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All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Spectra and structure of organophosphorus compounds. XII - Infrared and Raman spectra of /CH3/2PH and /CD3/2PH

The vibrational spectra of (CH3)2PH and (CD3)2PH have been studied and assignments made. In the infrared, the region between 4000 and 33 wavelength/cm was recorded for the gaseous and solid states, while Raman spectra from 3500 to 10 wavelength/cm in the gaseous, liquid and solid states were observed. There is some evidence of weak hydrogen bonding, based on the behavior of the phosphorus-hydrogen stretching and bending modes. There also appears to be considerable interaction between the methyl rocking and phosphorus-carbon stretching modes. The a double prime and a prime torsional modes appear to be accidentally degenerate at 182 and 142 wavelength/cm for the 'light' and 'heavy' compounds, respectively. This gives barriers of 2.14 and 2.30 kcal/mole, respectively.

Durig, J. R.↗
NASA NTRS1977

Analysis of torsional spectra of molecules with two internal C/3v/ rotors. III - Far-infrared and gas phase Raman spectra of dimethylamine-d0, -d3, and -d6

The Raman spectra of gaseous dimethylamine-d0, -d3, and -d6 have been recorded between 0 and 4000/cm. The far-infrared spectra have been recorded between 300 and 100/cm. Considerable torsional data are reported and used to characterize the torsional potential function based on a semi-rigid model. The average effective V3 for the dimethylamines was found to be 1052 plus or minus 12/cm. The cos-cos coupling term was approximately 15% of the effective V3, whereas the sine-sine coupling term was of an order of magnitude smaller for (CH3)2NH and (CD3)2NH. However, for the mixed isotope the sine-sine term was found to be negligible and the cos-cos about one-half the value obtained for the other two isotopes.

Durig, J. R.↗
NASA NTRS1980

Documentation for the machine-readable version of an atlas of ultraviolet stellar spectra and a second atlas of ultraviolet stellar spectra from OAO 2 observations

The magnetic tape version of the Orbiting Astronomical Observatory 2 atlases of ultraviolet stellar spectra is described. The first file of the tape contains ultraviolet stellar fluxes for 164 bright stars in lambda the spectral region 1200 to 1300 A with resolutions of 22 A in the region from 3600 to 1850 A and 12 A in the region from 1850 to 1160 A. Files two and three contain spectra for 132 stars in the region lamba 1200 to 1850 A and 34 stars in the lambda region 1800 to 3600 A, respectively, with resolutions as stated above. The monochromatic flux is given in units of ergs cm(-2)s(-1) (-1) for all data.

Warren, W. H., Jr.↗
NASA NTRS1980

High temperature crystal field spectra of transition metal-bearing minerals - Relevance to remote-sensed spectra of planetary surfaces

It is pointed out that transition metal ions in silicate minerals, glasses, and crystalline and amorphous oxyhydroxides and salts contribute to the visible-near infrared spectral profiles of planetary surfaces. Investigations are conducted to obtain spectral information which might be helpful in the interpretation of the remote-sensed spectra of planetary surfaces. A description is presented of the results of high temperature crystal field spectral measurements of a variety of heated minerals containing Cr(3+), Fe(3+), Fe(++), and Mn(++) ions in different coordination symmetries, taking into account a correlation of the temperature-induced variations with those previously observed for octahedrally coordinated Fe(++)-bearing silicates. The employed experimental methods are also discussed, giving attention to the preparation of the samples, the determination of the absorption spectra, electron microprobe analyses, and the curve fitting procedure.

Parkin, K. M.↗
NASA NTRS1986

An example of scaling MST Doppler spectra using median spectra, spectral smoothing, and velocity tracing

Although automatic, computer scaling methods appeared at the start of the MST (mesosphere stratosphere troposphere) radar technique, there is a continuing need for scaling algorithms that perform editing functions and increase the sensitivity of radar by post processing. The scaling method presented is an adaptation of the method of scaling MST Doppler spectra presented by Rastogi (1984). A brief overview of this method is as follows: a median spectrum is calculated from several sequential spectra; the median noise value is subtracted from this derived spectrum; the median spectrum is smoothed; the detection/nondetection decision is made by comparing the smoothed spectrum to the variance of the smoothed noise; and if a signal is detected, then the half-power points of the smoothed echo spectrum are used to place limits on the evaluation of the first two moments of the unsmoothed median spectrum. In all of the above steps, the algorithm is guided by tracing the expected velocity range upward from the lowest range as far as possible. The method is discussed in more detail.

