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Mineralogy and Petrography of MIL 090001, a Highly Altered CV Chondrite from the Reduced Sub-Group

MIL 090001 is a large (greater than 6 kg) CV chondrite from the reduced subgroup (CV(sub red)) that was recovered during the 2009-2010 ANSMET field season [1]. The CV(sub red) subgroup meteorites retain primitive characteristics and have escaped the Na and Fe meta-somatism that affected the oxidized (CV(sub ox)) subgroups. MIL 090001 is, however, reported to be altered [1], and thus a major objective of this study is to characterize its mineralogy and petrography and the extent of the alteration.

Keller, Lindsay P.↗

On the Relationship between Cosmic Ray Exposure Ages and Petrography of CM Chondrites

Carbonaceous (C) chondrites are potentially the most primitive among chondrites because they mostly escaped thermal metamorphism that affected the other chondrite groups. C chondrites are chemically distinguished from other chondrites by their high Mg/Si ratios and refractory elements, and have experienced various degrees of aqueous alteration. They are subdivided into eight subgroups (CI, CM, CO, CV, CK, CR, CB and CH) based on major element and oxygen isotopic ratios. Their elemental ratios vary over a wide range, in contrast to those of ordinary and enstatite chondrites which are relatively uniform. It is critical to know how many separate bodies are represented by the C chondrites. In this study we defined 4 distinct cosmic-ray exposure (CRE) age groups of CMs and systematically characterized the petrography in each of the 4 CRE age groups to determine whether the groups have significant petrographic differences with such differences probably reflecting different parent body (asteroid) geological processing, or multiple original bodies. We have reported the results of a preliminary grouping at the NIPR Symp. in 2013 [3], however, we revised the grouping and here report our new results.

Takenouchi, A.↗

Petrography and Geochemistry of Lunar Meteorite Miller Range 13317

Miller Range (MIL) 13317 is a 32-g lunar meteorite collected during the 2013-2014 ANSMET (Antarctic Search for Meteorites) field season. It was initially described as having 25% black fusion crust covering a light- to dark-grey matrix, with numerous clasts ranging in size up to 1 cm; it was tenta-tively classified as a lunar anorthositic breccia. Here we present the petrography and geochemistry of MIL 13317, and examine possible pairing relationships with previously described lunar meteorites.

Zeigler, R. A.↗

SEM petrography of dispersed organic matter in black shales: A review

Organic matter (OM)-hosted pores are important constituents of the pore system of black shales and play a crucial role in determining their methane adsorption capacity and porosity. OM-hosted pores are generally observed and described with scanning electron microscope (SEM) on Ar ion-milled surfaces. However, SEM imaging is not able to reliably distinguish OM types and relate the observed pores to specific macerals. Partly because of this inability to relate organic pores to macerals, the evolution of organic porosity during thermal maturation remains poorly understood. In this paper, we review the petrographic characteristics of dispersed organic matter (DOM) in black shales under the SEM. Organic petrographic classification of DOM developed for reflected-light microscopy is so far the most practical method when describing DOM in black shales under the SEM because this classification has information on the origin of DOM. Therefore, correlative microscopy (combination of reflected-light and electron microscopy) is the most effective method to identify both OM types and OM-hosted pores. This method, however, is not readily available to most researchers. Although identifying OM on the basis of SEM observations is a challenging task, it is achievable provided there is a good understanding of the studied shales, especially their thermal maturity and original OM composition. Therefore, the overall objective of this paper is to review petrographic characteristics of DOM in black shales under the SEM to provide some guidelines for identifying DOM from SEM observations. We also review factors that control the formation and preservation of OM-hosted pores. OM-hosted pores consist of primary and secondary organic pores. Primary organic pores are pores inherited from the biological structure of the original OM. Secondary organic pores develop during hydrocarbon generation and expulsion from oil-prone OM and are hosted by solid bitumen or pyrobitumen. The development of secondary organic pores is controlled by thermal maturity and OM type, and their preservation is subject to thermal maturity, OM content, and mineralogical composition. The presented view of the evolution of micropore and mesopore characteristics of OM with thermal maturity is based on data from the literature. The specific surface area and pore volume of OM in black shales follow a parabolic pattern with increasing thermal maturity (quantified via vitrinite reflectance, R o ). The initial increase reflects development of OM-hosted pores, and the subsequent decrease is due to denser stacking of aromatic units in the macromolecular structure of OM, with maximum values (specific surface area ~ 300 m 2 /g and pore volume ~ 0.3 cm 3 /g) reached at R o values in the 2.5-3.5% range. The contribution of OM-hosted pores to the pore characteristics of black shales depends on OM content, OM type, and thermal maturity.

