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At least 37 records · Page 2

The binding energies of one and two water molecules to the first transition-row metal positive ions

The bonding of water to the transition metal positive ions is electrostatic in origin. The electrostatic bonding is enhanced by a variety of mechanisms: mixing in 4p character, 4s-3d hybridization, and 4s promotion into the compact 3d orbital. The importance of these effects varies between the different metal ions due to changes in the separation of the metal ion atomic states. Furthermore, the change in the metal-water repulsion when a second water is added also changes the relative importance of the different metal asymptotes. The second water binding energy varies from being 11 kcal/mol smaller than the first for Mn(+) to 3 kcal/mol larger for V(+) and Fe(+).

Rosi, Marzio↗

Excitation of positive ions by low-energy electrons - Relevance to the Io Torus

The importance of measuring electron-ion excitation cross sections in singly and multiply charged positive ions is outlined, and recent results for Mg II and O II ions are given using the JPL's electron energy-loss merged-beams apparatus. Theoretical comparisons are given with two five-state close-coupling calculations. The energy variation of the collision strength is fitted with a semiempirical analytic function which includes approximations to polarization, resonance, and exchange contributions. In O II, first spectra anywhere of electron excitation of the optically allowed transitions are presented. In addition, excitations of two low lying, optically forbidden transitions are detected for the first time.

Smith, Steven J.↗

The Giotto three-dimensional positive ion analyser

An instrument to measure the three-dimensional energy distribution of positive ions in order to study the interaction between the solar wind and ionized Halley cometary particles was designed. Two sensors measure the distribution from 10 eV to 20 keV once per spacecraft spin and the distribution from 90 eV to 90 keV, with coarse mass discrimination, once every 32 spins. The instrument was turned on September 8, 1985. The performance throughout all testing was nominal. The spacecraft was greater than 10 million km from the earth in the solar wind. The only population identified is the solar wind. The Fast Ion Sensor follows solar wind variations with its autoranging capability. The Implanted Ion Sensor identifies higher mass ions such as O(6+) and O(5+) in the solar wind.

Johnstone, A. D.↗