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NASA NTRS1992

Energetic ion phase space densities in Neptune's magnetosphere

Ion phase densities of Neptune are presently ascertained at the first and second adiabatic invariants of charged-particle motion on the basis of an analysis of Voyager 2 measurements. The profiles thus obtained are interpreted as indicative of generally inward radial diffusion, with an energetic ion source near L = 10. Excellent agreement is obtained between inbound and outbound phase-space density profiles at the values of the invariants; this suggests approximately axisymmetric, quasi-stationary radiation belts. The inward diffusing power carried by energetic ions appears adequate for powering Neptune's aurora, if enough of the ions are lost to the Neptune atmosphere.

Cheng, Andrew F.↗

NASA NTRS1990

On the dip angle of subducting plates

A new approximate analytic model is developed for the thermal structure of a subducting plate with a finite length. This model provides the capability of easily examining the thermal and mechanical structure of a subducting plate with different lengths and at different angles. Also, the torque balance of a descending plate can be examined, and effects such as the leading edge effect, the adiabatic compression effect, and the phase change effect can be incorporated. A comparison with observed data indicates that short slabs are likely under torque equilibrium at present, while long slabs are probably dominated by their gravitational torques such that their dip angles are transient, moving toward a steeper dip angle similar to that of the Mariana slab.

Hsui, Albert T.↗

DOE OSTI2022

A Conical Intersection Influences the Ground State Rearrangement of Fulvene to Benzene

The rearrangement of fulvene to benzene is believed to play an important role in the formation of soot during hydrocarbon combustion. Previous work has identified two possible mechanisms for the rearrangement-a unimolecular path and a hydrogen-atom-assisted, bimolecular path. Computational results to date have suggested that the unimolecular mechanism faces a barrier of about 74 kcal/mol, which makes it unable to compete with the bimolecular mechanism under typical combustion conditions. This computed barrier is about 10 kcal/mol higher than the experimental value, which is an unusually large discrepancy for modern electronic structure theory. In the present work, we have reinvestigated the unimolecular mechanism computationally, and we have found a second transition state that is approximately 10 kcal/mol lower in energy than the previously identified one and, therefore, in excellent agreement with the experimental value. The existence of two transition states for the same rearrangement arises because there is a conical intersection between the two lowest singlet states which occurs in the vicinity of the reaction coordinates. The two possible paths around the cone on the lower adiabatic surface give rise to the two distinct saddle points. The lower barrier for the unimolecular mechanism now makes it competitive with the bimolecular one, according to our calculations. In support of this conclusion, we have reanalyzed some previous experimental results on anisole pyrolysis, which leads to benzene as a significant product and have shown that the unimolecular and bimolecular mechanisms for fulvene ? benzene must be occurring competitively in that system. Finally, we have identified that similar conical intersections arise during the isomerizations of benzofulvene and isobenzofulvene to naphthalene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2003

Development of a Cryogen-Free Continuous ADR for the Constellation-X Mission

Constellation-X is a multi-satellite x-ray astronomy mission presently being planned for launch in the 2010 time frame. Each of 4 identical satellites will contain a telescope and instruments for imaging and spectroscopic analysis of both hard and soft x-rays. The X- ray Microcalorimeter Spectrometer (XMS) instrument will use arrays of microcalorimeters to detect X-rays with energies from 0.2 to 6 keV. The technologies under development for this instrument include Transition-Edge Sensors (TES) with multiplexed SQUID readouts and NTD-Ge detectors with JFET readouts. Both will be operated at temperatures in the 50-60 mK range and both have a projected cooling power requirement of approximately 5 microwatts. In addition, in order to meet the lifetime requirement of 6 years (with a goal of 10 years), a mechanical cryocooler will be used to provide a heat sink for the low temperature cooler. The required performance is 20 mW at 6 K, with a goal of 4 K operation. In this paper we present the development status of an adiabatic demagnetization refigerator (ADR) that meets the cooling requirements of the X M S instrument. At present we have demonstrated a 4-stage ADR that operates continuously at 50 mK using a 4.2 K helium bath as a heat sink. The cooling power is 21 microwatts at 100 mK and 6 microwatts at 50 mK. Its efficiency when operating at 50 mK is 1 1 % of Carnot (accounting for all dissipation at 4.2 K and below, but not including power dissipation in the room temperature electronics), but this is expected to rise to 25% in the next generation system in which active gas-gap heat switches are replaced with passive devices. This will reduce the peak heat rejection rate of the ADR to less than 7 mW at 6 K. Details of the ADR s design and operation, as well as the development program leading up to a flight-qualified instrument, will be discussed.

