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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Multi-scale nonlinear stress analysis of Nb 3 Sn superconducting accelerator magnets

A multi-scale nonlinear procedure to analyze the stress in Nb 3 Sn superconducting accelerator magnets is presented to address one of the most challenging obstacles currently facing the successful development of high-field superconducting magnets—the issue of stress management. The study demonstrates that gaskets (special nonlinear materials) are capable of modeling the complex nonlinear deformation behavior of insulation layers within the Nb 3 Sn coil block and that Hill materials (orthotropic materials utilizing the Hill yield criterion) are suitable to enable homogenization of the filamentary regions and the resin-impregnated Nb 3 Sn Rutherford cables. With the whole magnet under preload, cool-down, and Lorentz forces, the nonlinear behavior of the Nb 3 Sn coil was simulated, in three orthongonal axes, by the combined properties of the gaskets (insulation layers) and Hill materials (resin-impreganted cable). The procedure entailes minimal material assumptions because it incorporated measured stress-strain curves in the analysis. The coil was simulated to a high level of detail consisting of the insulation layers and resin-impregnated cables. The computed compressive azimuthal stresses of the cables were used to assess the stress-induced performance degradation. Through submodeling, the area-weighted average axial strains of the strands were computed and employed to evaluate the strain-induced performance degradation. The overall performance degradation of the Nb 3 Sn coil was thus obtained, and this information was subsequently used to guide the design of the overall magnet. Besides Nb 3 Sn magnets, this procedure can also be employed in the design of LTS, HTS, and room temperature magnets or in any composite structures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2001

Accelerated Testing Methodology in Constant Stress-Rate Testing for Advanced Structural Ceramics: A Preloading Technique

Preloading technique was used as a means of an accelerated testing methodology in constant stress-rate ('dynamic fatigue') testing for two different brittle materials. The theory developed previously for fatigue strength as a function of preload was further verified through extensive constant stress-rate testing for glass-ceramic and CRT glass in room temperature distilled water. The preloading technique was also used in this study to identify the prevailing failure mechanisms at elevated temperatures, particularly at lower test rate in which a series of mechanisms would be associated simultaneously with material failure, resulting in significant strength increase or decrease. Two different advanced ceramics including SiC whisker-reinforced composite silicon nitride and 96 wt% alumina were used at elevated temperatures. It was found that the preloading technique can be used as an additional tool to pinpoint the dominant failure mechanism that is associated with such a phenomenon of considerable strength increase or decrease.

Choi, Sung R.↗
NASA NTRS2001

Accelerated Testing Methodology in Constant Stress-Rate Testing for Advanced Structural Ceramics: A Preloading Technique

Preloading technique was used as a means of an accelerated testing methodology in constant stress-rate (dynamic fatigue) testing for two different brittle materials. The theory developed previously for fatigue strength as a function of preload was further verified through extensive constant stress-rate testing for glass-ceramic and CRT glass in room temperature distilled water. The preloading technique was also used in this study to identify the prevailing failure mechanisms at elevated temperatures, particularly at lower test rates in which a series of mechanisms would be associated simultaneously with material failure, resulting in significant strength increase or decrease. Two different advanced ceramics including SiC whisker-reinforced composite silicon nitride and 96 wt% alumina were used at elevated temperatures. It was found that the preloading technique can be used as an additional tool to pinpoint the dominant failure mechanism that is associated with such a phenomenon of considerable strength increase or decrease.

Choi, Sung R.↗
NASA NTRS1990

Computational aspects of sensitivity calculations in linear transient structural analysis

A study was performed focusing on the calculation of sensitivities of displacements, velocities, accelerations, and stresses in linear, structural, transient response problems. One significant goal of the study was to develop and evaluate sensitivity calculation techniques suitable for large-order finite element analyses. Accordingly, approximation vectors such as vibration mode shapes are used to reduce the dimensionality of the finite element model. Much of the research focused on the accuracy of both response quantities and sensitivities as a function of number of vectors used. Two types of sensitivity calculation techniques were developed and evaluated. The first type of technique is an overall finite difference method where the analysis is repeated for perturbed designs. The second type of technique is termed semi-analytical because it involves direct, analytical differentiation of the equations of motion with finite difference approximation of the coefficient matrices. To be computationally practical in large-order problems, the overall finite difference methods must use the approximation vectors from the original design in the analyses of the perturbed models. In several cases this fixed mode approach resulted in very poor approximations of the stress sensitivities. Almost all of the original modes were required for an accurate sensitivity and for small numbers of modes, the accuracy was extremely poor. To overcome this poor accuracy, two semi-analytical techniques were developed. The first technique accounts for the change in eigenvectors through approximate eigenvector derivatives. The second technique applies the mode acceleration method of transient analysis to the sensitivity calculations. Both result in accurate values of the stress sensitivities with a small number of modes and much lower computational costs than if the vibration modes were recalculated and then used in an overall finite difference method.

