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Research and Development of High-Power and High-Energy Electrochemical Storage Devices

The accomplishments and technology progressmade during the U.S. Department of Energy (DOE) Cooperative Agreement No. DE-FC26- 05NT42403 (duration: July 11, 2005 through April 30, 2014, funded for $\$$125 million in cost- shared research) are summarized in this Final Technical Report for a total of thirty-seven (37) collaborative programs organized by the United States Advanced Battery Consortium, LLC (USABC). The USABC is a partnership, formed in 1991, between the three U.S. domestic automakers Chrysler, Ford, and General Motors, to sponsor development of advanced high-performance batteries for electric and hybrid electric vehicle applications. The USABC provides a unique opportunity for developers to leverage their resources in combination with those of the automotive industry and the Federal government. This type of pre-competitive cooperation minimizes duplication of effort and risk of failure, and maximizes the benefits to the public of the government funds. A major goal of this program is to promote advanced battery development that can lead to commercialization within the domestic, and as appropriate, the foreign battery industry. A further goal of this program is to maintain a consortium that engages the battery manufacturers with the automobile manufacturers and other key stakeholders, universities, the National Laboratories, and manufacturers and developers that supply critical materials and components to the battery industry. Typically, the USABC defines and establishes consensus goals, conducts pre-competitive, vehicle-related research and development (R&D) in advanced battery technology. The R&D carried out by the USABC is an integral part of the DOE’s effort to develop advanced transportation technologies that will significantly improve fuel economy, comply with projected emissions and safety regulations, and use domestically produced fuels. The USABC advanced battery development plan has the following three focus areas: 1. Existing technology validation, implementation, and cost reduction. 2. Identification of the next viable technology with emphasis on the potential to meet USABC cost and operating temperature range goals. 3. Support high-risk, high-reward battery technology R&D. Specific to the Cooperative Agreement DE- FC26-05NT42403, addressing High-Energy and High Power Energy Storage Technologies, the USABC focus was on understanding and addressing the following factors (listed in priority of effort): • Cost: Reducing the current cost of lithium- ion batteries (currently about 2-3 times the FreedomCAR target ($\$$20/kW). • Low Temperature Performance: Improving the discharge power and removing lithium plating during regenerative braking. • Calendar Life: Achieving 15-year life and getting accurate life prediction. • Abuse Tolerance: Developing a system level tolerance to overcharge, crush, and high temperature exposure. This Final Technical Report compilation is submitted in fulfillment of the subject Cooperative Agreement, and is intended to serve as a ready-reference for the outcomes of following eight categories of projects conducted by the USABC under award from the DOE’s Energy Efficiency and Renewable Energy ) Vehicle Technologies Program: USABC DoE Final Report – DoE Cooperative Agreement DE-FC26-95EE50425 8 Protected Information 1. Electric Vehicle (EV) (Section A of this report) 2. Hybrid Electric Vehicle (HEV) (Section B 3. Plug-In Hybrid Electric Vehicle (PHEV) (Section C) 4. Low-Energy Energy Storage Systems (LEESS) (Section D) 5. Technology Assessment Program (TAP) (Section E) 6. Ultracapacitors (Section F) 7. 12 Volt Start-Stop (Section G) 8. Separators (Section H) The report summarizes the main areas of activity undertaken in collaboration with the supplier community and the National Laboratories. Copies of the individual supplier final reports are available upon request. Using project gap analysis versus defined USABC goals in each area, the report documents known technology limits and provides direction on future areas of technology and performance needs for vehicle applications. The report was developed using information such as program plans, gap analysis charts, quarterly reports and final project reports submitted by the developers. The public benefit served by this USABC program is that it continues the development of critical advanced battery technology that is needed to make electric, hybrid electric, and fuel cell vehicles attractive to a wide segment of the vehicle market. This will allow for a substantial savings in petroleum fuel use as these vehicles are introduced into the nation’s transportation system. It will also allow a sharp reduction in automotive air pollution emissions in critical areas that are currently classified as non-attainment by the Environmental Protection Agency. This program will also help ensure the long term health and viability of the U.S. Battery and Ultracapacitor Manufacturing Industry. The goals of eight categories of projects follow and summarization of each of the project’s accomplishments are in sequence of the list above.