Green, J. L.↗
NASA NTRS1986

A Study of the Ultraviolet Absorptions in the Spectra of DA White Dwarfs and Ultraviolet Spectra of the Star HR6560

Two projects in conjunction with the International Ultraviolet Explorer Satellite are discussed. These projects were to: (1) study the properties of the H2 and H2+ quasi-molecular absorption features at lambda lambda 1600 and 1400 in the ultraviolet spectra of the hydrogen-rich DA white dwarfs and to search for additional spectroscopic features in the spectra of these stars; and (2) use the ultraviolet portion of the spectrum of the peculiar rare earth-rich late F type star, HR6560 (HD159870), to establish whether or not the element abundance anomalies are produced in conjunction with its having a white dwarf binary companion. The data show that HR6560 is probably not associated with any hot subluminous or degenerate star.

Wegner, Gary A.↗
NASA NTRS1987

Ultraviolet Spectra of Two Magnetic White Dwarfs and Ultraviolet Spectra of Subluminous Objects Found in the Kiso Schmidt Survey

Low resolution International Ultraviolet Explorer (IUE) spectroscopic observations of two magnetic white dwarfs BPM25114 and K813-14 were obtained using both the SWP and LWP cameras. The first object has an observed magnetic field of 4 x 10(7) Gauss and the second has one of 3 x 10(7) Gauss. Both objects have overall spectral energy distributions appropriate for cool DA white dwarfs with T(eff) near 10,000 K and accordingly show strong lambda lambda 1400 and 1600 absorption in their spectra. Compared to non-magnetic DA white dwarfs of comparable effective temperature, there are some differences in the profiles, presumably produced by the magnetic fields in these objects. In addition, the ultraviolet spectra of a number of hot subluminous stars in the Kiso Schmidt survey were observed.

Wegner, Gary A.↗
NASA NTRS1998

Track Structure Model for Radial Distributions of Electron Spectra and Event Spectra from High-Energy Ions

An analytic method is described for evaluating the average radial electron spectrum and the radial and total frequency-event spectrum for high-energy ions. For high-energy ions, indirect events make important contributions to frequency-event spectra. The method used for evaluating indirect events is to fold the radial electron spectrum with measured frequency-event spectrum for photons or electrons. The contribution from direct events is treated using a spatially restricted linear energy transfer (LET). We find that high-energy heavy ions have a significantly reduced frequency-averaged final energy (yF) compared to LET, while relativistic protons have a significantly increased yF and dose-averaged lineal energy (yD) for typical site sizes used in tissue equivalent proportional counters. Such differences represent important factors in evaluating event spectra with laboratory beams, in space- flight, or in atmospheric radiation studies and in validation of radiation transport codes. The inadequacy of LET as descriptor because of deviations in values of physical quantities, such as track width, secondary electron spectrum, and yD for ions of identical LET is also discussed.

Cucinotta, F. A.↗
NASA NTRS2019

Computing Rotational, Rovibrational, and Vibrational Spectra for Astronomical Observations: High Accuracy Line Lists for High Temperatures, Limited Line Lists for Biosignature Molecules, and PAH Emission Spectra

Over the last several years, our group has been involved in developing approaches to compute highly accurate spectroscopic constants and vibrational frequencies for small transient molecules that may be used in the interpretation and assignment of high-resolution laboratory experiments as well as high-resolution astronomical spectra. Additionally, we have used the computed spectroscopic constants to simulate purely rotational and rovibrational spectra so that these may be compared directly with high- resolution astronomical observations, and we have worked on developing approaches that can be applied to much larger molecules, such as PAHs, where we can explicitly determine an harmonic corrections to vibrational modes as well as take into account intensity sharing due to resonances. Another part of our work in spectroscopic signatures involves computing highly accurate line lists for common molecules, such as CO2, SO2, and NH3, which occur in many astrophysical environments, including the atmospheres of exoplanets, and often need to have their lines identified in high- resolution observations in order to determine which lines are due to other molecules. In order to characterize the atmospheres of hot exoplanets, these line lists need to be very accurate and extend to very high energies. I will discuss our latest work in these areas of astrochemical spectroscopy research.

