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Extinction parameters of submicron carbon, tungsten and Si particles in hydrogen measured at various temperatures, discussing scattering amplitude functions and Monte Carlo calculations
Extinction parameters of submicron carbon, tungsten and Si particles in hydrogen measured at various temperatures, discussing scattering amplitude functions and Monte Carlo calculations
The feasibility of developing a method for making monodisperse, unagglomerated spherical particles greater than 50 nm in diameter was demonstrated. Carbonaceous particles were made by pyrolyzing ethylene with a pulsed CO2 laser, thereby creating a non-equilibrium mixture of carbon, hydrogen, hydrocarbon vapors, and unpyrolyzed ethylene. Via a complex series of reactions, the carbon and hydrocarbon vapors quickly condensed into the spherical particles. By cooling and dispersing them in a supersonic expansion immediately after their creation, the hot newly-formed spheres were prevented from colliding and coalescing, thus preventing the problem of agglomeration which as plagued other investigators studying laser-simulated particle formation. The cold particles could be left suspended in the residual gases indefinitely without agglomerating. Their uniform sizes and unagglomerated nature were visualized by collecting the particles on filters that were subsequently examined using electron microscopy. It was found the mean particle size can be coarsely controlled by varying the initial ethylene pressure, and can be finely controlled by varying the fluence (energy/unit area) with which the laser irradiates the gas. The motivating application for this research was to manufacture particles that could be used as laser Doppler velocimetry (LDV) seeds in high-temperature high-speed flows. Though the particles made in this program will not evaporate until heated to about 3000 K, and thus could serve as LDV seeds in some applications, they are not ideal when the hot atmosphere is also oxidizing. In that situation, ceramic materials would be preferable. Research performed elsewhere has demonstrated that selected ceramic materials can be manufactured by laser pyrolysis of appropriate supply gases. It is anticipated that, when the same gases are used in conjunction with the rapid cooling technique, unagglomerated spherical ceramic particles can be made with little difficulty. Such particles would also be valuable to manufacturers of ceramic or abrasive products, and this technique may find its greatest commercial potential in those areas.
Kaoline, a hydrated aluminum silicate clay, is investigated as a seeding material for laser velocimetry. It is inexpensive but is polydispersed with some of the fineparticles being too large to follow wind tunnel flow and is in the form of nonspherical platelets having an aspect ratio of approximately 4/1. Gravity sedimentation experiments as a means of narrowing the fineparticle sizes distribution are being conducted. The fineparticle size distribution of Engelhard ASP 200 kaolin suspended in ethanol (0.00792 grams kaolin/ml ethanol) as received, after 24 hours gravity sedimentation and after 48 hours sedimentation, respectively is shown. A shearing atomizer is used to inject the fineparticles. Gravity sedimentation is carried out in an 800 ml pyrex beaker. Following gravity sedimentation, the top 3.5 inches are siphoned from the liquid, which has a column height of 4.5 inches. In a like manner, longer settling times will serve to further narrow the fineparticle distribution range. As successive sedimentations are effected, the number of fineparticles per unit volume of ethanol decreased markedly.
Researchers at the NASA Langley Research Center are applying laser velocimetry (LV) techniques to characterize the fluid dynamics of non-isothermal flows inside fused silica chambers designed for chemical vapor deposition (CVD). Experimental issues involved in the application of LV techniques to this task include thermophoretic effects on the LV seed particles, seeding the hazardous gases, index of refraction gradients in the flow field and surrounding media, optical access, relatively low flow velocities, and analysis and presentation of sparse data. An overview of the practical difficulties these issues represent to the use of laser velocimetry instrumentation for CVD applications is given. A fundamental limitation on the application of LV techniques in non-isothermal systems is addressed which involves a measurement bias due to the presence of thermal gradients. This bias results from thermophoretic effects which cause seed particle trajectories to deviate from gas streamlines. Data from a research CVD reactor are presented which indicate that current models for the interaction of forces such as Stokes drag, inertia, gravity, and thermophoresis are not adequate to predict thermophoretic effects on particle-based velocimetry measurements in arbitrary flow configurations.
