A reactive molecular dynamics study of phenol and phenolic polymers in extreme environments.
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Accident tolerant claddings must withstand the loss of coolant for longer times than conventional zirconium-based reactor claddings. Advanced steel alloys (such as Alloy 33, APMT) offer enhanced resistance to high-temperature oxidation in steam environments due to the formation of protective oxide layers of chromia and/or alumina oxides on the surface of the alloy, which enhance their stability at high temperatures by acting as an effective diffusion barrier, so resulting in low rate of oxidation. These passivating oxide layers, resistant to accelerated oxidation, offer an improvement over the current designs by reducing the production of hydrogen gas, and by delaying the release of fission products into the environment. Hence, these alloys present a great opportunity to explore alternative cladding materials with better accident tolerance for commercial light water reactors. Alloy 33 and APMT showed enhanced resistance to corrosion under the normal operation and off-nominal conditions of light water reactors.
Experimentation at irradiation test facilities are essential for reducing the innovation time of developmental fuels, fuel cladding, and structural materials employed in next-generation nuclear reactors. However, due to the harsh conditions generated in such reactors and limited instrumentation space, the evaluation of a material’s mechanical properties is often limited to characterization after the materials have been removed from reactor conditions, or post-irradiation examination. These experiments are costly, time-consuming, and fail to capture the critical time-evolving phenomena that occur during the irradiation experiments. Advanced manufactured digital image correlation patterns and strain sensor devices serve as two promising technologies that can be deployed in the confined and challenging orientations of these irradiation experiments while also providing key insight on salient materials phenomena (i.e., mechanical properties). To guide the development of the printed strain sensors prior to their deployment in critical experiments, the adhesion strength between the substrate and printed film interface is measured via tensile testing and a non-contact laser-induced spallation technique. The establishment of these process control steps helped guide the successful fabrication and testing of direct-write strain sensing devices discussed in this work. The fabrication process controls are necessary for enabling the sustained operation of these strain sensing device through experimentation and minimize the potential for premature failure.