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All sources NASA NTRS DOE OSTI

DOE OSTI2021

Quantifying Dam-Induced Fluctuations in Streamflow Frequencies Across the Colorado River Basin

Periodic fluctuations in natural streamflow are a major driver of river ecosystem dynamics and water resource management. However, most U.S. rivers are impacted both by long-term hydroclimatic trends and dams that alter flow variability. Despite these impacts, it remains largely unexplored how dams affect the dominant frequencies of natural streamflow over a highly regulated river network. We investigated the entire Colorado River Basin (CRB) to understand how the annual (10–14 months) and multi-annual (24–60 months) frequencies in natural flow regimes have been progressively altered by dams. Given the significant alteration over the CRB, we captured changes in streamflow frequencies between naturalized and observed monthly flows via wavelet analysis. Based on the similarity of changes in streamflow frequencies (annual and multi-annual) over the last 30 years, sections of the riverine network were classified into four groups. The annual frequency was relatively well preserved downstream of Hoover Dam, while showing a systematic trend of alteration downstream of Glen Canyon Dam until Hoover Dam. Meanwhile, the multi-annual frequency component was highly altered for the entire Lower Colorado main stem (i.e., downstream of Glen Canyon). We also identified dams with significant impacts on streamflow frequency by comparing wavelet coherence estimates. This study advances the notion that dams fundamentally alter river flow regimes across multiple frequencies and with varying amplitudes over time and space, with alteration propagating – or being dampened – by both hydroclimatic fluctuations and water resource management.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2021

mosartwmpy: A Python implementation of the MOSART-WM coupled hydrologic routing and water management model

mosartwmpy is a Python implementation of the Model for Scale Adaptive River Transport with Water Management (MOSART-WM). This new version retains the functionality of the legacy model (written in FORTRAN) while providing new features to enhance user experience and extensibility. MOSART is a large-scale river-routing model used to study riverine dynamics of water, energy, and biogeochemistry cycles across local, regional, and global scales (Li et al., 2013). The WM component introduced by Voisin et al. (2013) represents river regulation through reservoir storage and release operations, diversions from reservoir releases, and allocation to sectoral water demands. Each reservoir release is independently calibrated using long-term mean monthly inflow into the reservoir, long-term mean monthly demand associated with this reservoir, and reservoir goals (flood control, irrigation, recreation, etc.). Generic monthly pre-release rules and storage targets are set up for individual reservoirs; however, those releases are updated annually for inter-annual variability (dry or wet year) and daily for environmental constraints such as flow minimum release and minimum/maximum storage levels. The WM model allows an evaluation of the impact of water management over multiple river basins at once (global, continental scales) and with consistent representation of human operations over the full domain.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2022

River Organic Carbon Fluxes Modulated by Hydrodynamic Sorting of Particulate Organic Matter

Rivers regulate the global carbon cycle by transferring particulate organic carbon (POC) from terrestrial landscapes to marine sedimentary basins, but the processes controlling the amount and composition of fluvially exported POC are poorly understood. We propose that hydrodynamic sorting processes modify POC fluxes during fluvial transit. We test this hypothesis by studying POC transported along a ~1,200 km reach of the Rio Bermejo, Argentina. Nanoscale secondary ion mass spectrometry revealed that POC was either fine, mineral-associated organic matter, or coarse discrete organic particles. Mineral-associated POC is more resistant to oxidation and has a lower particle settling velocity than discrete POC. Consequently, hydraulic sorting and downstream fining amplify the proportion of fine, mineral-associated POC from ~55% to ~78% over 1,220 km of downstream transit. This suggests that mineral-associated POC has a greater probability of export and preservation in marine basins than plant detritus, which may be oxidized to CO 2 during transit.

