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All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

The NOL Gap Test: Past, present, and future

A brief history of the development of the gap test is presented with emphasis on accumulated knowledge of how best to use it as a tool to assess relative shock sensitivity of explosives and propellants. Present information about the detonation process in build-up, steady state, and failure is used to show that failure diameter cannot give the desired shock sensitivity assessment. Suggestions are made for improving the test to an experiment. The use of spherical donors, water as attenuator, and camera instrumentation are briefly discussed.

Jacobs, S. J.↗
DOE OSTI2012

Summary of Booster Development and Qualification Report

This report outlines booster development work done at Los Alamos National Laboratory from 2007 to present. The booster is a critical link in the initiation train of explosive assemblies, from complex devices like nuclear weapons to conventional munitions. The booster bridges the gap from a small, relatively sensitive detonator to an insensitive, but massive, main charge. The movement throughout the explosives development community is to use more and more insensitive explosive components. With that, more energy is needed out of the booster. It has to initiate reliably, promptly, powerfully and safely. This report is divided into four sections. The first provides a summary of a collaborative effort between LANL, LLNL, and AWE to identify candidate materials and uniformly develop a testing plan for new boosters. Important parameters and the tests required to measure them were defined. The nature of the collaboration and the specific goals of the participating partners has changed over time, but the booster development plan stands on its own merit as a complete description of the test protocol necessary to compare and qualify booster materials, and is discussed in its entirety in this report. The second section describes a project, which began in 2009 with the Department of Defense to develop replacement booster formulations for PBXN-7. Replacement of PBXN-7 was necessary because it contained Triaminotrinitrobenzene (TATB), which was becoming unavailable to the DoD and because it contained Cyclotrimethylenetrinitramine (RDX), which was sensitive and toxic. A LANL-developed explosive, Diaminoazoxyfurazan (DAAF), was an important candidate. This project required any replacement formulation be a drop-in replacement in existing munitions. This project was timely, in that it made use of the collaborative booster development project, and had the additional constraint of matching shock sensitivity. Additionally it needed to be a safety improvement, and a performance improvement, especially at cold temperatures. The requirements of this project necessitated novel test development and a different approach to ranking booster qualities. Results of this project have been documented to the DoD and the relevant portions are included within. The third section of this booster report outlines testing related to main charge initiation merit. Initiability can be evaluated by looking at critical diameter, run distance, and shock sensitivity. Once a booster is initiated, it needs to be powerful enough to initiate the main charge symmetrically and evenly. Main charge initiability is evaluated directly by observing detonation wave symmetry, curvature, and first break out over the surface of a charge. Furthermore it must be insensitive to accidents and insults, and safe and reliable across a range of temperatures. These effects, tests, and results will be discussed individually in the context of DAAF and other explosives similarly tested. The last section provides a conclusion and summary of our experimental work and recommendations for the path forward. References and additional supporting documentation and results are provided in the appendices at the end of this report.

36 MATERIALS SCIENCE↗
DOE OSTI2014

The violence of reaction from a fast projectile fired into heated PBX 9502

The shock sensitivity of hot PBX 9502 is of concern in abnormal combined insult situations. A series of fragment impacts into thin aluminum cased PBX 9502 heated to various temperatures was performed. The explosive was tightly radially confined but effectively unconfined axially. A 15.5 mm diameter by 3 mm thick heavy tungsten fragment (17.5 g/cc) fired at a velocity of approximately 1.4 km s –1 imparted an initial shock pressure of ≈15 GPa into the explosive. Under one dimensional shock conditions, the run to detonation in PBX 9502 at ambient temperature and at this pressure is ≈5 mm, however, given the small dimensions of the fragment in this insult, the pressure is quickly released from the edge so that a dying reaction is created. The situation is very different at higher explosive temperatures when the shock sensitivity of lightly confined PBX 9502 is much greater. Under these specific insult conditions, detonations were not observed at 22 and 70°C, but were observed at 170 and 108°C. The significance of these results is discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2019

