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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Stratospheric sulfate aerosol in and near the Northern Hemisphere polar vortex - The morphology of the sulfate layer, multimodal size distributions, and the effect of denitrification

Measurements were made of stratospheric sulfate aerosols using a passive cavity aerosol spectrometer and a condensation nucleus counter on a NASA ER-2 aircraft in the Airborne Arctic Stratospheric Experiment of 1989. The problems of representative and accurate sampling and particle evaporation were explicitly addressed in the design of the inlets and reduction of the data. The measurements suggest that the sulfate aerosol is bimodal in the polar vortex above the mass mixing ratio maximum in the sulfate layer. It appears that a nuclei mode of small, newly formed particles exists in this region. A stronger case is made for a nuclei mode in the upper few kilometers of the troposphere and in the lower few kilometers of the stratosphere. This mode is probably a global phenomenon occurring in all seasons. Comparison of denitrified and nondenitrified air suggests that denitrification removes some of the larger sulfate particles.

Wilson, J. G.↗
NASA NTRS1992

Particle size distributions in Arctic polar stratospheric clouds, growth and freezing of sulfuric acid droplets, and implications for cloud formation

The paper uses particle size and volume measurements obtained with the forward scattering spectrometer probe model 300 during January and February 1989 in the Airborne Arctic Stratospheric Experiment to investigate processes important in the formation and growth of polar stratospheric cloud (PSC) particles. It is suggested on the basis of comparisons of the observations with expected sulfuric acid droplet deliquescence that in the Arctic a major fraction of the sulfuric acid droplets remain liquid until temperatures at least as low as 193 K. It is proposed that homogeneous freezing of the sulfuric acid droplets might occur near 190 K and might play a role in the formation of PSCs.

Dye, James E.↗
NASA NTRS1992

A case of type I polar stratospheric cloud formation by heterogeneous nucleation

The NASA ER-2 aircraft flew on January 24, 1989, from Stavanger to Spitsbergen, Norway, at the 430-440 K potential temperature surface (19.2-19.8 km pressure altitude). Aerosols were sampled continuously by an optical particle counter (PMS-FSSP300) for concentration and size analyses, and during five 10-min intervals by four wire and one replicator impactor for concentration, size, composition, and phase analysis. During sampling, the air saturation of H2O with respect to ice changed from 20 to 100 percent, and of HNO3 with respect to nitric acid trihydrate (NAT) from subsaturation to supersaturation. Data from both instruments indicate a condensation of hydrochloric acid and, later, nitric acid on the background aerosol particles as the ambient temperature decreases along the flight track. This heterogeneous nucleation mechanism generates type I polar stratospheric cloud particles of 10-fold enhanced optical depth, which could play a role in stratospheric ozone depletion.

Pueschel, R. F.↗
NASA NTRS1992

The role of the World Data Centers in handling ocean climate data

The World Data Center System, set up for the International Geophysical Year in 1957, is an international network of data centers that links data contributors to data users in the geosciences. It includes means for the synthesis, analysis, and preparation of data products. It was set up in response to the needs of the international scientific community, and is still overseen by non-governmental scientific organizations. Because it is freely available to researchers in all countries, the World Data Center System has a special role to play in support of ocean climate research and monitoring programs. The World Data Centers face a number of challenges today. Apathy is probably the greatest, since many scientists take the system for granted. There is need to improve access and exploit new technology. The system must establish new links to assure continuity in a world with political changes. The multidisciplinary needs of global change research will demand capabilities for data and information management that go beyond the traditional emphasis on geophysics.

Webster, Ferris↗
NASA NTRS1992

Comet Halley as an aggregate of interstellar dust and further evidence for the photochemical formation of organics in the interstellar medium

Photolysis of mixtures of CO:NH3:H2O at 12 K results in the formation of an organic residue which is not volatile in high vacuum at room temperature. Analysis of this fraction by GC-MS resulted in the detection of C2-C3 hydroxy acids and hydroxy amides, glycerol, urea, glycine, hexamethylene tetramine, formamidine and ethanolamine. Use of isotopically labeled gases made it possible to establish that the observed products were not contaminants. The reaction pathways for the formation of these products were determined from the position of the isotopic labels in the mass spectral fragments. The significance of these findings to the composition of comets and the origins of life is discussed.