Greene, William H.↗
NASA NTRS1977

A NASTRAN DMAP alter for the coupling of modal and physical coordinate substructures

A method is described to derive a generalized coordinate model consisting of flexible cantilever modes and rigid body modes from a physical coordinate model using a direct matrix abstraction procedure alter to rigid format 3. This model can readily be coupled to other substructures using modal synthesis techniques. It allows the use of a reduced size model for structural analyses while maintaining the capability of recovering the accelerations, forces, stresses, etc., from the original, large, complex model. This output recovery is accomplished with the use of a loads transformation matrix which relates the output parameters to the modal coordinate accelerations. In addition, a method is described to synthesize structural models consisting of hybrid coordinates for use in dynamic response analyses where one structure is described using physical coordinates and the other using generalized modal coordinates.

Wilson, T. L.↗
DOE OSTI2022

Role of Local Structure in the Enhanced Dynamics of Deformed Glasses

External stress can accelerate molecular mobility of amorphous solids by several orders of magnitude. The changes in mobility are commonly interpreted through the Eyring model, which invokes an empirical activation volume. Here, we analyze constant-stress molecular dynamics simulations and propose a structure-dependent Eyring model, connecting activation volume to a machine-learned field, softness. We show that stress has a heterogeneous effect on the mobility that depends on local structure through softness. The barrier impeding relaxation reduces more for well-packed particles, which explains the narrower distribution of relaxation time observed under stress.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2023

Tuning Film Stresses for Open-Air Processing of Stable Metal Halide Perovskites

Challenges to upscaling metal halide perovskites (MHPs) include mechanical film stresses that accelerate degradation, dominate at the module scale, and can lead to delamination or fracture. In this work, we demonstrate open-air blade coating of single-step coated perovskite as a scalable method to control residual film stress after processing and introduce beneficial compression in the thin film with the use of polymer additives such as gellan gum and corn starch. The optoelectronic properties of MHP films with compression are improved with higher photoluminescence yields. MHP film stability is significantly improved under compression, under humidity, heat, and thermal cycling. By measuring the evolution of film stresses, we demonstrate for the first time that stress relaxation occurs in MHP films with tensile stress that correlates with film degradation. Finally, this discovery of a new mechanism underpinning MHP degradation shows that film stress can be used as a parameter to screen MHP devices and modules for quality control before deployment as a design for reliability criterion.

14 SOLAR ENERGY↗
DOE OSTI2018

Mechanism of Low-Temperature Reduction Degradation of Alumina-Containing Hematite Solid Solution Below 550 °C

Low-temperature reduction degradation (LTRD) of sinter has an adverse effect on blast furnace permeability, and it is mainly caused by the stress produced in the reduction process of hematite. This stress is strongly influenced by alumina dissolved in hematite crystal lattice. In this work, the experiments were conducted to investigate the effect of alumina dissolved in hematite solid solution (H{sub ss}) on LTRD by reducing H{sub ss} below 550 °C. Thermogravimetric analysis (TGA), X-ray diffraction (XRD), and optical microscope have been used to characterize the mass change and mineral change of samples, respectively. Jade software has been used to calculate the micro strain in magnetite for quantitatively studying the change of strain in reducing process. The results show that alumina was unfavorable to the reduction of H{sub ss} on thermodynamics, and the starting reduction temperature of H{sub ss} containing 6.0 mol pct alumina was 28 °C higher than that of pure hematite. According to the calculation on kinetics, the generation rate of stress was accelerated by dissolving alumina into hematite crystal lattice. The apparent activation energy of reduction reaction lowered from 47.89 to 28.07 kJ/mol with the increase of alumina content from 0.0 to 6.0 mol pct. The addition of alumina also increased the stress in the reduction products, and this stress was released in the form of LTRD.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2008

Fatigue Crack Growth in Peened Friction Stir Welds

Friction stir welding induces residual stresses that accelerates fatigue crack growth in the weld nugget. Shot peening over the weld had little effect on growth rate. Laser peening over the weld retarded the growth rate: Final crack growth rate was comparable to the base, un-welded material. Crack tunneling evident from residual compressive stresses. 2195-T8 fracture surfaces were highly textured. Texturing makes comparisons difficult as the material system is affecting the data as much as the processing. Material usage becoming more common in space applications requiring additional work to develop useful datasets for damage tolerance analyses.