25 ENERGY STORAGE↗

Quality Assessment of Molten Salt Thermochemical Property Data

Recommendations are made to enhance user confidence in property values included in the Molten Salt Thermal Database-Thermochemical Properties (MSTDB-TC). Specifically, it is recommended that all available measured values be included with a transparent assessment of each to arrive at a preferred value for each salt composition in the database. The use of a quality assessment and ranking system is recommended for data and property values compiled in the MSTDB-TC that is analogous to the approach developed for data and property values included in the MSTDB-Thermophysical Properties (TP) database. The approach includes assessments of five features of data collection: the method used to measure the property value, calibration of devices used to make the measurements, the quantified uncertainty of the results, control of the environmental conditions, and determination of the salt composition. The quality of each facet is ranked as High, Moderate, or Incomplete based on objective metrics. The overall quality of the dataset is ranked based on rankings of the five data features and traceability of the reported property value, with rankings of A and B indicating the data and property value are deemed suitable for quantitative use, C indicating the value is computed and not validated and U indicating uncertainties restrict the recommended use to qualitative purposes. Sufficient information should be provided or cited within each data set included in the database to verify the reported property value. The recommended approach is suitable for assessing data already in the MSTDB-TC and screening new entries.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Availability of Shielding Benchmark Experiment Data in the ICSBEP Handbook

The International Criticality Safety Benchmark Evaluation Projects (ICSBEP) has over two decades of experience under the auspices of the Organisation for Economic Co-operation and Development (OECD) Nuclear Energy Agency (NEA) to identify, evaluate, and compile a comprehensive data set of criticality safety benchmark data [1]. The activities of the ICSBEP have led to the continued success of the International Handbook of Evaluated Criticality Safety Benchmark Experiments (ICSBEP Handbook) [2]. The contents of the ICSBEP Handbook include benchmark specifications derived from nuclear facilities around the world, which have been utilized to support criticality safety efforts and also integral testing of nuclear data [3]. The 2020 edition of the ICSBEP Handbook will include data from 582 evaluations containing benchmark specifications for 5,053 critical, subcritical, or near-critical configurations. There are seven criticality-alarm-placement/shielding evaluations containing a total of 45 benchmark configurations, and ten fundamental physics evaluations containing a total of 237 measurements relevant to criticality safety applications. The purpose of this paper is to summarize those benchmarks relative to validation needs in shielding applications currently found within the ICSBEP Handbook. The current and future plans of shielding benchmarks with regards to the ICSBEP will also be discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

On the influence of the power plant operational history on the inventory and the uncertainties of radionuclides relevant for the final disposal of PWR spent fuel - 15149

A mandatory requisite for official granting safe final disposal approval of SNF is the comprehensive specification and declaration of the nuclear inventory in SNF by the NPP-operators. The whole radiochemical characterization of each spent fuel assembly hides many difficulties such as very high radiation burden, destruction method, the inhomogeneous burn-up of fuel assembly, very high cost. Thus, non-destructive characterization is usually applied on industrial scale. In this case only several nuclides can be measured, and the rest is calculated using simulations and typical irradiation history. Like any other German rad-waste acceptance requirements all these declarations will have to be checked and verified by an independent inspector. In this verification process not only values of radionuclide (RN) activities are important, but also their uncertainties. The simple simulation using burn-up calculations based on typical and generic reactor operational parameters do not answer the question about possible uncertainties observed in real reactor operations. At the same time, the details of irradiation history are often unknown, which complicates the assessment of declared RN inventories. Therefore, the development of dedicated generic proof tools, which can be applied to different types of waste, often of unknown origin and history is worth a serious consideration. Here, we have compiled a set of burn-up calculations considering the operational history of 339 published or anonymized real PWR fuel assemblies. This gives us the possibility to calculate the realistic variation or spectrum of RN inventories. These histories were used as a basis for 'SRP analysis', to provide information about the range of the values of the associated secondary reactor parameters (SRP's), i.e. initial enrichment (IE), specific power (SP), irradiation time (IT), downtime (DT), boric acid concentration (BA), moderator and fuel density (MD and FD) and temperatures (MT and MT) used as input parameters for the simulation models. Then, burn-up calculation codes provide the anticipated results for the entire nuclear inventory such as characteristic activity values and the corresponding minimum and maximum limits as a function of the fuel burn-up. These results are being validated with the experimental data from various publications and the online database - SFCOMPO and subsequently transferred and summarized into our own database. Ultimately, this database will provide the basis of proof tools for the operator independent verification of the declared nuclear inventories for the quality and safety assessment of a radioactive waste compound and bounding values for certain RN as a function of burn-up. The RN inventory can hence be verified without taking credit of the whole of the operational history of the SNF. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Ozone Observations by the Gas and Aerosol Measurement Sensor during SOLVE II

