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Ceramic Spheres From Cation Exchange Beads

Porous ZrO2 and hollow TiO2 spheres were synthesized from a strong acid cation exchange resin. Spherical cation exchange beads, polystyrene based polymer, were used as a morphological-directing template. Aqueous ion exchange reaction was used to chemically bind (ZrO)(2+) ions to the polystyrene structure. The pyrolysis of the polystyrene at 600 C produces porous ZrO2 spheres with a surface area of 24 sq m/g with a mean sphere size of 42 microns. Hollow TiO2 spheres were synthesized by using the beads as a micro-reactor. A direct surface reaction - between titanium isopropoxide and the resin beads forms a hydrous TiO2 shell around the polystyrene core. The pyrolysis of the polystyrene core at 600 C produces hollow anatase spheres with a surface area of 42 sq m/g with a mean sphere size of 38 microns. The formation of ceramic spheres was studied by XRD, SEM and B.E.T. nitrogen adsorption measurements.

Dynys, F. W.

Can the Equivalent Sphere Model Approximate Organ Doses in Space?

For space radiation protection it is often useful to calculate dose or dose,equivalent in blood forming organs (BFO). It has been customary to use a 5cm equivalent sphere to. simulate the BFO dose. However, many previous studies have concluded that a 5cm sphere gives very different dose values from the exact BFO values. One study [1] . concludes that a 9 cm sphere is a reasonable approximation for BFO'doses in solar particle event environments. In this study we use a deterministic radiation transport [2] to investigate the reason behind these observations and to extend earlier studies. We take different space radiation environments, including seven galactic cosmic ray environments and six large solar particle events, and calculate the dose and dose equivalent in the skin, eyes and BFO using their thickness distribution functions from the CAM (Computerized Anatomical Man) model [3] The organ doses have been evaluated with a water or aluminum shielding of an areal density from 0 to 20 g/sq cm. We then compare with results from the equivalent sphere model and determine in which cases and at what radius parameters the equivalent sphere model is a reasonable approximation. Furthermore, we address why the equivalent sphere model is not a good approximation in some cases. For solar particle events, we find that the radius parameters for the organ dose equivalent increase significantly with the shielding thickness, and the model works marginally for BFO but is unacceptable for the eye or the skin. For galactic cosmic rays environments, the equivalent sphere model with an organ-specific constant radius parameter works well for the BFO dose equivalent, marginally well for the BFO dose and the dose equivalent of the eye or the skin, but is unacceptable for the dose of the eye or the skin. The ranges of the radius parameters are also being investigated, and the BFO radius parameters are found to be significantly, larger than 5 cm in all cases, consistent with the conclusion of an earlier study [I]. The radius parameters for the dose equivalent in GCR environments are approximately between 10 and I I cm for the BFO, 3.7 to 4.8 cm for the eye, and 3.5 to 5.6 cm for the skin; while the radius parameters are between 10 and 13 cm for the BFO dose.

Lin, Zi-Wei

Planetary Education and Outreach Using the NOAA Science on a Sphere

Science On a Sphere (SOS) is a large visualization system, developed by the National Oceanic and Atmospheric Administration (NOAH), that uses computers running Redhat Linux and four video projectors to display animated data onto the outside of a sphere. Said another way, SOS is a stationary globe that can show dynamic, animated images in spherical form. Visualization of cylindrical data maps show planets, their atmosphere, oceans, and land, in very realistic form. The SOS system uses 4 video projectors to display images onto the sphere. Each projector is driven by a separate computer, and a fifth computer is used to control the operation of the display computers. Each computer is a relatively powerful PC with a high-end graphics card. The video projectors have native XGA resolution. The projectors are placed at the corners of a 30' x 30' square with a 68" carbon fiber sphere suspended in the center of the square. The equator of the sphere is typically located 86" off the floor. SOS uses common image formats such as JPEG, or TIFF in a very specific, but simple form; the images are plotted on an equatorial cylindrical equidistant projection, or as it is commonly known, a latitude/longitude grid, where the image is twice as wide as it is high (rectangular). 2048x] 024 is the minimum usable spatial resolution without some noticeable pixelation. Labels and text can be applied within the image, or using a timestamp-like feature within the SOS system software. There are two basic modes of operation for SOS: displaying a single image or an animated sequence of frames. The frame or frames can be setup to rotate or tilt, as in a planetary rotation. Sequences of images that animate through time produce a movie visualization, with or without an overlain soundtrack. After the images are processed, SOS will display the images in sequence and play them like a movie across the entire sphere surface. Movies can be of any arbitrary length, limited mainly by disk space and can be animated at frame rates up to 30 frames per second. Transitions, special effects, and other computer graphics techniques can be added to a sequence through the use of off-the-shelf software, like Final Cut Pro. However, one drawback is that the Sphere cannot be used in the same manner as a flat movie screen; images cannot be pushed to a "side", a highlighted area must be viewable to all sides of the room simultaneously, and some transitions do not work as well as others. We discuss these issues and workarounds in our poster.

