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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

The stability of ground ice in the equatorial region of Mars

The lifetime of an unreplenished layer of ground ice lying within 30 deg of the Martian equator was examined within the context of the existing data base on Martian regolith and climate. Data on the partial pressure of H2O in the Martian atmosphere and the range of mean annual temperatures indicated the ground ice would be restricted to latitudes poleward of 40 deg. However, the ground ice near the poles may be a relic from early Martian geologic times held in place by a thin layer of regolith. Consideration of twelve model pore size distributions, similar to silt- and clay-type earth soils, was combined with a parallel pore model of gaseous diffusion to calculate the flux of H2O molecules escaping from the subsurface ground ice layer. Martian equatorial ground ice was found to be influenced by the soil structure, the magnitude of the geothermal gradient, the climatic desorption of CO2 from the regolith. It is concluded that equatorial ground ice is present on Mars only if a process of replenishment is active.

Clifford, S. M.↗
NASA NTRS1992

Columnar and subsurface silicide growth with novel molecular beam epitaxy techniques

We have found novel growth modes for epitaxial CoSi2 at high temperatures coupled with Si-rich flux ratios or low deposition rates. In the first of these modes, codeposition of metal and Si at 600-800 C with excess Si leads to the formation of epitaxial silicide columns surrounded by single-crystal Si. During the initial stages of the deposition, the excess Si grows homoepitaxially in between the silicide, which forms islands, so that the lateral growth of the islands is confined. Once a template layer is established by this process, columns of silicide form as a result of selective epitaxy of silicide on silicide and Si on Si. This growth process allows nanometer control over silicide particles in three dimensions. In the second of these modes, a columnar silicide seed layer is used as a template to nucleate subsurface growth of CoSi2. With a 100 nm Si layer covering CoSi2 seeds, Co deposited at 800C and 0.01 nm/s diffuses down to grow on the buried seeds rather than nucleating surface silicide islands. For thicker Si caps or higher deposition rates, the surface concentration of Co exceeds the critical concentration for nucleation of islands, preventing this subsurface growth mode from occurring. Using this technique, single-crystal layers of CoSi2 buried under single-crystal Si caps have been grown.

Fathauer, R. W.↗
NASA NTRS1992

Subsurface emissions from Mercury - VLA radio observations at 2 and 6 centimeters

Radio observations of Mercury made with the VLA; once in 1986, and on two dates in February of 1988 are presented. These observations are the first to spatially map both hot regions associated with the theoretical hot poles. These 'hot poles' are separated by 180 deg and are a result of the unusual diurnal heating from Mercury's 3/2 spin-orbit resonance and eccentric orbit. The highest resolution data maps areas of the planet as small as 330 km. Maps of total intensity, brightness temperature, polarized intensity, fractional polarization, depolarization, and spectral index are included. It is found that the subsurface thermal emissions from Mercury are characteristic of blackbody reradiation from the solar insolation over a diurnal cycle. These observations to produce full-disk thermophysical models are used. The one-dimensional, time-dependent heat-diffusion equation for all observed disk elements at each epoch in order to constrain thermophsyical parameters and properties of the subsurface material are solved. Using typical lunar values for several of the parameters, it is possible to reproduce the temperature morphology and most of the observed temperature values. It is found that the best-fit models require a substantial contribution of the heat transport in the subsurface to be radiative in nature. The primary difficulty in the models is in predicting the observed temperature differences as a function of frequency.

Ledlow, Michael J.↗
NASA NTRSDate not supplied

Detecting Volcanic Co2 Emissions Hidden in Tropical Volcanic Forests Using Fixed-Wing sUAS