The Gas and Aerosol Measurement Sensor (GAMS) was deployed aboard the NASA DC-8 aircraft during the second SAGE III Ozone Loss and Validation Experiment (SOLVE II). GAMS acquired line-of-sight (LOS) direct solar irradiance spectra during the sunlit portions of ten science flights of the DC-8 between 12 January and 4 February 2003. Differential line-of-sight (DLOS) optical depth spectra are produced from the GAMS raw solar irradiance spectra. Then, DLOS ozone number densities are retrieved from the GAMS spectra using a multiple linear regression spectral fitting technique. Both the DLOS optical depth spectra and retrieved ozone data are compared with coincident measurements from two other solar instruments aboard the DC-8 platform to demonstrate the robustness and stability of the GAMS data. The GAMS ozone measurements are then utilized to evaluate the quality of the Wulf band ozone cross sections, a critical component of the SAGE III aerosol, water vapor, and temperature/pressure retrievals. Results suggest the ozone cross section compilation of Shettle and Anderson currently used operationally in SAGE III data processing may be in error by as much as 10-20% in theWulf bands, and their lack of reported temperature dependence is a significant deficiency. A second, more recent, cross section database compiled for the SCIAMACHY satellite mission appears to be of much better quality in the Wulf bands, but still may have errors as large as 5% near the Wulf band absorption peaks, which is slightly larger than their stated uncertainty. Additional laboratory measurements of the Wulf band cross sections should be pursued to further reduce their uncertainty and better quantify their temperature dependence.

Pitts, M. C.↗

Lockheed Martin Skunk Works Single Stage to Orbit/Reusable Launch Vehicle

Lockheed Martin Skunk Works has compiled an Annual Performance Report of the X-33/RLV Program. This report consists of individual reports from all industry team members, as well as NASA team centers. This portion of the report is comprised of a status report of Lockheed Martin's contribution to the program. The following is a summary of the Lockheed Martin Centers involved and work reviewed under their portion of the agreement: (1) Lockheed Martin Skunk Works - Vehicle Development, Operations Development, X-33 and RLV Systems Engineering, Manufacturing, Ground Operations, Reliability, Maintainability/Testability, Supportability, & Special Analysis Team, and X-33 Flight Assurance; (2) Lockheed Martin Technical Operations - Launch Support Systems, Ground Support Equipment, Flight Test Operations, and RLV Operations Development Support; (3) Lockheed Martin Space Operations - TAEM and A/L Guidance and Flight Control Design, Evaluation of Vehicle Configuration, TAEM and A/L Dispersion Analysis, Modeling and Simulations, Frequency Domain Analysis, Verification and Validation Activities, and Ancillary Support; (4) Lockheed Martin Astronautics-Denver - Systems Engineering, X-33 Development; (5) Sanders - A Lockheed Martin Company - Vehicle Health Management Subsystem Progress, GSS Progress; and (6) Lockheed Martin Michoud Space Systems - X-33 Liquid Oxygen (LOX) Tank, Key Challenges, Lessons Learned, X-33/RLV Composite Technology, Reusable Cyrogenic Insulation (RCI) and Vehicle Health Monitoring, Main Propulsion Systems (MPS), Structural Testing, X-33 System Integration and Analysis, and Cyrogenic Systems Operations.

Source record↗

PowerMappeR: Power-Optimized Mapping of SNNs onto ReRAM Crossbars coupled via Packet-Switched NoCs

