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Direct Measurement of Diffusion Coefficients: Evidence for Diffusive Stochastic Heating in Collisionless Plasmas

Open questions in collisionless plasma dissipation can be addressed using space-based observations in different astrophysical environments, with implications for both astrophysical and laboratory plasma systems. We study a low-𝛽, highly imbalanced, sub-Alfvénic stream observed by Parker Solar Probe (PSP) to identify and distinguish between signatures of stochastic heating (SH) and resonant heating (RH) by parallel ion cyclotron waves (∥-ICWs). Prior work studying this stream [Trevor A. Bowen et al., Stochastic heating in the sub-Alfvénic solar wind, Phys. Rev. Lett. 135, 255201 (2025)] showed that the SH rate, accounting for intermittency, matched the amplitude of the local energy transfer (LET) rate, while the RH rate did not. This comparison relied on a number of assumptions regarding the nature of the diffusive process and the calculation of the LET rate. We introduce a novel technique of inverting the proton guiding center equation to empirically measure velocity-space diffusion coefficients using three-dimensional proton velocity distribution functions, from the ion electrostatic analyzer (the Solar Probe Analyzer for Ions) on PSP. Measured diffusion coefficients are used to determine phase-space heating rates, leading to a calculation of a fully kinetic heating rate independent of assumptions made in prior work. We show that scale-dependent analytic expressions for SH via noncoherent fluctuations match the empirical measurements from PSP data, provided that we account for intermittency in the heating calculation. In contrast, the derived heating rates for SH that accounts for the effects of the helicity barrier and heating rates for RH via ∥-ICWs do not peak in the same region of velocity space as the empirical measurements, nor do they reach the required magnitude. Our approach provides novel methodology to uniquely identify and constrain heating processes in collisionless plasmas and shows evidence of a Fokker-Planck-like diffusive process in the near-Sun solar wind.

Plasma kinetic theory↗

Detecting gravitational signatures of dark matter with atom gradiometers

We study the purely gravitational signatures of dark matter from the ultralight to the ultraheavy mass range in proposed long-baseline atom gradiometers, focusing on terrestrial designs, such as AION-km and MAGIS-km, as well as space-based concepts, such as MAGIS-space, AEDGE and AEDGE+. Due to its exceptional acceleration sensitivity and depending on astrophysical backgrounds, a detector similar to AEDGE+ could detect a dark matter subcomponent which constitutes 𝒪⁡(10%) of the local dark matter energy density and is populated by compact clumps of mass between 10 6 kg and 10 10 kg (10 −25 ⁢𝑀⊙ ≲ 𝑀 ≲10 −21⁢ 𝑀⊙) in an otherwise unexplored region of dark matter model space. Furthermore, because the gravitational observable depends on the relative gravitational time delay measured by spatially separated atomic clouds, we find that atom gradiometers are parametrically more sensitive than laser interferometers, such as LIGO and LISA, to fast-oscillating spacetime perturbations sourced by energy density and pressure fluctuations of ultralight dark matter. Depending on astrophysical backgrounds, a detector akin to AEDGE+ could probe a DM overdensity of 𝒪⁡(10) times the local dark matter energy density for masses 𝑚 ≲10 −17 eV.

79 ASTRONOMY AND ASTROPHYSICS↗

OpenSAMPL: An Open Source Library for Timing and Synchronization Measurements and Analytics

Today's power grid operators are implementing timing and synchronization solutions that provide resilience to Global Navigation Satellite System (GNSS) vulnerabilities. These vendor-specific solutions often come with additional software applications that are designed to monitor that vendor's synchronization performance data. However, resilient timing architectures often resulting in multi-vendor solutions, including approaches that blend terrestrial clocks with space-based subscription services. In such an environment, collecting, analyzing, and visualizing data from a variety of sources within a single platform was heretofore not possible. To address this need, the US Department of Energy's Center for Alternative Synchronization and Timing (CAST) developed OpenSAMPL, the Open Synchronized Analytics and Monitoring Platform, an open-source Python framework for processing, loading, and observing clock measurement data from distributed devices. OpenSAMPL enables the ingestion of diverse clock-probe sources into a scalable time-series database and applies robust analytics. OpenSAMPL currently supports two vendor data pipelines, and will be extended to more in the near future, enabling seamless monitoring of a variety of timing and synchronization devices in a common environment.