Lee, Timothy J.↗
NASA NTRS1975

Spectroscopic analysis of solar and cosmic X-ray spectra. 1: The nature of cosmic X-ray spectra and proposed analytical techniques

Techniques for the study of the solar corona are reviewed as an introduction to a discussion of modifications required for the study of cosmic sources. Spectroscopic analysis of individual sources and the interstellar medium is considered. The latter was studied via analysis of its effect on the spectra of selected individual sources. The effects of various characteristics of the ISM, including the presence of grains, molecules, and ionization, are first discussed, and the development of ISM models is described. The expected spectral structure of individual cosmic sources is then reviewed with emphasis on supernovae remnants and binary X-ray sources. The observational and analytical requirements imposed by the characteristics of these sources are identified, and prospects for the analysis of abundances and the study of physical parameters within them are assessed. Prospects for the spectroscopic study of other classes of X-ray sources are also discussed.

Walker, A. B. C., Jr.↗
NASA NTRS1977

Analysis of torsional spectra of molecules with two internal C3v rotors. II - Far infrared and low frequency Raman spectra of dimethylether isotopes

The torsional far infrared and Raman spectra of gaseous CH3OCH3, CD3OCH3, and CD3OCD3 are presented. They are analyzed using a computer program which is based on the results of an extensive investigation of the isometric groups and of the symmetry groups of the rotation-internal rotation Hamiltonians of a series of semirigid two-top models. Four or more Fourier coefficients of the potential functions in two variables could be determined for each isotope. Strong evidence was found for Fermi-resonance-type interactions with the COC bending mode.

Groner, P.↗
NASA NTRS1986

A comparison of SIR-B directional ocean wave spectra with aircraft scanning radar spectra

Directional ocean wave spectra derived from Shuttle Imaging Radar-B (SIR-B) L-band imagery collected off the coast of Southern Chile on 11 and 12 October 1984 were compared with independent spectral estimates from two airborne scanning radars. In sea states with significant wave heights ranging from 3 to 5 meters, the SIR-B-derived sspectra at 18 deg and 25 deg off nadir yielded reasonable estimates of wavelengths, directions, and spectral shapes for all wave systems encountered, including a purely azimuth-traveling system. A SIR-B image intensity variance spectrum containing predominantly range-traveling waves closely resembles an independent aircraft estimate of the slope variance spectrum. The prediction of a U.S. Navy global spectral ocean wave model on 11 October 1984 exhibited no significant bias in dominant wave number but contained a directional bias of about 30 deg with respect to the mean of the aircraft and spacecraft estimates.

Beal, R. C.↗
NASA NTRS2012

Update from the Analysis of High Resolution Propane Spectra and the Interpretation of Titan's Infrared Spectra

Titan has an extremely thick atmosphere dominated by nitrogen, but includes a range of trace species such as hydrocarbons and nitriles. One such hydrocarbon is propane (C3H8). Propane has 21 active IR bands covering broad regions of the mid-infrared. Therefore, its ubiquitous signature may potentially mask weaker signatures of other undetected species with important roles in Titan's chemistry. Cassini's Composite Infrared Spectrometer (CIRS) observations of Titan's atmosphere hint at the presence of such molecules. Unfortunately, C3H8 line atlases for the vibration bands V(sub 8), V(sub 21), V(sub 20), and V(sub 7) (869, 922, 1054, and 1157 per centimeter, respectively) are not currently available for subtracting the C3H8 signal to reveal, or constrain, the signature of underlying chemical species. Using spectra previously obtained by Jennings, D. E., et al. at the McMath-Pierce FTIR at Kitt Peak, AZ, as the source and automated analysis utilities developed for this application, we are compiling an atlas of spectroscopic parameters for propane that characterize the ro-vibrational transitions in the above bands. In this paper, we will discuss our efforts for inspecting and fitting the aforementioned bands, present updated results for spectroscopic parameters including absolute line intensities and transition frequencies in HITRAN and GEISA formats, and show how these optical constants will be used in searching for other trace chemical species in Titan's atmosphere. Our line atlas for the V(sub 21) band contains a total number of 2971 lines. The band integrated strength calculated for the V(sub 21) band is 1.003 per centimeter per (centimeter-atm).

Klavans, V.↗