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All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Ultraviolet spectroscopy of cometary comae - An update

This report provides an update to the reviews of ultraviolet spectroscopy of comets presented by Feldman (1982, 1983). Recent developments are largely related to the use of the International Ultraviolet Explorer (IUE), which to date has now observed approximately 20 comets. Distant, dusty comets are considered, taking into account Comet Bowell (1982 I), and Comet Cernis (1983l). Attention is also given to earth-approaching comets, the periodic Comet Encke in 1980 and 1984, and planned ultraviolet observations of P/Halley. It is pointed out that a large number of ultraviolet spectroscopic and imaging programs are planned for the 1985-86 apparition of Comet Halley utilizing encounter spacecraft, satellite and Space Shuttle borne observatories, and suborbital sounding rocket flights.

Feldman, P. D.↗
DOE OSTI2025

Determination of nuclear charge radius by extreme-ultraviolet spectroscopy of Na-like ions

We report on a method for determining the absolute nuclear charge radius of high-𝑍 elements using extreme-ultraviolet spectroscopy of highly charged Na-like ions in tandem with highly accurate atomic structure calculations of transition energy differences. The application of this method has reduced the nuclear charge radius uncertainty of 191 Ir by a factor of 8 from the currently accepted literature value, with a recently reported charge radius of 5.435(12) fm. The result reduces the charge radius uncertainty along the full Ir isotopic chain when combined with prior optical isotope shift measurements. The technique utilizes only a few million ions stored in an ion trap, which should apply to measurements with small quantities of radioactive nuclei.

Atom & ion trapping & guiding↗
NASA NTRS2011

Ultraviolet Spectroscopy of Asteroid(4) Vesta

We report a comprehensive review of the UV-visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm arc derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope in the ultraviolet displays a sharp minimum ncar sub-Earth longitude of 20deg, and maximum in the eastern hemisphere. This is completely consistent with the distribution of the spectral slope in the visible wavelength. The uncertainty of the measurement in the ultraviolet is approx.20%, and in the visible wavelengths better than 10%. The amplitude of Vesta's rotational lightcurves is approx.10% throughout the range of wavelengths we observed, but is smaller at 950 nm (approx.6%) ncar the 1-micron mafic band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/ncar-infrared lightcurves with respect to sub-Earth longitude. Vesta's average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible. and ncar-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies lack of global space weathering on Vesta. Keyword,: Asteroid Vesta; Spectrophotometry; Spectroscopy; Ultraviolet observations; Hubble Space Telescope observations

Li, Jian-Yang↗
DOE OSTI2023

Quantitation of olefins in sustainable aviation fuel intermediates using principal component analysis coupled with vacuum ultraviolet spectroscopy

Olefins, a common intermediate from biomass conversion processes, are undesirable in jet fuel because of their poor thermal stability. This paper presents an approach for olefin quantitation using 2D gas chromatography coupled with vacuum ultraviolet spectroscopy. Principal component analysis was used to reduce the dimensionality of the spectroscopic data from a highly olefinic fuel intermediate. A principal component template was created that enabled olefin quantitation, which was compared to the existing GCxGC-VUV approach from the literature. The principal component method was able to identify and quantify trace amounts of cyclodienes, which were present at only 0.01 wt% in the fuel sample. The principal component approach also identifies species that fall outside of the GCxGC template. For instance, quantitation with the literature method resulted in an olefin concentration of 0.95 times that of the principal component method due to olefins falling outside of the expected GCxGC regions. The principal component results were compared with 13 C and 1 H NMR data, which confirmed that the fuel had a high concentration of olefins and alkanes with little aromatic content.

Kosir, Shane↗
NASA NTRS1999

Fourier Transform Ultraviolet Spectroscopy of the A Pi-2(3/2) Direct Current X Pi-2(3/2) Transition of BrO