For many years, the Vortex Research Facility used kerosene vapor as seeding particles. The kerosene vapor formed (approx. 1 micron) particles initially. After injection into the test section, the vapor would begin to condense and form larger particles. By switching to solid particles, this has been eliminated. The uniform-sized (approx. 1 micron) solid particle seeding is used both to seed the Laser Velocimeter system and for flow visualization. After injection, the solid particles reach a uniform suspension before the vehicle is launched. It is found that the kerosene vapor poses a problem because it is a heated gas which modified the test section temperature distribution. It also produces high turbulence and secondary air currents because it was continually injected from the time of vehicle launch until model passage. In cases where the effects of either turbulence or the vertical temperature distribution are of interest, this hot gas injection method is unsuitable. Both types of seeding particles provide adequate flow visualization but are sensitive to vertical temperature distributions.
We have initiated an experimental program to develop an ultrasound system for non-intrusively imaging the thermal field in opaque fluids under an externally imposed temperature gradient. Many industrial processes involve opaque fluids, such as molten metals, semiconductors, and polymers, often in situations in which thermal gradients are important. For example, one may wish to understand semiconductor crystal growth dynamics in a Bridgman apparatus. Destructive testing of the crystal after the process is completed gives only indirect information about the fluid dynamics of the formation process. Knowledge of the coupled thermal and velocity fields during the growth process is then essential. Most techniques for non-intrusive velocity and temperature measurement in fluids are optical in nature, and hence the fluids studied must be transparent. In some cases (for example, LDV (laser Doppler velocimetry) and PIV (particle imaging velocimetry)) the velocities of small neutrally buoyant seed particles suspended in the fluid, are measured. Without particle seeding one can use the variation of the index of refraction of the fluid with temperature to visualize, through interferometric, Schlieren or shadowgraph techniques, the thermal field. The thermal field in turn gives a picture of the pattern existing in the fluid. If the object of study is opaque, non-optical techniques must be used. In this project we focus on the use of ultrasound, which propagates easily through opaque liquids and solids. To date ultrasound measurements have almost exclusively relied on the detection of sound scattered from density discontinuities inside the opaque material of interest. In most cases it has been used to visualize structural properties, but more recently the ultrasound Doppler velocimeter has become available. As in the optical case, it relies on seed particles that scatter Doppler shifted sound back to the detector. Doppler ultrasound techniques are, however, not useful for studying convective fluid flow in crystal growth, because particle seeding is unacceptable and flow velocities are typically too low to be resolved, and may be even lower in microgravity conditions where buoyancy forces are negligible. We will investigate a different use of ultrasound to probe the flows of opaque fluids non-intrusively and without the use of seed particles: our goal is to ultrasonically visualize the thermal field of opaque fluids with relatively high spatial resolution. The proposed technique relies upon the variation of sound speed with temperature of the fluid. A high frequency ultra-sound pulse passing through a fluid-filled chamber will traverse the chamber in a time determined by the relevant chamber dimension and the temperature of the fluid through which the pulse passes. With high time-resolution instrumentation that compares the excitation signal with the received pulse we can detect the influence of the fluid temperature on the pulse travel time. This is effectively an interferometric system, which in its optical form is an extremely sensitive approach to measuring thermal fields in fluids. Moreover, the temperature dependence of sound velocity in liquid metals is comparable to the temperature dependence of the speed of light required for accurate interferometric thermal images in transparent fluids. With an array of transducers scanned electronically a map of the thermal field over the chamber could be produced. An alternative approach would be to use the ultrasound analog of the shadowgraph technique. In the optical version, collimated light passes through the fluid, where it is focused or defocused locally by temperature field induced variations of the index of refraction. The resulting image reveals the thermal field through the spatial pattern of light intensity variations. By analogy, an ultrasound plane wave traversing an opaque fluid sample would be also locally focused or defocused depending on the speed of sound variations, giving rise to spatial variations in sound intensity that will reveal the thermal field pattern. These approaches could be applied to any situation in which temperature differences are expected to occur, and will rapidly provide information about the flow that simply cannot be obtained by any current intrusive or non-intrusive diagnostic technique. As materials processing in microgravity matures it will become increasingly important to have available simple and versatile diagnostic tools, such as we will develop, for studying the flows of opaque fluids under thermal forcing.