03 NATURAL GAS↗

Physical properties, internal structure, and the three‐dimensional petrography of CI chondrites

physical properties and the nature of their breccation, we investigated nine samples of the Ivuna and Orgueil CI chondrites ranging in size from 1 mm to 4 cm in approximate diameter. The combined mass of unique material investigated in this work is 113 g. For our investigations, we use ideal gas pycnometry, 3-D laser scanning, x-ray computed microtomography (μCT), and accompanying digital data extraction techniques. We found that the bulk density of the samples ranged from 1.61 to 2.10 g cm −3 . Larger samples tend to have a lower bulk density. Grain density (ranging from 2.44 to 2.55 g cm −3 ) is significantly less variable than the bulk density in our samples and the quantity of porosity (ranging from 14.6% to 33.8%) is the dominant factor in determining the bulk density of CI chondrite material. Our μCT results show that the visible porosity across all sizes of our CI chondrite samples is in the form of cracks, but these cracks can account for less than two-thirds of the porosity in the CI chondrites. Other porosity is not visible, even at μCT resolutions of 2.7 μm voxel edge −1 and we conclude that it is sub-micron in nature. It is not clear if the cracks seen in our samples are indigenous to the chondrites or are a result of terrestrial processes. We also find that the CI chondrites are excellent examples of the fractal-like nature of brecciation, where clasts can be observed at all scales we imaged. The breccias are composed of sub-equant-shaped and sub-rounded-textured clasts like melt-free impact breccias on other solar system bodies. From our μCT volume and digital data extraction, we determine that the Ivuna CI chondrite breccia is organized: the mostly sub-equant clasts within our ~2 cm chunk of Ivuna have a mean diameter of 1.33 mm and their aligned longest axes define a lineation structure. We speculate that the lineation was imparted after fragmentation of the clasts by slight shear on the parent asteroid which could be the result of seismic-related granular flow or mild non-axial impact-related compaction. These data will help to place returned asteroidal material from asteroids 162173 Ryugu and 101955 Bennu and the CI chondrites into a mutual geological context.

CI chondrite↗

Vaterite Optical Petrography in Lake Sturgeon Otoliths

Vaterite occurring in fish otoliths exhibits plumose and spherulitic habits, the latter being like those grown from aqueous solutions. Vaterite spherulites are known to have sheaf-like texture and can be up to 100 μm in size. In thin section, the spherulites typically show uniaxial positive interference figures between cross-polarizers using a polarizing light microscope but without conoscopic or Bertrand lenses because the spherulites mimic the effect of these lenses. Plumose vaterite can show both uniaxial (+) and biaxial (+) interference figures with a small 2V, which suggests that crystal structural models for vaterite should have the plane of the carbonate group parallel to the optic axis or acute bisectrix. Finally, vaterite spherulites grown from aqueous solution exhibit similar structure and growth habits.

58 GEOSCIENCES↗

Luminescence petrography of lunar samples

Light-colored metaclastic rock fragments, mainly anorthositic breccias, are dominant in the lithic clasts of rock 14321 and constitute about 25% of the Apollo 14 soils. Concentration of anorthositic breccias is less in the Apollo 15 soils, but is higher in the Front samples. The Rille edge soils are rich in basalt fragments. The Apollo 15 soils are also rich in green glasses. True anorthosites in the Hadley region were found only at the St. George Crater site. Varying degrees of metamorphism were found in the anorthositic fragments, and luminescence zonations give independent evidence of metamorphism. Compositional zoning verifies the interpretation of luminescence. Rock 14321 gives evidence of modest annealing, but the light metaclastic fragments were metamorphosed before incorporation into the rock. Reaction rimming on plagioclase results in mosaicism and preferentially affects grains. The spectral analysis of luminescence in plagioclase shows that a red-infrared emission band is present in a small fraction of plagioclase grains. Samples from trench bottoms and from beneath a large boulder were compared with surface samples. Large variations in soil composition indicate marked layering in the Apollo 15 soils.