CO2 emissions are among the earliest indicators of subsurface state change and reactivation of volcanic systems and these deep signals reflect in faint diffuse emissions variations on volcanic flanks. Monitoring vast areas of rainforests covering tropical volcanoes is challenging, and space-borne sensors like OCO-2 are not sensitive enough. Fortunately, trees exposed to mild enhancements of CO2 may experience fertilization and build excess CO2 into excess biomass (Cawse-Nicholson, et al. 2018, Biogeosciences). They also process excess CO2 through photosynthesis, measurable by fluorescence (Bogue et al., 2019, Biogeosciences). Furthermore, spaceborne remote sensing instruments have demonstrated increasing NDVI months to years before eruptions, unexplained by other factors (e.g., Houlie et al. 2006, EPSL; Seiler et al. 2017, PLoS One). By providing a means to map large areas of above-canopy CO2 variations over tropical rainforest on the flanks of actively degassing volcanoes, we enable to interpret the signals plants provide in response to excess CO2 with airborne and spaceborne hyperspectral remote sensing methods, including a possible future Surface Biology and Geology (SBG) NASA satellite mission.As a critical step to mature and test this concept, we deployed small unmanned aerial systems (sUAS) using a fixed-wing sUAS designed for autonomous operations and long endurance in extreme environments, without causing significant disturbance of the sampled air. We integrated an in-situ sensor to record the CO2 enhancement field above the forest canopy. Test flight results on the flanks of Turrialba volcano in Costa Rica above forest canopies covering known moderate gas seeps demonstrate the sUAS-borne detection and mapping capabilities of above-canopy elevated CO2 gradients. The strong detection capabilities and high detector signal stability resulted from key system design elements including RF shielding, mechanical stabilization, and calibration procedures. This highly robust system is readily applied for diffuse volcanic CO2 emission studies on active volcanoes covered by dense vegetation.

Volcanic↗
NASA NTRS2000

Atmospheric energy for subsurface life on Mars?

The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H(2) and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H(2)O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life.

NASA Center JPL↗
NASA NTRS1981

On the spectrum of turbulent magnetic fields

Theoretical power spectra of magnetic fields subject to turbulent fluid motions in the kinematic regime are presented, and previous theories are reviewed, with reference to magnetic fields on the sun. Magnetic field diffusion in turbulence with persistent eddies is predicted to be described by an effective negative magnetic diffusivity. It is found that observations cannot be explained on the basis of turbulent kinematic theories unless the turbulent motions are three-dimensional, and the effective diffusivities are larger than the molecular diffusivities. Lower bounds on the turbulent viscosity are derived, suggesting that dynamical processes controlling the magnetic field spectrum occur at least 15,000 km below the surface. The results, which remain consistent with the assumption that effective diffusivity is uniform, suggest that surface magnetic field observations can be used as a diagnostic for subsurface flows.

Knobloch, E.↗
NASA NTRS1999

Characterization of Regolith Volatile Transport and Storage Properties by The MECA MSP 2001 Lander Payload

The diffusive and adsorptive properties of the Martian regolith influence the exchange of volatiles between the atmosphere and subsurface. Our quantitative knowledge of these properties is extremely poor -introducing substantial uncertainties in efforts to model long-term evolution of ground ice and diurnal, seasonal, and climatic cycles of CO2 and H20. This situation should significantly improve upon arrival of the 2001 Mars Surveyor Lander in 2002. In support of the Human Exploration and Development of Space (HEDS) enterprise, the 2001 mission will include a suite of instruments to characterize the nature of the Martian environment and assess whether it contains hazards that may threaten future human exploration. A major element of this effort is the Mars Environmental Compatibility Assessment (MECA) payload, which consists an optical microscopy system incorporating electrostatic, magnetic, and scratch-hardness materials testing palets, an atomic force microscope with imaging capabilities comparable to an SEM, a wet chemistry laboratory with four independent test cells, an electrometer on the robotic arm, material test patches, a camera also mounted on the arm, and a soil scoop for excavating down to about 50 cm into the soil. Although conceived to address the needs of HEDS, MECA payload is a sophisticated soil science laboratory that should provide a wealth of new data relevant to the volatile transport and storage properties of the regolith. Additional information os contained in the original.

Clifford, S. M.↗
NASA NTRS2022

Instantaneous Photosynthetically Available Radiation (IPAR) prediction models based on Neural Network for ocean waters.

Instantaneous photosynthetically available radiation (IPAR) at the ocean surface and its vertical profile below the surface play a critical role in models to calculate net primary productivity of marine phytoplankton. In this work, we report two IPAR prediction models based on neural network (NN) approach, one for open ocean and the other for coastal waters. These models are trained, validated, and tested using a large volume of synthetic datasets for open ocean and coastal waters simulated by a radiative transfer model. Our NN models are designed to predict IPAR under a large range of atmospheric and oceanic conditions. The NN models can compute subsurface IPAR profile very accurately up to euphotic zone depth. The root mean square errors associated with the diffuse attenuation coefficient of IPAR are less than 0.011 𝑚−1 and 0.036 𝑚−1 for open ocean and coastal waters respectively. The performance of the NN models is better than presently available semi analytical models, with significant superiority in coastal waters.

