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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Facet-Dependent Hydrogen Evolution Reaction on M 2 P (M = Ni, Co, Fe) Single Crystals

Transition-metal phosphides (MPs) are promising earth-abundant catalysts for hydrogen evolution reactions (HERs) due to their remarkable activity and stability. To further improve their properties, facet control is a key strategy. The growth of shape-selected nanoparticles may substantially enhance electrocatalytic activity, but this approach requires fundamental studies of facet-specific catalytic properties. There are only a few reports on the facet effects of MPs, which leads to a limited understanding of the activity of each facet and hampers catalyst design. Here, in this study, we grew large hexagonal-prism-shaped single crystals of three representative M 2 P (M = Ni, Co, and Fe) catalysts using metal flux routes. Two facets of M 2 P single crystals were tested to study facet-dependent HER activities, and it was consistently demonstrated that for all M 2 P crystals, a tip facet [(0001) for Ni 2 P/Fe 2 P and (010) for Co 2 P] had a higher activity than the side facet [(101̅0) for Ni 2 P/Fe 2 P and (100) for Co 2 P]. HER activity between the same facet elucidated the activity ordered between different transition metals as Fe 2 P > Co 2 P > Ni 2 P under low-potential regions. At high applied potentials, this trend is reversed due to the differences in Tafel slopes, with Ni 2 P becoming the most active catalyst, such that the activity of the (0001) facet of Ni 2 P approaches that of Pt. The calculated surface density of states (DOS) of each facet and its local curvature were found to be a useful descriptor for the activity trends among different transition metals of the same facets.

Co2P↗
NASA NTRS2000

The History of the XV-15 Tilt Rotor Research Aircraft: From Concept to Flight

This monograph is a testament to the efforts of many people overcoming multiple technical challenges encountered while developing the XV-15 tilt rotor research aircraft. The Ames involvement with the tilt rotor aircraft began in 1957 with investigations of the performance and dynamic behavior of the Bell XV-3 tilt rotor aircraft. At that time, Ames Research Center was known as the Ames Aeronautical Laboratory of the National Advisory Committee for Aeronautics (NACA). As we approach the new millennium, and after more than 40 years of effort and the successful completion of our initial goals, it is appropriate to reflect on the technical accomplishments and consider the future applications of this unique aircraft class, the tilt rotor. The talented engineers, technicians, managers, and leaders at Ames have worked hard with their counterparts in the U.S. rotorcraft industry to overcome technology barriers and to make the military and civil tilt rotor aircraft safer, environmentally acceptable, and more efficient. The tilt rotor aircraft combines the advantages of vertical takeoff and landing capabilities, inherent to the helicopter, with the forward speed and range of a fixed wing turboprop airplane. Our studies have shown that this new vehicle type can provide the aviation transportation industry with the flexibility for highspeed, long-range flight, coupled with runway-independent operations, thus having a significant potential to relieve airport congestion. We see the tilt rotor aircraft as an element of the solution to this growing air transport problem.

Maisel, Martin D.↗
NASA NTRS1979

Evaluation of turbo-propulsion simulators as a testing technique for fighter aircraft

Ames Research Center has under way a program to develop the technology for using turbine-powered jet engine simulators as a test technique for simulating installed jet engine characteristics in small-scale wind-tunnel models of complete VSTOL fighter configurations. The program consists of three key elements: (1) static testing SN003 prototype turbine engine simulator (MAPS), (2) the development of the Propulsion Simulator Calibration Laboratory at Ames, and (3) the design, fabrication, and testing of a twin-engine 'closely coupled' V/STOL fighter wind-tunnel model. The model will use the Compact Multi-mission Propulsion Simulator (CMAPS) and will also be tested in flow-through and jet-effects modes to assess the effect of simultaneous inlet and nozzle flow simulation. This paper includes a description of the planned effort and anticipated future tasks.

