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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Wake Closure Characteristics and Afterbody Heating on a Mars Sample Return Orbiter

Aeroheating wind-tunnel tests were conducted on a 0.028 scale model of an orbiter concept considered for a possible Mars sample return mission. The primary experimental objectives were to characterize hypersonic near wake closure and determine if shear layer impingement would occur on the proposed orbiter afterbody at incidence angles necessary for a Martian aerocapture maneuver. Global heat transfer mappings, surface streamline patterns, and shock shapes were obtained in the NASA Langley 20-Inch Mach 6 Air and CF4 Tunnels for post-normal shock Reynolds numbers (based on forebody diameter) ranging from 1,400 to 415,000, angles of attack ranging from -5 to 10 degrees at 0, 3, and 6 degree sideslip, and normal-shock density ratios of 5 and 12. Laminar, transitional, and turbulent shear layer impingement on the cylindrical afterbody was inferred from the measurements and resulted in a localized heating maximum that ranged from 40 to 75 percent of the reference forebody stagnation point heating. Comparison of laminar heating prediction to experimental measurement along the orbiter afterbody highlight grid alignment challenges associated with numerical simulation of three- dimensional separated wake flows. Predicted values of a continuum breakdown parameter revealed significant regions of non-continuum flow downstream of the flow separation at the MSRO shoulder and in the region of the reattachment shock on the afterbody. The presence of these regions suggest that the Navier-Stokes predictions at the laminar wind-tunnel condition may encounter errors in the numerical calculation of the wake shear layer development and impingement due to non-continuum effects.

Horvath, Thomas J.↗
NASA NTRS2004

Experimental Aerothermodynamics In Support Of The Columbia Accident Investigation

The technical foundation for the most probable damage scenario reported in the Columbia Accident Investigation Board's final report was largely derived from synergistic aerodynamic/aerothermodynamic wind tunnel measurements and inviscid predictions made at NASA Langley Research Center and later corroborated with engineering analysis, high fidelity numerical viscous simulations, and foam impact testing near the close of the investigation. This report provides an overview of the hypersonic aerothermodynamic wind tunnel program conducted at NASA Langley and illustrates how the ground-based heating measurements provided early insight that guided the direction and utilization of agency resources in support of the investigation. Global surface heat transfer mappings, surface streamline patterns, and shock shapes were measured on 0.0075 scale models of the Orbiter configuration with and without postulated damage to the thermal protection system. Test parametrics include angle of attack from 38 to 42 degs, sideslip angles of 38 to 42 degs, sideslip angles of plus or minus 1 deg, Reynolds numbers based upon model length from 0.05 x 10(exp 6) to 6.5 x 10(exp 6), and normal shock density ratios of 5 (Mach 6 Air) and 12 (Mach 6 CF4). The primary objective of the testing was to provide surface heating characteristics on scaled Orbiter models with outer mold line perturbations to simulate various forms of localized surface damage to the thermal protection system. Initial experimental testing conducted within two weeks of the accident simulated a broad spectrum of thermal protection system damage to the Orbiter windward surface and was used to refute several hypothesized forms of thermal protection system damage, which included gouges in the windward thermal protection system tiles, breaches through the wing new the main landing gear door, and protuberances along the wing leading edge that produced asymmetric boundary layer transition. As the forensic phase of the investigation developed and the condition of recovered debris was examined, increasing emphasis was placed on identifying wing leading edge damage (partially and fully missing reinforced carbon-carbon panels, and eventually holes in the wing leading edge with venting to the wing upper surface) that produced off-nominal heating trends consistent with extracted Orbiter flight recorder temperature data.