TATB Sensitivity to Shocks from Electrical Arcs

Use of insensitive high explosives (IHEs) has significantly improved ammunition safety because of their remarkable insensitivity to violent cook–off, shock and impact. Triamino–trinitrobenzene (TATB) is the IHE used in many modern munitions. Previously, lightning simulations in different test configurations have shown that the required detonation threshold for standard density TATB at ambient and elevated temperatures (250 °C) has a sufficient margin over the shock caused by an arc from the most severe lightning. In this paper, the Braginskii model with Lee–More channel conductivity prescription is used to demonstrate how electrical arcs from lightning could cause detonation in TATB. The steep rise and slow decay in typical lightning pulse are used in demonstrating that the shock pressure from an electrical arc, after reaching the peak, falls off faster than the inverse of the arc radius. For detonation to occur, two necessary detonation conditions must be met: the Pop–Plot criterion and minimum spot size requirement. The relevant Pop–Plot for TATB at 250 °C was converted into an empirical detonation criterion, which is applicable to explosives subject to shocks of variable pressure. The arc cross–section was required to meet the minimum detonation spot size reported in the literature. Furthermore, one caveat is that when the shock pressure exceeds the detonation pressure the Pop–Plot may not be applicable, and the minimum spot size requirement may be smaller.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2012

High Energy-Density Materials with Fast Energy Release: Molecular scale shock response of explosives (DTRA Basic Research Final Report 2012)

The principle goal of this $\$$150K/yr, 3-yr. project was to experimentally measure the time evolution of shock induced chemistry in the explosive RDX. Since direct measurements of shock induced chemistry in RDX, or any other explosive, have eluded researchers for several decades, new techniques had to be developed. Transient absorption was coupled to laser shock loading to probe the possible role of electronic excitations in the chemistry of RDX. Transient absorption signatures turned out to be a good indication of the relative degree of chemical reaction versus time, but were not conclusive regarding whether electronic excitation was an important factor in shock initiation. Preliminary efforts to sensitize shock induced chemistry with ultraviolet pulsed excitation were performed, but are not yet conclusive. The bulk of the effort of the project was directed at development of femtosecond stimulated Raman spectroscopy (FSRS) as a diagnostic of temperature in the presence of chemistry. This effort was significantly more difficult than initially anticipated. While we had planned to apply the method to single shot laser experiments, the sensitivity achieved during the project duration was insufficient to measure the sub-nanogram amounts of material shocked. Despite the difficulties applying this measurement to our current small scale laser shock experiments, it shows significant promise for measurements where there is more volume of material shocked. We have established the theoretical framework and experimentally validated FSRS as a sub-picosecond molecular vibrational temperature measurement diagnostic. We have also followed the shock induced chemistry of RDX through transient absorption spectroscopy and established the shock stresses required to achieve sub-nanosecond reaction rates. The project led to 3 peer reviewed journal articles, 4 conference proceedings, 3 invited talks at conferences, 2 contributed talks at conferences, and a number of other presentations.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Novel PBX formulations containing thermally-expandable microspheres for on-demand control of explosive behavior

In this work, we present the formulation and analysis of inert Plastic-Bonded eXplosive (PBX)-surrogates loaded with thermally expandable microspheres (TEMs). TEMs consist of a thermoplastic acrylonitrile shell (10-50 µm diameter) encapsulating an inert low boiling hydrocarbon. Upon heating, the TEMs expand as the shell softens while the hydrocarbon gasifies, increasing the internal pressure and expanding the particle by as much as 120 vol%. We hypothesize that TEM expansion within a PBX will introduce tunable changes in local density and porosity, and ultimately the shock sensitivity. This paper focuses on microstructural analysis of surrogate PBX-TEM formulations, both before and after thermally- induced TEM expansion. The formulations were analyzed by scanning electron microscopy (SEM), ultra-small angle neutron scattering (USANS), and X-ray Computed Tomography (x-ray CT) under various thermal conditions. Evidence suggests that TEM expansion within a PBX is a viable method to impart microstructural changes that are predicted to have a measurable, on-demand effect on the initiation sensitivity. Future work includes development of PBX-TEM formulations with HMX and shock initiation experiments.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2016

Development of Multi-Physics Dynamics Models for High-Frequency Large-Amplitude Structural Response Simulation

