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High temperature kinetic study of the reactions H + O2 = OH + O and O + H2 = OH + H in H2/O2 system by shock tube-laser absorption spectroscopy

The reactions: (1) H + O2 = OH + O; and (2) O + H2 = OH + H are the most important elementary reactions in gas phase combustion. They are the main chain-branching reaction in the oxidation of H2 and hydrocarbon fuels. In this study, rate coefficients of the reactions and have been measured over a wide range of composition, pressure, density and temperature behind the reflected shock waves. The experiments were performed using the shock tube - laser absorption spectroscopic technique to monitor OH radicals formed in the shock-heated H2/O2/Ar mixtures. The OH radicals were detected using the P(1)(5) line of (0,0) band of the A(exp 2) Sigma(+) from X(exp 2) Pi transition of OH at 310.023 nm (air). The data were analyzed with the aid of computer modeling. In the experiments great care was exercised to obtain high time resolution, linearity and signal-to-noise. The results are well represented by the Arrhenius expressions. The rate coefficient expression for reaction (1) obtained in this study is k(1) = (7.13 +/- 0.31) x 10(exp 13) exp(-6957+/- 30 K/T) cu cm/mol/s (1050 K less than or equal to T less than or equal to 2500 K) and a consensus expression for k(1) from a critical review of the most recent evaluations of k(1) (including our own) is k(1) = 7.82 x 10(exp 13) exp(-7105 K/T) cu cm/mol/s (960 K less than or equal to T less than or equal to 5300 K). The rate coefficient expression of k(2) is given by k(2) = (1.88 +/- 0.07) x 10(exp 14) exp(-6897 +/- 53 K/T) cu cm/mol/s (1424 K less than or equal to T less than or equal to 2427 K). For k(1), the temperature dependent A-factor and the correlation between the values of k(1) and the inverse reactant densities were not found. In the temperature range of this study, non-Arrhenius expression of k(2) which shows the upward curvature was not supported.

Ryu, Si-Ok

Some Effects of Tunnel Noise on Cylinder-Induced Mach 6 Transitional Shock Wave Boundary Layer Interactions

Experiments were conducted on a cylinder-induced shock wave boundary layer interaction (SBLI)as its state was brought through transition using a combination of boundary layer trips and Reynolds number sweep. A baseline case with no trips was also examined. The measurements were made in a Mach 6 freestream in the well-characterized Actively Controlled Expansion tunnel, which demonstrated a near tripling in fluctuation levels with unit Reynolds number increase from 3.0 to 3.5 million per meter. Surface oil flow and schlieren images suggested the jump in freestream noise served as the impetus for SBLI transition since the flow separation distance began to decrease as the Reynolds number progressed through those conditions. Likewise, surface mounted Kulite® pressure transducers indicated a rise in surface pressure fluctuations as well as initial growth in the instability responsible for transitioning the boundary layer within the interaction. Finally, heat transfer rates within the tripped SBLI were shown to be affected by the jump in freestream disturbance levels.

Andrew N Leidy

Summary of Shock Wave Turbulent Boundary Layer Interaction Experiments In a Circular Test Section

A series of experiments were performed at Mach 2.5 in a 17 cm diameter circular test section to characterize an impinging/reflected shock wave turbulent boundary layer interaction generated by a cone-cylinder centerbody. The cone-cylinder centerbody generates a conical shock wave that interacts with the naturally occurring boundary layer developing on the test section wall. Three different cone angles were used in the experiment to study unseparated, incipiently separated, and separated interactions. When the cone-cylinder centerbody is positioned on the centerline, a flowfield which is two-dimensional in the mean is generated. Three dimensional interactions were also created by offsetting the cone-cylinder centerbody from the test section centerline. The results are intended to provide benchmark quality datasets for computational fluid dynamics (CFD) validation without the pitfalls inherent in rectangular configurations where corner effects prohibit a truly two-dimensional flow in the mean. The experimental measurements included surface flow visualization, wall static pressure, flowfield Pitot tube pressure, constant-voltage anemometry (CVA) normal hot-wire, and particle image velocimetry (PIV) measurements. The hot-wire measurements were used to calculate mean mass flux and total temperature profiles, mass flux and total temperature turbulence intensities, and the mass flux-total temperature correlation. The PIV measurements provide three-dimensional mean velocity measurements. Agreement between the pressure, hot-wire, and PIV measurements is established in the undisturbed upstream flowfield.