Simon-Miller, A. A.

SPHERES National Lab Facility

SPHERES is a facility of the ISS National Laboratory with three IVA nano-satellites designed and delivered by MIT to research estimation, control, and autonomy algorithms. Since Fall 2010, The SPHERES system is now operationally supported and managed by NASA Ames Research Center (ARC). A SPHERES Program Office was established and is located at NASA Ames Research Center. The SPHERES Program Office coordinates all SPHERES related research and STEM activities on-board the International Space Station (ISS), as well as, current and future payload development. By working aboard ISS under crew supervision, it provides a risk tolerant Test-bed Environment for Distributed Satellite Free-flying Control Algorithms. If anything goes wrong, reset and try again! NASA has made the capability available to other U.S. government agencies, schools, commercial companies and students to expand the pool of ideas for how to test and use these bowling ball-sized droids. For many of the researchers, SPHERES offers the only opportunity to do affordable on-orbit characterization of their technology in the microgravity environment. Future utilization of SPHERES as a facility will grow its capabilities as a platform for science, technology development, and education.

Free Flyer

Electric potential on solid spheres in a plasma

Derivation of the general expression for the potential on a solid sphere immersed in a plasma, showing the dependence of the potential on the radius (a) of the sphere and the radius (s) of the plasma sheath that develops around the sphere. In the limit where the radius a is much larger than the sheath thickness s-a, the well-known result for the potential on an infinite wall in contact with a plasma is recovered from this expression. At the other extreme, where s is much larger than a, the result derived by Spitzer (1941) for the potential on spherical grains in the interstellar plasma is obtained. Since the surface of the sphere forms a sink for the charged particles, there is a net drift of the plasma towards the surface. The effect of this drift on the potential is examined. Finally, for very small metallic spheres, an effect leading to a revision of the potential is discussed. This effect consists in a lowering of the potential barrier for the electrons due to the image force. The various effects limiting the potential on spheres are discussed.

De, B. R.

An evaluation of temperature profiles from falling sphere soundings

An evaluation of 30 pairs of high-altitude inflatable falling spheres and independent thermistor soundings with a mean rocket-launch-time separation of 27 min shows average temperature differences within 6 C at 32-70 km, except for an average difference of 10 C at 68 km near Mach 1 in the sphere descent curve. The mean difference is exhibited as a negative bias (sphere temperature colder) for which various explanations are considered. The rms temperature differences are greatest near 50 km (7 C) and 68 km (11 C). From 70 to approximately 87.5 km, confidence in the reliability of the sphere temperature soundings is based on the 'repeatability' of pairs of sphere soundings taken within 20 min, temperature differences generally being less than 10 C. Illustrations of large atmospheric variations measured by the sphere soundings are given along with verification from independent measurements.

Quiroz, R. S.

Aerodynamics of spheres for Mach numbers from 0.6 to 10.5 including some effects of test conditions

Wind tunnel tests were made for spheres of various sizes over a range of Mach numbers and Reynolds numbers. The results indicated some conditions where the drag was affected by changes in the afterbody pressure due to a shock reflection from the tunnel wall. This effect disappeared when the Mach number was increased for a given sphere size or when the sphere size was decreased for a given Mach number. Drag measurements and Schlieren photographs show the possibility of obtaining inaccurate data when tests are made with a sphere too large for the test section size and Mach number. Tests were also made of an oblate spheroid. The results indicated a region at high Mach numbers where inherent positive static stability might occur with the oblate-face forward. The drag results are compared with those for a sphere and those for various other shapes. The drag results for the oblate spheriod and the sphere are also compared with some calculated results.

Spearman, M. Leroy

Method for calculating and observing microwave absorption by a sphere in a single mode rectangular cavity

A new theory of microwave absorption by a lossy dielectric sphere in a single mode rectangular cavity has been recently developed. The absorption was treated in the framework of an electromagnetic scattering problem. That theory is summarized here and calculated results that bear on optimizing the processing of materials are illustrated. Methods for observing power absorption and other results predicted by the scattering model are discussed. Cavity perturbation theory provides a bridge between theoretical calculations and experimental observations, and a special problem that arises when an established version of cavity perturbation theory is applied to spheres is identified, analyzed, and resolved. The direct problem of predicting shifts in frequency and Q from model calculations is discussed for a sphere in a cavity when the sphere's complex dielectric constant is known. Also, the inverse problem of determining the complex dielectric constants from measured values of those shifts is considered. The small sphere limit, where an electrostatic or quasistatic model is valid, is treated in detail, and planned work on parallel problems for larger spheres is described.