A process and apparatus for thermally decomposing silicon containing gas for deposition on fluidized nucleating silicon seed particles is disclosed. Silicon seed particles are produced in a secondary fluidized reactor by thermal decomposition of a silicon containing gas. The thermally produced silicon seed particles are then introduced into a primary fluidized bed reactor to form a fluidized bed. Silicon containing gas is introduced into the primary reactor where it is thermally decomposed and deposited on the fluidized silicon seed particles. Silicon seed particles having the desired amount of thermally decomposed silicon product thereon are removed from the primary fluidized reactor as ultra pure silicon product. An apparatus for carrying out this process is also disclosed.
A process and apparatus for thermally decomposing silicon containing gas for deposition on fluidized nucleating silicon seed particles is disclosed. Silicon seed particles are produced in a secondary fluidized reactor by thermal decomposition of a silicon containing gas. The thermally produced silicon seed particles are then introduced into a primary fluidized bed reactor to form a fludized bed. Silicon containing gas is introduced into the primary reactor where it is thermally decomposed and deposited on the fluidized silicon seed particles. Silicon seed particles having the desired amount of thermally decomposed silicon product thereon are removed from the primary fluidized reactor as ultra pure silicon product. An apparatus for carrying out this process is also disclosed.
The laser velocimeter (LV) is a unique tool for fluid flow measurements. In such measurements, even though the fluid velocity is of primary interest, the LV signal originates from seed particles present in the fluid and the LV actually measures the velocity of these particles. Thus it is important that a sufficient number of seed particles be present in the fluid and they scatter sufficient light to produce LV signals. Also, the seed particles should follow the fluid with high fidelity. Aerodynamic diameter is the true measure of a particle's ability to follow the flow. The aerodynamic diameter of a particle is defined as the diameter of a unit density sphere with same settling velocity as the particle in question. It is affected by geometric diameter, density and shape of the particle. For LV seeding, particles with smaller aerodynamic diameter are desirable because they follow the flow more readily. On the other hand, in general, the particle's ability to scatter light increases with its geometric diameter and its refractive index.
A combined experimental and detailed numerical study was conducted on the interaction between chemically inert solid particles and strained, atmospheric methane/air and propane/air laminar flames, both premixed and non-premixed. Experimentally, the opposed jet configuration was used with the addition of a particle seeder capable of operating in conditions of varying gravity. The particle seeding system was calibrated under both normal and micro gravity and a noticeable gravitational effect was observed. Flame extinction experiments were conducted at normal gravity by seeding inert particles at various number densities and sizes into the reacting gas phase. Experimental data were taken for 20 and 37 (mu) nickel alloy and 25 and 60 (mu) aluminum oxide particles. The experiments were simulated by solving along the stagnation streamline the conservation equations of mass, momentum, energy, and species conservation for both phases, with detailed descriptions of chemical kinetics, molecular transport, and thermal radiation. The experimental data were compared with numerical simulations, and insight was provided into the effects on extinction of the fuel type, equivalence ratio, flame configuration, strain rate. particle type. particle size. particle mass, delivery rate. the orientation of particle injection with respect to the flame and gravity. It was found that for the same injected solid mass, larger particles can result in more effective flame cooling compared to smaller particles, despite the fact that equivalent masses of the larger particles have smaller total surface area to volume ratio. This counter-intuitive finding resulted from the fact that the heat exchange between the two phases is controlled by the synergistic effect of the total contact area and the temperature difference between the two phases. Results also demonstrate that meaningful scaling of interactions between the two phases may not be possible due to the complexity of the couplings between the dynamic and thermal parameters of the problem.