Shirron, Peter↗

NASA NTRS2012

Effects of Riblets on Skin Friction in High-Speed Turbulent Boundary Layers

Direct numerical simulations of spatially developing turbulent boundary layers over riblets are conducted to examine the effects of riblets on skin friction at supersonic speeds. Zero-pressure gradient boundary layers with an adiabatic wall, a Mach number of M1 = 2.5, and a Reynolds number based on momentum thickness of Re = 1720 are considered. Simulations are conducted for boundary-layer flows over a clean surface and symmetric V- groove riblets with nominal spacings of 20 and 40 wall units. The DNS results confirm the few existing experimental observations and show that a drag reduction of approximately 7% is achieved for riblets with proper spacing. The influence of riblets on turbulence statistics is analyzed in detail with an emphasis on identifying the differences, if any, between the drag reduction mechanisms for incompressible and high-speed boundary layers.

Duan, Lian↗

DOE OSTI2024

Quantum simulations of hadron dynamics in the Schwinger model using 112 qubits

Hadron wave packets are prepared and time evolved in the Schwinger model using 112 qubits of IBM’s 133-qubit Heron quantum computer ibm_torino. The initialization of the hadron wave packet is performed in two steps. First, the vacuum is prepared across the whole lattice using the recently developed SC-ADAPT-VQE algorithm and workflow. SC-ADAPT-VQE is then extended to the preparation of localized states, and used to establish a hadron wave packet on top of the vacuum. This is done by adaptively constructing low-depth circuits that maximize the overlap with an adiabatically prepared hadron wave packet. Due to the localized nature of the wavepacket, these circuits can be determined on a sequence of small lattices using classical computers, and then robustly scaled to prepare wave packets on large lattices for simulations using quantum computers. Time evolution is implemented with a second-order Trotterization. To reduce both the required qubit connectivity and circuit depth, an approximate quasilocal interaction is introduced. This approximation is made possible by the emergence of confinement at long distances, and converges exponentially with increasing distance of the interactions. Using multiple error-mitigation strategies, up to 14 Trotter steps of time evolution are performed, employing 13,858 two-qubit gates (with a CNOT depth of 370). The propagation of hadrons is clearly identified, with results that compare favorably with Matrix Product State simulations. Finally, prospects for a near-term quantum advantage in simulations of hadron scattering are discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1982

Helium abundance enhancements in the solar wind

Evidence for a link between helium enhancements at 1 AU and transient coronal mass ejections is provided by the statistical analysis of 73 large helium abundance enhancement observations made by IMPs 6, 7 and 8 over 1972-1978. These events, in which helium abundance enhancement is greater than about 10%, are sporadic, sometimes clustered in time, occur approximately in phase with the solar cycle, and nearly 50% of them are associated with interplanetary shocks and/or geomagnetic activity sudden commencements. The plasma pattern associated with them is nevertheless independent of shock occurrence, and features high magnetic field strength, low alpha-proton velocity difference, and low proton temperature, suggesting that the enhancement is embedded in a closed, magnetically dominated structure that expands adiabatically. Evidence of an association between helium enhancement at 1 AU and type II and IV radio bursts in the corona is presented.

Borrini, G.↗

NASA NTRS2018

Design and On-Orbit Operation of the Adiabatic Demagnetization Refrigerator on the Hitomi Soft X-Ray Spectrometer Instrument

The Soft X-ray Spectrometer instrument on the Astro-H observatory contains a 6x6 array of x-ray microcalorimeters that is cooled to 50 mK by an adiabatic demagnetization refrigerator (ADR). The ADR consists of three stages in order to provide stable detector cooling using either a 1.2 K superfluid helium bath or a 4.5 K Joule-Thomson (JT) cryocooler as its heat sink. When liquid helium is present, two of the ADR's stages are used to single-shot cool the detectors while rejecting heat to the helium. After the helium is depleted, all three stages are used to continuously cool the helium tank (to about 1.5 K) and single-shot cool the detectors (to 50 mK), using the JT cryocooler as its heat sink. The Astro-H observatory, renamed Hitomi after its successful launch in February 2016, carried approximately 36 liters of helium into orbit. On day 5, the helium had cooled sufficiently (<1.4 K) to allow operation of the ADR. This paper describes the design, operation and on-orbit performance of the ADR, and the use of the ADR's heat rejection as a tool for mass gauging the helium tank.

adiabatic demagnetization refrigerator↗

NASA NTRS1994

Adiabatic invariants in stellar dynamics, 3: Application to globular cluster evolution

The previous two companion papers demonstrate that slowly varying perturbations may not result in adiabatic cutoffs and provide a formalism for computing the long-term effects of time-dependent perturbations on stellar systems. Here, the theory is implemented in a Fokker-Planck code and a suite of runs illustrating the effects of shock heating on globular cluster evolution are described. Shock heating alone results in considerable mass loss for clusters with R(sub g) less than or approximately 8 kpc: a concentration c = 1.5 cluster with R(sub g) kpc loses up to 95% of its initial mass in 15 Gyr. Only those with concentration c greater than or approximately 1.3 survive disk shocks inside of this radius. Other effects, such as mass loss by stellar evolution, will decrease this survival bound. Loss of the initial halo together with mass segregation leads to mass spectral indices, x, which may be considerably larger than their initial values.