Many recent efforts in developing hardware-accelerated spiking neural networks (SNNs) are characterized by deep co-design between algorithms, architectures, and devices. Architectural advances overcome device constraints by coupling together many small resistive-RAM (ReRAM) crossbars via a network-on-chip (NoC) for neuromorphic component operation. Concurrently, improved SNN training methods increase accuracy and structural sparsity in networks despite growing problem sizes. Finally, compilers leverage these attributes to minimize area and inter-crossbar communication while mapping large SNNs to sophisticated architectures. However, for compiler-driven co-design to realize increasingly complex and profitable optimizations, a compile-time view of power consumption is critical. We present PowerMappeR to express and optimize over mapping-, architecture-, and device-specific power consumption information. By modeling the dynamic power of well-established components, we develop an integer linear programming (ILP)-based, encoding-agnostic, parametric power estimation model. Using this model, we demonstrate practical improvements in area and inter-crossbar communication by 0%–9.5% and 1.4%–5.1%, respectively. We also limit hotspot formation during optimization, achieving comparable or better results in targeted metrics with up to 96.4%–97.1% restriction of hotspot magnitude. Finally, we introduce profile-guided formulations to reduce worst-case and expected-case hotspot magnitude by 40.7%–69.5% and 40.6%–56.3%, respectively. Optimizing worst-case hotspot magnitude incidentally improves expected-case magnitude by 10.85%–33.45%. Reciprocally, optimizing expected-case magnitude incidentally improves worst-case magnitude by 4.33%–39.87%. Validation against hardware simulators confirms that PowerMappeR can decrease dynamic power consumption by 12.6%–27.3%.

Pohl, Devin [ORNL] (ORCID:0009000040149027)↗

NOS3: NASA Operational Simulator for Small Satellites

The NASA Operational Simulator for Small Satellites (NOS3) is a suite of open-source software tools to aid in areas such as software development, integration & test (I&T), mission operations/training, verification and validation (V&V), and software systems check-out. NOS3 provides a software development environment, a multi-target build system, operational interface/ground software, dynamics and environment simulations, and software-based hardware models. NOS3 has just recently been open-sourced by NASA and is available for immediate use. It enables the development of flight software (FSW) early in the project life cycle when hardware availability is limited. Small satellite development suffers from extensive lead times on many of the commercial-off-the-shelf (COTS) components as well as limited funding for engineering test units (ETUs). To alleviate the need to provide a hardware test-bed for each developer/tester, NOS3 hardware models are based upon characteristic data or manufacturer's data sheets for each individual component. The NOS3 hardware models' fidelity is such that FSW executes unaware that physical hardware is not present. This allows FSW binaries to be compiled for both the simulation environment and the flight computer without changing the FSW source code. For hardware models that provide data which is dependent upon the environment and spacecraft dynamics, such as a GPS receiver or magnetometer, an open-source tool from NASA GSFC (42 Spacecraft Simulator) is used to provide the necessary data. The underlying infrastructure used to transfer messages between FSW and the hardware models can also be used to monitor, intercept, and inject messages, which has proven to be beneficial for V&V of larger missions such as James Webb Space Telescope (JWST). As hardware is selected and becomes available, drivers can be added to the NOS3 environment to enable hardware-in-the-loop (HWIL) testing. When strict time synchronization is not vital, any number of combinations of hardware components and software-based models can be tested. NOS3 was actively used for FSW development and component testing of the Simulation-to-Flight 1 (STF-1) CubeSat and the Lunar IceCube CubeSat. As NOS3 matures, hardware models have been added for common small satellite components such as GPS receivers, electrical power systems and batteries, and antenna systems.

Suder, Mark↗

Virtual Satellite

Virtual Satellite (VirtualSat) is a computer program that creates an environment that facilitates the development, verification, and validation of flight software for a single spacecraft or for multiple spacecraft flying in formation. In this environment, enhanced functionality and autonomy of navigation, guidance, and control systems of a spacecraft are provided by a virtual satellite that is, a computational model that simulates the dynamic behavior of the spacecraft. Within this environment, it is possible to execute any associated software, the development of which could benefit from knowledge of, and possible interaction (typically, exchange of data) with, the virtual satellite. Examples of associated software include programs for simulating spacecraft power and thermal- management systems. This environment is independent of the flight hardware that will eventually host the flight software, making it possible to develop the software simultaneously with, or even before, the hardware is delivered. Optionally, by use of interfaces included in VirtualSat, hardware can be used instead of simulated. The flight software, coded in the C or C++ programming language, is compilable and loadable into VirtualSat without any special modifications. Thus, VirtualSat can serve as a relatively inexpensive software test-bed for development test, integration, and post-launch maintenance of spacecraft flight software.

