Engineering PapersSearch

SEARCH · Engineering Papers

Results for “trace gas detection”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

Low-Power Architecture for an Optical Life Gas Analyzer

Analog and digital electronic control architecture has been combined with an operating methodology for an optical trace gas sensor platform that allows very low power consumption while providing four independent gas measurements in essentially real time, as well as a user interface and digital data storage and output. The implemented design eliminates the cross-talk between the measurement channels while maximizing the sensitivity, selectivity, and dynamic range for each measured gas. The combination provides for battery operation on a simple camcorder battery for as long as eight hours. The custom, compact, rugged, self-contained design specifically targets applications of optical major constituent and trace gas detection for multiple gases using multiple lasers and photodetectors in an integrated package.

Pilgrim, Jeffrey

Low-background trace-gas detector

Spectrophone detects very small concentrations of trace gases. With gas in sample cell, laser is tuned to absorption line of interest. Molecular absorption in cell produces pulsed acoustical pressure at chopper frequency. Two optical paths with very different absorption lengths are used to pretune cell to balance out background absorption by cell windows.

Rosengren, L.

Miniature Tunable Laser Spectrometer for Detection of a Trace Gas

An open-path laser spectrometer (OPLS) for measuring a concentration of a trace gas, the OPLS including an open-path multi-pass analysis region including a first mirror, a second mirror at a distance and orientation from the first mirror, and a support structure for locating the mirrors, a laser coupled to the analysis region and configured to emit light of a wavelength range and to enable a plurality of reflections of the emitted light between the mirrors, a detector coupled to the analysis region and configured to detect a portion of the emitted light impinging on the detector and to generate a corresponding signal, and an electronic system coupled to the laser and the detector, and configured to adjust the wavelength range of the emitted light from the laser based on the generated signal, and to measure the concentration of the trace gas based on the generated signal.

Christensen, Lance E.

No detection of methane on Mars from early ExoMars Trace Gas Orbiter observations

The detection of methane on Mars has been interpreted as indicating that geochemical or biotic activities could persist on Mars today. A number of different measurements of methane show evidence of transient, locally elevated methane concentrations and seasonal variations in background methane concentrations. These measurements, however, are difficult to reconcile with our current understanding of the chemistry and physics of the Martian atmosphere, which—given methane’s lifetime of several centuries—predicts an even, well mixed distribution of methane. Here we report highly sensitive measurements of the atmosphere of Mars in an attempt to detect methane, using the ACS and NOMAD instruments onboard the ESA-Roscosmos ExoMars Trace Gas Orbiter from April to August 2018. We did not detect any methane over a range of latitudes in both hemispheres, obtaining an upper limit for methane of about 0.05 parts per billion by volume, which is 10 to 100 times lower than previously reported positive detections. We suggest that reconciliation between the present findings and the background methane concentrations found in the Gale crater would require an unknown process that can rapidly remove or sequester methane from the lower atmosphere before it spreads globally.

Michael Doyle Smith

Integrating Metal-Hydride and Gas-Detector for Tritium Gas Detection

Detection of trace amounts of environmental tritium is a challenging problem, driving the need for field-deployable systems that offer high sensitivity, selectivity, and minimal false positives. We present a technique for high-sensitivity, high-selectivity tritium measurement, which integrates metal-hydride and gas-detector concepts into a compact field-deployable tritium sensor. A hydrogen-storage metal embedded in a gas proportional counter selectively absorbs protium (1H)/tritium (3H), which are subsequently released into the counter volume with a reduced radiation background. Ionizations induced by 3H beta particles are then measured in proportional counting mode, achieving high detection efficiency. Preliminary studies conducted with palladium (Pd) thin films coated on stainless-steel substrates demonstrated 3H absorption and metal-tritide formation, followed by 3H desorption upon heating the metal-tritide. These processes were confirmed using activity concentrations measured by a commercial tritium monitor and pulse height spectra acquired from a custom-built detector.

Gas-proportional counter

Automated Hydrogen Gas Leak Detection System

The Gencorp Aerojet Automated Hydrogen Gas Leak Detection System was developed through the cooperation of industry, academia, and the Government. Although the original purpose of the system was to detect leaks in the main engine of the space shuttle while on the launch pad, it also has significant commercial potential in applications for which there are no existing commercial systems. With high sensitivity, the system can detect hydrogen leaks at low concentrations in inert environments. The sensors are integrated with hardware and software to form a complete system. Several of these systems have already been purchased for use on the Ford Motor Company assembly line for natural gas vehicles. This system to detect trace hydrogen gas leaks from pressurized systems consists of a microprocessor-based control unit that operates a network of sensors. The sensors can be deployed around pipes, connectors, flanges, and tanks of pressurized systems where leaks may occur. The control unit monitors the sensors and provides the operator with a visual representation of the magnitude and locations of the leak as a function of time. The system can be customized to fit the user's needs; for example, it can monitor and display the condition of the flanges and fittings associated with the tank of a natural gas vehicle.

