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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Calendar life of lithium metal batteries: Accelerated aging and failure analysis

Lithium metal batteries (LMBs) are prime candidates for next-generation energy storage devices characterized by their remarkable energy storage capabilities. Despite the importance of understating the calendar aging impacts in LMBs, cycle life and calendar life have received inconsistent attention across various research and development stages. For acceptance into an application, especially electric vehicles, batteries are required to have sufficient calendar life to ensure performance over the life of vehicles which often experience extended periods of inactivity. In this study, an in-depth exploration into the calendar aging of LMB (Li/ Li[Ni 0.8 Mn 0.1 Co 0.1 ]O 2 in pouch cell format) is conducted. Specifically, the impact of calendar aging factors, state-of-charge (SOC), temperature, pressure, and operating conditions (open-circuit voltage, OCV and constant voltage, CV) on the surface morphology and thickness change rate in lithium metal anode is investigated. Notably, the results show that storing LMB pouch cells at an OCV, 80 % SOC, 25 °C, and 10 psi external pressure leads to a <1% reduction in capacity over 18 months. The results also suggest routes which can be utilized in the future for accelerated aging without altering the primary degradation modes. The results also show an accelerated calendar aging at high temperatures (45 °C), 100 % SOC, and CV suggesting they may serve as key accelerated aging methods for future studies. During calendar aging, pressure mitigates dendrite growth and extends calendar life. In conclusion, the insights from this study reinforce the viability of LMBs as a compelling solution for addressing increased energy storage needs in real-world applications.

25 ENERGY STORAGE↗
DOE OSTI2025

From Electronic Structure to Ion Transport: Photoelectron Spectroscopy and Molecular Dynamics Simulations Reveal the Role of Anions in Lithium Battery Electrolytes

Electrolyte anions are pivotal for lithium battery performance, yet their fundamental electronic structural properties are not well understood. In this work, we employ a combination of negative-ion photoelectron spectroscopy (NIPES), ab initio calculations, and molecular dynamics (MD) simulations to investigate the electronic structures of three representative electrolyte anions. This multiscale approach enables us to elucidate how their intrinsic electronic properties govern anion–solvent interactions in gas-phase clusters, as well as lithium-ion (Li + ) solvation structures and ion transport behavior in the condensed phase. NIPES reveals that difluoro(oxalato)borate (DFOB – ), bis(fluorosulfonyl)imide (FSI – ), and bis(oxalato)borate (BOB – ) all exhibit high electron binding energies, with vertical/adiabatic detachment energies increasing from DFOB – (6.09/5.70 eV) to FSI – (6.80/6.10 eV) to BOB – (6.82/6.40 eV), correlating with enhanced oxidation stability. Ab initio calculations reveal that DFOB – /FSI – –solvent complexes bind Li + ∼ 10 kcal/mol stronger than BOB – series, aligning with the strength of a Li + –anion model. DFOB – exhibits pronounced charge localization on both oxygen and fluorine atoms, enabling their involvement in Li + coordination. In contrast, fluorine atoms in FSI – are largely electron-depleted and remain excluded from direct Li + binding. MD simulations further demonstrate that LiDFOB and LiFSI systems exhibit Li + diffusion coefficients three and five times higher than those of LiBOB across four common solvents. Notably, LiFSI salt in acetonitrile (AN) exhibits the fastest Li + diffusion among 12 electrolyte systems, highlighting the synergistic effect of FSI – and AN in promoting ion mobility. In conclusion, these findings provide a molecular-level understanding of the critical roles of anion and its microsolvation in optimizing Li + diffusion dynamics, once again emphasizing the positioning of FSI – and DFOB – as prime candidates for next-generation electrolytes.