Weinberg, Martin D.↗

NASA NTRS1974

Two-stage fan. 2: Data and performance with redesigned second stage rotor uniform and distorted inlet flows

A two-stage fan with a first rotor tip speed of 1450 ft/sec (441.96 m/sec) and no inlet guide vanes was tested with uniform and distorted inlet flows, with a redesigned second rotor having a part span shroud to prevent flutter, with variable-stagger stators set in nominal positions, and without rotor casing treatment. The fan achieved a pressure ratio 2.8 at a corrected flow of 185.4 lbm/sec (84.0 kg/sec), an adiabatic efficiency of 85.0 percent, and a stall margin of 12 percent. The redesigned second rotor did not flutter. Tip radial distortion reduced the stall margin at intermediate speed, but had little effect on stall margin at high or low speeds. Hub radial distortion reduced the stall margin at design speed but increased stall margin at low speed. Circumferential distortion reduced stall pressure ratio and flow to give approximately the same stall lines with uniform inlet flow. Distortions were attenuated by the fan. For Vol. 1, see N74-11421.

Messenger, H. E.↗

NASA NTRS1978

The role of O-type neutral lines in magnetic merging during substorms and solar flares

An analytical model of O-type configurations was derived, for visualizing the geometry and for numerical treatment of plasma flows. It was found that at a certain distance from the neutral line the mean particle motion became decoupled from that of magnetic field lines (which obey the MHD condition). The decoupling distance depended on initial conditions in momentum space, suggesting that the MHD approximation which averages out such conditions may not suffice for describing plasma dynamics near the neutral line. It was also found that after inflowing particles are decoupled from the field line motion, they go over to a mode of runaway acceleration along the neutral line. It is concluded that if merging occurs at an X-O pair, two particle populations may be expected - low energy particles accelerated adiabatically by earthward convection past the X-type line and high-energy particles convected towards the O-type line. The second acceleration process depends critically on the rapidity of merging and is therefore expected to vary considerably from event to event.

Stern, D. P.↗

NASA NTRSDate not supplied

On-Orbit Performance of the Adiabatic Demagnetization Refrigerator on XRISM

The X-ray Imaging and Spectroscopy Mission (XRISM) observatory was launched on Sep 7, 2023 from Tanegashima Space Center in Japan. Resolve, one its two instruments, performs high-resolution spectroscopy in the soft x-ray band (0.2-13 keV) using a 6x6 microcalorimeter array. The array cooled to 50 mK by a 3-stage ADR, which is linked to both a liquid helium dewar (at <1.2 K) and a Joule-Thomson (JT) cryocooler operating at <4.5 K. While liquid helium is present, two of the ADR stages provide detector cooling at 50 mK and auxiliary cooling to 0.5 K to intercept some parasitic heat loads, while rejecting waste heat to the helium. Once the helium is exhausted, Resolve enters a cryogen-free mode in which all three ADR stages are operated to provide detector cooling at 50 mK and to continuously cool the helium tank to 1.4 K. In this mode, waste heat is rejected to the JT cryocooler. Cryogen-free operation can be sustained as long as the JT and other cryocoolers remain fully operational. At launch, the helium tank contained approximately 35.6 liters of liquid. Within a few days, the helium cooled below 1.15 K, with an estimated 35.0 liters remaining. With an expected time average heat load of 0.68 mW, the helium lifetime was projected to exceed 4 years, but measurements of He volume on orbit suggest a significantly longer lifetime. Details of the ADR’s design and performance are presented.

x-ray astromony↗

NASA NTRS1973

Base pressure in laminar supersonic flow.

An asymptotic description is proposed for supersonic laminar flow over a wedge or a backward-facing step, for large Reynolds number and for a base or step height which is small compared with the boundary-layer length. The analysis is carried out for adiabatic wall conditions and a viscosity coefficient proportional to temperature. In a particular limit corresponding to a very thick boundary layer, a similarity law is obtained for the base pressure. For a thinner boundary layer an asymptotic form for the base pressure is obtained which shows the dependence on the parameters explicitly and which permits good agreement with experiment. This latter result is based on an inviscid-flow approximation for the corner expansion and for reattachment with viscous forces important primarily in a thin sublayer about the dividing streamline. A prediction of the pressure distribution at reattachment is given and the result is compared with experimental pressure distributions.

