SEARCH · Engineering Papers

Results for “single entity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

All sources NASA NTRS DOE OSTI

DOE OSTI2020

Identifying Dense NiSe 2 /CoSe 2 Heterointerfaces Coupled with Surface High-Valence Bimetallic Sites for Synergistically Enhanced Oxygen Electrocatalysis

Constructing heterostructures with abundant interfaces is essential for integrating the multiple functionalities in single entities. Herein, the synthesis of NiSe 2 /CoSe 2 heterostructures with different interfacial densities via an innovative strategy of successive ion injection is reported. The resulting hybrid electrocatalyst with dense heterointerfaces exhibits superior electrocatalytic properties in an alkaline electrolyte, superior to other benchmarks and precious metal catalysts. Advanced synchrotron techniques, post structural characterizations, and density functional theory (DFT) simulations reveal that the introduction of atomic-level interfaces can lower the oxidation overpotential of bimetallic Ni and Co active sites (whereas Ni$^{2+}$ can be more easily activated than Co$^{2+}$) and induce the electronic interaction between the core selenides and surface in situ generated oxides/hydroxides, which play a critical role in synergistically reducing energetic barriers and accelerating reaction kinetics for catalyzing the oxygen evolution. Hence, the heterointerface structure facilitates the catalytic performance enhancement via increasing the intrinsic reactivity of metallic atoms and enhancing the synergistic effect between the inner selenides and surface oxidation species. This work not only complements the understanding on the origins of the activity of electrocatalysts based on metal selenides, but also sheds light on further surface and interfacial engineering of advanced hybrid materials.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Grain incompatibility determines the local structure of amorphous grain boundary complexions

Amorphous grain boundary complexions lack long-range crystalline order but are not featureless, as distinct gradients in structural short-range order have been reported through their thickness. In this work, we test the hypothesis that the distribution of short-range order is determined by the confining crystals using atomistic simulations of both Cu-Zr bicrystals and a random polycrystal. Voronoi polyhedra with structures similar to that of perfect face-centered cubic serve as signatures of high structural order and are only found at the amorphous-crystalline transition regions. The density of the ordered structural motifs within a specific amorphous-crystalline transition region is found to not be directly determined by the orientation and symmetry of the grain which touches it, but rather by the incompatibility between the two confining grains. Further, ordered polyhedra density is found to be inversely related to grain incompatibility, meaning that large incompatibilities between the confining crystals lead to less order in the amorphous-crystalline transition region. The finding that the entire grain-film-grain system must be considered to understand local structure unequivocally demonstrates that amorphous complexions are not simply a collection of independent phases which happen to nucleate at a grain boundary. Rather, an amorphous grain boundary complexion is a single entity that finds a local equilibrium configuration.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Modeling distributed energy resource aggregations in security constrained unit commitment and economic dispatch

The Federal Energy Regulatory Commission (FERC) recently issued Order 2222, which requires all wholesale electricity markets in the US to allow distributed energy resources (DERs) to participate in the market as aggregated resources. These DER aggregations may be composed of many individual resources that are offered and dispatched by the market as a single entity. We present here a model of a distributed energy resource aggregator (DERA) that is scheduled by a market operator’s security constrained unit commitment (SCUC) and security constrained economic dispatch (SCED). The DERA model includes constraints for battery energy storage systems (BESSs), demand response resources (DRRs), and a simple distributed energy resource (DER). This paper describes a model for each resource type and presents two methods for the DERA to generate market offer curves: a profit-maximizing optimization to compute cost curves and a direct cost algorithm to determine dispatch costs for each resource and combine into cost curves. Once all participating DERAs are scheduled in SCUC/SCED, the model is then modified to dispatch individual DERs to maximize profit or minimize schedule deviation of the DERAs. A simulation of a representative day illustrates the DERA offers, the scheduled generation, and the DERA dispatch. Findings show the potential for unavoidable schedule deviations due to internal DER constraints and due to economic incentives to deviate from the SCUC/SCED schedules. This highlights the importance of DERA offer construction on market efficiency and system reliability. Novel aspects of our approach include: (1) We consider the asymmetry of price incentives impacting DERAs from the wholesale market compared to those impacting consumers from the retail market, as imposed by current regulations and laws. (2) We model aggregate consumer response through statistically parameterizable utility functions rather than a potentially impractical approach of modeling each individual consumer. (3) We show how to use the DERA operational dispatch model to create offers into the wholesale electricity market. (4) We show how DERAs may fail to meet their scheduled dispatch because the market offer format may not permit them to fully express their operational features such as intertemporal costs and constraints to the market.