An analytic approach is demonstrated to reveal potential pyroshock-driven dynamic effects causing power losses in the Thermo-Electric (TE) module bars of the Mars Science Laboratory (MSL) Multi-Mission Radioisotope Thermoelectric Generator (MMRTG). This study utilizes high-fidelity finite element analysis with SIERRA/PRESTO codes to estimate wave propagation effects due to large-amplitude suddenly-applied pyro shock loads in the MMRTG. A high fidelity model of the TE module bar was created with approximately 30 million degrees-of-freedom (DOF). First, a quasi-static preload was applied on top of the TE module bar, then transient tri-axial acceleration inputs were simultaneously applied on the preloaded module. The applied input acceleration signals were measured during MMRTG shock qualification tests performed at the Jet Propulsion Laboratory. An explicit finite element solver in the SIERRA/PRESTO computational environment, along with a 3000 processor parallel super -computing framework at NASA AMES, was used for the simulation. The simulation results were investigated both qualitatively and quantitatively. The predicted shock wave propagation results provide detailed structural responses throughout the TE module bar, and key insights into the dynamic response (i.e., loads, displacements, accelerations) of critical internal spring/piston compression systems, TE materials, and internal component interfaces in the MMRTG TE module bar. They also provide confidence on the viability of this high-fidelity modeling scheme to accurately predict shock wave propagation patterns within complex structures. This analytic approach is envisioned for modeling shock sensitive hardware susceptible to intense shock environments positioned near shock separation devices in modern space vehicles and systems.

Shock Waves↗
DOE OSTI2016

Analysis on shock attenuation in gap test configuration for characterizing energetic materials

A pyrotechnic system consisting of donor/acceptor pair separated by a gap relies on shock attenuation characteristics of the gap material and shock sensitivity of the donor and the acceptor charges. Despite of its common use, a numerical study of such a pyrotechnic train configuration is seldom reported because proper modeling of the full process requires precise capturing of the shock wave attenuation in the gap prior to triggering a full detonation of a high explosive and accurate description of the high strain rate dynamics of the explosively loaded inert confinements. We apply a hybrid particle level-set based multimaterial hydrocode with reactive flow models for pentolite donor and heavily aluminized cyclotrimethylene-trinitramine as the acceptor charge. The complex shock interaction, a critical gap thickness, an acoustic impedance, and go/no-go characteristics of the pyrotechnic system are quantitatively investigated.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Effect of PBX prill size on the compressive properties of PBX 9502

Plastic-Bonded Explosive (PBX) prills are agglomerates a few millimeters in diameter composed of High Explosive crystals non-uniformly distributed in and surrounded by a polymer binder. When pressed at elevated temperatures at or above the binder melt temperature the polymer flows to uniformly coat the HE crystals to create a well-consolidated compaction. In reality it does so imperfectly, such that x-ray tomographic scans often look like a collection of prills mashed together. It is speculated that the larger the prill, the more non-uniform the binder distribution, but this has never been proven. Even if that were not so, the larger the prill the farther binder must flow toward the middle to homogenize during pressing. Thus, the degree of homogenization depends in part on prill size. The degree to which binder flows during pressing in turn affects the void distribution within pressed charges, which one suspects will affect shock sensitivity and material strength. In this paper we explore, for ~30 PBX 9502 formulation batches using the same TATB powder lot, how prill size affects the compressive mechanical properties.

36 MATERIALS SCIENCE↗
NASA NTRS2010

Ignition-and-Growth Modeling of NASA Standard Detonator and a Linear Shaped Charge

The main objective of this study is to quantitatively investigate the ignition and shock sensitivity of NASA Standard Detonator (NSD) and the shock wave propagation of a linear shaped charge (LSC) after being shocked by NSD flyer plate. This combined explosive train was modeled as a coupled Arbitrary Lagrangian-Eulerian (ALE) model with LS-DYNA hydro code. An ignition-and-growth (I&G) reactive model based on unreacted and reacted Jones-Wilkins-Lee (JWL) equations of state was used to simulate the shock initiation. Various NSD-to-LSC stand-off distances were analyzed to calculate the shock initiation (or failure to initiate) and detonation wave propagation along the shaped charge. Simulation results were verified by experimental data which included VISAR tests for NSD flyer plate velocity measurement and an aluminum target severance test for LSC performance verification. Parameters used for the analysis were obtained from various published data or by using CHEETAH thermo-chemical code.