Source record↗

Electron petrography of Apollo sample 14310.

Thin sections prepared from Apollo sample 14310 have been examined with 100-kV transmission electron microscopy. The sample is composed principally of anorthite and pyroxene. The anorthites fall into two categories. The transitional anorthites that show the characteristic 'c' type diffraction maxima are characterized by very fine antiphase domain structures and some fine twinning. The body-centered anorthites that show no 'c' reflections are characterized by an absence of fine twinning and a less well-defined antiphase domain structure. Although both orthopyroxene and clinopyroxenes are reported in sample 14310, only clinopyroxenes were observed in this study and all show exsolution structures. The augite exsolved in pigeonite commonly is along lamellae parallel to (100), although (001) lamellae are also present. This unusual orientation was verified by diffraction patterns. The pigeonite commonly shows antiphase domains, attributed to stacking errors when the sample inverted from its high-temperature disordered form. In augite as the host phase, the pigeonite lamellae contain very complex structures including antiphase domains.

Smith, D. K.↗

Electron petrography of Apollo 14 and 15 rocks.

Comparative optical and high-voltage electron petrographic analyses of igneous rocks and several types of breccias the Fra Mauro and Apennine sites of Apollo 14 and 15 are reported and interpreted. The crystalline rocks are found to differ substantially from the Apollo 11 and 12 basalts. Substructures in the Apollo 14 breccias are complex. At least two bonding mechanisms can be discerned from the electron petrographic examination: (a) 'shock sintering' due to high pressures and temperatures associated with the shock waves of meteoritic impacts; and (b) lithification by glass bonding.

Lally, J. S.↗

The age and petrography of two Luna 20 fragments and inferences for widespread lunar metamorphism.

Ages were determined by the Ar-40/Ar-39 method on two metaclastic rocks returned from the lunar highlands north of Mare Fecunditatis by the Luna 20 probe. Both samples gave very well-defined argon retention ages of 3.90 plus or minus 0.04 AE which are indistinguishable from each other within a resolution of 0.02 AE. Both fragments, 22006 and 22007, are highly recrystallized polymict breccias; there is no evidence of radiogenic Ar-40, and the age almost surely dates the time of recrystallization. The cosmic ray exposure ages of these fragments are similar and high: 900 million years for 22006, 1300 million years for 22007. 22007 also contains substantial trapped argon with a high Ar-40/Ar-36. The Luna 20 results greatly extend the area of the moon's surface exhibiting a well-defined record of metamorphism at 3.9 AE. So far, lunar history in the interval from 4.6 to 3.9 AE is not preserved in the ages of surface rocks. This obliteration suggests lunar-wide metamorphic conditions occurring or terminating at this time as a result of major impacts.

Podosek, F. A.↗

Apollo 16 soils - Grain size analyses and petrography

Soils from South Ray Crater, North Ray Crater, and the interray area of Station 10 have a similar provenance, containing breccia fragments of low to medium metamorphic grade and low light/dark lithic fragment ratios; these appear to be characteristic of the Cayley Formation. The primary difference between soils possibly derived from North Ray and South Ray craters is in the agglutinate content. A soil from Stone Mountain (Station 4) is characterized by breccia fragments of medium to high metamorphic grade and a high light/dark lithic fragment ratio; this soil may be derived from the Descartes Formation. Differences between the selenomorphic units, the Descartes and Cayley formations, may be lithologic as well as structural. The mean grain size varies from 84 to 280 microns, and all of the samples are poorly to very poorly sorted. There appears to be a relation between the sorting, grain size, and agglutinate content, with the finer-grained, better sorted soils containing more than 30% agglutinates. 'Shadowed' soils, collected close to large boulders, are similar in all respects to the 'reference' soils collected at least 5 m from the boulders.

Heiken, G. H.↗