Grant, Josh [ORNL] (ORCID:0000000163475060)↗

Measurement of Photons Emitted by High-Energy Charged Particles as Background in Single-Photon Resolving Image Sensors

This work introduces an advanced technique optimized for detecting photons generated by charged particles, leveraging Skipper charge coupled device (Skipper-CCD) image sensors. By analyzing background sources and detection efficiencies, the technique achieves strong agreement between experimental results and Cherenkov-based simulations. It also provides a robust framework for investigating secondary photon production in environments with high fluxes of ionizing particles, such as those anticipated in space-based astronomical instruments. These secondary photons present a critical challenge as background noise for next-generation single-photon resolving imagers used to study faint celestial objects. Furthermore, the method exhibits significant potential for broader applications, including exploring photon generation in various substrate materials and examining their transport through multiple interfaces.

Fernandez Moroni, Guillermo [Fermilab; Chicago U.,↗

Energy gain scale calibration of the XRISM Resolve microcalorimeter spectrometer: ground calibration results and on-orbit comparison

The Resolve instrument aboard the X-ray Imaging and Spectroscopy Mission (XRISM) is a 36-pixel microcalorimeter spectrometer that provides nondispersive spectroscopy with ∼ 5 eV spectral resolution in the soft X-ray waveband. Resolve has a requirement to provide an absolute energy-scale calibration of ± 2 eV from 0.3 to 12 keV. We describe our ground calibration strategy and results of a subset of the ground calibration campaigns, including a discussion of improvements in the energy scale ground calibration compared with Hitomi’s. These improvements include calibration of the low-energy band below 4 keV with the instrument in the flight dewar and the dewar aperture door open, which was not performed for Hitomi, and thorough measurements over an extended high-energy waveband to 22 keV. We also developed an improved technique for gain calibration of “mid-res” secondary events, which have suppressed gain due to proximity to a preceding X-ray event (18 to 70 ms) on the same pixel. We provide a discussion of the on-orbit energy scale monitoring campaigns and an assessment of the Resolve energy scale uncertainties, a key parameter for astrophysics analysis. Energy-scale calibration approaches for future space-based instruments, including the X-ray Integral Field Unit on Athena and microcalorimeter spectrometers proposed or under discussion for future X-ray observatory concepts, have heritage in the calibration of XRISM. We briefly comment on lessons learned from Resolve calibration that are relevant for these future instruments.

Aluminum↗

Towards satellite tests combining general relativity and quantum mechanics through quantum optical interferometry: progress on the deep space quantum link

The Deep Space Quantum Link (DSQL) is a space-mission concept that aims to explore the interplay between general relativity and quantum mechanics using quantum optical interferometry. This mission concept was formally presented to the United States National Academy of Science Decadal Survey as a research campaign for Fundamental Physics in 2022. Since then, advances have been made in the space-based quantum optical technologies required to conduct a DSQL-type mission. In addition, other research efforts have defined alternative measurement concepts to explore the same scientific questions motivating the DSQL mission. This paper serves as an update to the community on the status of the DSQL mission concept and related research and technology development efforts.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Atoms-to-devices models for post-irradiation annealing kinetics in III-V semiconductors

Understanding atomic displacement damage and propagating this understanding into validated defect-aware radiation damage models is a critical step toward achieving predictive, atoms-to-systems assessment of radiation vulnerabilities of microelectronics. These models are essential for evaluating the performance and reliability of nuclear stockpile components or space-based electronics (satellites). The goal of this project was to bridge a fundamental science gap between defect spectroscopies and atomistic modeling of radiation-induced defects on the one hand, and simulations of device response on the other hand, to develop predictive defect-aware damage models for high-fidelity device simulations of radiation-damaged III-V semiconductors.

36 MATERIALS SCIENCE↗

WEC Irradiation Can Thermal Testing Report

With renewed interest for the next generation of small modular reactors and space-based nuclear reactors, metal hydrides have been a focus of research for moderating materials to reduce the need for highly enriched fuel to maintain small core sizes. Yttrium hydride (YH) is an attractive candidate for these metal hydrides due to its ability to retain hydrogen at elevated temperatures as well as the low neutron absorption cross section of yttrium metal. Given the necessity for reactors to operate at elevated temperatures for extended periods of time, understanding hydrogen retention in moderator channels in simulated operating thermal conditions is paramount in predicting reactor performance and the long-term stability of YH. Additionally, coating strategies on the moderator encapsulating will be explored to ascertain if it aids in retention of hydrogen within the capsule and moderator.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Proliferated Resilient Economical Half-Meter Aperture Space Telescopes (PREEMPT)