The first spectra of the A (2)Pi(sub 3/2) from X (2)Pi(sub 3/2) electronic transition of BrO using Fourier transform ultraviolet spectroscopy are obtained. Broadband vibrational spectra acquired at 298 +/- 2 K and 228 +/- 5 K, as well as high-resolution rotational spectra of the A from X 7,0 and 12,0 vibrational bands are presented. Wavenumber positions for the spectra are obtained with high accuracy, and cross section assignments are made, incorporating the existing literature. With 35 cm(exp -1) (0.40 nm) resolution the absolute cross section at the peak of the 7,0 band is determined to be (1.58 +/- 0.12) x 10(exp -17) sq cm/molecule at 298 +/- 2 K and (1.97 +/- 0.15) x 10(exp -17) sq cm/molecule at 228 +/- 5 K. BrO dissociation energies are determined with a graphical Birge-Sponer technique, using Le Roy-Bernstein theory to place an upper limit on the extrapolation. From the ground-state dissociation energy, D(sub o)" = 231.0 +/- 1.7 kJ/mol, the heat of formation of BrO(g) is calculated, del(sub f)H(0 K) = 133.7 +/- 1.7 kJ/mol and del(sub f)H(298.15 K) = 126.2 +/- 1.7 kJ/mol. Cross sections for the high-resolution 7,0 and 12,0 rotational peaks are the first to be reported. The band structures are modeled, and improved band origins, rotational constants, centrifugal distortion constants, and linewidths are determined. In particular, J-dependent linewidths and lifetimes are observed for the both the 7,0 and 12,0 bands.

Wilmouth, David M.↗
DOE OSTI2021

Ultraviolet spectroscopy of pressurized and supercritical carbon dioxide

Abstract Carbon dioxide (CO 2 ) is prevalent in planetary atmospheres and sees use in a variety of industrial applications. Despite its ubiquitous nature, its photochemistry remains poorly understood. In this work we explore the density dependence of pressurized and supercritical CO 2 electronic absorption spectra by vacuum ultraviolet spectroscopy over the wavelength range 1455-2000 Å. We show that the lowest absorption band transition energy is unaffected by a density increase up to and beyond the thermodynamic critical point (137 bar, 308 K). However, the diffuse vibrational structure inherent to the spectrum gradually decreases in magnitude. This effect cannot be explained solely by collisional broadening and/or dimerization. We suggest that at high densities close proximity of neighboring CO 2 molecules with a variety of orientations perturbs the multiple monomer electronic state potential energy surfaces, facilitating coupling between binding and dissociative states. We estimate a critical radius of ~4.1 Å necessary to cause such perturbations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2008

In-Field Diffuse Ultraviolet Spectroscopy and Imaging of the Stardust Sample Return Capsule

In-field diffuse Ultraviolet (UV) spectroscopy and imaging systems were developed for the purposes of evaluating the surface chemical composition of spacecraft thermal control coatings and materials. The investigation of these systems and the compilation of an associated UV reflectance and luminescence database were conducted using the Stardust Sample Return Capsule (SRC), located at the Johnson Space Center. Spectral responses of the surfaces of the Stardust forebody and aftbody in both reflectance and fluorescence modes were examined post-flight. In this paper, we report on two primary findings of in-field diffuse UV spectroscopy and imaging: (1) deduction of the thermal history of thermal control coatings of the forebody and (2) bond line variations in the aftbody. In the forebody, the thermal history of thermal control coatings may be deduced from the presence of particular semiconducting defect states associated with ZnO, a common emissivity constituent in thermal control coatings. A spatial dependence of this history was mapped for these regions. In the aftbody, luminescing defect states, associated with Si and SiO2 color centers were found along regions of bond variability.

Pugel, D. Elizabeth↗
DOE OSTI2022

Synthetic aromatic kerosene property prediction improvements with isomer specific characterization via GCxGC and vacuum ultraviolet spectroscopy

This research explores an advanced method of fuel composition determination and builds upon typical hydrocarbon group type analyses performed with two-dimensional gas chromatography (GCxGC). In this study, structural information of individual species within Virent’s Synthetic Aromatic Kerosene (SAK) is identified by vacuum ultraviolet (VUV) spectroscopy. By mass, 71.3% of the components elute within six peaks of the chromatogram, from which 12 unique species are identified through a novel deconvolution method. Overall, the identification of 93.6%m across 26 structural isomers is made by the methods described in this work. With 93.6%m ascribed to specific isomers, the precision of fuel property predictions improves dramatically. For example, the absolute error of the viscosity prediction is reduced by 90% because of this advancement in diagnostic capability, and its 95-percentile confidence interval (precision only) is reduced by 93%. Additionally, the properties of SAK, blended with hydro processed esters fatty acids (HEFA), are demonstrated to have blended properties consistent with conventional jet fuel.