25 ENERGY STORAGE↗
NASA NTRS1995

An Experimental and Analytical Investigation of Stirling Space Power Converter Heater Head

NASA has identified the Stirling power converter as a prime candidate for the next generation power system for space applications requiring 60000 hr of operation. To meet this long-term goal, several critical components of the power converter have been analyzed using advanced structural assessment methods. Perhaps the most critical component, because of its geometric complexity and operating environment, is the power converter's heater head. This report describes the life assessment of the heater head which includes the characterization of a viscoplastic material model, the thermal and structural analyses of the heater head, and the interpolation of fatigue and creep test results of a nickel-base superalloy, Udimet 720 LI (Low Inclusions), at several elevated temperatures for life prediction purposes.

Abdul-Aziz, Ali↗
NASA NTRS2010

Simultaneous Spectral Temporal Adaptive Raman Spectrometer - SSTARS

Raman spectroscopy is a prime candidate for the next generation of planetary instruments, as it addresses the primary goal of mineralogical analysis, which is structure and composition. However, large fluorescence return from many mineral samples under visible light excitation can render Raman spectra unattainable. Using the described approach, Raman and fluorescence, which occur on different time scales, can be simultaneously obtained from mineral samples using a compact instrument in a planetary environment. This new approach is taken based on the use of time-resolved spectroscopy for removing the fluorescence background from Raman spectra in the laboratory. In the SSTARS instrument, a visible excitation source (a green, pulsed laser) is used to generate Raman and fluorescence signals in a mineral sample. A spectral notch filter eliminates the directly reflected beam. A grating then disperses the signal spectrally, and a streak camera provides temporal resolution. The output of the streak camera is imaged on the CCD (charge-coupled device), and the data are read out electronically. By adjusting the sweep speed of the streak camera, anywhere from picoseconds to milliseconds, it is possible to resolve Raman spectra from numerous fluorescence spectra in the same sample. The key features of SSTARS include a compact streak tube capable of picosecond time resolution for collection of simultaneous spectral and temporal information, adaptive streak tube electronics that can rapidly change from one sweep rate to another over ranges of picoseconds to milliseconds, enabling collection of both Raman and fluorescence signatures versus time and wavelength, and Synchroscan integration that allows for a compact, low-power laser without compromising ultimate sensitivity.

Blacksberg, Jordana↗
DOE OSTI2024

Characterization of build parameters and microstructure in low heat input WAAM of Ni-based superalloy Haynes 282

Conference paper for 2024 10th International Conference on Advances in Materials, Manufacturing &amp; Repair for Power Plants. Ni-based superalloy Haynes 282 is a prime candidate for advanced power generation systems due to its superior fabricability, weldability, and high-temperature performance. Additive manufacturing offers potential cost and time savings for gas turbine components. Wire-arc direct energy deposition can create large components but often requires post-processing treatments, such as hot isostatic pressing (HIP), to address porosity. This study explores a low heat-input, high deposition rate GMAW process to achieve fully dense Haynes 282 without HIP. Twenty-one blocks were deposited, varying travel and wire feed speeds. Initial analysis (visual inspection, microstructural examination, and CT) revealed the impact of build parameters on internal porosity and defects. Scanning electron microscopy provided insights into structural heterogeneity and microstructural properties. Related journal article can be found at https://doi.org/10.31399/asm.cp.am-epri-2024p0001.

Adam, Benjamin↗
DOE OSTI2026

Validating and Comparing Energy Estimation Methods at Water Resource Recovery Facilities

Water resource recovery facilities play a crucial role in the water-energy nexus, consuming a substantial amount of energy in the United States. Growing treatment volumes and more stringent water quality standards are expected to increase the amount of energy needed to treat wastewater, but accurately estimating energy consumption and potential remains challenging due to variability in scale, treatment methods, and effluent treatment standards. In this study, we used publicly available data to evaluate the accuracy of methods for estimating energy consumption and generation, then quantified uncertainty based on key factors like flow rate, treatment level, and geographic location. To validate methods, we estimated energy consumption and generation at the facility-level, then compared estimates to self-reported data from utilities in major U.S. cities. We found that process models of treatment trains under best practice configurations were accurate relative to other methods for estimating electricity use, total energy use, and electricity generation from biogas utilization, and less complex methods based on effluent treatment level and prime movers also performed well for estimating electricity consumption and generation, respectively. Applying the evaluated methods to a national inventory of treatment facilities, we estimate that annual energy consumption ranged from 56.3 x 10^3 to 82.5 x 10^3 TJ in 2012 and 83.6 x 10^3 to 127 x 10^3 TJ in 2042. Our results indicate that not all estimation methods are suited for every use case, so we recommend that researchers and practitioners select an estimation method based on data availability and desired computational intensity.