Bailey, R. O.↗
DOE OSTI2025

Enhancing stability, magnetic anisotropy, and coercivity of manganese aluminum: Machine learning, ab initio , and micromagnetic modeling

The binary manganese aluminum (MnAl) alloy with L⁢1 0 crystal structure is a promising rare earth (RE) element-free permanent magnetic material because of its exceptional magnetic properties. However, experimentally synthesizing it in a stable bulk form is extremely challenging. Here, in this study, an alternative method of stabilizing the material, a pathway for experimental synthesis and validation, is proposed and theoretically verified. This is done by partially substituting Mn and Al sites with Fe and Ni and identifying its enhanced phase stability, saturation magnetization density, magnetic anisotropy, and coercivity from density functional theory (DFT), machine learning (ML) crystal graph convolution neural network (CGCNN), and micro-magnetic modeling. When considering a fixed 50% Ni, the magnetic anisotropy increases with the increasing Fe content but decreases the formation energy. The calculated formation energies, elastic constants, and phonon frequencies demonstrate that the binary and quaternary compositions are stable. Most importantly, in 50% Fe and Ni-substituted-equiatomic phase, magnetic anisotropy constants and saturation magnetization density increase by 56% and 23% as compared to the MnAl. Further, the coercivity of the equiatomic phase predicted with micro-magnetic modeling is higher by 17% than the parent compound.

Bhandari, Churna [Ames National Laboratory, and Io↗
NASA NTRS1984

A summary of rotorcraft handling qualities research at NASA Ames Research Center

The objectives of the rotorcraft handling qualities research program at Ames Research Center are twofold: (1) to develop basic handling qualities design criteria to permit cost effective design decisions to be made for helicopters, and (2) to obtain basic handling qualities data for certification of new rotorcraft configurations. The research on the helicopter handling qualities criteria has focused primarily on military nap-of-the-earth (NOE) terrain flying missions, which are flown in day visual meteorological conditions (VMC) and instrument meteorological conditions (IMC), or at night. The Army has recently placed a great deal of emphasis on terrain flying tactics in order to survive and effectively complete the missions in modern and future combat environments. Unfortunately, the existing Military Specification MIL-H 8501A which is a 1961 update of a 1951 document, does not address the handling qualities requirements for terrain flying. The research effort is therefore aimed at filling the void and is being conducted jointly with the Army Aeromechanics Laboratory at Ames. The research on rotorcraft airworthiness standards with respect to flying qualities requirements was conducted to collaboration with the Federal Aviation Administration (FAA).

Chen, R. T.↗
DOE OSTI2026

Identifying materials-level sources of performance variation in superconducting transmon qubits

The Superconducting Quantum Materials and Systems Center, a U. S. Department of Energy National Quantum Information Science Research Center, has conducted a comprehensive and coordinated study using superconducting transmon qubit chips with known performance metrics to identify the underlying materials-level sources of device-to-device performance variation. Following qubit coherence measurements, these qubits of varying base superconducting metals and substrates have been examined with various non-destructive and invasive material characterization techniques at Northwestern University, Ames National Laboratory, and Fermilab as part of a blind study. We find trends in variations of the depth of the etched substrate trench, the thickness of the surface oxide, and the geometry of the sidewall, which when combined, lead to correlations with the T1 lifetime across different qubits on the same chip. In addition, we provide a list of features that varied from device to device, for which the impact on performance requires further studies. Finally, we identify two low-temperature characterization techniques that may potentially serve as proxy tools for qubit measurements. These insights provide materials-oriented solutions to not only reduce performance variations across neighboring devices but also to engineer and fabricate devices with optimal geometries to achieve performance metrics beyond the state-of-the-art values.