Hammrs, Stephan R.↗

Areal Distribution of the Oxygen-Isotope Ratio in Greenland

Mean values of the oxygen-isotope ratio relative to standard mean ocean water reported for 46 sites on the Greenland ice sheet are compiled together with data on mean annual surface temperature, latitude, 6180 elevation, and mean annual shortest distance to the open ocean denoted by the 10% sea-ice concentration boundary. Stepwise regression analyses, with 6180 as the dependent variable, define two robust models. In the forward mode at the 99.9% confidence level, only temperature enters the model. In the backward mode at the 95% confidence level, only temperature, latitude, and distance to the open ocean remain in the model. Inversions of the models on the basis of 160 gridpoint locations 100 km apart in the area delimited by the surface equilibrium line produce four contoured distributions of 6"0. Two distributions are based on the bivariate model and two on the multivariate model. The second distribution for each model is obtained substituting mean annual surface-temperature values obtained from the Nimbus-7 Temperature Humidity Infrared Radiometer (THIR) database. All four distributions are considered valid, and differences between them are evaluated using contoured anomaly maps. It is suggested that the inversion of the multivariate model using THIR data provides the more reliable pattern for studies of atmospheric advection or for the derivation of ice-flow adjustments for 6180 series obtained from deep-core or ablation-zone sites.

Zwally, H. Jay↗

How Universal is the Relationship Between Remotely Sensed Vegetation Indices and Crop Leaf Area Index? A Global Assessment

Leaf Area Index (LAI) is a key variable that bridges remote sensing observations to the quantification of agroecosystem processes. In this study, we assessed the universality of the relationships between crop LAI and remotely sensed Vegetation Indices (VIs). We first compiled a global dataset of 1459 in situ quality-controlled crop LAI measurements and collected Landsat satellite images to derive five different VIs including Simple Ratio (SR), Normalized Difference Vegetation Index (NDVI), two versions of the Enhanced Vegetation Index (EVI and EVI2), and Green Chlorophyll Index (CI(sub Green)). Based on this dataset, we developed global LAI-VI relationships for each crop type and VI using symbolic regression and Theil-Sen (TS) robust estimator. Results suggest that the global LAI-VI relationships are statistically significant, crop-specific, and mostly non-linear. These relationships explain more than half of the total variance in ground LAI observations (R2 greater than 0.5), and provide LAI estimates with RMSE below 1.2 m2/m2. Among the five VIs, EVI/EVI2 are the most effective, and the crop-specific LAI-EVI and LAI-EVI2 relationships constructed by TS, are robust when tested by three independent validation datasets of varied spatial scales. While the heterogeneity of agricultural landscapes leads to a diverse set of local LAI-VI relationships, the relationships provided here represent global universality on an average basis, allowing the generation of large-scale spatial-explicit LAI maps. This study contributes to the operationalization of large-area crop modeling and, by extension, has relevance to both fundamental and applied agroecosystem research.

Vegetation Index↗

Software to model AXAF image quality

This draft final report describes the work performed under this delivery order from May 1992 through June 1993. The purpose of this contract was to enhance and develop an integrated optical performance modeling software for complex x-ray optical systems such as AXAF. The GRAZTRACE program developed by the MSFC Optical Systems Branch for modeling VETA-I was used as the starting baseline program. The original program was a large single file program and, therefore, could not be modified very efficiently. The original source code has been reorganized, and a 'Make Utility' has been written to update the original program. The new version of the source code consists of 36 small source files to make it easier for the code developer to manage and modify the program. A user library has also been built and a 'Makelib' utility has been furnished to update the library. With the user library, the users can easily access the GRAZTRACE source files and build a custom library. A user manual for the new version of GRAZTRACE has been compiled. The plotting capability for the 3-D point spread functions and contour plots has been provided in the GRAZTRACE using the graphics package DISPLAY. The Graphics emulator over the network has been set up for programming the graphics routine. The point spread function and the contour plot routines have also been modified to display the plot centroid, and to allow the user to specify the plot range, and the viewing angle options. A Command Mode version of GRAZTRACE has also been developed. More than 60 commands have been implemented in a Code-V like format. The functions covered in this version include data manipulation, performance evaluation, and inquiry and setting of internal parameters. The user manual for these commands has been formatted as in Code-V, showing the command syntax, synopsis, and options. An interactive on-line help system for the command mode has also been accomplished to allow the user to find valid commands, command syntax, and command function. A translation program has been written to convert FEA output from structural analysis to GRAZTRACE surface deformation file (.dfm file). The program can accept standard output files and list files from COSMOS/M and NASTRAN finite analysis programs. Some interactive options are also provided, such as Cartesian or cylindrical coordinate transformation, coordinate shift and scale, and axial length change. A computerized database for technical documents relating to the AXAF project has been established. Over 5000 technical documents have been entered into the master database. A user can now rapidly retrieve the desired documents relating to the AXAF project. The summary of the work performed under this contract is shown.

