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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS2010

Using Leaf Chlorophyll to Parameterize Light-Use-Efficiency Within a Thermal-Based Carbon, Water and Energy Exchange Model

Chlorophylls absorb photosynthetically active radiation and thus function as vital pigments for photosynthesis, which makes leaf chlorophyll content (C(sub ab) useful for monitoring vegetation productivity and an important indicator of the overall plant physiological condition. This study investigates the utility of integrating remotely sensed estimates of C(sub ab) into a thermal-based Two-Source Energy Balance (TSEB) model that estimates land-surface CO2 and energy fluxes using an analytical, light-use-efficiency (LUE) based model of canopy resistance. The LUE model component computes canopy-scale carbon assimilation and transpiration fluxes and incorporates LUE modifications from a nominal (species-dependent) value (LUE(sub n)) in response to short term variations in environmental conditions, However LUE(sub n) may need adjustment on a daily timescale to accommodate changes in plant phenology, physiological condition and nutrient status. Day to day variations in LUE(sub n) were assessed for a heterogeneous corn crop field in Maryland, U,S.A. through model calibration with eddy covariance CO2 flux tower observations. The optimized daily LUE(sub n) values were then compared to estimates of C(sub ab) integrated from gridded maps of chlorophyll content weighted over the tower flux source area. The time continuous maps of daily C(sub ab) over the study field were generated by focusing in-situ measurements with retrievals generated with an integrated radiative transfer modeling tool (accurate to within +/-10%) using at-sensor radiances in green, red and near-infrared wavelengths acquired with an aircraft imaging system. The resultant daily changes in C(sub ab) within the tower flux source area generally correlated well with corresponding changes in daily calibrated LUE(sub n) derived from the tower flux data, and hourly water, energy and carbon flux estimation accuracies from TSEB were significantly improved when using C(sub ab) for delineating spatio-temporal variations in LUE(sub n). The results demonstrate the synergy between thermal infrared and shortwave reflective wavebands in producing valuable remote sensing data for operational monitoring of carbon and water fluxes.

Houlborg, Rasmus↗
NASA NTRS2011

Combining Observations in the Reflective Solar and Thermal Domains for Improved Mapping of Carbon, Water and Energy FLuxes

This study investigates the utility of integrating remotely sensed estimates of leaf chlorophyll (C(sub ab)) into a thermal-based Two-Source Energy Balance (TSEB) model that estimates land-surface CO2 and energy fluxes using an analytical, light-use-efficiency (LUE) based model of canopy resistance. Day to day variations in nominal LUE (LUE(sub n)) were assessed for a corn crop field in Maryland U.S.A. through model calibration with CO2 flux tower observations. The optimized daily LUE(sub n) values were then compared to estimates of C(sub ab) integrated from gridded maps of chlorophyll content weighted over the tower flux source area. Changes in Cab exhibited a curvilinear relationship with corresponding changes in daily calibrated LUE(sub n) values derived from the tower flux data, and hourly water, energy and carbon flux estimation accuracies from TSEB were significantly improved when using C(sub ab) for delineating spatio-temporal variations in LUE(sub n). The results demonstrate the synergy between thermal infrared and shortwave reflective wavebands in producing valuable remote sensing data for monitoring of carbon and water fluxes.

Houborg, Rasmus↗
NASA NTRS2015

Rapid Cycle Amine (RCA) 3.0 System Development

The Rapid Cycle Amine (RCA) 3.0 system is currently under development by NASA, the Lyndon B. Johnson Space Center (JSC) in conjunction with United Technologies Corporation Aerospace Systems (UTAS). The RCA technology is a new carbon dioxide (CO2) and humidity removal system that has been baselined for the Advanced Extravehicular Mobility Unit (AEMU) Portable Life Support System. The evolution of the RCA development has progressed through several iterations of technology readiness levels including RCA 1.0, RCA 2.0, and RCA 3.0 test articles. The RCA is an advancement over currently technologies due to its unique regeneration capability. The RCA is capable of simultaneously removing CO2 and humidity from an influent air steam and subsequent regeneration when exposed to a vacuum source. The RCA technology uses two solid amine sorbent beds in an alternating fashion to adsorb CO2 and water (uptake mode) and desorb CO2 and water (regeneration mode) at the same time. The two beds operate in an efficient manner so that while one bed is in the uptake mode, the other is in the regeneration mode, thus continuously providing an on-service sorbent bed by which CO2 and humidity may be removed. The RCA 2.0 and 3.0 test articles were designed with a novel valve assembly which allows for switching between uptake and regeneration modes with only one moving part while minimizing gas volume losses to the vacuum source by means of an internal pressure equalization step during actuation. The RCA technology also is low power, small, and has performed extremely well in all development testing thus far. A final design was selected for the RCA 3.0, fabricated, assembled, and performance tested in 2014 with delivery to NASAJSC in January 2015. This paper will provide an overview on the RCA 3.0 system design and results of pre-delivery testing with references to the development of RCA 1.0 and RCA 2.0.