The application of Doppler Global Velocimetry (DGV) to high-speed flows has its origins in the original development of the technology by Komine et al (1991). Komine used a small shop-air driven nozzle to generate a 200 m/s flow. This flow velocity was chosen since it produced a fairly large Doppler shift in the scattered light, resulting in a significant transmission loss as the light passed through the Iodine vapor. This proof-of-concept investigation showed that the technology was capable of measuring flow velocity within a measurement plane defined by a single-frequency laser light sheet. The effort also proved that velocity measurements could be made without resolving individual seed particles as required by other techniques such as Fringe- Type Laser Velocimetry and Particle Image Velocimetry. The promise of making planar velocity measurements with the possibility of using 0.1-micron condensation particles for seeding, Dibble et al (1989), resulted in the investigation of supersonic jet flow fields, Elliott et al (1993) and Smith and Northam (1995) - Mach 2.0 and 1.9 respectively. Meyers (1993) conducted a wind tunnel investigation above an inclined flat plate at Mach 2.5 and above a delta wing at Mach 2.8 and 4.6. Although these measurements were crude from an accuracy viewpoint, they did prove that the technology could be used to study supersonic flows using condensation as the scattering medium. Since then several research groups have studied the technology and developed solutions and methodologies to overcome most of the measurement accuracy limitations:
High-speed laminar-to-turbulent transition and turbulence affect the control of flight vehicles, the heat transfer rate to a flight vehicle's surface, the material selected to protect such vehicles from high heating loads, the ultimate weight of a flight vehicle due to the presence of thermal protection systems, the efficiency of fuel-air mixing processes in high-speed combustion applications, etc. Gaining a fundamental understanding of the physical mechanisms involved in the transition process will lead to the development of predictive capabilities that can identify transition location and its impact on parameters like surface heating. Currently, there is no general theory that can completely describe the transition-to-turbulence process. However, transition research has led to the identification of the predominant pathways by which this process occurs. For a truly physics-based model of transition to be developed, the individual stages in the paths leading to the onset of fully turbulent flow must be well understood. This requires that each pathway be computationally modeled and experimentally characterized and validated. This may also lead to the discovery of new physical pathways. This document is intended to describe molecular based measurement techniques that have been developed, addressing the needs of the high-speed transition-to-turbulence and high-speed turbulence research fields. In particular, we focus on techniques that have either been used to study high speed transition and turbulence or techniques that show promise for studying these flows. This review is not exhaustive. In addition to the probe-based techniques described in the previous paragraph, several other classes of measurement techniques that are, or could be, used to study high speed transition and turbulence are excluded from this manuscript. For example, surface measurement techniques such as pressure and temperature paint, phosphor thermography, skin friction measurements and photogrammetry (for model attitude and deformation measurement) are excluded to limit the scope of this report. Other physical probes such as heat flux gauges, total temperature probes are also excluded. We further exclude measurement techniques that require particle seeding though particle based methods may still be useful in many high speed flow applications. This manuscript details some of the more widely used molecular-based measurement techniques for studying transition and turbulence: laser-induced fluorescence (LIF), Rayleigh and Raman Scattering and coherent anti-Stokes Raman scattering (CARS). These techniques are emphasized, in part, because of the prior experience of the authors. Additional molecular based techniques are described, albeit in less detail. Where possible, an effort is made to compare the relative advantages and disadvantages of the various measurement techniques, although these comparisons can be subjective views of the authors. Finally, the manuscript concludes by evaluating the different measurement techniques in view of the precision requirements described in this chapter. Additional requirements and considerations are discussed to assist with choosing an optical measurement technique for a given application.