Ahmad, Anees↗

Prediction of binding affinity and efficacy of thyroid hormone receptor ligands using QSAR and structure-based modeling methods

The thyroid hormone receptor (THR) is an important member of the nuclear receptor family that can be activated by endocrine disrupting chemicals (EDC). Quantitative Structure–Activity Relationship (QSAR) models have been developed to facilitate the prioritization of THR-mediated EDC for the experimental validation. The largest database of binding affinities available at the time of the study for ligand binding domain (LBD) of THRβ was assembled to generate both continuous and classification QSAR models with an external accuracy of R{sup 2} = 0.55 and CCR = 0.76, respectively. In addition, for the first time a QSAR model was developed to predict binding affinities of antagonists inhibiting the interaction of coactivators with the AF-2 domain of THRβ (R{sup 2} = 0.70). Furthermore, molecular docking studies were performed for a set of THRβ ligands (57 agonists and 15 antagonists of LBD, 210 antagonists of the AF-2 domain, supplemented by putative decoys/non-binders) using several THRβ structures retrieved from the Protein Data Bank. We found that two agonist-bound THRβ conformations could effectively discriminate their corresponding ligands from presumed non-binders. Moreover, one of the agonist conformations could discriminate agonists from antagonists. Finally, we have conducted virtual screening of a chemical library compiled by the EPA as part of the Tox21 program to identify potential THRβ-mediated EDCs using both QSAR models and docking. We concluded that the library is unlikely to have any EDC that would bind to the THRβ. Models developed in this study can be employed either to identify environmental chemicals interacting with the THR or, conversely, to eliminate the THR-mediated mechanism of action for chemicals of concern. - Highlights: • This is the largest curated dataset for ligand binding domain (LBD) of the THRβ. • We report the first QSAR model for antagonists of AF-2 domain of THRβ. • A combination of QSAR and docking enables prediction of both affinity and efficacy. • Models can be used to identify environmental chemicals interacting with THRβ. • Models can be used to eliminate the THRβ-mediated mechanism of action.

60 APPLIED LIFE SCIENCES↗

Survey of Surveys: I. The largest compilation of radial velocities for the Galaxy

In the present-day panorama of large spectroscopic surveys, the amount, diversity, and complexity of the available data continuously increase. The overarching goal of studying the formation and evolution of our Galaxy is hampered by the heterogeneity of instruments, selection functions, analysis methods, and measured quantities. Here, we present a comprehensive catalogue, the Survey of Surveys (SoS), built by homogeneously merging the radial velocity (RV) determinations of the largest ground-based spectroscopic surveys to date, such as APOGEE, GALAH, Gaia-ESO, RAVE, and LAMOST, using Gaia as a reference. This pilot study serves to prove the concept and to test the methodology that we plan to apply in the future to the stellar parameters and abundance ratios as well. We have devised a multi-staged procedure that includes: (i) the cross match between Gaia and the spectroscopic surveys using the official Gaia cross-match algorithm, (ii) the normalisation of uncertainties using repeated measurements or the three-cornered hat method, (iii) the cross calibration of the RVs as a function of the main parameters on which depend (magnitude, effective temperature, surface gravity, metallicity, and signal-to-noise ratio) to remove trends and zero point offsets, and (iv) the comparison with external high-resolution samples, such as the Gaia RV standards and the Geneva-Copenhagen survey, to validate the homogenisation procedure and to calibrate the RV zero-point of the SoS catalogue. We provide the largest homogenised RV catalogue to date, containing almost 11 million stars, of which about half come exclusively from Gaia and half in combination with the ground-based surveys. We estimate the accuracy of the RV zero-point to be about 0.16–0.31 km s –1 and the RV precision to be in the range 0.05–1.50 km s –1 depending on the type of star and on its survey provenance. We validate the SoS RVs with open clusters from a high resolution homogeneous samples and provide the systemic velocity of 55 individual open clusters. Additionally, we provide median RVs for 532 clusters recently discovered by Gaia data. The SoS is publicly available and ready to be applied to various research projects, such as the study of star clusters, Galactic archaeology, stellar streams, or the characterisation of planet-hosting stars, to name a few. We also plan to include survey updates and more data sources in future versions of the SoS.

