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At least 37 records · Page 2

Rapid Polyolefin Hydrogenolysis by a Single‐Site Organo‐Tantalum Catalyst on a Super‐Acidic Support: Structure and Mechanism

The novel electrophilic organo-tantalum catalyst AlS/TaNp x (1) (Np=neopentyl) is prepared by chemisorption of the alkylidene Np 3 Ta=CH t Bu onto highly Brønsted acidic sulfated alumina (AlS). Here, the proposed catalyst structure is supported by EXAFS, XANES, ICP, DRIFTS, elemental analysis, and SSNMR measurements and is in good agreement with DFT analysis. Catalyst 1 is highly effective for the hydrogenolysis of diverse linear and branched hydrocarbons, ranging from C2 to polyolefins. To the best of our knowledge, 1 exhibits one of the highest polyolefin hydrogenolysis activities (9,800 (CH 2 units) ⋅ mol(Ta) −1 ⋅ h −1 at 200 °C/17 atm H 2 ) reported to date in the peer-reviewed literature. Unlike the AlS/ZrNp 2 analog, the Ta catalyst is more thermally stable and offers multiple potential C−C bond activation pathways. For hydrogenolysis, AlS/TaNp x is effective for a wide variety of pre- and post-consumer polyolefin plastics and is not significantly deactivated by standard polyolefin additives at typical industrial concentrations.

03 NATURAL GAS↗

Development and support structures for high-power solar arrays

A number of structurally efficient configurations for wing-type solar arrays are developed by a combination of deepening the planform of the blanket and structure and by partitioning the blanket with battens and frequent attachments to the support structure. This technique reduces the tension required to avoid a low natural frequency for the blanket, and the load reduction results in a lighter structure. The use of three different structures are investigated: the Astromast, the Extendible Support Structure (ESS), and a new beam called the STACBEAM (Stacking Triangular Articulated Compact Beam) and their relative performances are compared. The investigation of the STACBEAM is emphasized because its sequential deployment is more reliable for very long systems, and its linear deployment facilitates local attachments to the blanket and the development of a low mass deployer.

Knapp, K.↗

An across-the-bay flight support structure designed specifically for the Spartan program

The preliminary design of an across-the-bay Flight Support Structure optimized to the specific requirements of the Spartan program has been completed. Although approximately 15 percent heavier than the initial goal, preliminary analysis indicate very low stress levels and significant reduction in weight should be possible in the final design. This structure is capable of supporting two Spartan 200-class spacecraft or attached payloads of equivalent total weight. The inherent structural efficiency of monocoque type construction is utilized. The minimization of fabrication and assembly costs and provision for simple and versatile payload interfacing where given significant considerations. Modularity of this structure allows it to be readily adapted for use as the primary structure of an Aries-class Spartan free-flyer utilizing the Orbit trunning latch mechanisms, thus eliminating the need for a flight support structure.

Rast, J. J.↗

Structural Requirements and Scaling Analysis of a Fluidic Mirror Space Telescope Support Structure

The NASA FLUTE project proposes large-scale (50m) fluidic telescopes for astronomy applications. To continue to explore the universe, astronomers require larger and larger telescope apertures. The highest priority astrophysics targets such as exoplanets and early galaxies are extremely faint, motivating larger telescope apertures. However, mission costs depend on aperture diameter, and scaling apertures beyond 10-m apertures faces economic and technological viability challenges. An unsegmented primary mirror made in space via fluidic microgravity shaping would provide a scalable and cost-effective method to scale apertures to 50-m scale while achieving sub-nanometer (root mean square) surface quality. Such microgravity fluidic shaping has been demonstrated in laboratory neutral buoyance environments, parabolic microgravity experiments, as well aboard the International Space Station. One of the main components of a fluidic observatory is the mirror frame. The frame must provide a stable bounding circular ring which the edges of the fluid mirror surface can wet. The frame can optionally provide a ‘floor’ surface on the interior of the ring to provide additional fluid support and reduce required fluid volume. In this work, we evaluate several classes of structural frame architectures potentially suitable for a fluidic telescope support structure. We start by estimating stability requirements, orbital, station keeping, and slew loads based on a notional CONOPS. The scaling of overall fluid mass required for each architecture is evaluated. Preliminary results elucidate the importance of a support floor for overall mission viability above 10-m diameter. We then investigate the scaling of a tetrahedral truss frame support structure. We show that segmented solid shell support surfaces can provide sufficient stability at modest mass fractions. We estimate that the total fluid and frame mass for a 50-m telescope could be on the order of 15,000 kg. Finally, implementation considerations are discussed, including deployment/assembly methodologies. The results of this study establish feasibility of a large-scale fluidic telescope and will guide further architecture development and detailed structural design.