Supersonic

Summary of Shock Wave Turbulent Boundary Layer Interaction Experiments in a Circular Test Section

A series of experiments were performed at Mach 2.5 in a 17 cm diameter circular test section to characterize an impinging/reflected shock wave turbulent boundary layer interaction generated by a cone-cylinder centerbody. The cone-cylinder centerbody generates a conical shock wave that interacts with the naturally occurring boundary layer developing on the test section wall. Three different cone angles were used in the experiment to study unseparated, incipiently separated, and separated interactions. When the cone-cylinder centerbody is positioned on the centerline, a flowfield which is two-dimensional in the mean is generated. Three dimensional interactions were also created by offsetting the cone-cylinder centerbody from the test section centerline. The results are intended to provide benchmark quality datasets for computational fluid dynamics (CFD) validation without the pitfalls inherent in rectangular configurations where corner effects prohibit a truly two-dimensional flow in the mean. The experimental measurements included surface flow visualization, wall static pressure, flowfield Pitot tube pressure, constant-voltage anemometry (CVA) normal hot-wire, and particle image velocimetry (PIV) measurements. The hot-wire measurements were used to calculate mean mass flux and total temperature profiles, mass flux and total temperature turbulence intensities, and the mass flux-total temperature correlation. The PIV measurements provide three-dimensional mean velocity measurements. Agreement between the pressure, hot-wire, and PIV measurements is established in the undisturbed upstream flowfield.

compressible flow

Plasma wave phenomena observed at interplanetary shocks by the Ulysses URAP experiment

Results of a study of 24 interplanetary shocks observed by the Unified Radio and Plasma Wave Experiment (URAP) on the Ulysses spacecraft are presented. These shocks, observed between approximately 1 and 4 AU, display a variety of wave phenomena similar to those detected in earlier studies of shocks near 1 AU. The correspondence of the observed low frequency magnetic and electric field waves with the parallel index of refraction for whistler waves was investigated. Observed B/E ratios are found to be typically about a factor of 0.7 times the computed index of refraction, supporting the whistler interpretation of these waves, but also implying a prevalent electrostatic wave component which may be due to whistlers propagating at an angle to the interplanetary magnetic field. A statistical correlation of the amplitudes of the various types of waves with shock and solar wind properties is presented.

Lengyel-Frey, D.

Kinetics of nitric oxide formation and decomposition

Experiments on shock wave structure were conducted in the 12 inch shock tube facility, and it is shown that this work was motivated by the need for improved kinetics for the modeling of NO production in space shuttle flow fields. The experiments on shock structure involved simultaneous observations of pressure and temperature on the wall of the shock tube during reflection of normal shock waves in inert gases.

Kruger, C. H.

Convective response of a wall-mounted hot-film sensor in a shock tube

Shock tube experiments were performed in order to determine the response of a single hot-film element of a sensor array to transiently induced flow behind weak normal shock waves. The experiments attempt to isolate the response due only to the change in convective heat transfer at the hot-film surface mounted on the wall of the shock tube. The experiments are described, the results being correlated with transient boundary layer theory and compared with an independent set of experimental results. One of the findings indicates that the change in the air properties (temperature and pressure) precedes the air mass transport, causing an ambiguity in the sensor response to the development of the velocity boundary layer. Also, a transient, local heat transfer coefficient is formulated to be used as a forcing function in an hot-film instrument model and simulation which remains under investigation.

Roberts, A. Sidney, Jr.

Convective response of a wall-mounted hot-film sensor in a shock tube

Shock tube experiments were performed in order to determine the response of a single hot-film element of a sensor array to transiently induced flow behind weak normal shock waves. The experiments attempt to isolate the response due only to the change in convective heat transfer at the hot-film surface mounted on the wall of the shock tube. The experiments are described, the results being correlated with transient boundary layer theory and compared with an independent set of experimental results. One of the findings indicates that the change in the air properties (temperature and pressure) precedes the air mass transport, causing an ambiguity in the sensor response to the development of the velocity boundary layer. Also, a transient, local heat transfer coefficient is formulated to be used as a forcing function in a hot-film instrument model and simulation which remains under investigation.

Roberts, A. S., Jr.

Plasma wave phenomena at interplanetary shocks observed by the Ulysses URAP experiment

We present Ulysses URAP observations of plasma waves at seven interplanetary shocks detected between approximately 1 and 3 AU. The URAP data allows ready correlation of wave phenomena from .1 Hz to 1 MHz. Wave phenomena observed in the shock vicinity include abrupt changes in the quasi-thermal noise continuum, Langmuir wave activity, ion acoustic noise, whistler waves and low frequency electrostatic waves. We focus on the forward/reverse shock pair of May 27, 1991 to demonstrate the characteristics of the URAP data.

Lengyel-Frey, D.