PACE↗
NASA NTRS1991

Subsurface Growth of CoSi2 by Deposition of Co on Si-Capped CoSi2 Seed Regions

At a growth temperature of 800 C, Co deposited on Si(111) diffuses through a Si cap and exhibits oriented growth on buried CoSi2 grains, a process referred to as endotaxy. This occurs preferentially to surface nucleation of CoSi2 provided the thickness of the Si cap is less than a critical value between 100 and 200 nm for a deposition rate of 0.01 nm/s. Steady-state endotaxy is modeled under the assumption that the process is controlled by Co diffusion.

Fathauer, R. W.↗
NASA NTRS1983

Radar and infrared remote sensing of terrain, water resources, arctic sea ice, and agriculture

Radar range measurements, basic waveforms of radar systems, and radar displays are initially described. These are followed by backscatter from several types of terrain and vegetation as a function of frequency and grazing angle. Analytical models for this backscatter include the facet models of radar return, with range-angle, velocity-range, velocity-angle, range, velocity, and angular only discriminations. Several side-looking airborne radar geometries are presented. Radar images of Arctic sea ice, fresh water lake ice, cloud-covered terrain, and related areas are presented to identify applications of radar imagery. Volume scatter models are applied to radar imagery from alpine snowfields. Short pulse ice thickness radar for subsurface probes is discussed in fresh-water ice and sea ice detection. Infrared scanners, including multispectral, are described. Diffusion of cold water into a river, Arctic sea ice, power plant discharges, volcanic heat, and related areas are presented in thermal imagery. Multispectral radar and infrared imagery are discussed, with comparisons of photographic, infrared, and radar imagery of the same terrain or subjects.

Biggs, A. W.↗
NASA NTRS1973

Gas-phase hydrogen permeation through alpha iron, 4130 steel, and 304 stainless steel from less than 100 C to near 600 C

Gas phase hydrogen permeation studies were conducted on hollow, cylindrical membranes of triply zone-refined alpha iron, AISI 304 austenitic stainless steel, and AISI-SAE 4130 steel in both the normalized (ferrite and carbide) and quenched and tempered (martensite) conditions. Membrane temperature was varied from less than 100 C to near 600 C and hydrogen pressure was varied. For one membrane material, normalized 4130 steel, gas phase hydrogen transport under both steady state and nonsteady state conditions was demonstrated to be controlled by lattice diffusion. Additionally, Sievert's law was shown to be applicable. For all membrane materials, expressions for the coefficients for hydrogen permeation were determined by analysis of steady state transport; the coefficients for diffusion were determined by the lag time technique applied to nonsteady state transport; and through a knowledge of the Sievert's constants, the subsurface equilibrium lattice hydrogen concentrations were determined.

Nelson, H. G.↗
NASA NTRS1984

Macrosegregation in aluminum alloy ingot cast by the semicontinuous direct chill method

A theoretical model of the semicontinuous DC casting method is developed to predict the positive segregation observed at the subsurface and the negative segregation commonly found at the center of large commercial-size aluminum alloy ingot. Qualitative analysis of commercial-size aluminum alloy semicontinuous cast direct chill (DC) ingot is carried out. In the analysis, both positive segregation in the ingot subsurface and negative segregation at the center of the ingot are examined. Ingot subsurface macrosegregation is investigated by considering steady state casting of a circular cross-section binary alloy ingot. Nonequilibrium solidification is assumed with no solid diffusion, constant equilibrium partition ratio, and constant solid density.

Yu, H.↗
NASA NTRS2005

Mechanisms of O2 Sputtering from Water Ice by keV Ions

We have conducted experiments on the sputtering of water ice by 100 keV Ar(+) between 20 and 150 K. Our findings indicate that the temperature dependence of the total sputtering yield is heavily influenced by the thermal and irradiation history of the ice, showing a complex dependence on irradiation fluence that is correlated to the ejection of O2 molecules. The results suggest that O2 produced by the ions inside the ice diffuses to the surface where it is trapped and then ejected via sputtering or thermal desorption. A high concentration of O2 can trap in a subsurface layer during bombardment at 130 K, which we relate to the formation of hydrogen and its escape from that region. A simple model allows us to determine the depth profile of the absolute concentration of O2 trapped in the ice.