58 GEOSCIENCES↗

DOE OSTI2023

Finding middle ground: Flow regimes designed for salmon and energy value

In regulated rivers, shaping seasonal flows to recover species at risk depends on understanding when to expect conflicts with competing water users and when their interests are aligned. Multi-objective optimization can be used to reveal such conflicts and commonalities. When species are involved, multi-objective optimization is challenged by the need to simulate complex species responses to flow regimes. Previously, we addressed that challenge by developing a simplified salmon model (Quantus) that defines cohorts of salmon by the river section and time in which they were spawned. Salmon in these space-time cohorts are tracked from the time redds (nests) are constructed until the cohort exits the tributary en route to the ocean. In this study, we modeled seasonal patterns in energy value and developed a Pareto-optimal frontier of seasonal flow patterns to maximize in-river salmon survival and hydropower value. Candidate flow regimes were characterized by two pulse flows varying in magnitude, timing, and duration and constrained by a total annual flow near the historical median. Our analysis revealed times when economic and salmon objectives were aligned and times when they differed. Pulse flows that favored higher energy value were timed to meet demand during extreme temperatures. Both salmon and hydropower objectives produced optimal flow regimes with pulse flows in early summer, but only solutions favoring hydropower value included high flows in mid-winter. Solutions favoring higher age-0 salmon survival provided an extended pulse flow in late winter/early spring, which suggests that access to productive floodplain habitat allowed faster growth and earlier out-migration and reduced the need for higher temperature-moderating flows later in spring. Minimum flows were also higher among solutions favoring salmon over energy. The tools used to produce these results can help to design simplified seasonal flow regimes by revealing compromise solutions that satisfy both fish and energy producers and highlighting when potential conflicts are likely.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2022

Reservoir Assessment Tool 2.0: Stakeholder driven improvements to satellite remote sensing based reservoir monitoring

In light of the rapidly increasing regulation of rivers due to planned and constructed reservoirs, monitoring reservoir operations has become very crucial. The Reservoir Assessment Tool (RAT) framework was developed to monitor reservoir operations globally, using hydrological modeling and satellite observations. With feedback from stakeholders, improvements in the RAT framework are demonstrated in this study using the Mekong River Basin as an example. A novel multi-sensor reservoir area mapping technique was developed using complementary strengths of optical and SAR sensors at a 1-5 day temporal resolution, allowing the quantification of sub-weekly reservoir operations. Additionally, the skill of radar altimeters in the RAT framework was tested using the Jason-3 altimeter. Using in-situ data from three Thai reservoirs in the Mekong Basin, consistent improvements were observed as compared to the original RAT framework. A functionality for visualizing forecasted outflow was also added using historically inferred reservoir operations or stakeholder-driven target storage expectations.

Reservoirs↗

DOE OSTI2023

Warming of the lower Columbia River , 1853 to 2018

Abstract Water temperature is a critical ecological indicator; however, few studies have statistically modeled century‐scale trends in riverine or estuarine water temperature, or their cause. Here, we recover, digitize, and analyze archival temperature measurements from the 1850s onward to investigate how and why water temperatures in the lower Columbia River are changing. To infill data gaps and explore changes, we develop regression models of daily historical Columbia River water temperature using time‐lagged river flow and air temperature as the independent variables. Models were developed for three time periods (mid‐19th, mid‐20th, and early 21st century), using archival and modern measurements (1854–1876; 1938–present). Daily and monthly averaged root‐mean‐square errors overall are 0.89°C and 0.77°C, respectively for the 1938–2018 period. Results suggest that annual averaged water temperature increased by 2.2°C ± 0.2°C since the 1850s, a rate of 1.3°C ± 0.1°C/century. Increased water temperatures are seasonally dependent. An increase of approximately 2.0°C ± 0.2°C/century occurs in the July–Dec time‐frame, while springtime trends are statistically insignificant. Rising temperatures change the probability of exceeding ecologically important thresholds; since the 1850s, the number of days with water temperatures over 20°C increased from ~5 to 60 per year, while the number below 2°C decreased from ~10 to 0 days/per year. Overall, the modern system is warmer, but exhibits less temperature variability. The reservoir system reduces sensitivity to short‐term atmospheric forcing. Statistical experiments within our modeling framework suggest that increased water temperature is driven by warming air temperatures (~29%), altered river flow (~14%), and water resources management (~57%).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Impact of the Three Gorges Dam on riverbed scour and siltation of the middle reaches of the Yangtze River