The PREEMPT LDRD was motivated by a major national need for better space-based imaging systems that are both high performing and affordable for the US Government. Current optical payloads for intelligence, surveillance and reconnaissance (ISR) and space domain awareness (SDA) missions can cost hundreds of millions of dollars and take years to develop, which makes it difficult to build the large constellations required for persistent, world-wide coverage. To address this, the team aimed to advance a different kind of large-aperture (>25 cm) telescope, called a monolithic telescope, in which key optical surfaces are built into a single piece of fused silica. This design greatly reduces payload and spacecraft complexity, the need for precision focus actuators, improves mechanical and thermal robustness, and lowers cost when compared with traditional Cassegrain telescopes that rely on many precisely aligned components. The project focused on five primary thrusts. The first thrust was to advance the concept of a V10, 25 cm, monolithic telescope forward from optical design to flight-ready stage. This was accomplished in partnership with Optimax, who delivered the first test unit in the early stages of the LDRD. The team developed several technologies necessary for this optic to be integrated into a flight demonstration. These include carbon fiber housings, highly detailed structural and thermal models and stress-reducing elastic averaging Hirth groove designs. These technologies resulted in a successful maturation of the optic, which is now slated to fly in late 2026/early 2027 for a demonstration mission. The second thrust was to advance the manufacturability of these optics. In collaboration with NIF’s optical manufacturing shop, we reduced polishing time from 480 hours to 65 hours through the implementation of optimized processes and new tools. The NIF team utilized a conceptual V8 (18 cm) optic to demonstrate this optimization, though it can be applied to the rest of the monolithic optic portfolio. Third, the team developed the first conceptual V20 (50 cm) payload, which is slated to be the next generation of LLNL optical payload systems. A set of structural, dynamic and thermal simulations were performed to identify potential challenges in the future development of this payload. Early-stage simulations suggest the payload is feasible, though thermal management will be the key focus area to maintain optimal performance. Fourth, a non-linear model of Viton was developed, to further enhance the reliability of our structural and dynamic models for future payloads. Viton acts as the primary interface material between the optic and its housing. Lastly, the team focused on successfully displaying the feasibility of using additively manufactured metal composites for optical space payloads. The team successfully demonstrated layer by layer deposition of Al-SiC composites, which have highly tunable structural and coefficient of thermal expansion (CTE) properties. These are crucial for optical payloads because CTE mismatch is one of the causes for degraded optical performance for telescopes in orbit. Overall, the work showed that monolithic telescopes could become a practical, lower-cost path to high-resolution space imaging for both national security and scientific missions.

42 ENGINEERING↗

Studies of whistler propagation along a plasma density gradient that is parallel to the magnetic field

Low frequency plasma wave generation in space is important for both scientific and practical applications. One of the most promising techniques for doing this is to directly inject whistler waves into the space environment from an antenna onboard one or more satellites. This technique has been discussed for years, but there are still open questions about the best way to generate plasma waves. So far, most theoretical [Kondrat92], lab based [Pribyl2010, Stenzel2016] and space-based experiments [DSX] have focused on studying the generation of whistler waves from an electric dipole antenna. However, a dipole antenna is very inefficient because it puts a lot of energy in waves that are not effective for most applications. Theoretical [Kondrat92] and lab experimental [Stenzel2016] results indicate that a loop antenna is much more efficient at generating whistler waves than a dipole antenna. A satellite experiment will need to be developed to demonstrate that whistler waves can be generated from a loop antenna in the space environment. The challenge is that to efficiently transmit whistler modes in the natural plasma environment of space, the loop antenna will have to be very large. For example, at L=2 (one earth radius away from the surface of the earth) a loop antenna would need a radius on the order of ~200 m to radiate efficiently, as shown in fig. 1, left. The antenna size and complexity would require a prohibitively large and expensive satellite mission. Our proposed innovation is to exploit the fact that the characteristic wavelength of whistler waves decreases in more dense plasma, which reduces the size needed for an antenna to radiate efficiently. Fortunately, a technique already exists for enhancing the local plasma density in space, called a plasma contactor [Kovaleski2001]. A plasma contactor can be used to create a local environment where the plasma density is enhanced around the satellite, which in turn reduces the size of an antenna that is needed to radiate efficiently (Fig. 1, right).

