2 , and NO x reactions. Without these reactions on the surface, the density of O 3 monotonically decreases with increasing N 2 admixture due to power absorption by N 2 leading to the formation of nitrogen oxides. With N-based surface chemistry, the concentrations of O 3 are maximum with a few tenths of percent of N 2 depending on the O 3 destruction probability on the surface. The consequences of the surface chemistry on ozone production are less than the effect of gas temperature without surface processes. An increase in the O 3 density with N-based surface chemistry occurs when the surface destruction probability of O 3 or the surface roughness was decreased.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Plasma-assisted catalysis for ammonia synthesis in a dielectric barrier discharge reactor: key surface reaction steps and potential causes of low energy yield

Ammonia synthesis experiments were carried out in a coaxial dielectric barrier discharge (DBD) reactor packed with several different supports and metal catalysts. There was a marked increase in the reaction rate, over that obtained in an empty DBD plasma reactor, upon introduction of a packed bed of γ-Al 2 O 3 , Ru/γ-Al 2 O 3 , or SiO 2 particles. The difference in the reaction rates over γ-Al 2 O 3 and Ru/γ-Al 2 O 3 was minimal. Complementary zero-dimensional plasma kinetic model analysis was also performed using inputs from experimental data. This kinetic analysis allowed for gas phase reactions, Eley–Rideal (E–R) reactions, and direct adsorption of radical species on the γ-Al 2 O 3 surface. On the metal surface, dissociative adsorption of N 2 and H 2 , and Langmuir–Hinshelwood reactions were also included. This analysis revealed that, under the conditions of our experiments, ammonia synthesis proceeds principally by the formation of reactive radicals in the gas phase, which then adsorb and participate in E–R reactions on both the metal and support material surfaces. Furthermore, this finding illustrates a challenge for substantially increasing the energy yield for plasma-assisted ammonia synthesis in typical DBD reactors containing packed catalyst beads.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Impact of reverse flow induced by a sawtooth anode on the performance of an argon Hall thruster

This study reports the performance comparison of the RAIJIN-66 TAL-type Hall thruster with argon propellant, using two hollow anode designs, one with a simple straight shape and another one with a sawtooth shape. Simulations of the rarefied gas in the sawtooth hollow anode region suggest a successful reversal of the direction of neutral particle flow, with an average increase in the neutral particle density by 15.5% when compared to the straight-shaped hollow anode. This contributes to the improvement in performance across a range of discharge voltages that was measured experimentally. When the thruster is operated with a discharge voltage of 150 V and a flow rate of 70 SCCM, the propellant utilization efficiency with the straight anode is 14%, while with the sawtooth anode it is 25.1%. The anode efficiency reaches in the vicinity of 15% with the sawtooth anode in high voltage conditions, exceeding the efficiencies achieved with the straight anode in the same operating conditions. The optimal magnetic field condition for argon operation and the tuning parameters of the sawtooth anode design for RAIJIN-66 are also discussed.

Satpathy, Dibyesh [Univ. of Tokyo (Japan)] (ORCID:↗
DOE OSTI2023

HCOO - aq Degradation in Droplets by OH aq in an Atmospheric Pressure Glow Discharge

Plasmas in contact with liquids can degrade organic molecules in solution, as reactive oxygen and nitrogen species produced in the plasma solvate into the liquid. Immersing small droplets (tens of microns in diameter) in the plasma can more rapidly activate the liquid compared to treating a large volume of liquid with a smaller surface-to-volume ratio. The interactions between a radio frequency glow discharge sustained in He/H 2 O and a water droplet containing formate (HCOO - aq ) immersed in and flowing through the plasma were modeled using a 0-dimensional global plasma chemistry model to investigate these activation processes. HCOO - aq interacts with OH aq , produced from solvation of OH from the gas phase. HCOO - aq concentrations were benchmarked with previously reported experimental measurements. The diameter of the droplet, initial HCOO - aq concentration, and gas flow rate affect only the HCOO - aq concentration and OH aq density, leaving the OH density in the gas phase unaffected. Power deposition and gas mixture (e.g., percentage of H 2 O) change both the gas and liquid phase chemistry. A general trend was observed – during the first portion of droplet exposure to the plasma, OH aq primarily consumes HCOO - aq . However, O2 - aq , a byproduct of HCOO - aq consumption, consumes OH aq once O2 - aq reaches a critically large density. Using HCOO - aq as a surrogate for OH aq sensitive contaminants, combinations of residence time, droplet diameter, water vapor density, and power will determine the optimum remediation strategy.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Physics-Informed Deep Learning-Based Proof-of-Concept Study of a Novel Elastohydrodynamic Seal for Supercritical CO 2 Turbomachinery

