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At least 37 records · Page 2

[Photodissociation of Acetylene and Acetone using Step-Scan Time-Resolved FTIR Emission Spectroscopy]

The photodissociation of acetylene and acetone was investigated as a function of added quenching gas pressures using step-scan time-resolved FTIR emission spectroscopy. Its main components consist of Bruker IFS88, step-scan Fourier Transform Infrared (FTIR) spectrometer coupled to a flow cell equipped with Welsh collection optics. Vibrationally excited C2H radicals were produced from the photodissociation of acetylene in the unfocused experiments. The infrared (IR) emission from these excited C2H radicals was investigated as a function of added argon pressure. Argon quenching rate constants for all C2H emission bands are of the order of 10(exp -13)cc/molecule.sec. Quenching of these radicals by acetylene is efficient, with a rate constant in the range of 10(exp -11) cc/molecule.sec. The relative intensity of the different C2H emission bands did not change with the increasing argon or acetylene pressure. However, the overall IR emission intensity decreased, for example, by more than 50% when the argon partial pressure was raised from 0.2 to 2 Torr at fixed precursor pressure of 160mTorr. These observations provide evidence for the formation of a metastable C2H2 species, which are collisionally quenched by argon or acetylene. Problems encountered in the course of the experimental work are also described.

McLaren, Ian A.↗

Laser-induced gas breakdown - Spectroscopic and chemical studies.

Discussion of the results of several experimental investigations on laser-induced gas breakdown. The experiments included time-resolved spectroscopy, direct detection of H atoms with a TiO2 probe, and chemical reactions; each of them provided insight into the behavior of the medium at different times. Chemical reactions and explosions have been initiated by the laser beam when a plasma was created. No primary multiphotonic absorption and no macroscopic chemical reactions were observed below the breakdown threshold.

De Montgolfier, PH.↗

A NICER View of a Highly Absorbed Flare in GRS 1915+105

After 26 yr in outburst, the black hole X-ray binary GRS 1915+105 dimmed considerably in early 2018; its flux dropped sharply in mid-2019, and it has remained faint ever since. This faint period, the "obscured state," is punctuated by occasional X-ray flares, many of which have been observed by NICER as part of our regular monitoring program. Here we present detailed time-resolved spectroscopy of one bright flare, whose spectrum shows evidence of high column density partial covering absorption and extremely deep absorption lines (equivalent widths over 100 eV in some cases). We study the time-dependent ionization of the obscuring gas with xstar, ultimately attributing the absorption to a radially stratified absorber of density ∼10^(12)–10^(13) per cu.cm at ∼few ×10^(11) cm from the black hole. We argue that a vertically extended outer disk could explain this obscuration. We discuss several scenarios to explain the obscured state, including massive outflows, an increase in the mass accretion rate, and changes in the outer disk that herald the approach of quiescence, but none are entirely satisfactory. Alternative explanations, such as obscuration by the accretion stream impact point, may be testable with current or future data.

J. Neilsen↗

Simultaneous Spectral Temporal Adaptive Raman Spectrometer - SSTARS

Raman spectroscopy is a prime candidate for the next generation of planetary instruments, as it addresses the primary goal of mineralogical analysis, which is structure and composition. However, large fluorescence return from many mineral samples under visible light excitation can render Raman spectra unattainable. Using the described approach, Raman and fluorescence, which occur on different time scales, can be simultaneously obtained from mineral samples using a compact instrument in a planetary environment. This new approach is taken based on the use of time-resolved spectroscopy for removing the fluorescence background from Raman spectra in the laboratory. In the SSTARS instrument, a visible excitation source (a green, pulsed laser) is used to generate Raman and fluorescence signals in a mineral sample. A spectral notch filter eliminates the directly reflected beam. A grating then disperses the signal spectrally, and a streak camera provides temporal resolution. The output of the streak camera is imaged on the CCD (charge-coupled device), and the data are read out electronically. By adjusting the sweep speed of the streak camera, anywhere from picoseconds to milliseconds, it is possible to resolve Raman spectra from numerous fluorescence spectra in the same sample. The key features of SSTARS include a compact streak tube capable of picosecond time resolution for collection of simultaneous spectral and temporal information, adaptive streak tube electronics that can rapidly change from one sweep rate to another over ranges of picoseconds to milliseconds, enabling collection of both Raman and fluorescence signatures versus time and wavelength, and Synchroscan integration that allows for a compact, low-power laser without compromising ultimate sensitivity.