Chullen, Cinda↗
NASA NTRS2017

Assessing Uncertainties in Gridded Emissions: A Case Study for Fossil Fuel Carbon Dioxide (FFCO2) Emission Data

Fossil fuel carbon dioxide (CO2) emissions (FFCO2) are the largest input to the global carbon cycle on a decadal time scale. Because total emissions are assumed to be reasonably well constrained by fuel statistics, FFCO2 often serves as a reference in order to deduce carbon uptake by poorly understood terrestrial and ocean sinks. Conventional atmospheric CO2 flux inversions solve for spatially explicit regional sources and sinks and estimate land and ocean fluxes by subtracting FFCO2. Thus, errors in FFCO2 can propagate into the final inferred flux estimates. Gridded emissions are often based on disaggregation of emissions estimated at national or regional level. Although national and regional total FFCO2 are well known, gridded emission fields are subject to additional uncertainties due to the emission disaggregation. Assessing such uncertainties is often challenging because of the lack of physical measurements for evaluation. We first review difficulties in assessing uncertainties associated with gridded FFCO2 emission data and present several approaches for evaluation of such uncertainties at multiple scales. Given known limitations, inter-emission data differences are often used as a proxy for the uncertainty. The popular approach allows us to characterize differences in emissions, but does not allow us to fully quantify emission disaggregation biases. Our work aims to vicariously evaluate FFCO2 emission data using atmospheric models and measurements. We show a global simulation experiment where uncertainty estimates are propagated as an atmospheric tracer (uncertainty tracer) alongside CO2 in NASA's GEOS model and discuss implications of FFCO2 uncertainties in the context of flux inversions. We also demonstrate the use of high resolution urban CO2 simulations as a tool for objectively evaluating FFCO2 data over intense emission regions. Though this study focuses on FFCO2 emission data, the outcome of this study could also help improve the knowledge of similar gridded emissions data for non-CO2 compounds with similar emission characteristics.

FFCO↗
NASA NTRS2010

Atmospheric Airborne Pressure Measurements Using the Oxygen A Band for the ASCENDS Mission

We report on airborne atmospheric pressure measurements using new fiber-based laser technology and the oxygen A-band at 765 nm. Remote measurements of atmospheric temperature and pressure are required for a number of NASA Earth science missions and specifically for the Active Sensing of CO2 Emissions Over Nights, Days, and Seasons (ASCENDS) mission. Accurate measurements of tropospheric CO2 on a global scale are very important in order to better understand its sources and sinks and to improve predictions on any future climate change. The ultimate goal of a CO2 remote sensing mission, such as ASCENDS, is to derive the CO2 concentration in the atmosphere in terms of mole fraction in unit of parts-per-million (ppmv) with regard to dry air. Therefore, both CO2 and the dry air number of molecules in the atmosphere are needed in deriving this quantity. O2 is a stable molecule and uniformly mixed in the atmosphere. Measuring the O2 absorption in the atmosphere can thus be used to infer the dry air number of molecules and then used to calculate CO2 concentration. With the knowledge of atmospheric water vapor, we can then estimate the total surface pressure needed for CO2 retrievals. Our work, funded by the ESTO IIP program, uses fiber optic technology and non-linear optics to generate 765 nm laser radiation coincident with the Oxygen A-band. Our pulsed, time gated technique uses several on- and off-line wavelengths tuned to the O2 absorption line. The choice of wavelengths allows us to measure the pressure by using two adjacent O2 absorptions in the Oxygen A-band. Our retrieval algorithm fits the O2 lineshapes and derives the pressure. Our measurements compare favorably with a local weather monitor mounted outside our laboratory and a local weather station.