Supercritical carbon dioxide (sCO 2 ) power cycles show promising potential of higher plant efficiencies and power densities for a wide range of power generation applications such as fossil fuel power plants, nuclear power production, solar power, and geothermal power generation. sCO 2 leakage through the turbomachinery has been one of the main concerns in such applications. To offer a potential solution, we propose an elastohydrodynamic (EHD) seal that can work at elevated pressures and temperatures with low leakage and minimal wear. The EHD seal has a very simple, sleeve-like structure, wrapping on the rotor with minimal initial clearance at micron levels. Here, in this work, a proof-of-concept study for the proposed EHD seal was presented by using the simplified Reynolds equation and Lame’s formula for the fluid flow in the clearance and for seal deformation, respectively. The set of nonlinear equations was solved by using both the conventional Prediction–Correction (PC) method and modern Physics-Informed Neural Network (PINN). It was shown that the physics-informed deep learning method provided good computational efficiency in resolving the steep pressure gradient in the clearance with good accuracy. The results showed that the leakage rates increased quadratically with working pressures and reached a steady-state at high-pressure values of 15~20 MPa, where Q = 300 g/s at 20 MPa for an initial seal clearance of 255 μm. This indicates that the EHD seal could be tailored to become a potential solution to minimize the sCO 2 discharge in power plants.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2020

Fluorination effect for stabilizing cationic and anionic redox activities in cation-disordered cathode materials

We see that cation-disordered Li-excess cathodes with oxygen redox reactions are promising candidates for high-energy-density Li ion batteries. Nevertheless, the oxygen redox process that is required for the high capacity often comes with the oxygen loss, which leads to severe capacity degradation and voltage decay. In this work, we have successfully synthesized a series of Li-excess cation-disordered cathodes (Li 1.2 Mn 0.4+x Ti 0.4-x O 2-x Fx) (0 ≤ x ≤ 0.2) with different fluorine (F) contents. The electrochemical performance results show that the Li 1.2 Mn 0.55 Ti 0.25 O 1.85 F 0.15 (LMTOF0.15) exhibits the highest reversible capacity (275 mAh g -1 , under 30 mA g -1 ), cyclability, and voltage retentions. The mapping of resonant inelastic X-ray scattering (mRIXS) and differential electrochemical mass spectroscopy (DEMS) results reveal that the fluorination enhances the reversible lattice oxygen redox reaction while suppressing irreversible gas release and surface reactions. The X-ray Absorption Spectroscopy (XAS) during the initial two cycles shows that F-substitution alleviates the reduction of the Mn valence state during the whole (dis)charge processes in the bulk and at the surface of the material, results in higher average discharge voltage. In addition, the introduction of F improves the structural stability and suppresses local lattice distortion of the material. Therefore, LMTOF 0.15 is able to cycle with smaller polarization, less interfacial side reaction and Mn dissolution, and therefore results in enhanced cyclability. This work provides a comprehensive understanding of the fluorination effect on the cationic and anionic redox activities in cation-disordered Li-excess cathodes.