Horvath, Thomas J.↗
NASA NTRS2003

Experimental Hypersonic Aerodynamic Characteristics of the Space Shuttle Orbiter for a Range of Damage Scenarios

Aerodynamic tests in support of the Columbia accident investigation were conducted in two hypersonic wind tunnels at the NASA Langley Research Center, the 20-Inch Mach 6 Air Tunnel and the 20-Inch Mach 6 CF4 Tunnel. The primary purpose of these tests was to measure the forces and moments generated by a variety of outer mold line alterations (damage scenarios) using 0.0075-scale models of the Space Shuttle Orbiter (approximately 10 inches in length). Simultaneously acquired global heat transfer mappings were obtained for a majority of the configurations tested. Test parameters include angles of attack from 38 to 42 deg, unit Reynolds numbers from 0.26 to 3.0 x10^6 per foot, and normal shock density ratios of 5 (Mach 6 air) and 12 (Mach 6 CF4). The damage scenarios evaluated included asymmetric boundary layer transition, gouges in the windward surface acreage thermal protection system tiles, wing leading edge damage (partially and fully missing reinforced carbon-carbon (RCC) panels), holes through the wing from the windward surface to the leeside, deformation of the wing windward surface, and main landing gear door and/or gear deployment. The aerodynamic data were compared to the magnitudes and directions observed in flight, and the heating images were evaluated in terms of the location of the generated disturbances and how these disturbance might relate to the response of discrete gages on the Columbia Orbiter vehicle during entry. The measured aerodynamic increments were generally small in magnitude, as were the flight-derived values during most of the entry. Asymmetric boundary layer transition (ABLT) results were consistent with the flight-derived Shuttle ABLT model, but not with the observed flight trends for STS-107. The partially missing leading edge panel results best matched both the early aerodynamic and heating trends observed in flight. A progressive damage scenario is presented that qualitatively matches the flight observations for the full entry.

Brauckman, Gregory J.↗
NASA NTRS2004

Experimental Hypersonic Aerodynamic Characteristics of the Space Shuttle Orbiter for a Range of Damage Scenarios

Aerodynamic tests in support of the Columbia accident investigation were conducted in two hypersonic wind tunnels at the NASA Langley Research Center, the 20-Inch Mach 6 Air Tunnel and the 20-Inch CF4 Tunnel. The primary purpose of these tests was to measure the forces and moments generated by a variety of outer mold line alterations (damage scenarios) using 0.0075-scale models of the Space Shuttle Orbiter. Simultaneously acquired global heat transfer mappings were obtained for a majority of the configurations tested. Test parametrics included angles of attack from 38 to 42 deg, unit Reynolds numbers from 0.3 x 10(exp 6) to 3.0 x 10(exp 6) per foot, and normal shock density ratios of 5 (Mach 6 air) and 12 (CF4). The damage scenarios evaluated included asymmetric boundary layer transition, gouges in the windward surface thermal protection system tiles, wing leading edge damage (partially and fully missing reinforced carbon-carbon (RCC) panels), deformation of the wing windward surface, and main landing gear and/or door deployment. The measured aerodynamic increments for the damage scenarios examined were generally small in magnitude, as were the flight-derived values during most of the entry prior to loss of communication. A progressive damage scenario is presented that qualitatively matches the flight observations for the STS-107 entry.