Blacksberg, Jordana↗

Spectral Evolution in GRB 990510

We present time-resolved spectroscopy of the afterglow of GRB 990510. Through the identification of several absorption lines in the first epoch spectrum, we determine the redshift for this burst to be z >= 1.6190 +/- 0.0016. No clear emission lines are detected. From the absence of the Ly.alpha drop, we can put an upper limit to the redshift of z <= 2.3. We study the time evolution of the MgII absorption line in our spectra taken 0.8 and 3.9 days after the burst, whose equivalent width (E.W.) is expected to change in case the burst resides in a dense compact medium (Perna & Loeb 1998). We measure an E.W. of 2.5 /- 0.2 and 2.3 +/- 0.6 in the spectra 0.8 and 3.8 days after the burst, respectively. Our results suggest that the atoms responsible for the absorption are not in the vicinity of the site of the burst.

Vreeswijk, P. M.↗

Real-time measurement of materials properties at high temperatures by laser produced plasmas

Determination of elemental composition and thermophysical properties of materials at high temperatures, as visualized in the context of containerless materials processing in a microgravity environment, presents a variety of unusual requirements owing to the thermal hazards and interferences from electromagnetic control fields. In addition, such information is intended for process control applications and thus the measurements must be real time in nature. A new technique is described which was developed for real time, in-situ determination of the elemental composition of molten metallic alloys such as specialty steel. The technique is based on time-resolved spectroscopy of a laser produced plasma (LPP) plume resulting from the interaction of a giant laser pulse with a material target. The sensitivity and precision were demonstrated to be comparable to, or better than, the conventional methods of analysis which are applicable only to post-mortem specimens sampled from a molten metal pool. The LPP technique can be applied widely to other materials composition analysis applications. The LPP technique is extremely information rich and therefore provides opportunities for extracting other physical properties in addition to the materials composition. The case in point is that it is possible to determine thermophysical properties of the target materials at high temperatures by monitoring generation and transport of acoustic pulses as well as a number of other fluid-dynamic processes triggered by the LPP event. By manipulation of the scaling properties of the laser-matter interaction, many different kinds of flow events, ranging from shock waves to surface waves to flow induced instabilities, can be generated in a controllable manner. Time-resolved detection of these events can lead to such thermophysical quantities as volume and shear viscosities, thermal conductivity, specific heat, mass density, and others.

Kim, Yong W.↗

New Worlds / New Horizons Science with an X-ray Astrophysics Probe

In 2013 NASA commenced a design study for an X-ray Astrophysics Probe to address the X-ray science goals and program prioritizations of the Decadal Survey New World New Horizons (NWNH) with a cost cap of approximately $1B. Both the NWNH report and 2011 NASA X-ray mission concept study found that high-resolution X-ray spectroscopy performed with an X-ray microcalorimeter would enable the most highly rated NWNH X-ray science. Here we highlight some potential science topics, namely: 1) a direct, strong-field test of General Relativity via the study of accretion onto black holes through relativistic broadened Fe lines and their reverberation in response to changing hard X-ray continuum, 2) understanding the evolution of galaxies and clusters by mapping temperatures, abundances and dynamics in hot gas, 3) revealing the physics of accretion onto stellar-mass black holes from companion stars and the equation of state of neutron stars through timing studies and time-resolved spectroscopy of X-ray binaries and 4) feedback from AGN and star formation shown in galaxy-scale winds and jets. In addition to these high-priority goals, an X-ray astrophysics probe would be a general-purpose observatory that will result in invaluable data for other NWNH topics such as stellar astrophysics, protostars and their impact on protoplanetary systems, X-ray spectroscopy of transient phenomena such as high-z gamma-ray bursts and tidal capture of stars by massive black holes, and searches for dark matter decay.