79 ASTRONOMY AND ASTROPHYSICS↗

Transfer Factors for the FRMAC Assessment Manual and Turbo FRMAC to Improve Radiological Dose Assessment

The Turbo FRMAC analysis tool is used to perform complex calculations to quickly evaluate radiological consequences and aid in decision making during an emergency response by assessing impacts to the public, workers, and the food supply. Turbo FRMAC calculations are based on methods established by the Federal Radiological Monitoring and Assessment Center (FRMAC). To be able to assess impacts, input data called transfer factors that describe radionuclide uptake by local plants and animals are required. During the code application exercises in late 2016, identifying, finding, and validating nonstandard transfer factors proved to be time consuming and diverted the teams’ activity away from other critical tasks. As a result, a task was undertaken to dramatically expand the list of available transfer factors (food and non-food) and incorporate these factors into Turbo FRMAC. This will ultimately result in improved efficiency of the assessment team to perform calculations during times when the FRMAC is activated and provide more defensible, vetted data from which to calculate results. As a result of these and subsequent exercises, transfer factors were needed for the following items: bell peppers, Christmas tree, deer, flowers, fresh cucumbers, tomatoes, grapefruit, lichens, mushrooms, oranges, snap beans, squash, strawberries, sugarcane for sugar and seed, sweet corn, tea, tobacco, tree bark, and watermelon. To expand the applicability of the information tables, generic transfer data were also provided for common categories and recommendations were made for expanding the list of chemicals based on chemical similarity. The data presented in this report were compiled from recent literature with most of the data encompassing the period from 2000 to 2018. The following radionuclides were targeted during the literature search: elements associated with reactor accidents or nuclear detonations (Sr 89/90, Cs 134/137, Ce 141/144, Ru 103/106, I 129/131/133, Pu 238/239, Am 241, Zr 95, and Nb 95) and elements associated with industrial accidents or dirty bombs (Ir 192 and Co 60). Data from other elements were evaluated if they were identified during the literature search. In addition, reports were evaluated that were recommended by the research consultants. For each plant or animal transfer factor, the goal was to determine the geometric mean, the geometric standard deviation, the minimum, the maximum, and the number of measurements used. If only one measurement was available that was presented as the mean. Concentration ratios with large geometric standard deviations (GSDs) were generally the result of a paucity of measurements or a few disparate measurements. Measurement disparity was observed for data from different soil types. The geometric mean (GM) is a good reference value for planning and responses purposes, but the location-specific concentrations are unlikely to be similar to the model results. Recommendations for further work include: segregating the data to reflect the influence of soil type, developing approaches to incorporate animal data based on aggregated transfer measurements, and including data for foliar deposition on plants.

61 RADIATION PROTECTION AND DOSIMETRY↗

Microstructural Characterization of Metal Foams: An Examination of the Applicability of the Theoretical Models for Modeling Foams

Establishing the geometry of foam cells is useful in developing microstructure-based acoustic and structural models. Since experimental data on the geometry of the foam cells are limited, most modeling efforts use an idealized three-dimensional, space-filling Kelvin tetrakaidecahedron. The validity of this assumption is investigated in the present paper. Several FeCrAlY foams with relative densities varying between 3 and 15 percent and cells per mm (c.p.mm.) varying between 0.2 and 3.9 c.p.mm. were microstructurally evaluated. The number of edges per face for each foam specimen was counted by approximating the cell faces by regular polygons, where the number of cell faces measured varied between 207 and 745. The present observations revealed that 50 to 57 percent of the cell faces were pentagonal while 24 to 28 percent were quadrilateral and 15 to 22 percent were hexagonal. The present measurements are shown to be in excellent agreement with literature data. It is demonstrated that the Kelvin model, as well as other proposed theoretical models, cannot accurately describe the FeCrAlY foam cell structure. Instead, it is suggested that the ideal foam cell geometry consists of 11 faces with three quadrilateral, six pentagonal faces and two hexagonal faces consistent with the 3-6-2 Matzke cell. A compilation of 90 years of experimental data reveals that the average number of cell faces decreases linearly with the increasing ratio of quadrilateral to pentagonal faces. It is concluded that the Kelvin model is not supported by these experimental data.