Forth, Scott C.↗
NASA NTRS2003

Exposure to Carbon Nanotube Material: Assessment of Nanotube Cytotoxicity Using Human Keratinocyte Cells

Carbon nanotubes are new members of carbon allotropes similar to fullerenes and graphite. Because of their unique electrical, mechanical, and thermal properties, carbon nanotubes are important for novel applications in the electronics, aerospace, and computer industries. Exposure to graphite and carbon materials has been associated with increased incidence of skin diseases, such as carbon fiber dermatitis, hyperkeratosis, and naevi. We investigated adverse effects of single-wall carbon nanotubes (SWCNT) using a cell culture of immortalized human epidermal keratinocytes (HaCaT). After 18 h of exposure of HaCaT to SWCNT, oxidative stress and cellular toxicity were indicated by formation of free radicals, accumulation of peroxidative products, antioxidant depletion, and loss of cell viability. Exposure to SWCNT also resulted in ultrastructural and morphological changes in cultured skin cells. These data indicate that dermal exposure to unrefined SWCNT may lead to dermal toxicity due to accelerated oxidative stress in the skin of exposed workers.

Keratinocytes/drug effects↗
DOE OSTI2020

Behavior of Na and RbF-Treated CdS/Cu(In,Ga)Se 2 Solar Cells with Stress Testing under Heat, Light, and Junction Bias

In this work, the effects of Na and RbF alkali treatment on the metastability behavior of CdS/Cu(In,Ga)Se 2 solar cells are investigated with stress factors of heat, junction bias, and illumination. Four device types with and without Na or RbF treatments are subjected to heat- and light-soaking under open- and short-circuit (OC, SC) junction bias. Low-Na devices show a higher bandgap due to increased minimum Ga content, higher recombination current, and lower open-circuit voltage (V OC ). Devices with RbF post-deposition treatment (PDT) show an improvement in net doping density ≈10 16 cm –3 , V OC , and efficiency. Heat- and light-soaking under OC junction bias provokes an increase in net carrier concentration and V OC irrespective of the alkali treatments. After SC stress, a decrease in V OC and net carrier concentration is observed, which can be stabilized by RbF-PDT. An increase in Na and oxygen concentration in CIGS is observed for baseline and low-Na devices, respectively, after OC stress. The oxygen concentration in CdS decreases after heat- and light-soaking for devices without RbF-PDT, whereas it remains unchanged for devices with RbF-PDT. The atomic concentration profiles in CIGS significantly stabilize as a function of stress with the addition of RbF-PDT.

14 SOLAR ENERGY↗
DOE OSTI2017

Extended Pulse-Powered Humidity-Freeze Cycling for Testing Module-Level Power Electronics

An EMI suppression capacitor (polypropylene film type) failed by 'popcorning' due to vapor outgassing in pulse powered humidity-freeze cycles. No shorts or shunts could be detected despite mildly corroded metallization visible in the failed capacitor. Humidity-freeze cycling is optimized to break into moisture barriers. However, further studies will be required on additional module level power electronic (MLPE) devices to optimize the stress testing for condensation to precipitate any weakness to short circuiting and other humidity/bias failure modes.