Smith, Randall K.↗

Photospheric Radius Expansion and a Double-peaked Type-I X-Ray Burst from GRS 1741.9-2853

We present an analysis of two type-I X-ray bursts observed by NuSTAR originating from the very faint transient neutron star (NS) low-mass X-ray binary GRS 1741.9–2853 during a period of outburst in 2020 May. We show that the persistent emission can be modeled as an absorbed, Comptonized blackbody in addition to Fe Kα emission, which can be attributed to relativistic disk reflection. We measure a persistent bolometric, unabsorbed luminosity of L(bol) = 7.03(+0.04, -0.05) x 10^(36) erg/s, assuming a distance of 7 kpc, corresponding to an Eddington ratio of 4.5%. This persistent luminosity combined with light-curve analysis leads us to infer that the bursts were the result of pure He burning rather than mixed H/He burning. Time-resolved spectroscopy reveals that the bolometric flux of the first burst exhibits a double-peaked structure, placing the source within a small population of accreting NSs that exhibit multiple-peaked type-I X-ray bursts. We find that the second, brighter burst shows evidence for photospheric radius expansion (PRE) and that at its peak, this PRE event had an unabsorbed bolometric flux of F(peak)= 2.94 (+0.28, -0.26) 10^(-8) erg/sq.cm s. This yields a new distance estimate of d = 9.0 ± 0.5 kpc, assuming that this corresponds to the Eddington limit for pure He burning on the surface of a canonical NS. Additionally, we performed a detailed timing analysis that failed to find evidence for quasi-periodic oscillations or burst oscillations, and we place an upper limit of 16% on the rms variability around 589 Hz, the frequency at which oscillations have previously been reported.

Sean N. Pike↗

On the Hunt for Detectable Biosignatures in Jezero Crater: What to Look for and Where

Introduction: The Perseverance rover, which is currently exploring Jezero crater on Mars, is equipped with seven instruments that allow for observation of textures, minerals, color, structure, and chemistry of rocks and sediments in order to search for signs of ancient life, understand the geologic history of the crater, and identify candidates for sample return (Farley et al. 2020). The first of these aims includes the direct detection of potential biosignatures, including textures, organic molecules, minerals, and elemental chemistries that are of biogenic origin (Mustard et al. 2013). The presence of these biosignatures will be constrained by the habitability of the local region, the preservation potential of the host rocks, and the sensitivity of the instrument suite, and their biogenicity will be investigated after return to Earth as part of the Mars Sample Return campaign. Here, we examine key targets on the three planned campaigns, potential biosignatures that may be present, and the capabilities of key rover instruments. High Potential Biosignature Sites in Jezero: To date, measurements have been made on multiple sites that both contain minerals known in terrestrial settings to preserve biosignatures and likely were habitable settings (Williford et al. 2021). Two examples include the fine-grained rocks at the base of the delta fan and the NW inner margin of the crater. Fine-grained Rocks at Base of Delta Fan. Fine-grained, clay-bearing rocks may have been deposited as muddy lake sediments that could have hosted life and preserved biosignatures settling out of the water column. The report of organic molecules by the Curiosity rover in the Sheepbed mudstone and Murray formation has highlighted this site in particular. Potential biosignatures in mudstones, especially those rich in silica (McMahon et al. 2018), microbialites and complex organics. NW Inner Margin of Crater. This unit, located along the inner margin of the crater, contains strong carbonate signatures and may have been the littoral zone of a lake (Horgan et al. 2020). The potential biosignatures here include microfossils, microbialites, biominerals, and complex organics. Detectability of Biosignatures by the Mars 2020 Instrument Suite: The Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) instrument comprises a Deep UV spectrometer, context imager, and color camera to generate spatially resolved chemical maps (Bhartia et al. 2020). It is sensitive to trace organics as well as a range of minerals and can detect native fluorescence from aromatic organics; the WATSON and ACI cameras can be used to observe morphologies such as stromatolitic laminations or filaments ranging from the tens of micron to millimeter scale. SHERLOC can detect organics that may be present in either of the high potential biosignature targets, as well as detect carbonates in the latter. However, the presence of high amounts of iron, such as in iron-rich clays, would cause attenuation of spectral response through UV absorption. The Planetary Instrument for X-ray Lithochemistry (PIXL) comprises an X-ray fluorescence spectrometer and camera that can scan rock surfaces to generate elemental maps (Allwood et al. 2020). PIXL can detect chemical biosignatures such as spatial variations of elemental abundances that may have resulted from biological activity. PIXL would be particularly useful in detecting fine textures and elemental chemistries in either high potential biosignature target, but cannot directly detect minerals such as carbonate. The SuperCam instrument performs three types of spectroscopy, color imaging, and acoustic recording to remotely examine elemental composition, minerals, organics, and textures (Maurice et al. 2021). Using laser induced breakdown spectroscopy and time resolved luminescence spectroscopy, SuperCam can detect major elemental building blocks of organics (i.e., C, H, N, O, P, S) and conjugated organic structures, respectively, which may be found in either site. While in other contexts, luminescence is a useful tool for biosignature identification, luminescence generated by the 532 nm laser may obscure the Raman signal. Conclusion: The three instruments discussed can be used collaboratively to establish the presence of potential biosignatures in samples. These high-priority samples may then be returned to Earth for detailed laboratory analysis.