Messiter, A. F.↗

NASA NTRS1987

Theoretical studies of the potential surface for the F - H2 greater than HF + H reaction

The F + H2 yields HF + H potential energy hypersurface was studied in the saddle point and entrance channel regions. Using a large (5s 5p 3d 2f 1g/4s 3p 2d) atomic natural orbital basis set, a classical barrier height of 1.86 kcal/mole was obtained at the CASSCF/multireference CI level (MRCI) after correcting for basis set superposition error and including a Davidson correction (+Q) for higher excitations. Based upon an analysis of the computed results, the true classical barrier is estimated to be about 1.4 kcal/mole. The location of the bottleneck on the lowest vibrationally adiabatic potential curve was also computed and the translational energy threshold determined from a one-dimensional tunneling calculation. Using the difference between the calculated and experimental threshold to adjust the classical barrier height on the computed surface yields a classical barrier in the range of 1.0 to 1.5 kcal/mole. Combining the results of the direct estimates of the classical barrier height with the empirical values obtained from the approximation calculations of the dynamical threshold, it is predicted that the true classical barrier height is 1.4 + or - 0.4 kcal/mole. Arguments are presented in favor of including the relatively large +Q correction obtained when nine electrons are correlated at the CASSCF/MRCI level.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1989

Construction of surface pressure field from scatterometer wind field

An account of the construction of surface pressure fields from Seasat-A satellite scatterometer (SASS) winds as carried out by different methods, and the comparison of these pressure fields with those derived from in situ ship observations is presented. On the assumption that the pressure adjusts itself instantaneously to the motion field, it may be computed by various methods. One of these makes use of planetary boundary theory, and of the possible techniques in this category a two-layer iterative scheme admitting of the parametrization of diabatic and baroclinic effects and of secondary flow was chosen. A second method involves the assumption of zero two-dimensional divergence, leading to a Laplace's equation (the balance equation) in pressure, with the wind field serving as a forcing function. This method does not accommodate adiabatic or baroclinic effects, and requires a knowledge of the pressure at all boundary points. Two comparison fields are used for validation: the conventional operational analyses of the US National Meteorological Center (NMC), and the special analyses of the Gulf of Alaska Experiment (GOASEX), which were done by hand. The results of the computations were as follows: (1) The pressure fields, as computed from the SASS winds alone, closely approximated the NMC fields in regions where reasonable in situ coverage was available (typically, one or two mb differences over most of the chart, three to four mb in extreme cases); (2) In some cases the SASS-derived pressure fields displayed high-resolution phenomena not detected by the NMC fields, but evident in the GOASEX data; and, (3) As expected, the pressure fields derived from the balance equation were much smoother and less well resolved than the SASS-derived or NMC fields. The divergence as measured from the SASS winds is smaller than, but of the same order of magnitude as, the vorticity.

Wurtele, Morton G.↗

NASA NTRS1977

Persistent sunward flow of approximately 1.6 MeV protons at 1 AU

The paper is concerned with the anisotropy of 1.3 to 2.3 MeV protons measured with an electron/isotope spectrometer aboard the IMP 7 satellite during 317 six-hour periods, excluding periods when prompt solar particle events are observed. It is found that the diffusive streaming is predominantly toward the sun, indicating an essentially positive radial gradient in the particle density. The long-term average radial component of this anisotropy and its dependence on the solar wind speed are consistent with the anisotropy calculated with a steady-state propagation model including adiabatic energy loss.

Marshall, F. E.↗

DOE OSTI2020

HePHAESTUS: Heat Pipe Heterogeneous Approximation of Energy and Navier-Stokes Equations, Transience, and Non-Uniform Surface Heating [Slides]

A heat pipe is a liquid/vapor filled metal pipe capable of transporting large amounts of heat through evaporation of a liquid at one end and condensation of vapor at the other end creating a closed fluid loop. Heat pipes are widely used in the cooling of electronics and in space applications. Heat pipes are typically composed of a pipe wall, a wick material, a working fluid, and a central vapor channel. Heat is transferred into the working fluid at the “evaporator” end, through an adiabatic section, and heat is removed at the opposite end at the “condenser.” If no wick is used, gravitational acceleration can circulate the fluid due to the buoyancy of the vapor in the central core and a falling film of liquid at the pipe wall forming a “thermosyphon."

42 ENGINEERING↗

NASA NTRS1983

The time development of a blast wave with shock heated electrons

Accurate approximations are presented for the time development of both edge conditions and internal structures of a blast wave with shock heated electrons, and equal ion and electron temperatures at the shock. The cases considered evolve in cavities with power law ambient densities (including the uniform ambient density case) and have negligible external pressure. Account is taken of possible saturation of the thermal conduction flux. The structures evolve smoothly to the adiabatic structures.

Edgar, R. J.↗