25 ENERGY STORAGE↗
DOE OSTI2022

Collaborative Research: Unravelling the Physics Associated with the Production of Extremely Dense Plasma States of Microscale (Final Report) Nanosecond-pulsed Discharges

The aim of this project is to study and establish the physical mechanisms that contribute to the formation of anomalously dense plasmas in high-pressure nanosecond-pulsed discharges. These discharges have a broad range of applications such as plasma-assisted combustion, plasma flow actuators, biomedical sterilization and exotic materials synthesis. The structure and formation of these discharges, producing high plasma densities of ~10 14 -10 15 cm -3 , are well-studied and understood. Fast-pulsed microscale high-pressure discharges can be driven to even higher densities of > 10 19 cm -3 , approaching warm dense matter conditions. The mechanisms that generate these plasmas have not been understood. Analysis of the warm dense matter state under laboratory conditions is an expensive and non-trivial endeavor. For instance, dense plasmas can be generated by electrical explosions of metal foils and wires. Plasmas generated after the explosion have a short lifetime and often present difficult conditions for diagnostics. Generation of dense plasmas was also achieved during high-voltage nanosecond pulsed discharges when the so-called explosive electron emission is obtained. Unfortunately, this process is very difficult to control for the studies of warm dense matter. In our recent study, we have shown that additional heating of plasma by lasers can further increase the density of plasma and even lead to the fully ionized state. This method, potentially, allows better control of the plasma parameters. In this work, we studied a second stage laser-heated micro-discharge using a self-consistent one-dimensional particle-in-cell Monte Carlo-collision (1D PIC-MCC) model coupled with Maxwell’s equations. We predicted the generation of a fully ionized plasma on the picosecond time scale. However, this model considered the plasma as an ideal gas despite the high pressure and the nearly fully ionized state. The ideal plasma model assumes that the dilute gas approximation is valid, where the inter-particle interactions are negligible. For charged particles this assumption holds as long as the shielded Coulomb potential assumption is valid. For very high plasma densities, this concept breaks down since the Debye sphere surrounding each charged particle no longer contains enough electrons to statistically provide the shielding of the single particle Coulomb interaction potential. At such densities, the plasma can no longer be described as ideal and non-ideal coupling effects need to be considered. In this report, we elucidate our recent work of developing a PIC-MCC model with improvements for non-ideal plasma conditions due to Coulomb coupling at high densities. In particular, we study the interaction of green light radiation and a dense microplasma, and explore the non-ideal plasma effects in this interaction. In this computational model, we implement the two most important non-ideal effects: ionization potential depression (IPD) and enhanced collision cross sections. Our primary goal is to study the physics associated with electromagnetic (EM) wave heating, also called the second-stage wave-heating, and establish the role of plasma non-ideality in this phenomenon. Our secondary goal is to improve the chemistry mechanism of the 1D PIC-MCC model by including a more detailed excited species collision treatment. At high pressures, stepwise ionization from excited species might play an important role in the ionization process. Previously, this ionization mechanism was neglected due to the excitation collision cross section of xenon being smaller than that of ionization. However, a preliminary study showed that the excited species density in the initial microplasma was an order of magnitude higher than the electron density. Therefore, my aim is to determine the significance of this additional ionization pathway to the plasma generation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

First operation of a multi-channel Q-Pix prototype: measuring transverse electron diffusion in a gas time projection chamber

We report measurements of the transverse diffusion of electrons in P-10 gas (90% Ar, 10% CH 4 ) in a laboratory-scale time projection chamber (TPC) utilizing a novel pixelated signal capture and digitization technique known as Q-Pix. The Q-Pix method incorporates a precision switched integrating transimpedance amplifier whose output is compared to a threshold voltage. Upon reaching the threshold, a comparator sends a 'reset' signal, initiating a discharge of the integrating capacitor. The time difference between successive resets is inversely proportional to the average current at the pixel in that time interval, and the number of resets is directly proportional to the total collected charge. We developed a 16-channel Q-Pix prototype fabricated from commercial off-the-shelf components and coupled them to 16 concentric annular anode electrodes to measure the spatial extent of the electron swarm that reaches the anode after drifting through the uniform field of the TPC. The swarm is produced at a gold photocathode using pulsed UV light. The measured transverse diffusion agrees with simulations in PyBoltz across a range of operating pressures (200–1500 Torr). These results demonstrate that a Q-Pix readout can successfully reconstruct the ionization topology in a TPC.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Advances and challenges in KSTAR plasma control toward long-pulse, high-performance experiments