Brauckmann, Gregory J.↗
NASA NTRS2012

The Namibia Early Flood Warning System, A CEOS Pilot Project

Over the past year few years, an international collaboration has developed a pilot project under the auspices of Committee on Earth Observation Satellite (CEOS) Disasters team. The overall team consists of civilian satellite agencies. For this pilot effort, the development team consists of NASA, Canadian Space Agency, Univ. of Maryland, Univ. of Colorado, Univ. of Oklahoma, Ukraine Space Research Institute and Joint Research Center(JRC) for European Commission. This development team collaborates with regional , national and international agencies to deliver end-to-end disaster coverage. In particular, the team in collaborating on this effort with the Namibia Department of Hydrology to begin in Namibia . However, the ultimate goal is to expand the functionality to provide early warning over the South Africa region. The initial collaboration was initiated by United Nations Office of Outer Space Affairs and CEOS Working Group for Information Systems and Services (WGISS). The initial driver was to demonstrate international interoperability using various space agency sensors and models along with regional in-situ ground sensors. In 2010, the team created a preliminary semi-manual system to demonstrate moving and combining key data streams and delivering the data to the Namibia Department of Hydrology during their flood season which typically is January through April. In this pilot, a variety of moderate resolution and high resolution satellite flood imagery was rapidly delivered and used in conjunction with flood predictive models in Namibia. This was collected in conjunction with ground measurements and was used to examine how to create a customized flood early warning system. During the first year, the team made use of SensorWeb technology to gather various sensor data which was used to monitor flood waves traveling down basins originating in Angola, but eventually flooding villages in Namibia. The team made use of standardized interfaces such as those articulated under the Open Cloud Consortium (OGC) Sensor Web Enablement (SWE) set of web services was good [1][2]. However, it was discovered that in order to make a system like this functional, there were many performance issues. Data sets were large and located in a variety of location behind firewalls and had to be accessed across open networks, so security was an issue. Furthermore, the network access acted as bottleneck to transfer map products to where they are needed. Finally, during disasters, many users and computer processes act in parallel and thus it was very easy to overload the single string of computers stitched together in a virtual system that was initially developed. To address some of these performance issues, the team partnered with the Open Cloud Consortium (OCC) who supplied a Computation Cloud located at the University of Illinois at Chicago and some manpower to administer this Cloud. The Flood SensorWeb [3] system was interfaced to the Cloud to provide a high performance user interface and product development engine. Figure 1 shows the functional diagram of the Flood SensorWeb. Figure 2 shows some of the functionality of the Computation Cloud that was integrated. A significant portion of the original system was ported to the Cloud and during the past year, technical issues were resolved which included web access to the Cloud, security over the open Internet, beginning experiments on how to handle surge capacity by using the virtual machines in the cloud in parallel, using tiling techniques to render large data sets as layers on map, interfaces to allow user to customize the data processing/product chain and other performance enhancing techniques. The conclusion reached from the effort and this presentation is that defining the interoperability standards in a small fraction of the work. For example, once open web service standards were defined, many users could not make use of the standards due to security restrictions. Furthermore, once an interoperable sysm is functional, then a surge of users can render a system unusable, especially in the disaster domain.

Mandl, Daniel↗
DOE OSTI2026

Ecological Insights from Transferable Plant Biomass Mapping across the Arctic using High-resolution Structure-from-Motion and LiDAR Data

Warmer temperatures, permafrost thaw, and increased wildfire activity are driving rapid ecological change across the Arctic, significantly altering plant productivity and aboveground biomass (AGB). These rapid changes highlight the urgent need to improve monitoring of vegetation dynamics in the Earth’s northern ecosystems, where high spatiotemporal heterogeneity occurs at scales finer than those captured by traditional satellite observations. The growing use of Unoccupied Aerial Systems (UASs) presents an opportunity to overcome this limitation. Yet, the diversity of UAS platforms, sensors, and data collection and processing workflows presents challenges for developing standardized, generalizable approaches. To address this challenge, we compiled 672 AGB plots co-located with 183 UAS-based Structure-from-Motion (SfM) or Light Detection and Ranging (LiDAR) surveys collected across the Arctic. Here, we: (1) evaluated the generalizability of UAS-derived canopy structure derived from high-resolution SfM and LiDAR for estimating AGB, (2) assessed scaling errors and their sources in two recent satellite-based AGB products derived from Landsat and MODIS, and (3) demonstrated the use of high-resolution AGB maps to quantify biomass variation across tundra plant functional types (PFTs) and to monitor post-fire recovery. Our results show that both SfM and LiDAR accurately captured AGB and its variability across tundra PFTs using a Random Forest (RF) model (overall RMSE: 0.336 kg/m2), with mapping performance varying slightly by region and data source. Using UAS-derived AGB maps as a benchmark, we identified systematic biases in satellite-derived AGB products, largely attributable to the magnitude of AGB and structural heterogeneity within coarse-resolution pixels. Applying our model to repeat UAS surveys following a tundra fire on Seward Peninsula, we observed rapid AGB recovery in non-shrub patches, with biomass recovering to pre-fire levels within 2 years. In contrast, shrub patches recovered more slowly, with AGB gains continuing over 2–4 years through both in-patch growth and lateral expansion (via dispersal) into remaining burned areas. Overall, these findings demonstrate the generalizability of UAS-based SfM and LiDAR data for estimating tundra AGB and highlight the potential of our approach to be broadly applied to generate high-quality AGB data for ecological monitoring and model benchmarking across the Arctic.