Jackson, H. W.

Aerodynamics of a sphere and an oblate spheroid for Mach numbers from 0.6 to 10.5 including some effects of test conditions

Wind-tunnel tests were made for spheres of various sizes over a range of Mach numbers and Reynolds numbers. The results indicated some conditions where the drag was affected by changes in the afterbody pressure due to a shock reflection from the tunnel wall. This effect disappeared when the Mach number was increased for a given sphere size or when the sphere size was decreased for a given Mach number. Drag measurements and Schlieren photographs are presented that show the possibility of obtaining inaccurate data when tests are made with a sphere too large for the test section size and Mach number. Tests were also made of an oblate spheroid. The results indicated a region at high Mach numbers where inherent positive static stability might occur with the oblate-face forward. The drag results are compared with those for a sphere as well as those for various other shapes. The drag results for the oblate spheroid and the sphere are also compared with some calculated results.

Spearman, M. Leroy

Remote sensing estimates of cirrus particle size for tropical and midlatitude cirrus: Hexagonal crystals and ice spheres

A large discrepancy exists in current estimates of a mean cirrus particle size appropriate for calculations of the effects of these ice clouds on solar and thermal infrared radiative fluxes. For spheres with large size parameter (x = (2 pi r / lambda) is greater than 30, where r is particle radius), and moderate absorption (n(sup i) x less than 1, where n(sup i) is imaginary index of refraction for ice), the optimal effective particle radius is given by: r(sub e) = integral of r(exp 3)n(r)dr / integral of r(exp 2)n(r)dr. For the remote sensing of cirrus particle size at wavelengths of 0.83, 1.65, and 2.21 mu m, a 50 mu m ice sphere would have a size parameter of about 200, and values of n(sup i) x of 0, 0.045, and 0.06, satisfying the above conditions. However, while r(sub e) is a well-defined parameter for spheres, this cross-section area-weighted particle radius can only be extended to non-spherical particles by defining some equivalent sphere, typically an equivalent volume or equivalent cross-section area sphere. Using equivalent volume spheres, values of r(sub e) obtained over Lake Michigan on October 28, 1986, during FIRE phase I varied from 200 mu m (King Air 2D Imaging probes) to 60 mu m (Landsat reflectances at 0.83, 1.65, and 2.2 mu m), to 25 mu m (HIS spectrometer thermal emission between 8 and 12 mu m). Three major uncertainties were identified in this comparison: small ice particles missed by the 2D-C aircraft probes, uncertain ice refractive index, and uncertainties in the single scatter albedos and scattering phase functions used in the radiative calculations. Since the first FIRE cirrus results, advances have been made in all three areas. The present paper reports on improvements in the radiative modeling of ice particles at 0.83, 1.65, and 2.21 mu m wavelengths appropriate for comparisons to Landsat Thematic Mapper data. The paper also includes new results for Landsat observations of ice clouds in the eastern and western tropical Pacific.

Wielicki, Bruce A.

HALOE Temperature Data Comparison with Rocket-Borne Falling Sphere Temperatures

Recent comparison of upper stratospheric and mesospheric temperatures measured with the HALOE instrument on UARS and the rocket-borne passive inflatable falling sphere launched from Wallops Island reveals a temperature bias of up to 10 K between about 66 and 72 km. Falling sphere measurements analyzed between 1991 and 1995 were used in the comparison, however, these measurements were processed with an earlier version of the reduction software that included temperature bias in the region of 70 km. The bias arose from a discontinuity in the falling sphere drag table. This discontinuity occurs when the sphere's fall velocity changes from the supersonic to the subsonic flow regime and has been called the MACH 1 problem. Improvement to the software employed and the availability of a new atmospheric model is now used to initiate reduction of the radar tracking data. It is possible new reduction of the existing data will reduce the bias currently observed. We plan to show changes, if any, in the size of the bias between HALOE and the falling sphere temperatures after reprocessing of the sphere measurements.

Schmidlin, F. J.

SPHERES as Formation Flight Algorithm Development and Validation Testbed: Current Progress and Beyond

The MIT-SSL SPHERES testbed provides a facility for the development of algorithms necessary for the success of Distributed Satellite Systems (DSS). The initial development contemplated formation flight and docking control algorithms; SPHERES now supports the study of metrology, control, autonomy, artificial intelligence, and communications algorithms and their effects on DSS projects. To support this wide range of topics, the SPHERES design contemplated the need to support multiple researchers, as echoed from both the hardware and software designs. The SPHERES operational plan further facilitates the development of algorithms by multiple researchers, while the operational locations incrementally increase the ability of the tests to operate in a representative environment. In this paper, an overview of the SPHERES testbed is first presented. The SPHERES testbed serves as a model of the design philosophies that allow for the various researches being carried out on such a facility. The implementation of these philosophies are further highlighted in the three different programs that are currently scheduled for testing onboard the International Space Station (ISS) and three that are proposed for a re-flight mission: Mass Property Identification, Autonomous Rendezvous and Docking, TPF Multiple Spacecraft Formation Flight in the first flight and Precision Optical Pointing, Tethered Formation Flight and Mars Orbit Sample Retrieval for the re-flight mission.