42 ENGINEERING↗

Advancing ocean monitoring and knowledge for societal benefit: the urgency to expand Argo to OneArgo by 2030

The ocean plays an essential role in regulating Earth’s climate, influencing weather conditions, providing sustenance for large populations, moderating anthropogenic climate change, encompassing massive biodiversity, and sustaining the global economy. Human activities are changing the oceans, stressing ocean health, threatening the critical services the ocean provides to society, with significant consequences for human well-being and safety, and economic prosperity. Effective and sustainable monitoring of the physical, biogeochemical state and ecosystem structure of the ocean, to enable climate adaptation, carbon management and sustainable marine resource management is urgently needed. The Argo program, a cornerstone of the Global Ocean Observing System (GOOS), has revolutionized ocean observation by providing real-time, freely accessible global temperature and salinity data of the upper 2,000m of the ocean (Core Argo) using cost-effective simple robotics. For the past 25 years, Argo data have underpinned many ocean, climate and weather forecasting services, playing a fundamental role in safeguarding goods and lives. Argo data have enabled clearer assessments of ocean warming, sea level change and underlying driving processes, as well as scientific breakthroughs while supporting public awareness and education. Building on Argo’s success, OneArgo aims to greatly expand Argo’s capabilities by 2030, expanding to full-ocean depth, collecting biogeochemical parameters, and observing the rapidly changing polar regions. Providing a synergistic subsurface and global extension to several key space-based Earth Observation missions and GOOS components, OneArgo will enable biogeochemical and ecosystem forecasting and new long-term climate predictions for which the deep ocean is a key component. Driving forward a revolution in our understanding of marine ecosystems and the poorly-measured polar and deep oceans, OneArgo will be instrumental to assess sea level change, ocean carbon fluxes, acidification and deoxygenation. Emerging OneArgo applications include new views of ocean mixing, ocean bathymetry and sediment transport, and ecosystem resilience assessment. Implementing OneArgo requires about $100 million annually, a significant increase compared to present Argo funding. OneArgo is a strategic and cost-effective investment which will provide decision-makers, in both government and industry, with the critical knowledge needed to navigate the present and future environmental challenges, and safeguard both the ocean and human wellbeing for generations to come.

ARGO↗

Gravitational Photon Polarization Twist to Probe the Early Universe and the Galactic Center

It is known that gravitational wave backgrounds (GWBs) change the polarization state of photons. This letter explores the possibility of using this effect to detect GWBs. The proposed experiment features a vertically polarized laser pulse traveling through a GWB before reaching a birefringent material which separates photons by polarization. Photons that emerge the birefringent material horizontally polarized are counted as signal photons. A space-based setup of a million km (comparable to the LISA mission) with a millisecond laser pulse is capable to detect the hypothetical pulsars responsible for the excess of gamma rays from the galactic center. Varying the duration of the pulse can reveal a variety of GWBs from the early Universe as well.

Capdevilla, Rodolfo [Fermilab] (ORCID:000000020122↗

Warm-phase microphysical evolution in large-eddy simulations of tropical cumulus congestus: evaluating drop size distribution evolution using polarimetry retrievals, in situ measurements, and a thermal-based framework

Owing to uncertainties in convective microphysics processes, improving parameterizations in Earth system models (ESMs) can benefit from observationally constrained cases suitable for scaling between cloud-resolving models and ESMs. We propose a benchmark large-eddy simulation (LES) cumulus congestus case study from the NASA Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP 2 Ex) for evaluating and improving ESMs in single-column model (SCM) mode. We seek observational constraints using novel polarimetric retrievals and in situ cloud microphysics measurements. Simulations using bulk and bin microphysics initialized with observed aerosol profiles are compared to cloud-top retrievals of cloud droplet effective radius (R eff ), effective variance (ν eff ), and number concentration (N d ) from the airborne Research Scanning Polarimeter (RSP). Both schemes reproduce characteristics of cloud-top N d and R eff that increase and decrease with altitude, respectively. Cloud-top N d is low-biased relative to RSP retrievals in both schemes, potentially due to limitations in both simulations and retrieval assumptions. Cloud-top R eff is low-biased in the bulk scheme but reasonably reproduced by the bin scheme. Profiles of N d and R eff are sensitive to the collision–coalescence process and the vertical variation in aerosol size distribution. Comparison of simulated and in situ droplet size distributions (DSDs) shows that, to first order, integrated moments are always sensitive to sizes < ~ 30 µm and can also be sensitive to larger sizes if the DSDs are sufficiently broad, with implications for the assumed maximum observed size retrieved by the RSP. The bin scheme captures the observed extended tail of the DSD, while the bulk scheme is unable to due to parametric constraints. Differences in expected relationships between in situ measurements of cloud cores and cloud-top retrievals by RSP demonstrate difficulty in constraining well the case presented herein. Finally, a thermal-tracking framework demonstrates that the dilution of N d throughout a thermal's lifetime is heavily determined by collision–coalescence and the height-varying aerosol distribution and that, in the absence of these, the impact of entrainment on diluting N d is largely offset by secondary activation. Implications for evaluating warm-phase convective microphysics schemes in ESMs and translating results for use on global, space-based polarimetry platforms are discussed.