Christine Gregg↗

Pactruss support structure for precision segmented reflectors

The application of the Pactruss deployable structure to the support of large paraboloidal reflectors of very high precision was studied. The Pactruss concept, originally conceived for the Space Station truss, is shown to be suitable for use in a triangular arrangement to support a reflector surface composed of hexagonal reflector panels. A hybrid of Pactruss structural and deployable single-fold beams is shown to accommodate a center body. A minor alteration in the geometry is in order to avoid lockup during deployment. To assess the capability of the hybrid Pactruss structure, an example truss supporting a full-scale (20 meter diameter) infrared telescope was analyzed for static and dynamic performance. A truss structure weighing 800 kilograms gave adequate support to a reflector surface weighing 3,000 kilograms.

Hedgepeth, John M.↗

Integrated support structure for GASCAN 2

The focus of the Worcester Polytechnic Institute (WPI) Advanced Space Design Program was the preliminary design of the Integrated Support Structure for GASCAN II, a Get Away Special canister donated by the MITRE Corporation. Two teams of three students each worked on the support structure. There was a structural design team and a thermal design team. The structure will carry three experiments also undergoing preliminary design this year, the mu-gravity Ignition Experiment, the Rotational Flow in Low Gravity Experiment, and the Ionospheric Properties and Propagation Experiment. The structural design team was responsible for the layout of the GASCAN and the preliminary design of the structure itself. They produced the physical interface specifications defining the baseline weights and volumes for the equipment and produced layout drawings of the system. The team produced static and modal finite element analysis of the structure using ANSYS. The thermal design team was responsible for the power and timing requirements of the payload and for the identification and preliminary analysis of potential thermal problems. The team produced the power, timing, and energy interface specifications and assisted in the development of the specification of the battery pack. The thermal parameters of each experiment were cataloged and the experiments were subjected to worst case heat transfer scenarios.

Source record↗

Surface generation and editing operations applied to structural support of aerospace vehicle fuselages

The Solid Modeling Aerospace Research Tool (SMART) is a computer aided design tool used in aerospace vehicle design. Modeling of structural components using SMART includes the representation of the transverse or cross-wise elements of a vehicle's fuselage, ringframes, and bulkheads. Ringframes are placed along a vehicle's fuselage to provide structural support and maintain the shape of the fuselage. Bulkheads are also used to maintain shape, but are placed at locations where substantial structural support is required. Given a Bezier curve representation of a cross sectional cut through a vehicle's fuselage and/or an internal tank, this project produces a first-guess Bezier patch representation of a ringframe or bulkhead at the cross-sectional position. The grid produced is later used in the structural analysis of the vehicle. The graphical display of the generated patches allows the user to edit patch control points in real time. Constraints considered in the patch generation include maintaining 'square-like' patches and placement of longitudinal, or lengthwise along the fuselage, structural elements called longerons.

Schwartz, Susan K.↗

Implementation of Sacrificial Support Structures for Hybrid Manufacturing of Thin Walls

Thin-walled features can be difficult to produce with traditional machining methods which often rely on excess stock material for stiffness. This challenge is increased in hybrid manufacturing where the feature is already near net shape before machining. Significant workpiece deflection can result in poor geometric and surface finish tolerances on the finished part. A potential solution to this problem is to implement sacrificial support structures to the as-printed geometry. The supports are then machined away during the finishing portion of the hybrid process. In the present work, several different design parameters for these sacrificial supports were evaluated to determine their impact on the quality of representative thin wall geometry samples. The angle, height, and spacing of triangular support structures were varied for each sample and then machined and examined. The addition of these supports relative to an unsupported configuration provided a deflection reduction of around 0.2 mm. Surface roughness was improved by approximately 1.5 µm. Increasing values of support height were found to correspond to reduced wall deflection. Similarly, decreasing values of support angle and support spacing improved geometric accuracy. Efficiency comparisons showed that increases in print time corresponded to rapidly diminishing gains in geometric accuracy but continued to improve surface roughness. Implications for hybrid finishing of additively manufactured thin-walled structures is briefly discussed.