S. Sharma↗

An analytical approach to evaluation of space radiation effects on materials for long-life missions

An analytical model was developed which quantifies effects on organic composite matrix materials of high energy electrons and of UV as well as interactions between the two radiations. Literature data on polyethylene were used to construct a degradation kinetics scheme corresponding to an Earth orbit at L=3. Analysis of the model showed that steady state concentrations of radicals put limits on accelerated test conditions. These conclusions were validated by an experimental study on polymethylmethacrylate using UV laser excitation. Relationships for balancing electron and UV radiations to equal acceleration factors are derived. Pulse radiolysis using an electron-beam along with time-resolved spectroscopy is shown to be able to separate primary form secondary reactions. Implications of these reactions to changes in engineering material properties are indicated. The use of mechanistic studies is discussed in the context of general test strategies for evaluating materials for space applications.

Moacanin, J.↗

Cataclysmic variables. Recent multi-frequency observations and theoretical developments; Proceedings of the 93rd IAU Colloquium, Bamberg, West Germany, June 16-19, 1986

Papers are presented on the formation and evolution of low-mass close binaries with compact components, the periods of cataclysmic variables, multiwavelength observations of dwarf novae during outbursts, and radio emission from cataclysmic variables. Also considered are long-term optical photometry of the dwarf nova VW Hyi, periodic modulations in the optical light curves of EX Hydrae, and Echelle-Mepsicron time-resolved spectroscopy of the dwarf nova SS Cygni. Other topics include UV and X-ray observations of cataclysmic variables, new EXOSAT observations of TV Columbae, accretion disk evolution, and the boundary layer in cataclysmic variables.

Drechsel, H.↗

International Conference on Vacuum Ultraviolet Radiation Physics, 8th, Lunds Universitet, Sweden, Aug. 4-8, 1986, Proceedings

The interactions of VUV radiation with solids are explored in reviews and reports of recent theoretical and experimental investigations from the fields of atomic and molecular physics, solid-state physics, and VUV instrumentation. Topics examined include photoabsorption and photoionization, multiphoton processes, plasma physics, VUV lasers, time-resolved spectroscopy, synchrotron radiation centers, solid-state spectroscopy, and dynamical processes involving localized levels. Consideration is given to the fundamental principles of photoemission, spin-polarized photoemission, inverse photoemission, semiconductors, organic materials, and adsorbates.

Nilsson, Per-Olof↗

Evidence for a high-mass white dwarf in nova V1500 Cygni 1975

Time-resolved spectroscopy of V1500 Cyg are presented from 1981, when the nebular lines from the nova ejecta had faded sufficiently to permit reliably radial velocity measurements on emission lines from the binary remnant. The spectra possess a typical AM Herculis signature. The wavelength region 3800-5100 A contains a number of strong lines, in particular the Balmer series and He II 4686 A. All lines show periodic velocity changes with the same period as the photometric variations. On the first night the lines are relatively weak and narrow, are in phase with the photometric cycle, and suffer extreme modulation; two months later they are strong and broad, are roughly 90 deg out of phase with the photometric cycle, and have relatively less variation in their line fluxes. These features support the suggestion that the remnant is an AM Her system. The observed radial velocity of the secondary is 193 + or - 9 km/s. Various constraints suggest that the magnetic white dwarf in this system has a mass over 0.9 solar.

Horne, Keith↗

Quiescent accretion disks in black hole X-ray novae

We present detailed time-resolved spectroscopy of the Balmer emission lines from two black hole binary systems in quiescence, A0620-00 and Nova Muscae 1991. We find extraordinary similarities between the two systems. There are 30-40 km/s velocity variations of the emission lines over the orbital period, the phases of which are not aligned with the expected phase of the motion of the compact primary. Detailed modeling of both systems is complicated by variable hot spot components, regions of optical thickness, and intermittent excess emission in the blue line wings of the H-alpha lines. Both sources also display low velocities at the outer edge of the accretion disk, implying a large primary Roche lobe and extreme mass ratios. These complications suggest that although simple optically thin, Keplerian alpha-disk models provide a useful parameterization of emission lines from these systems, the straightforward physical models they imply should be treated with great caution.