Kong, Edmund M.

Time Resolved Irradiance of an Integrating Sphere Illuminated by a Mode-Locked Optical Parametric Oscillator

Tunable laser based illumination sources have been adopted by a number of recent hyperspectral instruments for pre-launch spectral radiometric calibration. Some of these sources use mode-locked cavity configurations, which produce a pulse train and create an undesirable fluctuation in the radiometric source at the mode locking frequency. Although typically this frequency is several orders of magnitude higher than the instrument response, care must be taken to ensure the resultant calibration is not biased due to detector or electronic saturation effects. The temporal averaging properties of an integrating sphere can be used to reduce high frequency fluctuations to an acceptable level. In this work, the time resolved output of an integrating sphere coupled with a mode-locked source was measured. A 76 cm diameter sphere with 30 cm output aperture was illuminated using a mode-locked pulse train at 76 MHz, with single pulse durations of 12 ps. The time constant of the sphere was found to be 36 ns, and the resultant temporal averaging of pulses produced a maximum time varying irradiance at the output of 20% of the mean. The form of this time variance is a sawtooth pattern, with a sharp rise during the introduction of each pulse into the sphere followed by a slower decay between pulses. A comparison of instrument calibration data generated with this integrating sphere using both a mode locked source and a continuous wave source is also given. .

McAndrew, Brendan

Recent researches on the air resistance of spheres

The following conclusions on air resistance of spheres are drawn: 1) disturbances in front of the sphere and even single fine wires affect the critical Reynolds Number; 2) disturbances around the sphere increased the drag of the sphere without martially affecting the value of the Reynolds Number(sub crith); 3) great disturbances of the boundary layer of the sphere likewise change R.N.(sub crith); 4) turbulence of the approaching air stream lowers critical R.N.

AERODYNAMICS

Critical levitation loci for spheres on cryogenic fluids.

The conditions which allow a fluid to support a sphere having a higher specific gravity than its own are investigated. Three basic parameters which together define the maximum floating conditions are considered, including the Bond number, the wetting angle of the interface, and the ratio of solid-liquid specific gravities. The Bond number represents the ratio of buoyancy to surface tension forces. An analysis of the forces at the sphere-liquid interface is conducted to determine the optimum levitation loci, that is, the conditions permitting flotation of a maximum density sphere. Data for glycerine, carbon tetrachloride, and water spheres floating on a liquid nitrogen surface appear to be in good agreement with the analysis. Data for Teflon spheres on water also appear to be in agreement with the analytical results.

Hendricks, R. C.

Dual falling sphere determination of density and transition flow parameter

A new approach to the analysis of falling sphere drag data is described in which the data from two trajectories through the same region of the atmosphere are analyzed simultaneously. The analysis provides important aerodynamic information which is used to obtain an improved value of atmospheric density. The technique is applied to a set of falling sphere data in which a sphere transition-flow parameter and atmospheric density results are obtained in the 80-120 km region from published data for falling spheres over Kwajalein. Another set of data for a falling sphere test over Wallops Island is also analyzed with comparable results.

Karr, G. R.

Resonance frequency shift of an acoustic chamber containing a rigid sphere

The resonance frequency shift of an acoustic rectangular chamber due to the presence of a rigid sphere has been measured for l = 1,2 modes as a function of sphere size and position. The frequency shift is the results of volume exclusion and wave scattering. An analytical Green's function calculation was used to explain the data, providing excellent agreement between the measured and the calculated values. Also reported are similar measurements for a thin disk and the ratio of second harmonic to fundamental pressure as a function of sphere position. The measurement shows that the sphere reduces the first harmonic content, with sharply peaked suppression minima at specific sphere positions.

Leung, E.

Evaporative coating of a sphere from a point source

To optimize the procedure for evaporating a metal film onto a sphere, calculations of the film thickness distribution for various motions of the sphere have been carried out. These calculations, including shadowing effects of sphere support rods, are presented in this paper. Also, an apparatus and procedure for the evaporative coating of a sphere are described. A comparison of measured thickness with the calculated values is made for one example of sphere motion. The implications of the calculated results for coating techniques are discussed.

Strayer, D. M.