aggregations↗

DOE OSTI2021

Electrochemical and spectroelectrochemical characterization of bacteria and bacterial systems

Microbes, such as bacteria, can be described, at one level, as small, self-sustaining chemical factories. Based on the species, strain, and even the environment, bacteria can be useful, neutral or pathogenic to human life, so it is increasingly important that we be able to characterize them at the molecular level with chemical specificity and spatial and temporal resolution in order to understand their behavior. Bacterial metabolism involves a large number of internal and external electron transfer processes, so it is logical that electrochemical techniques have been employed to investigate these bacterial metabolites. In this mini-review, we focus on electrochemical and spectroelectrochemical methods that have been developed and used specifically to chemically characterize bacteria and their behavior. First, we discuss the latest mechanistic insights and current understanding of microbial electron transfer, including both direct and mediated electron transfer. Second, we summarize progress on approaches to spatiotemporal characterization of secreted factors, including both metabolites and signaling molecules, which can be used to discern how natural or external factors can alter metabolic states of bacterial cells and change either their individual or collective behavior. Finally, we address in situ methods of single-cell characterization, which can uncover how heterogeneity in cell behavior is reflected in the behavior and properties of collections of bacteria, e.g. bacterial communities. Recent advances in (spectro)electrochemical characterization of bacteria have yielded important new insights both at the ensemble and the single-entity levels, which are furthering our understanding of bacterial behavior. Furthermore, these insights, in turn, promise to benefit applications ranging from biosensors to the use of bacteria in bacteria-based bioenergy generation and storage.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Quantifying selective solvent transport under an electric field in mixed-solvent electrolytes

Electrolytes in lithium-ion batteries comprise solvent mixtures, but analysis of ion transport is always based on treating the solvents as a single-entity. We combine electrophoretic NMR (eNMR) measurements and molecular dynamics (MD) simulations to quantify electric-field-induced transport in a concentrated solution containing LiPF 6 salt dissolved in an ethylene carbonate/ethyl methyl carbonate (EC/EMC) mixture. The selective transport of EC relative to EMC is reflected in the difference between two transference numbers, defined as the fraction of current carried by cations relative to the velocity of each solvent species. This difference arises from the preferential solvation of cations by EC and its dynamic consequences. The simulations reveal the presence of a large variety of transient solvent-containing clusters which migrate at different velocities. Rigorous averaging over different solvation environments is essential for comparing simulated and measured transference numbers. Our study emphasizes the necessity of acknowledging the presence of four species in mixed-solvent electrolytes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2020

Commissioning plan for LCLS II 2 K cold box

Commissioning of the LCLS II cryogenic plant has been planned with respect to electrical and mechanical systems checkout, equipment cleanup, cool-down, and individual performance evaluation. This plant consists of warm and cold storage, helium compressors, 4.5 K and 2 K cold boxes, and all auxiliaries typical for helium refrigeration processes. The 2 K cold box, consisting of five cold compressors in series to produce the flow and pressures necessary for 2K operation, will be the last equipment installed and, along with an additional 10,000 L helium dewar, will allow the entire plant to be commissioned as a single entity. The pre-commissioning stages, commissioning plan for 2 K cold box without connecting to the LCLS II LINAC, additional test equipment needed to simulate the loads, all process studies and associated results are described herein.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Networked Microgrid Ownership, Data, and Control Implications: Challenges and Open Questions

Microgrid deployments increasingly favor the potential to form networks for greater benefits to resilience, reliability, and energy sovereignty. Both independent and networked micro-grids predominantly have a single-entity-ownership and control, where the associations from ownership to data requirements to control functions to microgrid objectives is linear. The emerging model, however, is cyclical, with bidirectional causal impacts between each of the 4 pillars: there are more complex mixed ownership models across the physical, electrical, data, communications, protection, and control boundaries that impact the data requirements for meeting control functions that help realize the use-cases or objectives. This paper is the first to delineate the pillars for effective ownership and controllability of both independent as well as networked microgrids through the cyclical model, and present barriers to the adoption of such a model.