Source record

Miniaturized Gas Correlation Radiometer for the Detection of Trace Gases in the Martian Atmosphere

We present a miniaturized and simplified version of a gas correlation radiometer (GCR) capable of simultaneously mapping multiple trace gases and identifying active regions on the Mars surface. Gas correlation radiometry (GCR) has been shown to be a sensitive and versatile method for detecting trace gases in Earth's atmosphere. Reduction of the size and mass of the GCR was achieved by implementing compact, light-weight 1 mm inner diameter hollow-core optical fibers (hollow waveguides) as the gas correlation cells. In a comparison with an Earth orbiting CO2 GCR instrument, exchanging the 10 m multipass cells with hollow waveguide gas correlation cells of equivalent path length reduces the mass from approximately 150 kg to approximately 0.5 kg, and reduces the volume from 1.9 m x 1.3 m x 0.86 m to a small bundle of fiber coils approximately 1 meter in diameter by 0.05 m in height (mass and volume reductions of greater than 99%). A unique feature of this instrument is its stackable module design, with a single module for each trace gas. Each of the modules is self-contained, and fundamentally identical; differing by the bandpass filter wavelength range and gas mixtures inside the hollow-waveguide absorption cells. The current configuration contains four stacked modules for simultaneous measurements of methane (CH4), formaldehyde (H2CO), water vapor (H2O), and deuterated water vapor (HDO) but could easily be expanded to include measurements of additional species of interest including nitrous oxide (N2O), hydrogen sulfide (H2S), methanol (CH3OH), and sulfur dioxide (SO2), as well as carbon dioxide (CO2) for a simultaneous measure of mass balance. Preliminary results indicate that a 1 ppb detection limit is possible for both formaldehyde and methane with one second of averaging. Using non-optimized components, we have demonstrated an instrument sensitivity equivalent to approximately 30 ppb for formaldehyde, and approximately 500 ppb for methane. We expect custom bandpass filters and 6 m long waveguides to significantly improve these promising results. Ongoing testing is being conducted on water vapor and deuterated water vapor.

Melroy, Hilary R.

Compact Laser Multi-gas Spectral Sensors for Spacecraft Systems

The objective of this research effort has been the development of a new gas sensor technology to meet NASA requirements for spacecraft and space station human life support systems for sensitive selective and real time detection of trace gas species in the mid-infrared spectral region.

Tittel, Frank K.

ExoMars/TGO Science Orbit Design

This paper describes the development of the science orbit for the 2016 ESA/NASA collaborative ExoMars/Trace Gas Orbiter (TGO) mission. The initial requirements for the ExoMars/TGO mission simply described the science orbit as circular with a 400 km altitude and a 74 deg inclination. Over the past year, the JPL mission design team worked with the TGO science teams to refine the science orbit requirements and recommend an orbit that would be operationally feasible, easy to maintain, and most important allow the science teams to best meet their objectives.

science orbit

Measuring trace dispersants in gas streams

Detection system uses phase shift of acoustic waves to measure amount of gaseous substances on sorption sensor. Three-part device optimizes stability and assists in achieving low-phase-noise levels.

Updike, O. L.

Development of an automated diode-laser-based multicomponent gas sensor

The implementation and application of a portable fiber-coupled trace-gas sensor for the detection of several trace gases, including CO2, CH4, and H2CO, are reported. This particular sensor is based on a cw fiber-amplified near-infrared (distributed Bragg reflector) diode laser and an external cavity diode laser that are frequency converted in a periodically poled lithium niobate crystal to the mid-IR spectroscopic fingerprint region (3.3-4.4 micrometers). A continuous absorption spectrum of CH4 and H2CO from 3.37 to 3.10 micrometers with a spectral resolution of 40 MHz (approximately 0.0013 cm-1) demonstrated the spectral performance that can be achieved by means of automated wavelength tuning and phase matching with stepper motor control. Autonomous long-term detection of ambient CO2 and CH4 over a 3- and 7-day period was also demonstrated.

NASA Discipline Environmental Health

Water Vapor Sensors Go Sky-High to Assure Aircraft Safety

JPL used a special tunable diode laser, which NASA scientists could tune to different wavelengths, like a radio being tuned to different frequencies, to accurately target specific molecules and detect small traces of gas. This tunable diode laser was designed to emit near-infrared light at wavelengths absorbed by the gas or gases being detected. The light energy being absorbed by the target gas is related to the molecules present. This is usually measured in parts per million or parts per billion. Multiple measurements are made every second, making the system quick to respond to variations in the target gas. NASA scientists developed this technology as part of the 1999 Mars Polar Lander mission to explore the possibility of life-giving elements on Mars. NASA has since used the tunable diode laser-based gas sensor on aircraft and on balloons to successfully study weather and climate, global warming, emissions from aircraft, and numerous other areas where chemical gas analysis is needed. SpectraSensors, Inc., was formed in 1999 as a spinoff company of JPL, to commercialize tunable diode laser-based analyzers for industrial gas-sensing applications (Spinoff 2000). Now, the San Dimas, California-based firm has come back to the market with a new product featuring the NASA-developed instrument for atmospheric monitoring. This instrument is now helping aircraft avoid hazardous weather conditions and enabling the National Weather Service to provide more accurate weather forecasts.