Yang, Daryl [ORNL] (ORCID:0000000317057823)↗
DOE OSTI2024

Elucidating Photoinduced Processes of Photosystem I Via Multidimensional Electronic and Vibrational Spectroscopies

This project was motivated by an overarching goal to elucidate the mechanism of energy and electron transfer that governs the efficient charge separation in photosystem I (PSI) complexes. PSI is a natural light harvesting complex that drives oxygenic photosynthesis in plants, algae, and cyanobacteria. It uses ~300 tightly packed chlorophylls (Chls) to absorb photons, transfer the excitation energy to the reaction center (RC), and generate a charge separated state with near unity quantum efficiency (QE). A better understanding of the mechanism of energy transfer and charge separation in PSI is required for understanding the high QE of natural light harvesting complexes, and it could lead to the further development of artificial photosynthetic systems for solar energy conversion and modification of light harvesting complexes to improve crop yields. We applied two-dimensional optical spectroscopies to different cyanobacterial photosystem I complexes, including PSI complexes that contain Chl f molecules, to map energy transfer pathways and gain insight into the efficient light harvesting of PSI. We used two-dimensional electronic spectroscopies (2DES) to map energy transfer in Chl a and Chl f containing PSI complexes. To investigate the Chl f PSI complexes, we modified our spectrometer to probe the lower energy states associated with Chl f molecules. We interpreted the 2DES spectra through global analysis procedures to generate maps of energy transfer. We also constructed a two-dimensional electronic vibrational (2DEV) spectrometer that will be used to investigate charge transfer transitions and dynamics within PSI complexes. Measurements were performed on model systems to establish general data analysis procedures for interpreting 2D spectra and gain insight into protein cofactor interactions.

14 SOLAR ENERGY↗
NASA NTRS2025

Mission-Maps For Outbound Cislunar Transfer Trajectories

This study quantifies the robustness and sensitivity of an outbound cislunar trajectory for a lunar lander in the form of mission-maps, or topological maps that allows either a computer program or mission designer to intuitively optimize the placement of critical outbound correction burns from the derived sensitivity data. The non-linear multi-body dynamics are applied to generate an outbound cislunar reference profile used by a linear covariance analysis (LinCov) tool to compute the expected Δv and trajectory dispersions due to the initial state uncertainty, sensor errors, maneuver execution errors, and disturbance accelerations along the outbound cislunar profile. The rapid performance analysis capabilities of LinCov are complimented with parallel processing techniques to evaluate hundreds and thousands of different translational burn locations, placements, and targeting constraints to identify the combination that minimizes the total Δv usage (nominal plus 3σ Δv) and trajectory dispersions at lunar orbit insertion. This study utilizes a generalized reference targeting algorithm to quickly assess the integrated closed-loop GN&C system performance due to different targeting configurations and constraints. The resulting mission maps provide an intuitive insight to ascertain each trajectory correction maneuver’s (TCM) sensitivity to different burn times along an outbound cislunar trajectory and quickly identify desirable engineering tradeoffs when performing analysis on the number and placement of these burns that nominally zero. Multiple mission maps are generated for a variety of different performance parameters that allow engineers to visually identify optimal solutions for trajectory correction maneuver placements, the number of correction burns, and the targeting constraints for each burn.