Teolis, B. D.↗
NASA NTRS2013

Wells for In Situ Extraction of Volatiles from Regolith (WIEVR)

A document discusses WIEVRs, a means to extract water ice more efficiently than previous approaches. This water may exist in subsurface deposits on the Moon, in many NEOs (Near- Earth Objects), and on Mars. The WIEVR approach utilizes heat from the Sun to vaporize subsurface ice; the water (or other volatile) vapor is transported to a surface collection vessel where it is condensed (and collected). The method does not involve mining and extracting regolith before removing the frozen volatiles, so it uses less energy and is less costly than approaches that require mining of regolith. The only drilling required for establishing the WIEVR collection/recovery system is a well-bore drill hole. In its simplest form, the WIEVRs will function without pumps, compressors, or other gas-moving equipment, relying instead on diffusive transport and thermally induced convection of the vaporized volatiles for transport to the collection location(s). These volatile extraction wells could represent a significant advance in extraction efficiency for recovery of frozen volatiles in subsurface deposits on the Moon, Mars, or other extraterrestrial bodies.

Walton, Otis R.↗
NASA NTRS2003

In Situ Remediation of Polychlorinated Bephenyls Using Palladium Coated Iron or Magnesium

The remediation of polychlorinated biphenyls (PCBs) and other chlorinated synthetic aromatic compounds are of great concern due to their toxicity and persistence in the environment. When released into the environment, PCBs are sorbed to particulate matter that can then disperse over large areas. Although the US Environmental Protection Agency (EPA) has banned the manufacture of PCBs since 1979, they are still present in the environment posing possible adverse health affects to both humans and animals. Thus, it is of utmost importance to develop a method that remediates PCB-contaminated soil, sediments, and water. The objective of our research was to develop an in-situ PCB remediation technique that is applicable for the treatment of soils and sediments. Previous research conducted at the University of Central Florida (UCF) proved the feasibility of using an emulsified system to dehalogenate a dense non-aqueous phase liquid (DNAPL) source, such as TCE, in the subsurface by means of an in-situ injection. The generation of a hydrophobic emulsion system drew the DNAPL TCE, through the oil membrane where it diffused to the iron particle and underwent degradation. TCE continued to enter, diffuse, degrade and exit the droplet maintaining a concentration gradient across the membrane, thus maintaining the driving force of the reaction.

Geiger, Cherie L.↗
NASA NTRS1984

Raman lidar for the remote measurement of subsurface ocean parameters

The Raman lidar technique was developed for the remote measurement of temperature and salinity profiles. A temperature accuracy of 0.5 degrees Centigrade is attainable in a practical field system for depths of up to 3 diffuse attentuation lengths, which can be 100 meters or more in the open ocean. In this paper field test results are reviewed and performance specifications for typical Raman lidar systems are presented.

Leonard, D. A.↗
NASA NTRS1992

Study of the oxygen transport through Ag (110), Ag (poly), and Ag 2.0 Zr

The transport of oxygen through high-purity membranes of Ag (110), Ag (poly), Ag (nano), and Ag 2.0 Zr has been studied by an ultrahigh vacuum permeation method over the temperature range of 400-800 C. The data show that there are substantial deviations from ordinary diffusion-controlled transport. A surface limitation has been confirmed by glow-discharge studies where the upstream O2 supply has been partially converted to atoms, which, for the same temperature and pressure, gave rise to over an order of magnitude increase in transport flux. Further, the addition of 2.0 wt percent Zr to the Ag has provided increased dissociative adsorption rates, which, in turn, increased the transport flux by a factor of 2. It was also observed that below a temperature of 630 C, the diffusivity exhibits an increase in activation energy of over 4 kcal/mol, which has been attributed to trapping of the atomic oxygen and/or kinetic barriers at the surface and subsurface of the vacuum interface. Above 630 C, the activation barrier decreases to the accepted value of about 11 kcal/mol for Ag (poly), consistent with zero concentration at the vacuum interface.

Outlaw, R. A.↗
NASA NTRS1974

Use of visible, near-infrared, and thermal infrared remote sensing to study soil moisture

Two methods are described which are used to estimate soil moisture remotely using the 0.4- to 14.0 micron wavelength region: (1) measurement of spectral reflectance, and (2) measurement of soil temperature. The reflectance method is based on observations which show that directional reflectance decreases as soil moisture increases for a given material. The soil temperature method is based on observations which show that differences between daytime and nighttime soil temperatures decrease as moisture content increases for a given material. In some circumstances, separate reflectance or temperature measurements yield ambiguous data, in which case these two methods may be combined to obtain a valid soil moisture determination. In this combined approach, reflectance is used to estimate low moisture levels; and thermal inertia (or thermal diffusivity) is used to estimate higher levels. The reflectance method appears promising for surface estimates of soil moisture, whereas the temperature method appears promising for estimates of near-subsurface (0 to 10 cm).

Blanchard, M. B.↗