10 SYNTHETIC FUELS↗
NASA NTRS1980

Ultraviolet spectroscopy of the outer layers of stars

Ultraviolet observations of the extended atmospheres and circumstellar envelopes of early-type and cool stars are reviewed. UV spectra of OB stars have shown that mass loss occurs in virtually all these stars and in many Be stars, and the Copernicus satellite has also provided information on the physical conditions and variability of the winds. The winds have been interpreted in terms of hot coronal wind models, imperfect flow models and radiation pressure models, and estimates of mass loss ranging from 10 to the -10th to 9 x 10 to the -6th solar masses/year have been obtained. Further UV data of faint stars, additional wavelengths and time variability are required. Recent UV and X-ray experiments have detected stellar chromospheres, transition regions coronas and winds in cool stars. Semiempirical line-profile and line-flux models and purely theoretical atmospheric models have been constructed to explain chromosphere, corona and wind data, and future observations of the physical properties of stellar chromospheres, coronas and winds, terms in the energy balance equation, stellar activity and its long-term variability and atmospheric modifications due to the presence of companion stars are proposed for such missions as Spacelab.

Snow, T. P., Jr.↗
NASA NTRS1995

The composition and structure of white dwarf atmospheres revealed by extreme ultraviolet spectroscopy

The ROentgen SATellite (ROSAT) and Extreme UltraViolet Explorer (EUVE) all-sky surveys have resulted in an important change in our understanding of the general composition of hydrogen-rich DA white dwarf atmospheres, with the photospheric opacity dominated by heavy elements rather than helium in the hottest stars (T > 40, 000 K). Most stars cooler than 40,000 K have more or less pure H atmospheres. However, one question, which has not been resolved, concerned the specific nature of the heavy elements and the role of helium in the hottest white dwarfs. One view of white dwarf evolution requires that H-rich DA stars form by gravitational settling of He from either DAO or He-rich central stars of planetary nebulae. In this case, the youngest (hottest) DA white dwarfs may still contain visible traces of He. Spectroscopic observations now available with EUVE provide a crucial test of these ideas. Analysis of data from the EUVE Guest Observer programme and EUVE public archive allows quantitative consideration of the sources of EUV opacity and places limits on the abundance of He which may be present.

Barstow, Martin A.↗
NASA NTRS1982

Ultraviolet spectroscopy of planetary nebulae in the Magellanic Clouds

Ultraviolet spectra of the high excitation planetary nebulas LMC P40, SMC N2, and SMC N5 are presented in an investigation of their chemical composition in an effort to make reliable estimates of the carbon abundance in extragalactic planetary nebulas. The carbon abundance is found to be almost 40 times more abundant in the SMC planetaries than in the SMC interstellar medium, and is about 6 times more abundant in the LMC planetary than in the LMC interstellar medium. The net result of carbon synthesis and convective dredgeup in the progenitors of planetary nebulas as reflected in the nebular carbon abundance is roughly the same in the Galaxy, the LMC, and the SMC.

Maran, S. P.↗
NASA NTRS1981

Solar Maximum Mission Experiment - Ultraviolet Spectroscopy and Polarimetry on the Solar Maximum Mission

The Ultraviolet Spectrometer and Polarimeter on the Solar Maximum Mission spacecraft is described. It is pointed out that the instrument, which operates in the wavelength range 1150-3600 A, has a spatial resolution of 2-3 arcsec and a spectral resolution of 0.02 A FWHM in second order. A Gregorian telescope, with a focal length of 1.8 m, feeds a 1 m Ebert-Fastie spectrometer. A polarimeter comprising rotating Mg F2 waveplates can be inserted behind the spectrometer entrance slit; it permits all four Stokes parameters to be determined. Among the observing modes are rasters, spectral scans, velocity measurements, and polarimetry. Examples of initial observations made since launch are presented.

Tandberg-Hanssen, E.↗
NASA NTRS1991

Ultraviolet spectroscopy of cometary comae

During the past decade, vacuum ultraviolet spectra of over 30 comets have been obtained with the IUE satellite observatory. With few exceptions, the spectra of these comets appear to be similar, with OH and H produced by the photodissociation of water being the dominant species and emissions of C, O, S, CS and CO2(+) usually present. Although signs of variabiity of many kinds in comet spectra appear, the evidence from the UV observations suggests that all comets have the same basic chemical composition and that observed differences are due to evolution and ageing processes. During the 1985-86 apparition of Comet Halley, spectra were also obtained by other spacecraft and by sounding rocket instruments, including a long-slit imaging spectrograph.

Feldman, Paul D.↗
NASA NTRS1994

Extreme ultraviolet spectroscopy of PKS 2155-304

We present the extreme ultraviolet (75-110 A) spectrum of the BL Lac object PKS 2155-304, the first spectrum of an extragalactic source obtained with the Extreme Ultraviolet Explorer (EUVE). The spectrum shows a generally smooth continuum, which can be modeled by a single power law plus interstellar absorption, and possibly an absorption feature at approximately 80 A. The best fit to the data suggests that the EUV spectrum can be interpreted as a simple extrapolation of the X-ray continuum, with an energy index alpha is approximately = 1.6; however, shallower or steeper power laws with indices between -0.4 and 2.7 cannot be ruled out by the existing EUV data alone. The data provide strong constraints on the interstellar neutral H and He along the line of sight. Using a column density of 1.36 x 10(exp 20)/sq cm for the Galactic neutral hydrogen along the PKS 2155-304 line of sight, the neutral helium column density is constrained to be 9%-10% of the hydrogen amount.