Shock Compression of Liquid Helium to 56 GPa (560) Kbar

Shock-wave data are presented for liquid helium which has been compressed to densities up to five times greater than the normal liquid. The helium was heated to temperatures up to 21,000 K, while the maximum pressure attained was 56 GPa. The properties of helium and hydrogen are important for modeling the giant planets Saturn and Jupiter where these elements are the major constituents. Conditions on Saturn are of particular interest because studies have suggested that this planet has an internal energy source which is associated with unmixing and gravitational separation the hydrogen-helium fluid at pressures below 1 TPa. The existence of this phase transition depends very sensitively on the hydrogen and helium equation of state. In the experiments, strong shock waves were generated by the impact of planar projectiles into cryogenic specimen holders.

Nellis, W. J.

Shock compression of liquid helium to 56 GPa (560 kbar)

Shock-wave data are presented for liquid helium which has been compressed to densities up to five times greater than the normal liquid. The helium was heated to temperatures up to 21,000 K, while the maximum pressure attained was 56 GPa. The properties of helium and hydrogen are important for modeling the giant planets Saturn and Jupiter where these elements are the major constituents. Conditions on Saturn are of particular interest because studies have suggested that this planet has an internal energy source which is associated with unmixing and gravitational separation of the hydrogen-helium fluid at pressures below 1 TPa. The existence of this phase transition depends very sensitively on the hydrogen and helium equation of state. In the experiments, strong shock waves were generated by the impact of planar projectiles into cryogenic specimen holders.

Nellis, W. J.

Producing Refractory Microballoons

Metals, ceramics, and glasses just some of possible raw materials. Key components of equipment for new microballoon fabrication process nozzle, crucible assembly, and drop tube. Recessed, conical inner orifice aids in producing uniform, symmetrical microballoons. All-graphite crucible assembly resistant to misalinement and cracks. Drop tube ensures timely solidification of microballoons used in fluidized-bed heat exchangers; as containers for hazardous materials; catalysts in chemical and pharmaceutical processes; solid fuel for rockets; fuel containers for fusion power experiments; shock-wave dampers; and starting materials for high-strength, low-density sintered alloys and ceramics.

Lee, M. C.

High-pressure phase transition and equation of state of CsI

Stuructural properties of CsI at high pressure have been investigated by the use of synchrotron X-ray-diffraction techniques with the diamond-anvil cell at 300 K. The results indicate that the material undergoes a continuous distortion from B2 to an hcp-like phase, which is stable to at least 302 GPa. The intermediate orthorhombic phase is geometrically different from previous assignments and about 10 percent denser. With the new structure, the p-V results of static pressure experiments, shock-wave studies, and theoretical calculations are now in good agreement.

Mao, H. K.

Thermal expansivity, bulk modulus, and melting curve of H2O-ice VII to 20 GPa

Equation of state properties of ice VII and fluid H2O at high pressures and temperatures have been studied experimentally from 6 to 20 GPa and 300-700 K. The techniques involve direct measurements of the unit-cell volume of the solid using synchrotron X-ray diffraction with an externally heated diamond-anvil cell. The pressure dependencies of the volume and bulk modulus of ice VII at room temperature are in good agreement with previous synchrotron X-ray studies. The thermal expansivity was determined as a function of pressure and the results fit to a newly proposed phenomenological relation and to a Mie-Gruneisen equation of state formalism. The onset of melting of ice VII was determined directly by X-ray diffraction at a series of pressures and found to be in accord with previous volumetric determinations. Thermodynamic calculations based on the new data are performed to evaluate the range of validity of previously proposed equations of state for fluid water derived from static and shock-wave compression experiments and from simulations.

Fei, Yingwei

Hypersonic shock-wave turbulent-boundary-layer interaction flows - Experiment and computation

Solutions of the Reynolds-averaged Navier-Stokes equations are presented and compared with experimental surface data for a series of hypersonic shock-wave/turbulent-boundary-layer interaction flows. The turbulence models used include the standard k-epsilon two-equation eddy viscosity model, a two-layer modification to this model, and a third model with several modifications to account for compressibility effects. Both modified models gave significant improvements for all the test flows.

Horstman, C. C.

Stratospheric-related research using the shock tube

The capabilities of shock tubes used in stratospheric-related research are considered, and the results of three independent shock tube research projects are reported. The studies are concerned with the evaluation of stratospheric ozone depletion. In the first experiment, photoabsorption cross sections of Freon 11 and 12 at stratospheric temperatures were measured using rarefaction waves. In the second experiment, reaction-rate coefficients were determined from measurements made behind reflected shock waves. In the third experiment, electronic-transition moments of the O2 Schumann-Runge system and the A2Pi-X2Pi system of ClO were deduced from intensity measurements made behind the incident shock.

Cooper, D. M.