Abstract This study investigated the influence of the Three Gorges Dam (TGD) on the evolution of nearby channels in the Yangtze River (Changjiang River) system in order to better understand the environmental impact of large‐scale reservoir operations. From 2003 to 2017, the amounts of runoff and sediment transport in the Yangtze River were reduced by 3.3–14.5% and 67.8–92.7%, respectively, relative to 1955–2002 before the TGD was operational. Topographic measurements of the middle reaches (Yichang to Hukou) of the Yangtze River were analyzed from 1975 to 2017, during which time the cumulative erosion of the flood channel was 22.78 × 10 8 m 3 , and the dry channel accounted for 90.3% of the erosion. Following commissioning of the TGD, the scouring intensity of the sandy gravel section near the dam initially increased then decreased, whereas the scouring intensity of sandy sections away from the dam continued to increase. Beaches on convex banks of curved sections were scoured, and deep channels on concave banks became silted. In braided sections, the braids tended to shrink, and the diversion ratio of the main branch during dry seasons reduced, resulting in frequent branch alternation. Compared to changes in the downstream river channels of other large reservoirs worldwide, scouring from the TGD is extensive. The findings of this study are significant for river channel regulation and waterway planning in the Yangtze River and worldwide.

Yang, Yunping↗

NASA NTRS2021

Managing wetlands to solve the water crisis in the Katuma River ecosystem, Tanzania

The formerly perennial Katuma River in western Tanzania starts in a protected forest, it then flows through irrigated rice farms before reaching Lake Katavi, a floodplain wetland whose outflow regulates the river flow through the Katavi National Park (KNP) down to its outlet at Lake Rukwa, which has no outlet. In recent years, due to overexploitation of water for irrigation, the Katuma River dried out for up to four months per year and this greatly degraded the KNP ecosystem, the siltation of river lead to flooding of the adjacent areas during heavy rains, and the water level of Lake Rukwa has decreased by 4 m since 1992 while its fishery yield and water quality also deteriorated. In 2016, a total of 46 illegal weirs were removed from the Katuma River upstream of KNP. Following that, the river zero-flow periods were reduced by two months and Lake Rukwa water level rose by 1 m. We suggest that the construction of a low V-notch weir at the outlet of the Lake Katavi wetlands would further reduce the Katuma River zero-flow periods by an additional month, thus returning the river nearly to its former perennial status. The enforcement of regulations governing the construction of irrigation weirs is essential. These ecohydrology solutions do not eliminate the threats, but they amplify the opportunities for sustainable development at the basin scale. This example of active governance of water resources at the basin scale can be applied throughout Tanzania and in semi-arid East Africa in general.

Satellite altimetry↗

DOE OSTI2020

Aligned FTICR-MS, Respiration, and Biochemical Transformation Data from Columbia River Sediment Incubations Associated with: “Carbon Limitation Leads to Thermodynamic Regulation of Aerobic Metabolism”

Columbia River hyporheic zone sediments from the Hanford Site 300 Area in eastern Washington were incubated in a full factorial design with different organic matter (OM) amendments. The aim of the experiment was to test the influence of OM thermodynamics on aerobic respiration across different organic carbon pools and concentrations. This dataset is comprised of (1) a csv with high resolution characterization of dissolved organic matter via 12 Tesla Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) analyzed through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory), (2) a csv with sample IDs, replicates, amendments, dissolved oxygen (DO) measurements, and sampling time points, (3) a csv with sample IDs, replicates, respiration rates, FTICR summary metrics, and relative abundance of chemical classes; and (4) a csv with the number of chemical transformations in each sample replicate (microcosm). The data are associated with the publication “Carbon Limitation Leads to Thermodynamic Regulation of Aerobic Metabolism” published in ES&T Letters (Garayburu-Caruso et al., 2020). Please use the data package’s DOI to cite the data package. We ask that you acknowledge the U.S. Department of Energy (DOE) Biological and Environmental Research (BER) Subsurface Biogeochemical Research (SBR) program when using the data. All data are free to be used for any purpose, such as for manuscripts, presentations, and grant proposals. There is no obligation to include data package authors as co-authors.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

An Integrated Hydroclimatic Assessment of Future Reservoir and Hydropower Operations in the U.S.