Hodson, Abigayle↗
NASA NTRS1989

Non linear evolution of a second mode wave in supersonic boundary layers

Presented here are several direct simulations of one 2-D second mode perturbation wave, superimposed upon a prescribed mean flow. Periodicity is assumed in the streamwise direction (Fourier) and the variables are expanded in Chebyshev series in the direction normal to the flat plate. The code is fully explicit and is time advanced with a 3rd order Runge-Kutta scheme. The second mode wave (R delta prime = 8000), interacts with itself to generate higher streamwise harmonics. Physical parameters are chosen to maximize the linear growth rate at the prescribed Reynolds number. Initial results indicate that the nonlinear processes begin in the critical layer region and are the result of the cubic interactions in the momentum equations, rather than due to the higher streamwise harmonics. Analysis of the various terms in the momentum equations combined with numerical experiments in which various modes are artificially suppressed, lead to the conclusion that asymptotic methods will produce the saturated state in one or two order of magnitude less computer time than that required by the direct numerical simulations.

Erlebacher, Gordon↗
NASA NTRS1990

Space Station Freedom solar dynamic power generation

Viewgraphs on Space Station Freedom solar dynamic power generation are presented. Topics covered include: prime contract activity; key solar dynamic power module requirements; solar dynamic heat receiver technology; and solar concentrator advanced development.

Springer, T.↗
DOE OSTI2023

Advanced Turbulence Models for Large-Scale Atmospheric Boundary Layer Flows

We present high-fidelity large-eddy-simulation (LES) modeling approaches for the turbulent atmospheric boundary layer (ABL) flows. Wind energy is a prime example of an application driven by ABL. Generation of electrical energy from farms of wind turbines at night in the stable ABL is a particularly interesting situation. In this report, we consider the well-known GEWEX (Global Energy and Water Cycle Experiment) Atmospheric Boundary Layer Study (GABLS) stably stratified benchmark LES case. We use a high-order spectral element code Nek5000/RS, which is supported under the DOE's Exascale Computing Project (ECP) Center for Efficient Exascale Discretizations (CEED) project, targeting application simulations on various acceleration-device based exascale computing platforms. In our earlier ANL report, we demonstrated our newly developed subgrid-scale (SGS) models based on high-pass filter (HPF), mean-field eddy viscosity (MFEV), and Smagorinsky (SMG) with no-slip and traction boundary conditions, provided with low-order statistics, convergence and turbulent structure analysis. In this report, we extend the range of our SGS modeling approaches in the context of the mean-field eddy viscosity (MFEV), to include the solution of an SGS turbulent kinetic energy equation (TKE). We demonstrate the model fidelity of Nek5000/RS in comparison to that of AMR-Wind, a block-structured second-order finite-volume code with adaptive-mesh-refinement capabilities, with which we studied scaling performance for both codes in comparison on DOE's leadership computing platforms.

17 WIND ENERGY↗
NASA NTRS1984

Electromagnetic thrusters for spacecraft prime propulsion

The benefits of electromagnetic propulsion systems for the next generation of US spacecraft are discussed. Attention is given to magnetoplasmadynamic (MPD) and arc jet thrusters, which form a subset of a larger group of electromagnetic propulsion systems including pulsed plasma thrusters, Hall accelerators, and electromagnetic launchers. Mission/system study results acquired over the last twenty years suggest that for future prime propulsion applications high-power self-field MPD thrusters and low-power arc jets have the greatest potential of all electromagnetic thruster systems. Some of the benefits they are expected to provide include major reductions in required launch mass compared to chemical propulsion systems (particularly in geostationary orbit transfer) and lower life-cycle costs (almost 50 percent less). Detailed schematic drawings are provided which describe some possible configurations for the various systems.