Murthy, Akshay A. [Fermilab] (ORCID:00000001767768↗
NASA NTRS2006

Time Relevance of Convective Weather Forecast for Air Traffic Automation

The Federal Aviation Administration (FAA) is handling nearly 120,000 flights a day through its Air Traffic Management (ATM) system and air traffic congestion is expected to increse substantially over the next 20 years. Weather-induced impacts to throughput and efficiency are the leading cause of flight delays accounting for 70% of all delays with convective weather accounting for 60% of all weather related delays. To support the Next Generation Air Traffic System goal of operating at 3X current capacity in the NAS, ATC decision support tools are being developed to create advisories to assist controllers in all weather constraints. Initial development of these decision support tools did not integrate information regarding weather constraints such as thunderstorms and relied on an additional system to provide that information. Future Decision Support Tools should move towards an integrated system where weather constraints are factored into the advisory of a Decision Support Tool (DST). Several groups such at NASA-Ames, Lincoln Laboratories, and MITRE are integrating convective weather data with DSTs. A survey of current convective weather forecast and observation data show they span a wide range of temporal and spatial resolutions. Short range convective observations can be obtained every 5 mins with longer range forecasts out to several days updated every 6 hrs. Today, the short range forecasts of less than 2 hours have a temporal resolution of 5 mins. Beyond 2 hours, forecasts have much lower temporal. resolution of typically 1 hour. Spatial resolutions vary from 1km for short range to 40km for longer range forecasts. Improving the accuracy of long range convective forecasts is a major challenge. A report published by the National Research Council states improvements for convective forecasts for the 2 to 6 hour time frame will only be achieved for a limited set of convective phenomena in the next 5 to 10 years. Improved longer range forecasts will be probabilistic as opposed to the deterministic shorter range forecasts. Despite the known low level of confidence with respect to long range convective forecasts, these data are still useful to a DST routing algorithm. It is better to develop an aircraft route using the best information available than no information. The temporally coarse long range forecast data needs to be interpolated to be useful to a DST. A DST uses aircraft trajectory predictions that need to be evaluated for impacts by convective storms. Each time-step of a trajectory prediction n&s to be checked against weather data. For the case of coarse temporal data, there needs to be a method fill in weather data where there is none. Simply using the coarse weather data without any interpolation can result in DST routes that are impacted by regions of strong convection. Increasing the temporal resolution of these data can be achieved but result in a large dataset that may prove to be an operational challenge in transmission and loading by a DST. Currently, it takes about 7mins retrieve a 7mb RUC2 forecast file from NOAA at NASA-Ames Research Center. A prototype NCWF6 1 hour forecast is about 3mb in size. A Six hour NCWFG forecast with a 1hr forecast time-step will be about l8mb (6 x 3mb). A 6 hour NCWF6 forecast with a l5min forecast time-step will be about 7mb (24 x 3mb). Based on the time it takes to retrieve a 7mb RUC2 forecast, it will take approximately 70mins to retrieve a 6 hour NCWF forecast with 15min time steps. Until those issues are addressed, there is a need to develop an algorithm that interpolates between these temporally coarse long range forecasts. This paper describes a method of how to use low temporal resolution probabilistic weather forecasts in a DST. The beginning of this paper is a description of some convective weather forecast and observation products followed by an example of how weather data are used by a DST. The subsequent sections will describe probabilistic forecasts followed by a descrtion of a method to use low temporal resolution probabilistic weather forecasts by providing a relevance value to these data outside of their valid times.

Chan, William N.↗
DOE OSTI2025

In Silico Design of Methyl-Driven Overhauser Dynamic Nuclear Polarization Agents

Overhauser effect (OE) dynamic nuclear polarization (DNP) has drawn attention owing to its enhanced performance at ultrahigh magnetic fields. The lack of design principles has, nevertheless, limited the development of OE polarizing agents when compared to those used for cross-effect DNP. Here, we measured the 19 F OE DNP performance of a series of CF 3 -functionalized Blatter-type radicals. Using density functional theory calculations, we accurately predict the methyl-driven OE performance, paving the way for computer-aided design of optimized OE DNP polarizing agents.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Defect-induced displacement of topological surface state in quantum magnet MnBi2Te4