Orosz, Jerome A.↗

Super Photon Counters

The perfect photon detector would measure the arrival time, the energy, the polarization, and the position of every arriving quantum, but that is easier said than done. Two groups have now succeeded in doing time-resolved spectroscopy on the Crab Nebula pulsar, measuring everything but the polarization, with reports from Romani et al. at Stanford and from Perryman et al. at ESTEC. Both groups use superconducting detectors to gain the necessary speed and sensitivity. The photon can heat the electrons in a superconductor biased in the middle of its resistive transition, or break bound superconducting electron-hole pairs, which can then be collected. Three years ago, Peacock et al. reported that they had detected single optical photons with a superconducting tunnel junction (STJ), and Paresce wrote a News and Views article. A tunnel junction uses two pieces of conductive material, separated by a tiny gap of insulating material or even vacuum. If the gap is thin enough, electrons can tunnel across anyway, and if the conductors are superconductors, the junction displays very useful quantum mechanical properties and electrical nonlinearities. Amplifiers, detectors, oscillators, and computer circuits can all be made from them. Their special advantage is that they operate at very low temperatures, dissipate very little power, operate very fast, and are very small.

Mather, John↗

Science Capabilities of the GLAST Burst Monitor

The Large Area Telescope (LAT) on GLAST will make pioneering observations of gamma-ray bursts in the energy range above about 20 MeV. The primary function of the GLAST Burst Monitor (GBM) is to extend the energy range for GRB observations down to about 10 keV, allowing time-resolved spectroscopy over an energy range of six decades or more for strong bursts. The GBM will also generate alerts for strong bursts outside the LAT field-of-view, permitting re-orientation of the spacecraft so that the LAT can observe prompt or delayed high-energy emission. Burst locations will be disseminated rapidly to ground observers. The GBM will also provide data suitable for a variety of other studies, including discovery of gamma-ray transient sources, monitoring of Soft Gamma Repeaters, and observations of solar flares.

Meegan, Charles↗

Optical Pulse Synthesis Using Brillouin Selective Sideband Amplification

Optical pulse generation using Fourier synthesis is attractive for a number of applications, including photonic A/D conversion, electro-optic sampling, and time-resolved spectroscopy, because the bandwidth, shape, and repetition rate of the pulse can be easily controlled.

optical pulse brillouin selective sideband↗

Correlative Analysis of GRBs Detected by Swift and Suzaku- WAM

It is now well known that a complete understanding of the energetics of the prompt phase of gamma-ray bursts (GRBs) requires full knowledge of the spectrum, extending at least as high as the peak energy (Epeak) of the vF(v) spectrum. Since most gamma-ray bursts (GRBs) have Epeak above the energy range (15-150 keV) of the Burst Alert Telescope (BAT) on Swift, a full understanding of the prompt emission from Swift GRBs requires spectral fits over as broad an energy range as possible. This can be completed for bursts which are simultaneously detected by Swift BAT and the Suzaku Wide-band All-Sky Monitor (WAM), which covers the energy range from 50-5000 keV. Between the launch of Suzaku in July 2005 and the end of 2008, there were 44 gamma-ray bursts (GRBs) which triggered both Swift and WAM and an additional 41 bursts which triggered Swift and were detected by WAM, but did not trigger. A joint BAT-WAM team has cross-calibrated the two instruments using GRBs, and we are now able to perform joint fits on these bursts to determine spectral parameters including Epeak. The results of broad spectral fits allows us to understand the distribution of Epeak for Swift bursts and to calibrate Epeak estimators when Epeak is within the BAT energy range. For those bursts with spectroscopic redshifts, we can calculate the isotropic energy and study various correlations between Epeak and other global burst parameters. Here we present the results of joint Swift/BAT-Suzaku/WAM spectral fits for 77 of the bursts jointly detected by the two instruments. We show that the distribution of spectral fit parameters is consistent with distributions from earlier missions and confirm that Swift bursts are consistent with earlier reported relationships between Epeak and isotropic energy. We show through time-resolved spectroscopy that individual burst pulses are also consistent with this relationship.

Krimm, H.A.↗