Rudolph, L. K.↗
NASA NTRS2005

AC/DC Power Systems with Applications for future Lunar/Mars base and Crew Exploration Vehicle

ABSTRACT The Power Systems branch at JSC faces a number of complex issues as it readies itself for the President's initiative on future space exploration beyond low earth orbit. Some of these preliminary issues - those dealing with electric power generation and distribution on board Mars-bound vehicle and that on Lunar and Martian surface may be summarized as follows: Type of prime mover - Because solar power may not be readily available on parts of the Lunar/Mars surface and also during the long duration flight to Mars, the primary source of power will most likely be nuclear power (Uranium fuel rods) with a secondary source of fuel cell (Hydrogen supply). The electric power generation source - With nuclear power being the main prime mover, the electric power generation source will most likely be an ac generator at a yet to be determined frequency. Thus, a critical issue is whether the generator should generate at constant or variable frequency. This will decide what type of generator to use - whether it is a synchronous machine, an asynchronous induction machine or a switched reluctance machine. The type of power distribution system - the distribution frequency, number of wires (3- wire, 4-wire or higher), and ac/dc hybridization. Building redundancy and fault tolerance in the generation and distribution sub-systems so that the system is safe; provides 100% availability to critical loads; continues to operate even with faulted sub-systems; and requires minimal maintenance. This report descril_es results of a summer faculty fellowship spent in the Power Systems Branch with the specific aim of investigating some of the lessons learned in electric power generation and usage from the terrestrial power systems industry, the aerospace industry as well as NASA's on-going missions so as to recommend novel surface and vehicle-based power systems architectures in support of future space exploration initiatives. A hybrid ac/dc architecture with source side and load side redundancies and including emergency generators on both ac and dc sides is proposed. The generation frequency is 400 Hz mostly because of the technology maturity at this frequency in the aerospace industry. Power will be distributed to several ac load distribution buses through solid state variable speed, constant frequency converters on the ac side. A segmented dc ring bus supplied from ac/dc converters and with the capability of connecting/disconnecting the segments will supply power to multiple de load distribution buses. The system will have the capability of reverse flow from dc to ac side in the case of an extreme emergency on the main ac generation side.

Chowdhury, Badrul H.↗
NASA NTRS2018

Multiwavelength Light Curves of Two Remarkable Sagittarius A* Flares

Sgr A* , the supermassive black hole (SMBH) at the center of our Milky Way Galaxy, is known to be a variable source of X-ray, near-infrared (NIR), and submillimeter radiation and therefore a prime candidate to study the electromagnetic radiation generated by mass accretion flow onto a black hole and/or a related jet. Disentangling the power source and emission mechanisms of this variability is a central challenge to our understanding of accretion flows around SMBHs. Simultaneous multiwavelength observations of the flux variations and their time correlations can play an important role in obtaining a better understanding of possible emission mechanisms and their origin. This paper presents observations of two flares that both apparently violate the previously established patterns in the relative timing of submillimeter/NIR/X-ray flares from Sgr A* . One of these events provides the first evidence of coeval structure between NIR and submillimeter flux increases, while the second event is the first example of the sequence of submillimeter/X-ray/NIR flux increases all occurring within ∼1 hr. Each of these two events appears to upend assumptions that have been the basis of some analytic models of flaring in Sgr A* . However, it cannot be ruled out that these events, even though unusual, were just coincidental. These observations demonstrate that we do not fully understand the origin of the multiwavelength variability of Sgr A* and show that there is a continued and important need for long-term, coordinated, and precise multiwavelength observations of Sgr A* to characterize the full range of variability behavior

accretion↗
DOE OSTI2023

Compressor system with heat recovery

A system includes a first working fluid compressor configured to pressurize a working fluid, and a prime mover coupled to the first working fluid compressor and configured to provide a mechanical input into the first working fluid compressor. An exhaust assembly is coupled to the prime mover and is configured to receive exhaust heat from the prime mover, the exhaust assembly including a generator configured to generate electric current based on the exhaust heat received by the exhaust assembly. A second working fluid compressor includes an electric motor electrically and synchronously coupled to the generator and configured to pressurize the working fluid.