GN&C↗
DOE OSTI2024

Catalytically Active Site Mapping Realized through Energy Transfer Modeling

Abstract The demands of a sustainable chemical industry are a driving force for the development of heterogeneous catalytic platforms exhibiting facile catalyst recovery, recycling, and resilience to diverse reaction conditions. Homogeneous‐to‐heterogeneous catalyst transitions can be realized through the integration of efficient homogeneous catalysts within porous matrices. Herein, we offer a versatile approach to understanding how guest distribution and evolution impact the catalytic performance of heterogeneous host–guest catalytic platforms by implementing the resonance energy transfer (RET) concept using fluorescent model systems mimicking the steric constraints of targeted catalysts. Using the RET‐based methodology, we mapped condition‐dependent guest (re)distribution within a porous support on the example of modular matrices such as metal–organic frameworks (MOFs). Furthermore, we correlate RET results performed on the model systems with the catalytic performance of two MOF‐encapsulated catalysts used to promote CO 2 hydrogenation and ring‐closing metathesis. Guests are incorporated using aperture‐opening encapsulation, and catalyst redistribution is not observed under practical reaction conditions, showcasing a pathway to advance catalyst recyclability in the case of host–guest platforms. These studies represent the first generalizable approach for mapping the guest distribution in heterogeneous host–guest catalytic systems, providing a foundation for predicting and tailoring the performance of catalysts integrated into various porous supports.

Thompson, William J.↗
DOE OSTI2024

Catalytically Active Site Mapping Realized through Energy Transfer Modeling

Abstract The demands of a sustainable chemical industry are a driving force for the development of heterogeneous catalytic platforms exhibiting facile catalyst recovery, recycling, and resilience to diverse reaction conditions. Homogeneous‐to‐heterogeneous catalyst transitions can be realized through the integration of efficient homogeneous catalysts within porous matrices. Herein, we offer a versatile approach to understanding how guest distribution and evolution impact the catalytic performance of heterogeneous host–guest catalytic platforms by implementing the resonance energy transfer (RET) concept using fluorescent model systems mimicking the steric constraints of targeted catalysts. Using the RET‐based methodology, we mapped condition‐dependent guest (re)distribution within a porous support on the example of modular matrices such as metal–organic frameworks (MOFs). Furthermore, we correlate RET results performed on the model systems with the catalytic performance of two MOF‐encapsulated catalysts used to promote CO 2 hydrogenation and ring‐closing metathesis. Guests are incorporated using aperture‐opening encapsulation, and catalyst redistribution is not observed under practical reaction conditions, showcasing a pathway to advance catalyst recyclability in the case of host–guest platforms. These studies represent the first generalizable approach for mapping the guest distribution in heterogeneous host–guest catalytic systems, providing a foundation for predicting and tailoring the performance of catalysts integrated into various porous supports.

Thompson, William J.↗
DOE OSTI2023

DOE Bioenergy Technologies Office (BETO) 2023 Project Peer Review: WBS 2.4.1.100 Bench Scale Research & Development

Bench Scale Integration develops and optimizes fermentation processes to produce bio-based fuels and chemicals for commercial scale-up. The project uses fermentation science to achieve high titers and production rates by, for example, manipulating how the microorganisms are fed biomass sugars and nutrients, modifying fermentation conditions (pH, temperature, aeration) or developing online control strategies for better fermentation operations and high titer, rates, and yield (TRY). For this period of performance, we continued our development of a commercial-ready 2,3-butanediol (BDO) fermentation from biomass sugars utilizing NREL's proprietary Zymomonas mobilis microorganism. The engineered Z. mobilis can use all the main sugars in corn stover biomass, which are glucose, xylose, and arabinose. BDO is a versatile, low-carbon chemical which can be catalytically upgraded to a variety of hydrocarbon fuels and chemicals. The project had three goals during this review period; evaluate the technical feasibility of using whole slurry pretreated corn stover to achieve the techno-economic analysis (TEA) performance goals, continue optimizing a liquor-based fed-batch fermentation process for high titer, and develop strategies to enable scale-up. After evaluating different iterations of a whole slurry fermentation that did not meet the TEA goals, a Go/No-Go decision was made to pivot to liquor-only with new TEA performance targets, the main one being 140 g/L titer. We successfully met this goal, producing 141 g/L BDO at 1 g/L-hr productivity and 84% process yield. This titer and productivity attracted industrial interest to scale the fermentation resulting in a Technology Commercialization Fund project award in 2022. We used an NREL developed near-infra red (NIR) spectroscopy method for rapid analysis which allowed for changes to aeration levels and sugar feeding during the fermentation to maximize BDO production. The NIR analysis can be done using a hand-held spectrometer, essentially taking the analysis on to the plant floor during scale-up and preliminary work shows the feasibility of using an online probe for continuous monitoring and control. The other scale-up tool is mapping oxygen transfer coefficient (kLa) and oxygen transfer rate (OTR) in various vessels to find conditions that match the optimized 500 mL vessels. Showing a correlation to the mapping work, which is done with water and a dissolved oxygen probe, can reduce the risk of failed fermentations during scale-up. Our end-of-project goal is to meet the design target BDO titer (140-150 g/L) from DMR corn stover liquor at 1000L or larger scale to demonstrate BDO process design case and transfer the technology to industrial fermentation stakeholders for commercialization.