An overview of advances and progress on the KSTAR plasma control improvement is given. The enhancement of the KSTAR plasma control system (PCS) continues in order to enable implementations of more sophisticated control algorithms and capabilities of integrated controls on magnets, gas, heating and off-normal event handling. Features and functionalities on the generic magnetic controls, kinetic controls and new fault scheme design are added for the operation space expansion, mainly regarding recent achievements of higher plasma current up to 1.0–1.2MA, high-performance long pulse up to 90s, and discharges relevant to ITER. Technical challenges and prospective upgrades in the near future are described.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

Removal of Calcium and Silica from Simulated Blowdown Water Using CO 2 -Assisted Magnesium Electrocoagulation

Blowdown water from various industries and cooling facilities contains high concentrations of calcium (Ca), magnesium (Mg), silica, and corrosion inhibitors, which render the water unsuitable for discharge into surface water and wastewater treatment plants. Electrocoagulation (EC) is effective at removing Ca and silica. Here, in this study, Mg-alloy electrodes EC resulted in ∼91% silica removal at a 5400 C/L charge loading. Ca removal, however, was only 31%. To enhance Ca removal, carbon dioxide (CO 2 ) containing gas was introduced. CO 2 addition formed carbonate ions, which reacted with Ca/Mg ions to generate carbonate precipitates. Introducing 5% and 14% CO 2 , simulating natural gas-fired and coal-fired flue gas, enhanced Ca removal to 38% and 47%, respectively. Pure CO 2 facilitated 70% Ca removal, more than two times higher than that without CO 2 , while maintaining high silica removal. FTIR, XRD, and SEM-EDS analyses confirmed enhanced Ca/Mg carbonate formation upon CO 2 . In situ Raman spectroscopy was employed to monitor carbonate-ions formation. The results demonstrated carbonate-ions removal through Ca-carbonate formation after CO 2 addition. A techno-economic assessment showed that recycled electrode materials and flue gas lead to ∼3 times lower cost compared with conventional silica/Ca removal through chemical coagulation, softening, or membrane filtration. The study demonstrated that CO 2 addition removes high concentrations of Ca and silica ions from wastewaters at a competitive cost.

blowdown water↗
DOE OSTI2021

Assessing Global Ocean Circulation Sensitivity to Changes in Antarctic Ice Discharge

The principal goal of this research is to assess how projected increases in meltwater discharge and iceberg calving from the Antarctic Ice Sheet will impact climate in the next 250 years. In short, the sensitivity of the global ocean circulation and climate, and in particular the Atlantic Meridional Overturning Circulation (AMOC), to large increases in iceberg calving and meltwater discharges to the Southern Ocean are poorly understood. The requirement to investigate this topic is heightened by growing evidence that the West Antarctic Ice Sheet (WAIS) is vulnerable to rapid retreat and collapse through marine-ice-sheet-instability (MISI) on multidecadal-to-centennial timescales. Future model simulations of the AIS show the potential for rapid ice sheet retreat in the next 50 – 300 years, with such a collapse associated with the discharge of enormous volumes of ice and meltwater to the Southern Ocean. This project uses a combination of an ice sheet/shelf model and a fully coupled (ocean-atmosphere-seaice) model (CESM 1.2) to explore the sensitive of global climate to future changes in runoff from the Antarctic continent under future greenhouse gas emissions scenarios IPCC RCP4.5 and 8.5. Overall, accounting for Antarctic meltwater reduces the projected global mean anthropogenic greenhouse warming by up to 2 deg C. during peak WAIS collapse and by ~1 deg. for most of the simulation. In addition, the increased meltwater contribution raises sub-surface ocean temperatures at the Antarctic ice sheet margin by more than 1ºC, such that the ice shelf basal melt rates increase beyond those currently projected. In contrast, the model predicts a strong cooling of both the surface air and ocean temperatures over the Southern Ocean that results in a massive expansion and thickening of the perennial sea-ice. The slow-down in anthropogenic warming also results in the onset of ice-free conditions in the Arctic being delayed in the model by several decades, and the projected slowdown in the AMOC to reduce.