The topological magnet MnBi2⁢Te4 (MBT), with gapped topological surface state, is an attractive platform for realizing quantum anomalous Hall and axion insulator states. However, the experimentally observed surface state gaps fail to meet theoretical predictions, although the exact mechanism behind the gap suppression has been debated. Recent theoretical studies suggest that intrinsic antisite defects push the topological surface state away from the MBT surface, closing its gap and making it less accessible to scanning probe experiments. Here, we report on the local effect of defects on the MBT surface states and demonstrate that high defect concentrations lead to a displacement of the surface states well into the MBT crystal, validating the theorized mechanism. The local and global influence of antisite defects on the topological surface states are studied with samples of varying defect densities by combining scanning tunneling microscopy, angle-resolved photoemission spectroscopy, and density functional theory. Our findings identify a combination of increased defect density and reduced defect spacing as the primary factors underlying the displacement of the surface states and suppression of surface gap, guiding further development of topological quantum materials.

Lupke, Felix [Carnegie Mellon University (CMU)]↗
DOE OSTI2026

Coexisting paramagnetic spins and long-range magnetic order in Ba4⁢(Ru0.92⁢Ir0.08)3⁢O10

We investigate the effect of dilute Ir substitution on the magnetism of the trimer-based ruthenate Ba4⁢Ru3⁢O10 using neutron diffraction, magnetic susceptibility measurements, first-principles calculations, and atomistic simulations. Neutron diffraction shows that Ir doping preserves the zigzag antiferromagnetic structure and the ordered-moment magnitude of the parent compound, in which the moments reside exclusively on the two outer Ru(2) sites of each Ru3⁢O12 trimer, while the central Ru(1) site remains nonmagnetic. The Néel temperature is reduced from ∼105 to 84.0(1) K upon 8% Ir substitution, while magnetic susceptibility reveals a pronounced low-temperature Curie-like upturn, indicating the coexistence of paramagnetic spins with long-range antiferromagnetic order. Density-functional calculations show that Ir preferentially occupies the central Ru(1) site, which disrupts the exchange pathways of the affected Ru3⁢O12 trimer state. Atomistic simulations incorporating this paramagnetic dilution reproduce the suppressed ordering temperature and the coexistence of ordered and paramagnetic components.

Islam, Farhan [Ames Laboratory]↗
NASA NTRS1976

Airborne simulation of Shuttle/Spacelab management and operation

The ASSESS (Airborne Science/Spacelab Experiments System Simulation) program is discussed. A simulated Spacelab operation was carried out aboard the CV-990 airborne laboratory at Ames Research Center. A scientific payload was selected to conduct studies in upper atmospheric physics and infrared astronomy with principal investigators from France, the Netherlands, England and the U.S. Two experiment operators (EOs) from the U.S. and two from Europe were trained to function as proxies for the principal investigators in operating, maintaining, and repairing the scientific instruments. The simulated mission, in which the EOs and a Mission Manager were confined to the aircraft and living quarters for a 1-week period while making scientific observations during nightly flights, provided experience in the overall management of a complex international payload, experiment preparation, testing, and integration, the training and selection of proxy operators, and data handling.

Mulholland, D. R.↗
NASA NTRS1984

An updated history of NACA/NASA rotary-wing aircraft research 1915-1984

Highlights are drawn from 'A History of NACA/NASA Rotating-Wing Aircraft Research, 1915-1970' by F. Gustafson to build an historical base upon which to build an extension from 1970-1984. Fundamental changes in how NASA conducted rotary-wing research in the early 1970s included an increasing level of contract research and closer ties with research conducted by the U.S. Army. The work done at the Army Research Laboratories at Ames, Langley, and Lewis Research Centers during 1970-1976 is briefly reviewed. In 1976 the Ames Research Center was assigned the Lead Center responsibility for helicopter research, though Langley retained research roles in structures, noise, dynamics, and aeroelasticity in support of rotorcraft. By 1984, NASA Rotorcraft Program Funding reached $35 million per year.