Sundararajan, Aditya↗

DOE OSTI2020

Evaluation of Hybrid FPOG Applications in Regulated and Deregulated Markets Using HERON

Recent changes in the U.S. energy market, such as low natural gas prices and increased electricity production for variable renewable energy (VRE) sources, have led to an economic crisis for existing light-water reactor (LWR) nuclear power plants (NPP). Many owners and operators of LWRs have elected to decommission these plants rather than continue using them as consistent sources of clean baseload power. This has led to exploration of various possibilities to increase the economic viability of these units, including market restructuring to monetize benefits LWRs already provide to the grid through ancillary markets, load following and economic dispatch, and possible integration of secondary systems directly to the NPP for production of additional products through technologies such as hydrogen electrolysis or water desalination. Previous studies have considered the technologies associated with these Integrated Energy Systems (IES) activities, and the analysis of markets for these secondary products. To analyze the economic viability of various system configurations including IES, especially given the uncertainty surrounding load demand, electricity prices, and the availability of VRE resources, the stochastic technoeconomic analysis package HERON (Heuristic Energy Resource Optimization Network) was released earlier this year as an extension of the risk analysis framework RAVEN (Risk Analysis Virtual Environment). HERON focuses foremost on making the complex uncertainty quantification analysis tools approachable for energy systems analysts, also providing general dispatch optimization algorithms for those workflows. HERON continues to be improved and tested as a significant part of the IES viability analyses performed in this work. HERON is not a capacity expansion model. To consider market and grid energy system development in a variety of scenarios, HERON is best used in coupling with modelling tools such as US-REGEN, which sacrifice some of the uncertainty analysis and resolution of HERON's modelling for the ability to efficiently predict the change in the grid energy system's profile due to economic drivers over decades. HERON can then use this information to explore the economic viability of introducing changes to the predicted outcomes, such as the introduction of an IES. In this work, experts at EPRI using US-REGEN provide six projection scenarios for use in HERON stochastic technoeconomic analysis (STEA) in considering the options available for increasing LWR economic viability through introduction of a hydrogen-centric IES using a high-temperature steam electrolysis plant (HTSE), hydrogen storage, and a constant-rate contracted hydrogen consumer. The results obtained are differential in nature; they do not report expected profits for any configuration, but rather report on the possible increase in the NPV of a configuration with respect to a baseline no-IES configuration. Due to the uncertainty captured in the variable net load of the systems, there is likewise uncertainty in the mean values reported. We consider this viability both in terms of a regulated market, where the energy producers and IES are owned and operated by single entity, as well as a deregulated market, where the IES chooses its bid for electricity generation and is then dispatched by the grid system operator. Results indicate that for deregulated markets, the inclusion of the IES is often statistically beneficial. This is especially true in policies that are not favorable towards nuclear, as nuclear is less often dispatched and is forced to deal with frequent idle capacity. In the nominal case as well as the case of carbon tax policies, inclusion of the IES clearly benefited the economic performance of the NPP. In the regulated case, however, there was a trend towards minimizing the IES, likely due to the optimal sizing performed by US-REGEN of the NPP within the system as well as the lack of penalty for idle capacity at the NPP in the regulated market analyses.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2023

Virtual Power Plants and Energy Justice

The Federal Energy Regulatory Commission's (FERC) Order 2222, issued in September 2020, removes barriers for distributed energy resources (DERs) to participate in wholesale energy markets by allowing DERs to aggregate and participate in wholesale markets as a single entity, known as a virtual power plant (VPP). VPPs can provide balancing, reliability, and resiliency grid services and can participate in capacity, energy and ancillary services markets. They can also increase customer energy access and lower electricity bills. This report focuses on VPP business models, including considerations of energy justice (EJ). Through an analysis of the VPP value chain, business models, programs, and pilots, several VPP applications are identified and grouped by their ability to have quantitatively measurable or monetized benefits. Benefits and barriers specific to underserved communities are outlined, and VPP programs with an intentional focus on underserved communities are compared to those without such a focus.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2023