Riris, Haris↗
NASA NTRS2011

Atmospheric Airborne Pressure Measurements Using the Oxygen A Band for the ASCENDS Mission

We report on airborne atmospheric pressure measurements using new fiber-based laser technology and the oxygen A-band at 765 nm. Remote measurements of atmospheric temperature and pressure are required for a number of NASA Earth science missions and specifically for the Active Sensing of CO2 Emissions Over Nights, Days, and Seasons (ASCENDS) mission. Accurate measurements of tropospheric CO2 on a global scale are very important in order to better understand its sources and sinks and to improve predictions on any future climate change. The ultimate goal of a CO2 remote sensing mission, such as ASCENDS, is to derive the CO2 concentration in the atmosphere in terms of mole fraction in unit of parts-per-million (ppmv) with regard to dry air. Therefore, both CO2 and the dry air number of molecules in the atmosphere are needed in deriving this quantity. O2 is a stable molecule and uniformly mixed in the atmosphere. Measuring the O2 absorption in the atmosphere can thus be used to infer the dry air number of molecules and then used to calculate CO2 concentration. With the knowledge of atmospheric water vapor, we can then estimate the total surface pressure needed for CO2 retrievals. Our work, funded by the ESTO IIP program, uses fiber optic technology and non-linear optics to generate 765 nm laser radiation coincident with the Oxygen A-band. Our pulsed, time gated technique uses several on- and off-line wavelengths tuned to the O2 absorption line. The choice of wavelengths allows us to measure the pressure by using two adjacent O2 absorptions in the Oxygen A-band. Our retrieval algorithm fits the O2 lineshapes and derives the pressure. Our measurements compare favorably with a local weather monitor mounted outside our laboratory and a local weather station.

Riris, Haris↗
NASA NTRS2014

Searching for Reduced Carbon on the Surface of Mars: The SAM Combustion Experiment

The search for reduced carbon has been a major focus of past and present missions to Mars. Thermal evolved gas analysis was used by the Viking and Phoenix landers and is currently in use by the Sample Analysis at Mars (SAM) instrument suite on the Mars Science Laboratory (MSL) to characterize volatiles evolved from solid samples, including those associated with reduced organic species. SAM has the additional capability to perform a combustion experiment, in which a sample of Mars regolith is heated in the presence of oxygen and the composition of the evolved gases is measured using quadrupole mass spectrometry (QMS) and tunable laser spectrometry (TLS) [1]. Organics detection on the Martian surface has been complicated by oxidation and destruction during heating by soil oxidants [2], including oxychlorine compounds, and terrestrial organics in the SAM background contributed by one of the SAM wet chemistry reagents MTBSTFA (N-Methyl-N-tertbutyldimethylsilyl- trifluoroacetamide) [3,4]. Thermal Evolved Gas Analysis (TEGA) results from Phoenix show a mid temperature CO2 release between 400 C - 680 C speculated to be carbonate, CO2 adsorbed to grains, or combustion of organics by soil oxidants [5]. Low temperature CO2 evolutions (approx. 200 C - 400 C) were also present at all three sites in Gale Crater where SAM Evolved Gas Analysis (EGA) was performed, and potential sources include combustion of terrestrial organics from SAM, as well as combustion and/or decarboxylation either indigenous martian or exogenous organic carbon [4,6]. By performing an experiment to intentionally combust all reduced materials in the sample, we hope to compare the bulk abundance of CO2 and other oxidized species evolved by combustion to that evolved during an EGA experiment to estimate how much CO2 could be contributed by reduced carbon sources. In addition, C, O, and H isotopic compositions of CO2 and H2O measured by TLS can contribute information regarding the potential sources of these volatiles.

Stern, J. C.↗
NASA NTRS1988

Estimating the seasonal carbon source-sink geography of a natural, steady-state terrestrial biosphere

The estimation of the seasonal dynamics of biospheric-carbon sources and sinks to be used as an input to global atmospheric CO2 studies and models is discussed. An ecological biosphere model is given and the advantages of the model are examined. Monthly maps of estimated biospheric carbon source and sink regions and estimates of total carbon fluxes are presented for an equilibrium terrestrial biosphere. The results are compared with those from other models. It is suggested that, despite maximum variations of atmospheric CO2 in boreal latitudes, the enormous contributions of tropical wet-dry regions to global atmospheric CO2 seasonality can not be ignored.

