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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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As part of our investigation into the process optimization of 2,6-diaminopyrazine-1-oxide (DAPO), small-scale sensitivity testing (impact, friction, and ESD) was conducted on the precursor, N-nitroso-bis(cyanomethyl)amine (NBCMA). NBCMA exhibited moderate sensitivity to friction, whereas no sensitivity to impact or spark was observed.
Gases are often by-products of battery materials during cell formation and degradation, affecting the cycle life and safety of rechargeable batteries. However, understanding gas-mediated (electro)-chemical reactions and nanoscale structural transformations during the synthesis of battery electrode materials remains challenging because of the lack of suitable characterization routes and the complexity of the interplay between thermodynamics and kinetics. Here, in this study, we use operando synchrotron X-ray diffraction, in situ transmission X-ray microscopy and multiscale modelling to elucidate the reaction pathways and microstructural defect development of earth-abundant Mn-rich layered oxides as positive electrode materials for sodium-based batteries. In particular, we demonstrate the dominant role of CO 2 over O 2 and H 2 O (g) in modulating the competition between entropy and enthalpy during solid-state synthesis. Using Ni 0.25 Mn 0.75 CO 3 as a model precursor, we reveal that CO 2 generation favours the formation of entropy-driven metastable intermediates, suppresses closed pore/nanovoids formation and decreases chemical heterogeneity and residual lattice strain of Mn-rich layered oxides during the synthesis. This result motivates a fast-sintering strategy to promote CO 2 release, which ultimately leads to improved chemo-mechanical and electrochemical stability of the Mn-rich positive electrodes when tested in non-aqueous Na metal coin cells.
Primary zinc-silver oxide battery - separator material, construction, and prototype cell evaluation
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High energy density primary battery development - anode-electrolyte, cupric fluoride cathode, and chemical stability tests
Highly conductive nonaqueous electrolytes for high energy battery
High energy density primary battery - film formation on cupric fluoride cathodes discharged in organic electrolytes
Zinc-silver oxide battery design for improved and activated charge retention, voltage control, and temperature stability
Design of silver oxide-zinc battery of limited cycle life with no degradation in discharge voltage characteristics
Electrochemical study of prospective electrode- electrolyte systems for high-energy primary battery with minimum of 200 watt hours per pound of total battery weight
High energy density primary battery development - electrochemical half-cell screening of anode- electrolyte combinations, cell discharge, and potential studies
Temperature of discharging high-power-density primary battery maintained below specified level by evaporation of suitable liquid from jacket surrounding battery, according to proposal. Pressure-relief valve regulates pressure and boiling temperature of liquid. Less material needed in cooling by vaporization than in cooling by melting. Technique used to cool batteries in situations in which engineering constraints on volume, mass, and location prevent attachment of cooling fins, heat pipes, or like.
Cathodic materials for high energy density storage battery
Determination of the number of micrometeoroid impact craters on the camera provided an opportunity to make a sensitive direct measurement of the flux of interplanetary dust particles impacting the lunar surface. Optical and scanning electron microscope studies were performed. Low velocity impact and flux analyses are presented.
Primary arcing induced by spacecraft charging presents a significant hazard to thin film solar cells if left unchecked. Here, we present the results of a preliminary effort to quantify the impacts of primary arcing to perovskite solar cells. Solar cells operating in a charged environment are susceptible to electrostatic discharges known as arcing. While primary arcs are not generally considered a major concern for traditional space PV, for thin film cells, these can induce significant heating and subsequent damage. We conducted ESD testing in a LEO-like plasma in the National Plasma Interaction Facility at NASA Glenn Research Center to quantify impacts to cell performance by arcing. The perovskites tested saw a decrease of short circuit current with an increased number of arcs, averaging a relative change of 73.89 ± 15.90% after 60 total arcs supplied a cumulative energy dose of 76.12 mJ to the string. Ongoing work entails testing with larger perovskite data sets and expanding to include additional thin film cell technologies to demonstrate the risk unmitigated primary arcing presents.
Evaluation of various anode-electrolyte and cathode-electrolyte combinations for high energy density battery
The role of the Power Branch/EP5 of JSC in primary battery applications is to support those JSC organizations having direct application responsibility with trade studies, battery selection recommendations, and with development, qualification, and provisioning of primary batteries. Battery subsystem management is provided. Payload hazard report preparation is supported, as is the review and comment of such reports for the JSC Payload Safety Panel, who approves the flight safety for all Orbiter payloads. JSC battery users are provided with safety analysis and test support to achieve safety approval. Finally, it is the responsibility of the Power Branch to define and maintain battery safety requirement documentation for JSC.
Lithium anodes, inorganic and organic cathodes, vacuum-distilled solvents, and methods for sintering cupric fluoride on lightweight metal substrates - development of high energy battery