The introduction of non-intrusive measurement techniques in wind tunnel experimentation has been a turning point in error free data acquisition. Laser velocimetry has been progressively implemented and utilized in various wind tunnels; e.g. subsonic, transonic, and supersonic. The success of the laser velocimeter technique is based on an accurate measurement of scattered light by seeding particles introduced into the flow stream in the wind tunnel. Therefore, application of appropriate seeding particles will affect, to a large extent the acquired data. The seeding material used depends on the type of experiment being run. Among the seeding material for subsonic tunnel are kerosene, Kaolin, and polystyrene. Polystyrene is known to be the best because of being solid particles, having high index of refraction, capable of being made both spherical and monodisperse. However for high temperature wind tunnel testing seeding material must have an additional characteristic that is high melting point. Typically metal oxide powders such as Al2O3 with melting point 3660 F are used. The metal oxides are, however polydispersed, have a high density, and a tendency to form large agglomerate that does not closely follow the flow velocity. The addition of flame phase silica to metal oxide helps to break up the agglomerates, yet still results in a narrow band of polydispersed seeding. The less desirable utility of metal oxide in high temperature wind tunnels necessitates the search for a better alternative particle seeding which this paper addresses. The Laser Velocimetry (LV) characteristic of polystyrene makes it a prime candidate as a base material in achieving the high temperature particle seeding inexpensively. While polystyrene monodisperse seeding particle reported has been successful in a subsonic wind tunnel, it lacks the high melting point and thus is not practically usable in a high temperature wind tunnel. It is well known that rise in melting point of polystyrene can be achieved by a cross-linking technique. Since polystyrene already possesses all the desired characteristics for LV, to circumvent the low melting point, a cross-linking technique was investigated.
Monodisperse latexes having a particle size in the range of 2 to 40 microns are prepared by seeded emulsion polymerization in microgravity. A reaction mixture containing smaller monodisperse latex seed particles, predetermined amounts of monomer, emulsifier, initiator, inhibitor and water is placed in a microgravity environment, and polymerization is initiated by heating. The reaction is allowed to continue until the seed particles grow to a predetermined size, and the resulting enlarged particles are then recovered. A plurality of particle-growing steps can be used to reach larger sizes within the stated range, with enlarge particles from the previous steps being used as seed particles for the succeeding steps. Microgravity enables preparation of particles in the stated size range by avoiding gravity related problems of creaming and settling, and flocculation induced by mechanical shear that have precluded their preparation in a normal gravity environment.
Due to the failure of existing seeders to meet the stringent specifications required for benchmark experiments in high pressure, high temperature, rapidly accelerating flowfields, an effort is made to improve an existing solid particle seeder. The goal is to produce a more monodisperse seed from the 0.3 micro alumina powder with more than 99 percent of the particles in the submicron range while maintaining a high seeding rate. Coiled-wire inserts are installed within the ends of the nitrogen injection lines in the primary seeder to produce swirling conical jets to vigorously agitate the seed bed. A secondary swirler, constructed from a 25 cm length of 3.8 cm ID steel pipe having threaded end caps, is connected to the output line of the primary seeder. The seeded nitrogen from the primary seeder is injected tangentially at near sonic velocity into the secondary swirler 9.4 cm above its base. Independently controlled auxiliary nitrogen used to increase the swirl in the secondary chamber is also injected tangentially 2.5 cm below the seeded nitrogen lines. Large seed particles are collected by bleeds in the swirler cap and directed overboard. The remaining seeded nitrogen is collected on the center line of the secondary swirler and ducted to the rig.