Box, Elgene O.↗
NASA NTRS1999

Combustion of Metals in Reduced-Gravity and Extraterrestrial Environment

As a result of the ongoing exploration of Mars and the several unmanned and manned missions planned for the future, increased attention has been given to the use of the natural resources of the planet for rocket propellant production and energy generation. Since the atmosphere of Mars consists of approximately 95% carbon dioxide (CO2), this gas is the resource of choice to be employed for these purposes. Unfortunately, CO2 is also a final product in most combustion reactions, requiring further processing to extract useful reactants such as carbon monoxide (CO), oxygen (O2), and hydrocarbons. An exception is the use Of CO2 as an oxidizer reacting directly with metal fuel. Since many metals burn vigorously with CO2, these may be used as an energy source and as propellants for an ascent/descent vehicle in sample-collection missions on Mars. In response to NASA's Human Exploration and Development of Space (HEDS) Enterprise to search for appropriate in-situ resource utilization techniques, this investigation will study the burning characteristics of promising metal/CO2 combinations. The use of reduced gravity is essential to eliminate the intrusive buoyant flows that plague the high-temperature metal reactions, to remove the destructive effect of gravity on the shape of molten metal samples, and to study the influence of radiative heat transfer from solid oxides undisturbed by natural convection. In studies with large metal specimens, the burning process is invariably influenced by strong convective currents that accelerate the reaction and shorten the burning times. Although these currents are nearly absent from small burning particles, the high emissivity of the flames, rapid reaction, small length scales, and intermittent explosions make the gathering of any useful information on burning rates and flame structure very difficult. This investigation has the ultimate goal of providing a careful probing of flame structure and dynamics by taking advantage of large, free-floating spherical metal samples and their corresponding long burning times available in reduced gravity. The first set of experiments has been conducted with magnesium (Mg) samples burning in the low-gravity environment generated by an aircraft flying parabolic trajectories. Owing to its high adiabatic flame temperature, oxidizer/fuel ratio, and heat per unit mass of fuel, as well as its low toxicity and low ignition temperature, Mg has been identified as a promising metal fuel with CO2 as oxidizer. The experimental effort is complemented by the development of a numerical model combining gas-phase chemical kinetics and transport mechanisms.

Abbud-Madrid, A.↗
NASA NTRS1991

Production and uses of liquefied atmosphere (CO2) on Mars

Carbon dioxide is universally accessible on Mars, and can be liquefied and separated from residual atmospheric gases by various compress-refrigeration cycles. Liquid CO2, stored under elevated pressures, can be used as a source of high pressure gas for nighttime power generation at a Martian base powered by solar energy during the daytime. Carbon dioxide can also be used for vehicular power. The extractable energy per unit mass of CO2 can exceed that of commercial lead-acid batteries for operating cycles without heat addition. Improved performance is possible using heat input from the ambient atmosphere or thermochemical agents. A unique vehicular application uses pressurized CO2 as a non-combustion low performance propellant for intermediate distance surface transportation. The thermodynamic properties of CO2 are presented with typical operating cycles for the application classes described above.

Waldron, R. D.↗
NASA NTRS1974

Venus cloud properties: Infrared opacity and mass mixing ratio

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is inferred from the infrared spectrum of the planet between 450 and 1250/cm. Justification for applying the homogeneous cloud model is found in the fact that numerous polarization and infrared data are mutually consistent within the framework of such a model; on the other hand, dense cloud models are not satisfactory. Volume extinction coefficients varying from 0.000005 to 0.000015/cm depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 0.000005 and a particle concentration of about 900 particles per cu cm at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.

Samuelson, R. E.↗
NASA NTRS1975

Venus cloud properties - Infrared opacity and mass mixing ratio

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is inferred from the infrared spectrum of the planet between 450 and 1250 per cm. Volume extinction coefficients varying from 0.000005 to 0.000015 per cm, depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 0.000005 and a particle concentration of about 900 particles per cu cm at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.

Samuelson, R. E.↗
NASA NTRS1977

Dispersed fluorescence observations of the CO/A 1Pi to X 1Sigma+/ transitions from photodissociation of CO2

The spectra of vacuum ultraviolet (vuv) fluorescence resulting from the excitation of CO2 by photons from an intense line emission source at 15 wavelengths in the range 449-955 A were obtained. The vibrational population distributions for the v = 0, 1, and 2 levels of the CO(A 1Pi) fragments were obtained at several incident photon wavelengths from 700 to 923 A. At incident photon wavelengths of 901 and 923, the relative intensities of the CO(A to X) bands were determined, permitting examination of the variation of the electronic transition moment with the r centroid.