14 SOLAR ENERGY↗
DOE OSTI2019

Thermally Conductive Backsheets (TCB) for Reduced Operating Temperatures

The performance of photovoltaic (PV) modules is primarily influenced by the plane of array (POA) irradiance and their operating temperature. The lower the module operating temperature, the higher is its performance. Increasing a module’s operating temperature reduces its power output due to an increase in the semiconductor’s intrinsic carrier density, leading to a reduction in the open-circuit voltage and, subsequently, reducing the maximum power point voltage. Reducing the operating temperature lowers the levelized cost of energy (LCOE) via increased energy production (i.e., more kilowatt hour over the life of the asset) and increased service lifetime (years in the field). The module operating temperature is dictated by the weather parameters and the thermal properties of module construction materials. The primary weather parameters influencing the PV module temperature are: the ambient temperature (directly related), irradiance (directly related), and wind speed (inversely related). The primary thermal properties of module construction materials influencing the PV module temperature are: the optical transmissivity and thermal conductivity of superstrate, the thermal conductivity of substrate, the thermal conductivity of encapsulant and the efficiency of the encapsulated solar cells. The primary goal of this study is to reduce the operating temperature of PV modules using thermally conductive backsheet (TCB) substrates developed by the industry. The temperature of PV modules installed in a large multi-MW plant can also be influenced by their physical locations in the plants due to the influence of wind direction. A thermal mapping of PV plants has also been investigated and presented in this study. The most commonly used PV backsheet material has been polyvinyl fluoride (DuPont trade name “Tedlar”)-based backsheet, which typically has three layers: Tedlar–polyethylene terephthalate (PET)–Tedlar (TPT). The primary goal of this project is to reduce the module operating temperature below the benchmark TPT backsheet temperature using newly developed TCBs by the industry. The overall approach of this project involves six focus areas: i) select and procure one TPT and thirteen promising TCBs available in the industry; ii) construct a large number of 1-cell and 9-cell modules using benchmark TPT and selected TCBs [all other construction materials are fixed and they are: glass superstrate, EVA encapsulant, mono-Si cell and junction box]; iii) to identify best performing TCBs, monitor the long-term field operating temperatures of the constructed modules which are installed in three climatic conditions (hot-low wind [Mesa, AZ], hot-high wind [Maricopa County, AZ] and temperate [Cumberland County, NC]; iv) to identify the most durable TCB, perform extended accelerated reliability testing of modules constructed with best three TCBs and benchmark TPT; v) to predict module temperature, develop physical and empirical thermal models with and without thermal properties of all construction materials in the modules, respectively; and vi) to determine the influence of wind speed and direction on the module operating temperature in a plant, and perform thermal mapping of PV modules in two large PV plants [Maricopa County, AZ and Cumberland County, NC]. The key achievements of this project are listed below: Backsheet selection: 14 backsheets were procured after an extensive literature and industry search. Finally, based on the thermal and other selection criteria, 1 TPT and 4 thermally conductive backsheets were selected for this project. Fabrication of mini modules: 50 one-cell modules were fabricated in year 1 for thermal performance evaluation. The module design was changed to nine-cell module at start of year 2 to mimic commercial design. 20 nine-cell modules were fabricated in year 2 for thermal performance evaluation. 28 four-cell modules were fabricated in year 3 for accelerated stress-testing. Thermal conductivity of backsheets: Year 1 TCBs showed at least 8% higher thermal conductivities than TPT. Year 2 and 3 TCBs showed at least 20% higher thermal conductivities than TPT. Installation of mini PV modules at three sites: 6 one-cell modules and 8 nine-cell modules were installed at AZ-1 site [Mesa, AZ]. 12 one-cell modules and 6 nine-cell modules were installed at each of two powerplants (AZ-2 [Maricopa County, AZ] and NC sites). Nominal operating cell temperatures (NOCT) of mini PV modules: NOCT of TCBs were observed to be lower than TPT with differences as high as 2°C. Comparison of thermal performance: The median operating temperature of one-cell modules was found to be reduced by 2°C by using TCB_A modules compared to TPT modules on several days in a month for few months in a year. The median temperature improvement of 4oC was achieved at several instances on a few days, but not all days, in a year using multiple TCBs compared to TPT. The final project milestone of achieving median temperature improvement of 5oC was achieved at several instances on a few days, but not all days, in a year using TCB_A compared to TPT. Empirical thermal model (without the need of construction material properties): Empirical thermal model for one-cell module was developed based on the input data of irradiance, wind speed and ambient temperatures. The primary input data differentiator for temperature differences between TPT and TCBs appears to be the irradiance level (solar gain). Accelerated durability testing: 20 four-cell modules using 4 backsheets (1 TPT and 3 TCBs) were exposed to Damp Heat 1000 hours (8 modules), UV/Thermal cycling (50 cycles)/Humidity freeze (10 cycles) test sequence (8 modules) and UV Weathering for qualification (8 modules). All the modules with four selected backsheets passed the stress tests per the retest guidelines of IEC 61215 standard for the backsheet change. Simplified comparative LCOE analysis: Using backsheet-specific power degradation levels in the accelerated tests (for TCB_A and TPT only), efficiency, service lifetime and assuming same cost for all backsheets, the LCOE of modules using TCB_A is determined to be lower than TPT. Due to lower operating temperature of TCB_A-based modules compared to TPT-based modules, the operating efficiency and service life of TCB_A-based modules are calculated to be higher than TPT-based modules. Temperature mapping of PV power plants: A distinct temperature difference (as high as 4°C) has been observed between the modules located in various parts of a single PV plant.