A New Paradigm for Observing and Modeling of Air-Sea Interactions to Advance Earth System Prediction

The protection of people, property, and environmental resources from extreme weather, seasonal patterns, and climate change drives the need for predictions of weather, ocean, and climate patterns that have skill and value at timescales longer than traditional 1-10-day forecasts, including outlooks spanning weeks to decades. Advancing Earth System Prediction (ESP) skill at this range of timescales requires improved observations, understanding, and modeling of the processes in the ocean boundary layer, the atmospheric boundary layer, and their interface. A new way of referring to this coupled system is the Air-Sea Transition Zone (ASTZ). The report that follows is framed by the paradigm that the ASTZ is a single entity that regulates the flow of energy and matter between the ocean and the atmosphere. The ASTZ is thus the medium through which the ocean and atmosphere respond to and influence one another across their often disparate scales of variability. ASTZ modeling, observing, and understanding needs are particularly acute because very few measurements exist over oceans, and even fewer span the entire ASTZ, even though oceans cover 70% of Earth’s surface and are the source of most of the rain and snow that falls on both the land and the oceans.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

SCALE 6.3 Validation: Nuclear Criticality Safety

The KENO codes have been used extensively around the world since their initial development in the 1960s. Therefore, a large number and wide range of validation reports have been generated for KENO by a variety of organizations. This section provides a synopsis of recent validation reports generated at ORNL, along with a brief list of some older validation reports generated in Oak Ridge, Tennessee. Some of the oldest reports are not attributed directly to ORNL, as the Y-12 Plant (currently the Y-12 National Security Complex), the K-25 Gaseous Diffusion Plant (now the East Tennessee Technology Park), and the X-10 Site (ORNL) were operated as a single entity.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2026

Drone Fleet Summary: NNLEMS UxS Rolodex entry for Sandia

Sandia’s UAS Aviation Operations Unit (UAOU) was established in 2019 to be the single entity at Sandia conducting UAS Ops in support the labs Uncrewed Aircraft Systems (UAS) activities. The UAOU currently consists of >330 FAA Registered UAS with a large variety of primarily Class 1&2 UAS: fixed wing (>90), multi-rotor (>230), hybrids, VTOLs, jets, and balloons. Many of these are threat vehicles presented as targets to Counter-UAS (CUAS) systems as part of performance tests, with the remainder in support of other projects across Sandia often with custom payload needs. The UAOU has ~15 primary pilots and reach back to another ~45 FAA Certified Remote Pilots across Sandia. The team conducts flight and CUAS operations at many test locations, including OCONUS. Sandia was awarded the 2024 DOE Federal Aviation Safety Program Award.

42 ENGINEERING↗

NASA NTRS1974

Critical problems in establishing the morphology of substorms in space

A phenomenological model of the magnetospheric substorm has been developed which divides the substorm into three phases: a growth phase, an expansion phase, and a recovery phase. Current research is reviewed in the light of criticism of this model. The most important inadequacies of the model concern the fact that the tail lobe and the plasma sheet do not always react as single entities as previously supposed. Further research is needed on the problems of substorm variability, errors in onset time, the number of distinct spatial regions, and the dependence of magnetic activity on past history.

Mcpherron, R. L.↗

NASA NTRS1988

A new look at coding for APD-based direct-detection optical channels

Coding for avalanche-photodiode (APD)-based direct-detection optical channels is investigated using a simple channel model that clearly points out the difference between the signal-dependent optical noise channel model and the additive white Gaussian noise channel model. Coding and modulation are viewed as a single entity, and the coding/modulation gain (CMG) is used to analyze and construct good codes for APD-based optical receivers. It is shown that the structure of block codes, when used in conjunction with on-off keying signaling, renders these codes fairly inefficient with respect to obtaining reasonable CMG on the optical channel. In contrast, codes (or modulations) that use fewer channel ones (pulses) than information ones per block can offer substantial CMG on the optical channel. For bandwidth-constrained applications, it is proposed that pulse-position modulation be used with more than one pulse per word to obtain reasonable CMG while consuming small amounts of bandwidth.