Phillips, E.↗
NASA NTRS1978

Photodissociation of CO2 and quenching of metastables

Investigations in four different areas were carried out to further our understanding of the chemistry of the atmospheres of Mars and Venus. CO2 photodissociation quantum yields were determined in the 1300-1500 A spectral region by measuring both CO and oxygen atoms. The O(1S) quantum yield was determined for CO2 photodissociation in the 1060-1175 A spectral region. The measurement resolves the differences between two earlier experiments, and demonstrates that the O(1S) yield is unity throughout most of the measured region. The pathways for the quenching of O(1S) by N2O, CO2, H2O and NO were investigated and the source of the Venus nightglow, detected by Venera 9 and 10, was investigated. What appears to be a new O2 band system, was detected although the identity of the transition is not yet evident.

Slanger, T. G.↗
NASA NTRS1986

Theoretical study on the effect of the design of small (milli-Newton) thruster jets on molecular contamination for the space station

The self-induced molecular contamination around the space station could have adverse effects on space station components (for example solar panels) as well as scientific experiments that might be done on or near the space station. Aerospace engineers need to design a space station (SS) propulsion system that keeps the SS in a stable orbit and at the same time does not allow the propellant gases to interfere with the experiments of the user. One scenario that might accomplish the above requirements is to use an electrothermal propulsion system, resistojet, that will thrust continuously in the hundreds of milli-Newton range which will provide a constant altitude for the SS with a low g environment. As a first attempt to understand the contamination from such a propulsion system, a point source model was developed. The numerical results of the point source model are given. Number column densities for CO2 are presented as a function of direction of observation (line of sight), temperature of the exit gas, and mean exit velocity. All the results are for a constant exhaust rate of 5,000 kg/year. In addition, a mathematical model to study the effect of nozzle design on the induced molecular environment around the space station produced by simple gas propellants is described. The mathematical model would allow one to follow the expansion of the gas from the throat of a nozzle to the nozzle exit plane and then into the space external to the nozzle.

Riley, B. R.↗
NASA NTRS1987

A critical review of measurements of water vapor absorption in the 840 to 1100 cm(-1) spectral region

A set of eleven measurements of the water vapor continuum absorption in the 840 to 1100 sq cm spectral region is reviewed and compared with spectral models maintained by the Air Force Geophysics Laboratory. The measurements were made in four different ways: spectrometer with a White cell, CO2 laser with a White cell, CO2 laser with a spectrophone, and broadband radiation source over a long atmospheric path. Where possible, the data were selected at a water vapor partial pressure of ten torr buffered to 760 torr with N2 or synthetic air and a temperature of between 296 and 300 K. The intercomparison of the data leads to several observations and conclusions. First, there are four sets of laboratory data taken with nitrogen as the buffer gas which generally agree well mutually and with AFGL's HITRAN code. Second, there is one set of laboratory data that shows that using air as the buffer gas gives a few percent decrease in the water vapor continuum compared with using nitrogen as the buffer gas. Third, the atmospheric long-path measurements for water vapor partial pressure below about 12 torr are roughly grouped within 20 percent of the HITRAN values. Fourth, there are three sets of spectrophone data for water vapor in synthetic air which are significantly higher than any of the other measurements. This discrepancy is attributed to the effects of impurity gases in the cell.

Grant, William B.↗
NASA NTRS1988

Are there carbonate deposits in the Valles Marineris, Mars?

The precipitation of 30 mbar of Martian atmosphere CO2 as carbonates in lakes is suggested to be the source of thick sequences of layered deposits found in the Valles Marineris. Support is adduced for this scenario from processes occurring in the perennially frozen dry valley lakes of Antarctica, where the lake water is supersaturated with atmospheric gases. Atmospheric CO2 would have accumulated in such Martian lakes as temperatures fell, and the presence of an insulating ice cover would have allowed liquid water to exist.

Mckay, Christopher P.↗
NASA NTRS1989

Are there carbonate deposits in the Valles Marineris, Mars?

The precipitation of 30 mbar of Martian atmosphere CO2 as carbonates in lakes is suggested to be the source of thick sequences of layered deposits found in the Valles Marineris. Support is adduced for this scenario from processes occurring in the perennially frozen dry valley lakes of Antarctica, where the lake water is supersaturated with atmospheric gases. Atmospheric CO2 would have accumulated in such Martian lakes as temperature fell, and the presence of an insulating ice cover would have allowed liquid water to exist.

Nedell, Susan S.↗