14 SOLAR ENERGY↗
DOE OSTI2020

In-Situ Measurement of Power Loss for Crystalline Silicon Modules Undergoing Thermal Cycling and Mechanical Loading Stress Testing

An in-situ method is proposed for monitoring and estimating the power degradation of mc-Si photovoltaic (PV) modules undergoing thermo-mechanical degradation tests that primarily manifest through cell cracking, such as mechanical load tests, thermal cycling and humidity freeze tests. The method is based on in-situ measurement of the module’s dark current-voltage (I-V) characteristic curve during the stress test, as well as initial and final module flash testing on a Sun simulator. The method uses superposition of the dark I-V curve with final flash test module short-circuit current to account for shunt and junction recombination losses, as well as series resistance estimation from the in-situ measured dark I-Vs and final flash test measurements. The method is developed based on mc-Si standard modules undergoing several stages of thermo-mechanical stress testing and degradation, for which we investigate the impact of the degradation on the modules light I-V curve parameters, and equivalent solar cell model parameters. Experimental validation of the method on the modules tested shows good agreement between the in-situ estimated power degradation and the flash test measured power loss of the modules, of up to 4.31 % error (RMSE), as the modules experience primarily junction defect recombination and increased series resistance losses. However, the application of the method will be limited for modules experiencing extensive photo-current degradation or delamination, which are not well reflected in the dark I-V characteristic of the PV module.

14 SOLAR ENERGY↗
DOE OSTI2020

Prediction of Climate-Specific Degradation Rate for Photovoltaic Encapsulant Discoloration

Encapsulant discoloration is a well-known field degradation mode of crystalline-silicon photovoltaic modules, particularly in the hot climate zones. The discoloration rate is influenced by several weathering factors, such as UV light, module temperature, and humidity, as well as the permeability of oxygen into the module. Here, a rate dependence model employing the modified Arrhenius equations to predict the degradation rate for encapsulant discoloration in different climates is presented. Two modeling approaches are introduced, which utilize the field and accelerated UV testing degradation data in conjunction with the field meteorological data to determine the acceleration factor for encapsulant browning. A novel method of accelerated UV stress testing at three simultaneous module temperatures in a single environmental chamber test run is implemented to estimate the activation energy for browning. The test was performed on three field-retrieved modules to capture the wear-out failure mechanism. The degradation in short-circuit current Isc rather than maximum power is used as a decisive parameter for the discoloration analysis. Furthermore, the developed model has been used to predict the Isc degradation rate for the Arizona field characterized by a hot and dry climate and is validated against the field-measured value. It has also been applied to other climate types, e.g., the cold and dry climate of New York.

14 SOLAR ENERGY↗
DOE OSTI2016

Hamiltonian analysis for linearly acceleration-dependent Lagrangians

We study the constrained Ostrogradski-Hamilton framework for the equations of motion provided by mechanical systems described by second-order derivative actions with a linear dependence in the accelerations. We stress out the peculiar features provided by the surface terms arising for this type of theories and we discuss some important properties for this kind of actions in order to pave the way for the construction of a well defined quantum counterpart by means of canonical methods. In particular, we analyse in detail the constraint structure for these theories and its relation to the inherent conserved quantities where the associated energies together with a Noether charge may be identified. The constraint structure is fully analyzed without the introduction of auxiliary variables, as proposed in recent works involving higher order Lagrangians. Finally, we also provide some examples where our approach is explicitly applied and emphasize the way in which our original arrangement results in propitious for the Hamiltonian formulation of covariant field theories.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

Sequential Stress Identifies Processing Defects in Bifacial Photovoltaic Modules That Limit Durability

Here, we use sequential stress to investigate hurdles to bifacial photovoltaic (PV) module durability from lamination defects. We test mini-modules with glass/glass (G/G) and glass/transparent-backsheet (G/TB) constructions using either ethylene vinyl acetate or polyolefin elastomer (POE) based encapsulants under a modified IEC 63209-2 sequential stress. This sequence includes multiple iterations of damp heat (DH200), full spectrum light exposure (A3), thermal cycling (TC50), and humidity/freeze (HF10). We compare indoor stress with outdoor exposure. Results show similar relative trends in degradation after a year outdoors compared to our first stress cycle. Subsequent stress cycles impart more severe damage than outdoor exposure for the short outdoor duration used here. Edge-pinch lamination defects in G/G mini-modules limit durability causing delamination and cell cracks. Conversely, we observe greater degradation in G/TB mini-modules compared to G/G in the later stages of the stress sequence when the backsheets are directly exposed to UV-containing light. Our results highlight: 1) the utility of sequential stress testing to uncover degradation modes in bifacial PV, 2) implications of using mini-modules for testing PV quality, and 3) the importance of lamination defects that must be avoided to ensure durability as the industry adopts G/G or G/TB packaging.

14 SOLAR ENERGY↗