Oguz, Sirri↗
DOE OSTI2024

The Effects of Material-Filled Voids on Detonation Wave Shape in Rubberized RDX Explosives

The sensitivity of explosives is affected by inhomogeneities within the material. This is evident in the increased shock sensitivity of explosives with slightly lower densities resulting from an increased number of hotspots. The influence of hotspots on explosive initiation has been well studied; however, few studies have been conducted on the effect of intermediate-sized voids (0.1–10 mm) on a propagating detonation wave. Cylindrical voids filled with air have been studied for diameters ranging from 0.3 mm to 0.8 mm for both 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX) and 1,3,5-trinitro-1,3,5-triazinane (RDX)-based rubberized explosives. Continuing the investigation into single cylindrical voids, this study examined the effects of 0.5 mm diameter voids filled with different inert cylindrical metals on the detonation wave shape for an RDX-based rubberized explosive. The metals selected for experiments were 1066 aluminum, brass, copper, and tungsten. The propagation of the detonation wave was captured using a digital streak camera. Experimental results showed that the extent of detonation wave shaping was closely tied to the density differential between the bulk explosive and metal insert. Forty-four different filler materials, including non-metals, were simulated using a hydrodynamic code to further analyze material inclusion effects. The main factors hypothesized to be of interest were bulk sound speed, shock impedance, and filler material density. We found that the local detonation delay could be correlated fairly well to a ratio of bulk sound speed and density. Understanding the influence of material inclusions on detonation performance and wave shape allows for tailoring of detonations.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2021

SURFplus model calibration for PBX 9012

PBX 9012 is a plastic bonded explosive composed of 90.2 wt % HMX (cyclo-tetramethylene-tetranitramine) and 9.8 % Viton A (vinylidene-hexafluoropropylene copolymer). It has nearly the same composition as LX-07 (90% HMX and 10% Viton A) but with a slightly lower density. Hence it has a higher porosity and is slightly more shock sensitive. Here we describe the SURFplus model calibration for PBX 9012 using data from five shock-to-detonation transition (SDT) gas gun experiments by Burns and Chiquete, detonation front shape data from rate stick experiments and cylinder test experiment reported in Anderson et al., Jackson et al. The SDT experiments provide Pop plot data points (run distance-to-detonation) which characterize shock initiation, Lagrangian velocity time histories from embedded magnetic velocity gauges which give information on the reaction behind the lead shock, and Hugoniot data points for the reactants EOS. The rate stick experiments provide data on the curvature effect which characterize propagating detonation waves. The cylinder test experiments provide data on the detonation release isentrope used to calibrate the products EOS. The HE model uses a Davis reactants EOS with parameters that Burns and Chiquete [2020] fit to Hugoniot data, and Davis products EOS with parameters that Anderson et al. [2020] fit to cylinder test data.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2014

MICRO-SEISMOMETERS VIA ADVANCED MESO-SCALE FABRICATION

The Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) seek revolutionary sensing innovations for the monitoring of nuclear detonations. Performance specifications are to be consistent with those obtainable by only an elite few products available today, but with orders of magnitude reduction in size, weight, power, and cost. The proposed commercial innovation calls upon several technologies including the combination of meso-scale fabrication and assembly, photonics-based displacement / motion detection methods, and the use of digital control electronics . Early Phase II development has demonstrated verified and repeatable sub 2ng noise floor from 3Hz to 100Hz, compact integration of 3-axis prototypes, and robust deployment exercises. Ongoing developments are focusing on low frequency challenges, low power consumption, ultra-miniature size, and low cross axis sensitivity. We are also addressing the rigorous set of specifications required for repeatable and reliable long-term explosion monitoring, including thermal stability, reduced recovery time from mass re-centering and large mechanical shocks, sensitivity stability, and transportability. Successful implementation will result in small, hand-held demonstration units with the ability to address national security needs of the DOE/NNSA. Additional applications envisioned include military/defense, scientific instrumentation, oil and gas exploration, inertial navigation, and civil infrastructure monitoring.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1986