Torrey, David Allan↗
NASA NTRS1976

Growth kinetics of gamma-prime precipitates in a directionally solidified eutectic, gamma/gamma-prime-delta

A directionally solidified eutectic alloy (DSEA), of those viewed as potential candidates for the next generation of aircraft gas turbine blade materials, is studied for the gamma-prime growth kinetics, in the system Ni-Nb-Cr-Al, specifically: Ni-20 w/o Nb-6 w/o Cr-2.5 w/o Al gamma/gamma-prime-delta DSEA. Heat treatment, polishing and etching, and preparation for electron micrography are described, and the size distribution of gamma-prime phase following various anneals is plotted, along with gamma-prime growth kinetics in this specific DSEA, and the cube of gamma-prime particle size vs anneal time. Activation energies and coarsening kinetics are studied.

Tewari, S. N.↗
DOE OSTI2025

Solving the strong CP problem with massless grand-color quarks

We propose a solution to the strong CP problem that specifically relies on massless quarks and has no light axion. The QCD color group SU(3) c is embedded into a larger, simple gauge group (grand-color) where one of the massless, colored fermions enjoys an anomalous chiral symmetry, rendering the strong CP phase unphysical. The grand-color gauge group G GC is Higgsed down to SU(3) c × ${G}_{c^{\prime }}$, after which ${G}_{c^{\prime }}$ eventually confines at a lower scale, spontaneously breaking the chiral symmetry and generating a real, positive mass to the massless, colored fermion. Since the chiral symmetry has a ${G}_{c^{\prime }}$ anomaly, there is no corresponding light Nambu-Goldstone boson. The anomalous chiral symmetry can be an accidental symmetry that arises from an exact discrete symmetry without introducing a domain wall problem. Potential experimental signals of our mechanism include vector-like quarks near the TeV scale, pseudo Nambu-Goldstone bosons below the 10 GeV scale, light dark matter decay, and primordial gravitational waves from the new strong dynamics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1980

Thermal stress fracture in elastic-brittle materials

The reported investigation shows that the assessment of the possibility of the thermal fracture of brittle materials depends upon an accurate evaluation of the thermal stresses and the determination of the resulting stress intensity factors. The stress intensity factors can be calculated in a variety of ways ranging from the very precise to approximate, but only for a limited number of geometries. The main difficulty is related to the determination of the thermal stress field because of its unusual character and its dependence upon boundary conditions at points far from the region of thermal activity. Examination of a number of examples suggests that the best visualization of the thermal stresses and any associated fracture can be made by considering the problem to be the combination of thermal and isothermal problems or by considering that the prime effect of the temperature is in the generation of thermal strains and that the thermal stresses are simply the result of the region trying to accommodate these strains.

Emery, A. F.↗
NASA NTRS1986

A finite element approach for solution of the 3D Euler equations

Prediction of thermal deformations and stresses has prime importance in the design of the next generation of high speed flight vehicles. Aerothermal load computations for complex three-dimensional shapes necessitate development of procedures to solve the full Navier-Stokes equations. This paper details the development of a three-dimensional inviscid flow approach which can be extended for three-dimensional viscous flows. A finite element formulation, based on a Taylor series expansion in time, is employed to solve the compressible Euler equations. Model generation and results display are done using a commercially available program, PATRAN, and vectorizing strategies are incorporated to ensure computational efficiency. Sample problems are presented to demonstrate the validity of the approach for analyzing high speed compressible flows.

Thornton, E. A.↗