Herro, Mark A.↗

NASA NTRS1989

Polar wander of an ice shell on Europa

The present consideration of a hypothesized ice shell around Europa, which is decoupled from the silicate core by a liquid water layer and possesses a spatially varying thermal equilibrium thickness profile, proceeds through the development of equations for variations in the inertia tensor of a body when second-harmonic-degree topography is added to the crustal base. Attention is given to a realistic model in which the shell and ocean are assumed to undergo reorientations as a single entity independently of the core, but subject to viscous dissipation within the shell. Shell friction is in this case noted to preclude polar wander, unless a low conductivity regolith increases the near-surface temperature by a few tens of degrees C; the ice beneath the regolith would then behave viscously on the time-scale of polar wander.

Ojakangas, Gregory W.↗

NASA NTRS1991

The business case for connectivity

Information systems that provide competitive advantages to organizations can be broadly classified into those that improve the effectiveness of a business function and those that improve the reach of information in the organization. The latter, organizational connectivity systems, can be categorized as intraorganizational and interorganizational systems. Intraorganization systems provide connectivity to function areas within the business, while interorganizational systems support the exchange of business data between independent business units. These system are not confined to a single entity but span organizational boundaries which can be national or international in scope. A series of case studies was undertaken in an effort to better understand the issues and problems associated with providing an increased flow of information within and outside of an organization. Ten issues emerged from this study. In summary, it is necessary for firms to first consider how effective their internal communications systems are before launching projects that tie the organization to external systems.

Adams, Dennis↗

NASA NTRS1992

Autonomous power system: Integrated scheduling

The Autonomous Power System (APS) project at NASA Lewis Research Center is designed to demonstrate the abilities of integrated intelligent diagnosis, control and scheduling techniques to space power distribution hardware. The project consists of three elements: the Autonomous Power Expert System (APEX) for fault diagnosis, isolation, and recovery (FDIR), the Autonomous Intelligent Power Scheduler (AIPS) to determine system configuration, and power hardware (Brassboard) to simulate a space-based power system. Faults can be introduced into the Brassboard and in turn, be diagnosed and corrected by APEX and AIPS. The Autonomous Intelligent Power Scheduler controls the execution of loads attached to the Brassboard. Each load must be executed in a manner that efficiently utilizes available power and satisfies all load, resource, and temporal constraints. In the case of a fault situation on the Brassboard, AIPS dynamically modifies the existing schedule in order to resume efficient operation conditions. A database is kept of the power demand, temporal modifiers, priority of each load, and the power level of each source. AIPS uses a set of heuristic rules to assign start times and resources to each load based on load and resource constraints. A simple improvement engine based upon these heuristics is also available to improve the schedule efficiency. This paper describes the operation of the Autonomous Intelligent Power Scheduler as a single entity, as well as its integration with APEX and the Brassboard. Future plans are discussed for the growth of the Autonomous Intelligent Power Scheduler.

Ringer, Mark J.↗

NASA NTRS1992

A spatial, kinematical, and dynamical analysis of Abell 400

The paper presents a detailed spatial, kinematical, and dynamical analysis for the cluster A400, based on a nearly complete redshift survey of bright galaxies within 1 Mpc of the cluster center. A dispersed component with a high fraction of spiral galaxies at a velocity of 8200 km/s, and a background group with a mean velocity of 13,400 km/s are identified. It is proposed that the main body of A400 is composed of at least two individual subclusters. If subclustering is ignored, the derived dispersion of the 88 galaxies with measured velocities within 4000 km/s of the bright dumbbell galaxy near the cluster center is 702 km/s. When kinematic information is used to split A400 into likely subclusters, the velocity dispersions of the individual units which make up this cluster are on the order of 200-300 km/s. If A400 is considered a single entity, the inferred blue mass-to-light ratio is 1210 solar masses/solar luminosities. It is argued that A400 is an example of a presently occurring merger, and that the individual components of the dumbbell galaxy were once individual D galaxies within the premerger subclusters.

Beers, Timothy C.↗