Fruscione, Antonella↗
DOE OSTI2020

Application of Generalized Standard Addition Method and Ultraviolet Spectroscopy to Quantify Electrolytic Depolymerization of Lignin

Industrial lignin waste is an important byproduct of bio-refineries and the paper industry. Depolymerization of this industrial lignin could generate useful aromatic compounds. This group has focused on electrolytic decomposition of biorefinery lignin. To quantify electrolytic decomposition of the lignin in a highly caustic solution, ultraviolet (UV) spectroscopy provides a useful probe. The conversion of the neat lignin to the oxidized products achieved by the electrolytic reactor may be measured by quantifying the amount of unreacted neat lignin that remains in the effluent. Because the properties of electrolytic decomposition products are largely unknown, a useful approach to quantify decomposition of the neat lignin is to use a multivariate calibration method referred to as the generalized standard addition method (GSAM). In this approach, the electrolytic decomposition products represent a background interference and the neat lignin that remains can be quantified. Furthermore, this approach allows the conversion of the neat lignin to be calculated in a solution that is a complex mixture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1995

Extreme ultraviolet spectroscopy and photometry of VV Puppis during a high accretion state

We determine the physical properties of the accretion region of the AM Her-type binary VV Puppis using extreme ultraviolet (EUV) medium-resolution spectroscopy and photometry obtained with the Extreme Ultraviolet Explorer (EUVE) observatory. The EUV continuum from VV Pup was detected in the wavelength range from 75 to 135 A and was simultaneously recorded with the Deep Survey/Spectrometer (DS/S) imaging telescope, allowing for the extraction of an accurate light curve. VV Pup appeared to have entered a high-accretion state just prior to the pointed EUVE observations. We use the EUV light curve to infer the diameter of the accretion region (d = 220 km) assuming a hemispherical geometry and a radius of 9000 km for the white dwarf. We perform a model atmosphere analysis and, based on the light curve properties and assuming a distance of 145 pc, we derive an effective temperature of the accretion region in the range 270,000 is less than T(sub eff) is less than 360,000 K and a neutral hydrogen column density in the local interstellar medium of n(sub H) = 1.9 - 3.7 x 10(exp 19)/sq cm. The total EUV/soft X-ray energy radiated by the accretion region is approximately 3.5 x 10(exp 32) ergs/s. Our results provide a first verification of past suggestions that deep heating of the white dwarf surface produces the soft X-ray flux from the polars. We present a possible detection of O VI absortion features, and we suggest that extensive EUVE observations targeting high-accretion events may result in oxygen and heavier element abundance determination in the accretion region.

Vennes, Stephane↗
NASA NTRS1987

The progenitor of SN 1987A - Spatially resolved ultraviolet spectroscopy of the supernova field

Careful deconvolution of spatially resolved IUE ultraviolet spectra shows that only two of the three stars detected in plate material before 1987 are now present near the site of SN 1987A. The separation, magnitudes, and spectra of these two are consistent with their identification as star 2 and star 3 of the Sanduleak -69 deg 202 trio. The clear implication is that star 1, the 12th mag B3 I star, has disappeared, and it may be identified as the progenitor of SN 1987A.

Sonneborn, George↗
NASA NTRS1989

Ultraviolet spectroscopy of pre-main-sequence accretion disks

Low-resolution, ultraviolet spectra of the pre-main-sequence objects Z Canis Majoris, V1057 Cygni, and FU Orionis are presented. Ultraviolet absorption features indicate spectral types of A5 I for FU Ori and F5 I for Z CMa. These results are in reasonable agreement with predictions of simple accretion disk models. The lack of significant veiling of ultraviolet absorption features implies that a hot boundary layer at the inner edge of the disk contributes less than 20 percent of the radiation at 2600-3200 A, which is significantly smaller than expected. It is suggested that accretion has significantly modified the structure of the underlying pre-main-sequence stars in these systems (perhaps by expanding the photosphere or by spinning up a radiative photosphere close to breakup velocity, or both), or that the boundary layer region is much more extended above the disk midplane than standard thin disk theories predict.

Kenyon, S. J.↗