2 3-butanediol↗
DOE OSTI2017

Extending ORNL HPDM Capabilities for Design and Optimization of New Refrigerant Blends – FY18 1st Quarterly Milestone: Perform literature review to collect heat transfer, pressure drop correlations and compressor mapping method for alternative refrigerants

Through a comprehensive literature survey, we identified heat transfer and pressure drop correlations for two-phase evaporation and condensation in fin-and-tube coils using microfin tubes and micro-channel heat exchangers. We also developed a compressor mapping method to convert the maps originally developed for R-22 or R-410A to be used by the alternative lower GWP refrigerants. The correlations and method will be implemented in HPDM for design and optimization of air conditioners and heat pumps using the new refrigerants/blends.

42 ENGINEERING↗
NASA NTRS1977

The application of remote sensing technology to the solution of problems in the management of resources in Indiana

The author has identified the following significant results. The Lydich quadrangle area was successfully classified into seven cover types: (1) trees, (2) poorly drained soil and water, (3) pasture land, (4) well drained brown soil, (5) moderately well drained dark brown soil, (6) moderately drained soil, and (7) medium to poorly drained soil. Measurements of the percent of mapping unit represented by a named soil series range from 44 to 55 percent. If the class identified as vegetation is combined with the named unit, the range increases from 54 to 64 percent. The Xenia mapping unit was the only unit represented by less than 50 percent of the named unit. Results from the intensive tent moth study in Owensburg and Williams were interpreted from 70 mm color infrared and visually transferred to maps. A correction factor was necessary, because the date the sample photography was taken was a month later than the intensive site data (CF x acres defoliated in each level = expanded defoliated acres).

Weismiller, R. A.↗
NASA NTRS1977

The utility of short wavelength (1mm) remote sensing techniques for the monitoring and assessment of hydrologic parameters

Remote sensing programs that respond to the requirements of the water resources management and hydrologic communities are reviewed. The major areas where the needs of water resources management are being met involve the mapping and monitoring of snowcovered areas, hydrologic landuse, and surface water area. In the case of snowcovered area mapping the transfer of technology process is now being accomplished in the Western United States in a cooperative effort involving 6 federal agencies and 3 state agencies along with NASA. A new collaborative effort of the U.S. Army Corps of Engineers and NASA involves the mapping of landuse by Landsat and its use in hydrologic engineering watershed models employed in flood control/waterworks planning, design, and management. Improved systems planned for implementation in the 1978-1981 time frame can be expected to result in increased utilization of visible and near infrared remote sensing observations.

Rango, A.↗
DOE OSTI2021

Artificial Neural Networks as Mappings between Proton Potentials, Wave Functions, Densities, and Energy Levels

We report artificial neural networks (ANNs) have become important in quantum chemistry. Herein, applications to nuclear quantum effects, such as zero-point energy, vibrationally excited states, and hydrogen tunneling, are explored. ANNs are used to solve the time-independent Schrödinger equation for single- and double-well potentials representing hydrogen-bonded molecular systems capable of proton transfer. ANN mappings are trained to predict the lowest five proton vibrational energies, wave functions, and densities from the proton potentials and to predict the excited state proton vibrational energies and densities from the proton ground state density. For the inverse problem, ANN mappings are trained to predict the proton potential from the proton vibrational energy levels or the proton ground state density. This latter mapping is theoretically justified by the first Hohenberg-Kohn theorem establishing a one-to-one correspondence between the external potential and the ground state density. ANNs for two- and three-dimensional systems are also presented to illustrate the straightforward extension to higher dimensions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