Ward, J.↗
NASA NTRS1986

CGI delay compensation

Computer-generated graphics in real-time helicopter simulation produces objectionable scene-presentation time delays. In the flight simulation laboratory at Ames Research Center, it has been determined that these delays have an adverse influence on pilot performance during agressive tasks such as nap of the earth (NOE) maneuvers. Using contemporary equipment, computer generated image (CGI) time delays are an unavoidable consequence of the operations required for scene generation. However, providing that magnitude distortions at higher frequencies are tolerable, delay compensation is possible over a restricted frequency range. This range, assumed to have an upper limit of perhaps 10 or 15 rad/sec, conforms approximately to the bandwidth associated with helicopter handling qualities research. A compensation algorithm is introduced here and evaluated in terms of tradeoffs in frequency responses. The algorithm has a discrete basis and accommodates both a large, constant transport delay interval and a periodic delay interval, as associated with asynchronous operations.

Mcfarland, R. E.↗
NASA NTRS1986

CGI delay compensation

Computer-generated graphics in real-time helicopter simulation produces objectionable scene-presentation time delays. In the flight simulation laboratory at Ames Research Center, it has been determined that these delays have an adverse influence on pilot performance during aggressive tasks such as nap-of-the-earth (NOE) maneuvers. Using contemporary equipment, computer-generated image (CGI) time delays are an unavoidable consequence of the operations required for scene generation. However, providing that magnitide distortions at higher frequencies are tolerable, delay compensation is possible over a restricted frequency range. This range, assumed to have an upper limit of perhaps 10 or 15 rad/sec, conforms approximately to the bandwidth associated with helicopter handling qualities research. A compensation algorithm is introduced here and evaluated in terms of tradeoffs in frequency responses. The algorithm has a discrete basis and accommodates both a large, constant transport delay interval and a periodic delay interval, as associated with asynchronous operations.

Mcfarland, Richard E.↗
NASA NTRS1946

Effect of Mach and Reynolds Numbers on Maximum Lift Coefficient

A knowledge of the effects of Mach and Reynolds numbers on the maximum lift coefficient is becoming of greater importance as the speeds and altitudes attainable by modern airplanes continually increase. Since most maximum-lift tests conducted to date have been either at full-scale Reynolds numbers and low Mach numbers or at high Mach numbers and small Reynolds numbers, very little is known about the inter-related effects of these two parameters on the maximum lift coefficient. In order to obtain quantitative information on these effects, flight tests were conducted at Ames Aeronautical Laboratory on six airplanes, three having NACA conventional airfoil sections, two having NACA low-drag sections, and the sixth having a North American Aviation - NACA compromise low-drag section. The results of these tests which cover a range of Mach numbers from 0.15 to 0.72 and of Reynolds numbers from 4,400,000 to 19,500,000 are assembled, together with a considerable quantity of pertinent wind-tunnel data, and analyzed in the present report. From this analysis, general conclusions have been reached indicating the manner in which the maximum lift coefficient is influenced by variations of Mach and Reynolds numbers.

AIRPLANES - BELL P-63A (AMER ) FLIGHT TESTS↗
NASA NTRS1945

Pressure Lag in Tubing Used in Flight Research

Tests described in this report were undertaken to obtain a quantitative measure of the pressure lag in typical pressure-tubing systems used by the Ames Aeronautical Laboratory in flight research investigations. Lag measurements were made with both single-direction and oscillating pressure changes. Single-direction pressure changes were investigated to determine if the lag in orifice-pressure lines and in the research airspeed and altitude measuring systems of pursuit-type airplane undergoing flight tests was sufficient to cause an appreciable error in the record of a sudden pressure change. Oscillating pressure changes were investigated with particular reference to the accuracy of pressure peaks in pressure-distribution measurements during the time of buffeting conditions as found in stalls. (author)

Turner, Howard L↗