JPL pyro shock test approaches and results

This paper presents the overall approach at JPL in performing spacecraft pyrotechnic shock qualification testing. Initially, the assembly shock requirements are developed early in the program based on previous spacecraft test experience and data. Pyrotechnic device development testing firings and spacecraft Development Test Model (DTM) pyro firings are then conducted to verify the adequacy of the assembly shock requirements and to determine the subsystem test firing and the subsequent system level test firing requirements. The electro-dynamic shaker, through shock synthesis techniques, is utilized to qualify the shock sensitive flight equipment with margins applied. Actual pyrotechnic device firings on spacecraft equipment or science instruments are performed when the influence of the pyros is localized and can be ignored at the system level. Full spacecraft system level shock tests, which include multiple firings of certain critical pyro devices, are conducted to verify the spacecraft design structural integrity and functions as well as to qualify hardware items which have not been previously qualified. These tests also provide a source of data from which assembly level requirements can be evaluated and compared. For example, during the Galileo program, the results demonstrated that good agreement between predicted and measured shock environments and adequate qualification of the flight spacecraft was achieved.

Chang, Kurng Y.↗
NASA NTRS1980

What's wrong with the NOL card gap test?

The card gap test, originally developed for explosives, was adopted for determining the shock sensitivity of propellants. Testing solid propellants resulted in the discovery of several deficiencies in the test. The effects of critical diameter, donor pulse duration, and initiator variability are discussed. Reproducibility of results is shown to be worse for solid propellants than is reported for explosives. The calibration to express test results as shock pressure is of questionable accuracy. Use of the test in its present form leads to erroneous conclusions.

Brown, B.↗
DOE OSTI2018

Review of PBX 9502 Pop Plot data

Pop plot data (distance of run and time to detonation as a function of shock pressure) is a simple characterization of shock initiation of a high explosive. It is used, along with other data, to calibrate reactive burn models. For the insensitive TATB based explosive PBX 9502, there are data at 5 initial temperatures (77 K, -55 C, 23 C, 76 C, 130 C) and for several lots. Here we review the dependence of the Pop plot on temperature and the variation with lot. There is a significant increase in shock sensitivity with temperature.Since the Pop plot is important for modeling, fit parameters are interpolated to cover the temperature range –55 < T < 76 C. The scatter in the data and variation with lot is important for assessing the accuracy to which a model can be calibrated.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2013

HERMES Model Modifications and Applications 2012

HERMES was developed to meet requirements for a model to describe explosive response to impacts that do not produce prompt detonation, but can include delayed detonations such as DDT and XDT. Such response is termed High Explosive Violent Response (HEVR). The HERMES model includes a constitutive description of strength as a function of pressure, strain-rate, strain, and ambient temperature; the development of damage including fragmentation and porosity; the conditions leading to ignition; the propagation of a burning reaction through the volume of damaged explosive; the burn-up of the damaged and undamaged explosive; and the development of detonation using the Computational Reaction Evolution dependent on Entropy (S) and Time (CREST) detonation model. CREST can distinguish gradual pressure increases from shock waves, and also predict the increase in shock sensitivity to detonation that results from increased porosity. This year HERMES has been implemented as a User Defined Function in ALE 3D. As a result, modifications to the model can be implemented in a timely fashion asynchronously from the ALE 3D distribution process. There are differences between the implementation of HERMES in ALE 3D and the implementation in LS DYNA. The major difference is the propagation of an ignition front from an element that has started to burn. In LS DYNA, the time at which an element begins to burn is based on the minimum line-of-sight distance between the element and any previously ignited element. In ALE 3D the time to burn is based on a level-set method that propagates the ignition front from all elements that were previously ignited. The ALE 3D implementation modifies the time of ignition when element deformation changes the distance from the element to the source. The LS DYNA implementation does not. There are also differences in the implementation of artificial viscosity, which is important for CREST since the artificial viscosity increases the element entropy in a shock. In general, however, the differences have proven minor. In collaboration with the Atomic Weapons Establishment, UK (AWE), we have characterized two additional explosives – PETN and Composition B, a mixture of 60% RDX and 40% TNT by weight. Applications of HERMES to these explosives are described below.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