Stanford, McKenna Wallace [Columbia Univ., New Yor↗

Stratospheric aerosol forcing for CMIP7 – Part 1: optical properties for pre-industrial, historical, and scenario simulations

Stratospheric aerosols, most of which originate from explosive volcanic sulfur emissions into the stratosphere, are a key natural driver of climate variability. They are thus a forcing provided by the Coupled Model Intercomparison Project (CMIP) Climate Forcings Task Team to climate modelling groups participating in phase 7 of CMIP. For the historical period, we provide two datasets covering 1750–2023: (i) a volcanic upper tropospheric-stratospheric sulfur emission dataset, documented in a companion paper; and (ii) a stratospheric sulfate aerosol optical property dataset, documented in this paper. For the satellite era (from 1979 onwards), stratospheric aerosol optical properties are derived from the Global Space-based Stratospheric Aerosol Climatology (GloSSAC) dataset. For the pre-satellite era (1750–1978), optical properties are derived from our volcanic SO 2 emission dataset using a new version of the reduced-complexity volcanic aerosol model Easy Volcanic Aerosol (Height) (EVA_H v2). A background, non-volcanic stratospheric aerosol climatology is derived from the 1998–2001 period with a trend over 1850–1978 accounting for increasing anthropogenic aerosols. A monthly stratospheric aerosol climatology is derived from the 1850–2021 average for both pre-industrial and scenario (future) simulations, with a 9-year ramp over 2022–2030 for scenario simulations to ensure a smooth transition from the historical period. CMIP7 simulations should use version 2.2.1 of our pre-industrial and historical datasets, and version 2.2.2 of our scenario dataset. Our methodology to produce historical aerosol optical properties significantly differs from CMIP6 for the pre-satellite era, and the resulting forcings in turn largely differ. In particular, the CMIP6 dataset was mostly based on the sparse and uncertain pyrheliometer record, which resulted in strongly underrepresented emissions from small-to-moderate magnitude eruptions. The resulting bias is addressed in CMIP7, which is entirely emission-derived in the pre-satellite era and uses more recent ice-core-based volcanic sulfur emission inventories than CMIP6. Our approach results in an overall larger volcanic aerosol forcing for CMIP7, with the 1850–2014 mean mid-visible global mean stratospheric aerosol optical depth (SAOD) in CMIP7 (0.0138) being 29 % higher than in CMIP6 (0.0107). The pre-industrial mean of the same variable is 26 % higher in CMIP7 (0.0135, derived from the historical 1850–2021) than CMIP6 (0.0107, derived from the historical 1850–2014 mean). Using a reduced-complexity climate model, we simulate a global mean surface temperature that is 0.07 °C colder for 1850–1900 when using the CMIP7 dataset instead of CMIP6, whereas 2000–2014 is 0.03 °C warmer in CMIP7. Our dataset also exhibits lower forcing for 1960–1980, resulting in temperatures 0.06 °C warmer when averaged over 1960–1990, a period for which CMIP6 climate models exhibit a cold bias. Given the large uncertainties characterizing the dataset, in particular for the pre-satellite era, we advise against treating the CMIP7 or CMIP6 dataset as uniquely superior for any specific year and highlight the need for further evaluation. We conclude the study by discussing sources of uncertainty for the dataset, future research avenues to improve it, as well as requirements to operationalize the production of the dataset, i.e. extend it and update it on an annual basis instead of every 5–7 years following CMIP cycles.