The engineering of rivers by dams is a formative feature of human-nature systems and the interconnectivity of water, energy, and the climate. Sufficient and broad-based representations of dams in large-scale hydrological models prove essential to mapping their extensive regulation of river flow and biogeochemistry and gauging climate-linked provisions, including freshwater supply and hydropower. We present an integrated modeling framework to investigate future streamflow and hydropower generation in the Contiguous U.S. (1990–2075), leveraging an ensemble of six downscaled and bias-corrected General Circulation Models (GCMs) from the high-end SSP585 scenario of the CMIP6. To achieve this, we develop a reservoir operations and parameterization scheme for 1,384 dams in a high-resolution river network, including simulated hydropower generation for 326 dams. For the GCM ensemble mean, we simulate a widespread increase in regulated streamflow into the late-century (11% annual and 17% in winter for the dam median) with region-specific changes in summer streamflow that feature prominent declines in the Northwest (−7%). Mediation by reservoirs is shown to dampen intra-annual streamflow changes, delivering additional summer releases that partially mitigate declining flows. Total hydropower generation is projected to increase modestly (+3%), with boosted generation in the winter (+9%) and spring (+5%) offsetting declined summer generation (−3.4%), suggesting strong adaptation potential for hydropower in the future energy portfolio. Further analysis reveals that the choice of GCM, particularly in western regions, has significant bearing on projected streamflow and hydropower changes.

13 HYDRO ENERGY↗

DOE OSTI2024

The environmental impact of hydropower: a systematic review of the ecological effects of sub-daily flow variability on riverine fish

Hydropower can help facilitate power grid decarbonization because it can respond to short-term changes in power demand and is comparatively more reliable than intermittent wind and solar. However, flexible hydropower operations can create rapid and abnormal fluctuations in downstream flow conditions, which can negatively impact aquatic ecosystems. Accordingly, we conducted a systematic review on the ecological effects of hydropower-driven sub-daily flow variability (SDFV) on riverine fishes. We reviewed and synthesized 109 articles relevant to fish-SDFV relationships from seven sources, most of which focused on Salmonids in North America and northern and western Europe and were published in the last 15 years. We found strong agreement in the literature that SDFV increases fish stranding risk, destabilizes habitat, and decreases production and diversity. We found moderate agreement that SDFV interrupts fish reproduction, increases or has no impact on condition, and prompts or discourages movement depending on local channel conditions. We found little to no agreement for relationships between SDFV and mortality, physiology, and behavior. The effects of SDFV on riverine fish ecology are intertwined in the complex suite of biotic and abiotic characteristics that structure aquatic ecosystems and are highly site-, species-, and life stage-specific. Assessments of the impact of SDFV on fish ecology should first characterize local habitat and channel quality and fish community composition to identify specific, measurable ecological outcomes to sustain or enhance, and then design mitigation strategies tailored to those ecological objectives.

13 HYDRO ENERGY↗

DOE OSTI2021

Impact of river channel lateral migration on microbial communities across a discontinuous permafrost floodplain

Permafrost soils store approximately twice the amount of carbon currently present in Earth’s atmosphere and are acutely impacted by climate change due to the polar amplification of increasing global temperature. Many organic-rich permafrost sediments are located on large river floodplains, where river channel migration periodically erodes and re-deposits the upper tens of meters of sediment. Channel migration exerts a first-order control on the geographic distribution of permafrost and floodplain stratigraphy and thus may affect microbial habitats. Here, to examine how river channel migration in discontinuous permafrost environments affects microbial community composition, we used amplicon sequencing of the 16S rRNA gene on sediment samples from floodplain cores and exposed riverbanks along the Koyukuk River, a large tributary of the Yukon River in west-central Alaska. Microbial communities are sensitive to permafrost thaw: communities found in deep samples thawed by the river closely resembled near-surface active layer communities in non-metric multidimensional scaling analyses but did not resemble floodplain permafrost communities at the same depth. Microbial communities also displayed lower diversity and evenness in permafrost than in both the active layer and permafrost-free point bars recently deposited by river channel migration. Taxonomic assignments based on 16S and quantitative PCR for the methyl-coenzyme M reductase functional gene demonstrated that methanogens and methanotrophs are abundant in older permafrost-bearing deposits, but not in younger, non-permafrost point bar deposits. The results suggested that river migration, which regulates the distribution of permafrost, also modulates the distribution of microbes potentially capable of producing and consuming methane on the Koyukuk River floodplain.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2024

Subsurface Redox Interactions Regulate Ebullitive Methane Flux in Heterogeneous Mississippi River Deltaic Wetland