58 GEOSCIENCES↗
DOE OSTI2020

Durability of Disposable N95 Mask Material When Exposed to Improvised Ozone Gas Disinfection

The principle finding of this report is that both commercial and a novel material used for N95 mask filters can endure many cycles of disinfection by ozone gas (20 ppm for 30 minutes) without detectable degradation or loss of filtration efficiency. N95 masks and surgical masks (hereafter referred to as masks) typically use a filtration material fabricated from meltblown polypropylene. To achieve maximum filtration efficiency while maintaining a reasonable pressure drop, these nonwoven fabrics are also electrostatically charged (corona discharge is the most common method used), to maximize attraction and capture of aerosols and solid particulates. Under normal circumstances, the reuse of masks is generally discouraged, but in times of crisis has become a necessity, making disinfection after each use a necessity. To be acceptable, any disinfection procedure must cause minimal degradation to the performance of the filter material. Possible performance degradation mechanisms include mechanical damage, loss of electrostatic charge, or both. One of the most practical and direct ways to measure combined mechanical and electrostatic integrity, and the subsequent ability to reuse mask filter material, is by the direct measurement of filtration efficiency. In this paper, we report that small numbers of disinfection cycles at reasonable virucidal doses of ozone do not significantly degrade the filtration efficiency of meltblown polypropylene filter material. By comparison, laundering quickly results in a significant loss of filtration efficiency and requires subsequent recharging to restore the electrostatic charge and filtration efficiency. A common assumption among biomedical scientists that ozone is far too destructive for this application. However, these direct measurements show that mask materials, specifically the filtration material, can withstand dozens of ozone disinfection cycles without any measurable degradation of filtration efficiency, nor any visible discoloration or loss of fiber integrity. The data are clear: when subjected to a virucidal dose of ozone for a much longer duration than is required for viral inactivation, there was no degradation of N95 filtration efficiency. The specific dosages of ozone needed for ~99% viral inactivation are thought to be at least 10 ppm for up to 30 minutes based upon an extensive literature review, but to standardize our testing, we consider a dose of 20 ppm for 30 minutes to be a reasonable and conservatively high ozone disinfection cycle. Finally, the material tested in this study withstood dosages of up to 200 ppm for 90 minutes, or alternatively 20 ppm for up to 36 hours, without detectable degradation, and further testing suggests that up to 30 or more disinfection cycles (at 20 ppm for 30 minutes) would result in less than a 5% loss of filtration efficiency. This report does not address the effect of ozone cycling on other mask components, such as elastics.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

Wall conditioning and ELM mitigation with boron nitride powder injection in KSTAR

Results from KSTAR powder injection experiments, in which tens of milligrams of boron nitride (BN) were dropped into low-power H-mode plasmas, show an improvement in wall conditions in subsequent discharges and, in some cases, a reduction or elimination of edge-localized modes (ELMs). Injected powder is distributed by the plasma flow and is deposited on the wall and, over the course of several discharges, was observed to gradually reduce recycling by 33%, and decrease both the ELM amplitude and frequency. This is the first demonstration of the use of BN for ELM mitigation. In all of these experiments, an Impurity Powder Dropper (IPD) was used to introduce precise, controllable amounts of the materials into ELMy H-mode KSTAR discharges. The plasma duration was between 10 s and 15 s, I p = 500 kA, B T = 1 . 8 T, P NBI = 1 . 6 MW, and P ECH = 0 . 6 MW. Plasma densities were between 2 and 3 × 1 0 19 m -3 . In all cases, the pre-fill and startup gas-fueling was kept constant, suggesting that the decrease in baseline D &#x3B1; emission is in fact due to a reduction in recycling. The results presented herein highlight the viability of powder injection for intra-shot and between-shot wall conditioning

36 MATERIALS SCIENCE↗