Discovery by Cassini's plasma instrument of heavy positive and negative ions within Titan's upper atmosphere and ionosphere has advanced our understanding of ion neutral chemistry within Titan's upper atmosphere, primarily composed of molecular nitrogen, with approx.2.5% methane. The external energy flux transforms Titan's upper atmosphere and ionosphere into a medium rich in complex hydrocarbons, nitriles and haze particles extending from the surface to 1200 km altitudes. The energy sources are solar UV, solar X-rays, Saturn's magnetospheric ions and electrons, solar wind and shocked magnetosheath ions and electrons, galactic cosmic rays (CCR) and the ablation of incident meteoritic dust from Enceladus' E-ring and interplanetary medium. Here it is proposed that the heavy atmospheric ions detected in situ by Cassini for heights >950 km, are the likely seed particles for aerosols detected by the Huygens probe for altitudes <100km. These seed particles may be in the form of polycyclic aromatic hydrocarbons (PAH) containing both carbon and hydrogen atoms CnHx. There could also be hollow shells of carbon atoms, such as C60, called fullerenes which contain no hydrogen. The fullerenes may compose a significant fraction of the seed particles with PAHs contributing the rest. As shown by Cassini, the upper atmosphere is bombarded by magnetospheric plasma composed of protons, H(2+) and water group ions. The latter provide keV oxygen, hydroxyl and water ions to Titan's upper atmosphere and can become trapped within the fullerene molecules and ions. Pickup keV N(2+), N(+) and CH(4+) can also be implanted inside of fullerenes. Attachment of oxygen ions to PAH molecules is uncertain, but following thermalization O(+) can interact with abundant CH4 contributing to the CO and CO2 observed in Titan's atmosphere. If an exogenic keV O(+) ion is implanted into the haze particles, it could become free oxygen within those aerosols that eventually fall onto Titan's surface. The process of freeing oxygen within aerosols could be driven by cosmic ray interactions with aerosols at all heights. This process could drive pre-biotic chemistry within the descending aerosols. Cosmic ray interactions with grains at the surface, including water frost depositing on grains from cryovolcanism, would further add to abundance of trapped free oxygen. Pre-biotic chemistry could arise within surface microcosms of the composite organic-ice grains, in part driven by free oxygen in the presence of organics and any heat sources, thereby raising the astrobiological potential for microscopic equivalents of Darwin's "warm ponds" on Titan.
An experimental study of the horizontal Bridgman growth of pure succinonitrile (SCN) and of a succinonitrile-1.0 mol.% acetone alloy (SCN-1.0 mol.% ACE) has been performed. Experiments involving both a stationary thermal field (no-growth case) and a translating thermal field (growth case) were conducted. Growth rates of 2 and 40 micrometers/s were investigated. For the pure SCN experiments, the velocity field in the melt was estimated using video images of seed particles in the melt. Observations of the seed particles indicate that a primary longitudinal convective cell is formed. The maximum velocity of two different particles which traveled along similar paths was the same and equal to 1.49 +/- 0.01 mm/s. The general accuracy of velocity measurements is estimated to be +/- 0.08 mm/s, though the data shows consistency to within +/- 0.02 mm/s. The shape of the solid/liquid interface was also quantitatively determined. The solid/liquid interface was stable (non-dendritic and non-cellular) but not flat; rather it was significantly distorted by the influence of convection in (he melt and, for the growth case, by the moving temperature boundary conditions along the ampoule. It was found that the interface shape and position were highly dependent on the alignment of the ampoule in the apparatus. Consequently, the ampoule was carefully aligned for all experiments. The values for front location agree with those determined in previous experiments. For the alloy experiments, the solid/liquid interface was determined to be unstable at growth rates greater than 2.8 micrometers/s, but stable for the cases of no-growth and growth at 2 micrometers/s. When compared to the shape of the pure SCN interface, the alloy interface forms closer to the cold zone, indicating that the melting temperature decreased due to the alloying element. Extensive temperature measurements were performed on the outside of the ampoule containing pure SCN. The resulting thermal profiles are presented in detail in the results section. It is intended that the interface shape, thermal boundary condition and velocity data presented in this paper be used to test numerical simulations.