Abstract As interfaces connecting terrestrial and ocean ecosystems, coastal wetlands develop temporally and spatially complex redox conditions, which drive uncertainties in greenhouse gas emission as well as the total carbon budget of the coastal ecosystem. To evaluate the role of complex redox reactions in methane emission from coastal wetlands, a coupled reactive‐transport model was configured to represent subsurface biogeochemical cycles of carbon, nitrogen, and sulfur, along with production and transport of multiple gas species through diffusion and ebullition. This model study was conducted at multiple sites along a salinity gradient in the Barataria Basin at the Mississippi River Deltaic Plain. Over a freshwater to saline gradient, simulated total flux of methane was primarily controlled by its subsurface production and consumption, which were determined by redox reactions directly (e.g., methanogenesis, methanotrophy) and indirectly (e.g., competition with sulfate reduction) under aerobic and/or anaerobic conditions. At fine spatiotemporal scales, surface methane fluxes were also strongly dependent on transport processes, with episodic ebullitive fluxes leading to higher spatial and temporal variability compared to the gradient‐driven diffusion flux. Ebullitive methane fluxes were determined by methane fraction in total ebullitive gas and the frequency of ebullitive events, both of which varied with subsurface methane concentrations and other gas species. Although ebullition thresholds are constrained by local physical factors, this study indicates that redox interactions not only determine gas composition in ebullitive fluxes but can also regulate ebullition frequency through gas production.

03 NATURAL GAS↗

DOE OSTI2020

Evaluating the efficacy and equity of environmental stopgap measures

Contemporary environmental policy is rife with measures that do not fully resolve a problem, but instead are proposed to “buy time” for the development and future implementation of more durable solutions. In this perspective, we define such measures as “stopgap measures,” and examine examples from wildfire risk management, hydrochlorofluorocarbon regulation, and Colorado River water management. We introduce an analytical framework to assess stopgaps, and apply this framework to solar geoengineering, a controversial stopgap for climate action. Studying stopgaps as a novel category of policy and management measures can help us understand the why stopgaps emerge, and weigh the equity and efficacy of stopgaps against other policy proposals

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Collateral benefits: River flow normalization for endangered fish enabled riparian rejuvenation

Abstract Like most rivers worldwide, the transboundary North American Kootenay/i River has experienced multiple impacts including watershed developments, river channelization, and floodplain clearing, draining, and diking. Construction of Libby Dam was authorized by the 1964 Columbia River Treaty (CRT) between the United States and Canada, and in 1975 began regulating downstream flows for flood risk management and hydropower generation. Following cumulative impacts, the endemic Kootenai River White Sturgeon population collapsed and was designated as endangered in 1994 (U.S. Endangered Species Act). Subsequent Biological Opinions from the U.S. Fish and Wildlife Service prescribed Libby Dam operations to provide springtime flow pulses for sturgeon spawning. These provided the unanticipated benefit of substantial seedling recruitment of native and introduced riparian cottonwoods and willows. The regulated flow regime was further adaptively managed to provide a more normative (natural) regime, to balance ecological functions with flood risk management and hydropower generation. The broadened ecological considerations would be consistent with the proposed priorities for the modernization of the international CRT. The observed responses revealed that (1) diverse aquatic and riparian organisms are dependent on common river flow characteristics; (2) a normalized flow regime provided substantial ecological benefits; and (3) due to multiple influences, hybrid ecosystems develop along regulated rivers, with a blending of natural and altered processes and communities. For other regulated rivers, we recommend that (1) high springtime flows be allowed, as feasible; (2) followed by the gradual post‐peak recession; and (3) the maintenance of sufficient flows through the warm and dry interval of mid to late summer.

Rood, Stewart B.↗

DOE OSTI2022

How Does Flow Alteration Propagate Across a Large, Highly Regulated Basin? Dam Attributes, Network Context, and Implications for Biodiversity