Raj, S. V.↗

When can we detect lianas from space? Toward a mechanistic understanding of liana‐infested forest optics

Abstract Lianas, woody vines acting as structural parasites of trees, have profound effects on the composition and structure of tropical forests, impacting tree growth, mortality, and forest succession. Remote sensing could offer a powerful tool for quantifying the scale of liana infestation, provided the availability of robust detection methods. We analyze the consistency and global geographic specificity of spectral signals—reflectance across wavelengths—from liana‐infested tree crowns and forest stands, examining the underlying mechanisms of these signals. We compiled a uniquely comprehensive database, including leaf reflectance spectra from 5424 leaves, fine‐scale airborne reflectance data from 999 liana‐infested canopies, and coarse‐scale satellite reflectance data covering 775 ha of liana‐infested forest stands. To unravel the mechanisms of the liana spectral signal, we applied mechanistic radiative transfer models across scales, establishing a synthesis of the relative importance of different mechanisms, which we corroborate with field data on liana leaf chemistry and canopy structure. We find a consistent liana spectral signal at canopy and stand scales across globally distributed sites. This signature mainly arises at the canopy level due to direct effects of more horizontal leaf angles, resulting in a larger projected leaf area, and indirect effects from increased light scattering in the near and short‐wave infrared regions, linked to lianas' less costly leaf construction compared with trees on average. The existence of a consistent global spectral signal for lianas suggests that large‐scale quantification of liana infestation is feasible. However, because the traits responsible for the liana canopy‐reflectance signal are not exclusive to lianas, accurate large‐scale detection requires rigorously validated remote sensing methods. Our models highlight challenges in automated detection, such as potential misidentification due to leaf phenology, tree life history, topography, and climate, especially where the scale of liana infestation is less than a single remote sensing pixel. The observed cross‐site patterns also prompt ecological questions about lianas' adaptive similarities in optical traits across environments, indicating possible convergent evolution due to shared constraints on leaf biochemical and structural traits.

Environmental Sciences & Ecology↗

Advanced Laboratory and Field Arrays (ALFA)/Lab Collaboration Project (LCP) for Marine Energy (Final Scientific/Technical Report)

The objective of the Advanced Laboratory and Field Arrays (ALFA) project was to reduce the Levelized Cost of Energy (LCOE) of Marine and Hydrokinetic (MHK) energy by leveraging research, development, and testing capabilities at Oregon State University, University of Washington, and the University of Alaska, Fairbanks. ALFA is a project within the Pacific Marine Energy Center (PMEC; formerly NNMREC), a multi-institution entity with a diverse funding base that focuses on research and development for marine renewables. The ALFA project aimed to accelerate the development of next-generation arrays of wave energy conversion (WEC) and tidal energy conversion (TEC) devices through a suite of field-focused R&D activities spanning a broad range of strategic opportunity areas identified in the Funding Opportunity Announcement: • Device and/or array operation and maintenance (O&M) logistics development; • High-fidelity resource characterization and/or modeling technique development and validation; • Array-specific component technology development (e.g. moorings and foundations, transmission, and other offshore grid components); • Array performance testing and evaluation; and • Novel cost-effective environmental monitoring techniques and instrumentation testing and evaluation. The objective of the Lab Collaboration Project (LCP) was to accelerate the development of next-generation marine energy conversion systems. The LCP aimed to achieve these project objectives in collaboration with the national laboratories by: • Developing concept generation and assessment tools; • Improving access to existing testing resources; • Validating collision risk models between fish and turbines; and • Advancing analysis and simulation capabilities for wave-WEC interactions and PTO analysis in nonlinear ocean waves. The ALFA portion of the project was comprised of six overarching technical tasks: • Task 1: Debris Modeling, Detection and Mitigation; • Task 2: Autonomous Monitoring & Intervention; • Task 3: Resource Characterization for Extreme Conditions; • Task 4: Robust Models for Design of Offshore Anchoring and Mooring Systems; • Task 5: Performance Enhancement for Marine Energy Converter (MEC) Arrays; and • Task 6: Evaluating Sampling Techniques for MHK Biological Monitoring. The LCP was divided into four overarching technical tasks: • Task 7: Project Management and Reporting • Task 8: Novel Design and Assessment Methodologies for Wave Energy Converter Design (Wave- SPARC) • Task 9: Testing Access for Commercial Marine Renewable Energy Technology Developers • Task 10: Quantifying Collision Risk for Fish and Turbines • Task 11: Nonlinear Ocean Waves and PTO Control Strategy Each ALFA/LCP task listed above functioned as a separate and discreet project. A final Technical Report was written for each individual task and these reports were uploaded to OSTI, after receiving DOE approval. The following document is a compilation of each of these final, approved reports arranged as individual chapters.

13 HYDRO ENERGY↗