Aubry, Thomas J. [Univ. of Exeter, Devon (United K↗

Quantum Gravity and Laser Interferometry: Towards Observable Predictions

Understanding quantum gravity remains one of the deepest challenges in modern physics, as direct experimental access to Planck-scale effects is beyond current technological reach. However, recent theoretical advances indicate that quantum fluctuations of spacetime may produce measurable effects in precision experiments, particularly near causal horizons. This opens new avenues for testing quantum gravity phenomena through high-precision measurement techniques. This dissertation develops multiple theoretical models to characterize these effects and examines their potential observational signatures in future gravitational wave interferometers. We begin by investigating the role of quantum fluctuations in near-horizon geometries through the lens of the AdS/CFT correspondence, which provides a powerful framework for understanding the interplay between quantum field theory and general relativity via holographic principles. By modeling stochastic energy-momentum sources in Rindler-AdS spacetime, we demonstrate that vacuum fluctuations transform the Einstein equations into a Langevin-type stochastic differential equation, leading to potentially observable fluctuations in photon traversal times. Extending this approach to Minkowski spacetime, we establish a correspondence between gravitational shockwaves and fluid dynamics, showing that near-horizon perturbations satisfy an equation analogous to that governing incompressible fluids, thereby reinforcing the membrane paradigm and hydrodynamic analogies in the context of the fluid/gravity duality. Furthermore, we construct the covariant phase space of a spherically symmetric causal diamond in Minkowski spacetime, identifying two fundamental charges that govern its evolution. These results provide a foundation for quantizing causal horizons and understanding their microscopic degrees of freedom. Building upon these theoretical developments, we further examine a related stochastic phenomenon: the gravitational wave memory background arising from the cumulative memory steps produced by supermassive black hole mergers. After reviewing the standard stochastic gravitational wave background, gravitational memory effects, and BMS symmetries, we model the stochastic memory background using a Brownian motion framework. We show that while the cumulative memory background initially appears above the sensitivity curve of space-based interferometers like LISA, the realistic subtraction of individually resolvable merger events substantially suppresses the residual signal, making its detection more challenging. This highlights the critical importance of source subtraction when evaluating the detectability of gravitational memory effects. By bridging fundamental theory with experimental prospects, this dissertation contributes to the ongoing effort to uncover the quantum nature of spacetime through precision measurement techniques. Whether through detecting quantum spacetime fluctuations, gravitational memory backgrounds, or probing the symmetries of causal horizons, the pursuit of observable quantum gravity phenomena continues to expand the frontiers of both theory and experiment.

Zhang, Yiwen [Caltech] (ORCID:0000000323559416)↗

Reliable Power for Remote Applications

Optical power beaming - using lasers to transmit energy across distances - could change how remote devices receive power. The National Laboratory of the Rockies (NLR) seeks partners to explore the next stage in long-distance power beaming for terrestrial and space-based applications.

14 SOLAR ENERGY↗

Comparisons of the v11.1 Orbiting Carbon Observatory‐2 (OCO‐2) X CO2 Measurements With GGG2020 TCCON

The Orbiting Carbon Observatory 2 (OCO-2) is NASA's first Earth observation satellite mission dedicated to studying the sources and sinks of carbon dioxide (CO 2 ) on a global scale. The observations of reflected sunlight are inverted in a retrieval algorithm to produce estimates of the dry air mole-fractions of CO 2 (X CO2 ). The OCO-2 Level 2 data release, version 11.1 (v11.1) retrievals from the Atmospheric Carbon Observations from Space (ACOS) algorithm, includes significant improvements in the X CO2 data product compared to older OCO-2 data versions. This work compares the v11.1 X CO2 from OCO-2 against X CO2 estimates collected from a global ground-based network known as the Total Carbon Column Observing Network (TCCON), OCO-2's primary validation source. The OCO-2 project provides a version of the Level 2 data product, called “lite” files that include calibrated and bias-corrected XCO2 values, accessible together with all OCO-2 data products through the NASA Goddard Earth Sciences Data and Information Services Center (GES DISC). This work shows that OCO-2 X CO2 observations made between September 2014 and December 2023, after quality filtering and the application of an averaging kernel correction, agree well with coincident TCCON data for all OCO-2 observational modes of land (nadir, glint, target) and ocean (glint). The aggregated, bias-corrected, and quality-filtered absolute average bias values are less than or equal to 0.20 parts per million (ppm) globally for all OCO-2 observation modes, where the biases do not indicate a statistically significant time dependence. The land nadir/glint mode has the lowest bias value of −0.03 ± 0.85 ppm.

54 ENVIRONMENTAL SCIENCES↗