Source record

Tracking the Hunga Tonga-Hunga Ha’apai Eruption Stratospheric Aerosol and Trace Gas Plumes Using Machine Learning

The Hunga Tonga-Hunga Ha’apai (HTHH) submarine volcano had an explosive eruption phase on January 15, 2022, that thrusted ash, gases, and water vapor through the troposphere and into the stratosphere. The stratospheric volcanic plume included aerosol precursor gases such as SO2 and H2S as well as anomalously high water vapor concentrations due to the submarine oceanic origin. With these atmospheric constituents, the sulfuric gases and water vapor formed sulfate (SO4) particles via gas-to-particle reactions and these aerosols likely increased in size due to hygroscopic growth within anomalously humid regions. Strong easterlies and gravity waves propagated the volcanic impacts throughout the stratosphere. Orbital and suborbital passive sensor retrievals detected changes in the aerosol and trace gas characteristics within the atmospheric column for cloud-free regions over the southern hemisphere. While the CALIPSO lidar can detect aerosol layers in the stratosphere, passive sensors such as MODIS retrieved the total column aerosol abundance and characteristics. Previous studies used manual tracking methods to determine volcanic plume positions and compared them to ground observations. In this study, we examine the machine learning (ML) approaches including segmentation, object detection, and object tracking to identify and track aerosol and trace gas plumes using orbital and suborbital sensor data. This ML implementation strives to provide a more systematic approach to separate total column effects from those of the stratosphere. Similar ML tracking may be useful for stratospheric impact events observed historically by CALIPSO and in the future with EarthCare and the Atmosphere Observing System (AOS) lidar-capable missions.

Rhys Leahy

Next-generation wildlife tracking devices and integrated sensors for measuring species-environment interactions and advancing conservation

Global land use and climate change have magnified the importance of collecting accurate animal movement and environmental data to improve our ability to model species interactions with the environment and promote effective conservation. Advanced animal tracking devices that couple cutting-edge technologies with our expanding need for ecological information is critical. In addition to further optimizing device size to monitor small, sensitive species, new paradigms for collecting, storing, and transmitting data about animals and their environments will propel wildlife tracking devices forward. Advanced telemetry capabilities will increase our ability to pair location and sensor data from tagged wildlife with remote sensing data. The USGS Western Ecological Research Center, NASA Ames Research Center, and collaborators have been developing new wildlife tracking devices and integrated environmental sensors to address these challenges. We describe a new, miniaturized solar GPS-enabled Globalstar satellite transmitter with accelerometer capability that is 20% lighter and 25% less expensive than existing commercially available tags. We also introduce a novel peer-to-peer, solar-powered network tag that uses long-range, low-power, wireless platform technology. Concurrently, we began adapting a carbon nanotube (CNT) sensor to detect dimethyl sulfide (DMS), a trace gas relevant to marine ecology and climate studies. CNT sensors offer a small, lightweight, and low-power technology that can detect changes in resistance across carbon nanotubes coated with adsorbent selected to specifically bind with a variety of reactive trace gasses. We flew a prototype sensor in a small UAS and sampled an apparent increase in DMS concentration consistent with a well-defined marine frontal boundary. Currently we are integrating project components to create a hybridized architecture of networked peer-to-peer and satellite tags with integrated CNT and additional on-board and remote sensors to advance animal tracking and to provide information for next generation wildlife conservation.

Ian G. Brosnan

ANITA Air Monitoring on the International Space Station: Results Compared to Other Measurements

ANITA (Analysing Interferometer for Ambient Air) is a flight experiment precursor for a permanent continuous air quality monitoring system on the ISS (International Space Station). For the safety of the crew, ANITA can detect and quantify quasi-online and simultaneously 33 gas compounds in the air with ppm or sub-ppm detection limits. The autonomous measurement system is based on FTIR (Fourier Transform Infra-Red spectroscopy). The system represents a versatile air quality monitor, allowing for the first time the detection and monitoring of trace gas dynamics in a spacecraft atmosphere. ANITA operated on the ISS from September 2007 to August 2008. This paper summarizes the results of ANITA s air analyses with emphasis on comparisons to other measurements. The main basis of comparison is NASA s set of grab samples taken onboard the ISS and analysed on ground applying various GC-based (Gas Chromatography) systems.

Honne, A.

Atmosphere and water quality monitoring on Space Station Freedom

In Space Station Freedom air and water will be supplied in closed loop systems. The monitoring of air and water qualities will ensure the crew health for the long mission duration. The Atmosphere Composition Monitor consists of the following major instruments: (1) a single focusing mass spectrometer to monitor major air constituents and control the oxygen/nitrogen addition for the Space Station; (2) a gas chromatograph/mass spectrometer to detect trace contaminants; (3) a non-dispersive infrared spectrometer to determine carbon monoxide concentration; and (4) a laser particle counter for measuring particulates in the air. An overview of the design and development concepts for the air and water quality monitors is presented.

Niu, William