Abstract Large dams are a leading cause of river ecosystem degradation. Although dams have cumulative effects as water flows downstream in a river network, most flow alteration research has focused on local impacts of single dams. Here we examined the highly regulated Colorado River Basin (CRB) to understand how flow alteration propagates in river networks, as influenced by the location and characteristics of dams as well as the structure of the river network—including the presence of tributaries. We used a spatial Markov network model informed by 117 upstream‐downstream pairs of monthly flow series (2003–2017) to estimate flow alteration from 84 intermediate‐to‐large dams representing >83% of the total storage in the CRB. Using Least Absolute Shrinkage and Selection Operator regression, we then investigated how flow alteration was influenced by local dam properties (e.g., purpose, storage capacity) and network‐level attributes (e.g., position, upstream cumulative storage). Flow alteration was highly variable across the network, but tended to accumulate downstream and remained high in the main stem. Dam impacts were explained by network‐level attributes (63%) more than by local dam properties (37%), underscoring the need to consider network context when assessing dam impacts. High‐impact dams were often located in sub‐watersheds with high levels of native fish biodiversity, fish imperilment, or species requiring seasonal flows that are no longer present. These three biodiversity dimensions, as well as the amount of dam‐free downstream habitat, indicate potential to restore river ecosystems via controlled flow releases. Our methods are transferrable and could guide screening for dam reoperation in other highly regulated basins.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2021

Influences on Discharge Partitioning on a Large River Delta: Case Study of the Mississippi-Atchafalaya Diversion, 1926-1950

The modern Mississippi River (M.R.) Delta is plumbed by the Mississippi and Atchafalaya rivers, setting water and sediment dispersal pathways for Earth’s fifth-largest river system. The Atchafalaya River’s (A.R.) partial annexation of discharge from the M.R., particularly between 1926 and 1950, prompted warnings of a rapid river avulsion and the construction of the Old River Control Structure to regulate flow. Natural and anthropogenic causes of this discharge annexation are difficult to disentangle. Here, we develop and validate a hydrodynamic model of flow partitioning through the historic channel network. We then isolate how several key changes to the system affected discharge partitioning and stage at the A.R.-M.R. diversion. Simulations show that erosion of the upper A.R. can account for 73% of the water discharge increase. Dredging in the lower A.R. between 1932 and 1950 can account for 35% of the water discharge increase, and was also an important control on shear stress distribution. The lower M.R. was slightly erosional during this period, and therefore hindered the A.R. discharge increase. Significant lacustrine delta deposition in A.R. had little effect on partitioning. These findings highlight the importance of A.R. enlargement processes on avulsion dynamics at this site. Given the essential nature of this river junction to the society, transportation, and commerce of the United States, improved attribution of discharge increases may lead to future management strategies that are broadly impactful.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Scaling hyporheic nitrogen cycling in large river alluvial aquifers

Research Element 1: Denitrification is a difficult flux to measure when fluxes are low and when the ecosystem is difficult to sample. These attributes describe Nyack floodplain, a large gravel-bedded aquifer adjacent to the Middle Fork Flathead River. Given that denitrification is simply respiration with nitrate as a terminal electron acceptor, we reasoned that N 2 production should negatively covary with oxygen respiration so long that oxygen is available. We sampled 16 wells 8 times throughout a year and analyzed these water samples on a membrane-inlet mass spectrometer for N 2 :Ar and O 2 . We fit multilevel models to N 2 :Ar as a function of dissolved oxygen. Within wells, there was no relationship between O 2 and N 2 :Ar. Among wells N 2 :Ar increased as O 2 declined. Based on the slope of this relationship, ~ -0.07, and estimated oxygen respiration in Nyack derived from prior studies, a possible range for denitrification is 0-8 mmol m -2 d -1 corresponding to a turnover rate for nitrate of 0-0.2/d. This estimated turnover rate is in the lower 20% of rates measured in the LINX 2 study, yet shows that even in a low nitrate (0.005 mmol/L) aquifer denitrification can be a substantial sink for dissolved N. Research Element 3 and 4: We developed a new theoretical approach to describe the relationship between water inflow, water outflow, and water age in porous media control volumes under dynamic flow conditions. Our approach had three distinct steps. First we described the application of well-established equations borrowed from Chemical Engineering to describe water age distributions in the hyporheic zone under steady state conditions. We published the associated results in the scientific journal PLOS ONE. Second, we developed a new theory ("flow spans") to describe how predicted steady-state water age distributions will respond to time varying imbalances in hyporheic discharge and recharge. Finally, we developed a proof-of-concept simulation model based on the new theory and used the model to examine the effects of flow regulation on a simulated river with characteristics representative of western U.S. montane rivers with expansive hyporheic zones.

54 ENVIRONMENTAL SCIENCES↗