Briggs, R.↗
NASA NTRS1992

Oligomerization reactions of ribonucleotides - The reaction of the 5'-phosphorimidazolide of nucleosides on montmorillonite and other minerals

The reaction of ImpA in the presence of Na(+)-montmorillonite 22A or Na(+)-Volclay in aqueous, pH 8 solution gives a 50-60 percent yield of dimers and trimers (pA)2 and (pA)3. The ratio of 3',5'-phosphodiester bond formation is twice as great as 2',5'-bond formation. The reaction requires the presence of Mg2+ and is inhibited by 0.4 M imidazole. N-methylimidazole enhances the rate of the reaction but does not cause major changes in yield or product composition. Higher yields were obtained when Li+- or Ca2+-montmorillonites were used in place of Na+-montmorillonite. Little or no phosphodiester bond formation was observed with Mg2+- or Al3+-montmorillonite. Montmorillonites other than 22A and Volclay exhibited litle or no catalysis. In addittion, little or no catalysis was exhibited in ferrugenous smectite, nontronite, allophane, imogolite or sepiolite. Oligomers were also formed by the reaction of ImpG, 2-methylImpG, ImpC and ImpU in the presence of Na+-montmorillonite. The pyrimidine nucleotides gave significantly lower yields of oligomers.

Ferris, James P.↗
NASA NTRS1986

Testing experience with unheated stain-gage balances in the NTF

A series of cryogenic (cryo) cycles was conducted in the cryo chamber at the National Transonic Facility (NTF) in order to identify the cause of apparent strain shifts in axial force with temperature for the Pathfinder I model and to minimize their effects. The results of the investigation indicated that the major cause of axial force end point shifts and thermal hysteresis loops was the thickness of the Teflon insulation on the instrumentation wires crossing the balance. By reducing the thickness of the insulation and the total number and size of the wires, apparent strain values were achieved for the model with instrumentation wires which were nearly identical to those for the model without wires. Because of the special design features used, the balance output was very accurate and repeatable over the entire NTF temperature range, even with balance thermal gradients as large as 64 F and transient conditions as large as 3 F/minute.

Jacobs, Peter F.↗
NASA NTRS1992

Diminished effects of El Chichon on stratospheric aerosols, early 1984 to late 1986

Stratospheric aerosol collections by wire impactors, taken mainly over the western U.S. from early 1984 to late 1986, show the diminishing effects of El Chichon's 1982 eruption, and provide a set of data for judging subsequent volcanic effects. Decrease in sulfate burden during the study time is due to preferential gravitational settling-out of large (above 0.5-micron diameter) sulfate aerosol droplets. As a result of settling from higher levels, lower altitude (12.2-15.2 km) air early in 1984 tends to contain more sulfate than higher level (19.8-21.3 km) air. As of late 1986, however, high- and low-altitude sulfate contents have decreased and are similar, suggesting large-particle settling has been completed. The later sulfate collection size distributions resemble unimodal background spectra, whereas earlier ones are bimodal. Average sulfate load for all altitudes decreases during the period of study from 0.4 to 0.08 microgram/cu m. The latter value is somewhat higher than a volcanically unenriched pre-El Chichon level, suggesting that even as of 1987, stratospheric background had not been obtained.

Snetsinger, K. G.↗
NASA NTRS1993

An improved method for determining force balance calibration accuracy

The results of an improved statistical method used at Langley Research Center for determining and stating the accuracy of a force balance calibration are presented. The application of the method for initial loads, initial load determination, auxiliary loads, primary loads, and proof loads is described. The data analysis is briefly addressed.

Ferris, Alice T.↗
NASA NTRS1993

Oligomerization reactions of ribonucleotides - The reaction of the 5'-phosphorimidazolide of adenosine with diadenosine pyrophosphate on montmorillonite and other minerals

The overall regiospecificity of the 3',5'-phosphodiester bond formation is shown to be increased from 64 to 83 percent when a 9:1 ratio of ImpA to A5'ppA instead of ImpA alone is reacted in the presence of Na(+)-montmorillonite. The major factor in the regiospecificity increase is the formation of 3',5'-linked A5'ppA3'pA and A5'pp-A3'pA3'pA. The results obtained show that ImpA reacts more readily with A5'ppA than it does with another ImpA molecule and that A5'ppA plays a central role in directing the formation of 3',5'-phosphodiester bonds.

Ferris, James P.↗
NASA NTRS1951

Preliminary Investigation of a New Type of Supersonic Inlet

A supersonic inlet with supersonic deceleration of the flow entirely outside of the inlet is considered. A particular arrangement with fixed geometry having a central body with a circular annular intake is analyzed, and it is shown theoretically that this arrangement gives high pressure recovery for a large range of Mach number and mass flow and therefore is practical for use on supersonic airplanes and missiles. For some Mach numbers the drag coefficient for this type of inlet is larger than the drag coefficient for the type of inlet with supersonic compression entirely inside, but the pressure recovery is larger for all flight conditions. The differences in drag can be eliminated for the design Mach number. Experimental results confirm the results of the theoretical analysis and show that pressure recoveries of 95 percent for Mach numbers of 1.33 and 1.52, 92 percent for a Mach number of 1.72, and 86 percent for a Mach number of 2.10 are possible, with the configurations considered. If the mass flow decreases, the total drag coefficient increases gradually and the pressure recovery does not change appreciably. The results of this work were first presented in a classified document issued in 1946.

DIFFUSERS, SUPERSONIC↗