36 MATERIALS SCIENCE↗

Microwave limb sounder, graphite epoxy support structure

The manufacturing and processing procedures which were used to fabricate a precision graphite/epoxy support structure for a spherical microwave reflecting surface are described. The structure was made fromm GY-70/930 ultra high modulus graphite prepreg, laminated to achieve an isotropic in plane thermal expansion of less than + or - 0.1 PPM/F. The structure was hand assembled to match the interface of the reflective surface, which was an array of 18 flexure supported, aluminum, spherically contoured tiles. Structural adhesives were used in the final assembly to bond the elements into their final configuration. A eutectic metal coating was applied to the composite surface to reduce dimensional instabilities arising from changes in the composite epoxy moisture content due to environmental effects. Basic materials properties data are reported and the results of a finite element structural analysis are referenced.

Pynchon, G.↗

OC6 project Phase IV: validation of numerical models for novel floating offshore wind support structures

Abstract. This paper provides a summary of the work done within Phase IV of the Offshore Code Comparison Collaboration, Continued with Correlation and unCertainty (OC6) project, under International Energy Agency Wind Technology Collaboration Programme Task 30. This phase focused on validating the loading on and motion of a novel floating offshore wind system. Numerical models of a 3.6 MW horizontal-axis wind turbine atop the TetraSpar floating support structure were compared using measurement data from a 1:43-Froude-scale test performed in the University of Maine's Alfond Wind–Wave (W2) Ocean Engineering Laboratory. Participants in the project ran a series of simulations, including system equilibrium, surge offsets, free-decay tests, wind-only conditions, wave-only conditions, and a combination of wind and wave conditions. Validation of the models was performed by comparing the aerodynamic loading, floating support structure motion, tower base loading, mooring line tensions, and keel line tensions. The results show a relatively good estimation of the aerodynamic loading and a reasonable estimation of the platform motion and tower base fore–aft bending moment. However, there is a significant dispersion in the dynamic loading for the upwind mooring line. Very good agreement was observed between most of the numerical models and the experiment for the keel line tensions.

17 WIND ENERGY↗

Fabrication of experimental three-meter space telescope primary and secondary mirror support structure

The fabrication of prototype titanium alloy primary and secondary mirror support structures for a proposed experimental three-meter space telescope is discussed. The structure was fabricated entirely of Ti-6Al-4V tubing and plate. Fabrication included the development of procedures including welding, forming, and machining. Most of the structures was fabricated by gas-shielding tungsten-arc (GTA) welding with several major components fabricated by high frequency resistance (HFR) welding.

Mishler, H. W.↗

Electromagnetic Analysis of ITER Electron Cyclotron Emission Components and Support Structures for the Preliminary Design Review

The ITER electron cyclotron emission (ECE) diagnostic system is located at Design Shield Module (DSM) 2, Equatorial Port (EP) 9 to measure electron temperature profile and electron temperature fluctuations and also to assess nonthermal electron distributions via the oblique view. Therefore, ECE has both radial and oblique views with two couples of mirrors for two different optical views. This ECE diagnostic system shall be exposed to significant power due to unabsorbed electron cyclotron heating power in the plasma. It shall also receive large electromagnetic (EM) loads up to 100 MN/m 3 force density due to the eddy currents generated by the short 16-ms transient plasma disruption. The global EM models of EP12 and EP11 with the worst case of plasma disruption Major Disruption Downward Exponential 16 ms Category III (MD_DW_EXP16MS_CATIII) have been provided by ITER. However, the support structure for these critical components, including four mirrors, is still under the design and development phase, especially during the period of preliminary design reviews (PDRs). For those small in-vessel components that are not modeled explicitly for the PDRs, we can extract the magnetic field (B) data and flux variations (dB/dt) at those locations from the global model and then use the B and dB/dt method to calculate the eddy currents, EM forces, and torques on those components in the local submodels. In conclusion, this paper will present the detailed PDR EM analysis results of the ECE components and support structures.

Electromagnetic↗

Mission Peculiar Equipment Support Structure: A platform for space construction

The Space Shuttle requires carriers to support payloads in the cargo bay. As a result, the Mission Peculiar Equipment Support Structure (MPESS) was designed to carry partial payloads aboard the shuttle. The efforts to customize the MPESS for the Experimental Assembly of Structure in EVA (EASE) and Assembly Concept for Construction of Erectable Space Structure (ACCESS) experiments are summarized.

Hill, Robert↗

ECAR-6589 Rev 0 Reflector Support Structure Analysis

The purpose of this ECAR is to document compliance with best engineering practices, ANSI/AISC N690 and the seismic requirements of IBC-2015 for the Reflector Support Structure of the MARVEL microreactor.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