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36 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Survey of baffle plate samples, specimen machining, and hydrogen measurements

This report outlines preliminary results on the survey and characterization of irradiated baffle plate, baffle former, and flux thimble tube specimens as part of the ongoing investigation into irradiation-induced embrittlement in austenitic stainless steels at ambient (room temperature) conditions. The specimens originated from commercial pressurized water reactor (PWR) components, covering displacement damage doses ranging from approximately 0.065 to 75 dpa. Initial scanning electron microscopy (SEM) surveys revealed that specimen surfaces exhibited fine machining marks and in-service-formed oxide layers on the side surfaces of the analyzed specimens. The oxide layers revealed specific features resembling localized "pitting-like" corrosion. An additional set of specimens representing in-service oxidation is being preserved for future microstructure analysis work. As believed, this will provide additional insights into long-term material degradation in PRWs. Specimen machining challenges emerged due to a complex failure of the electric discharge machining (EDM) system located in hot area. Despite partial restoration, issues persist with the EDM’s secondary power supply, necessitating the exploration of alternative EDM or computer numerical control (CNC) machining approaches to facilitate tensile specimen preparation. Currently, low speed saw cutting is in progress to prepare specimens for hydrogen measurements and general microstructure analysis. The near-term goals include completing tensile specimen machining for advanced mechanical testing and characterizing fracture mechanisms, and stress-corrosion cracking testing, ultimately aiming to identify and mitigate the ambient-condition intergranular cracking through targeted post-irradiation annealing strategies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Quantifying the Reactivity of Isolated Li x Si Domains in Si Anodes Using Operando NMR

The use of Si anodes can greatly improve the energy density of Li-ion batteries. However, understanding and mitigation of calendar aging remains a barrier to commercialization. Here, in this short report, we utilize operando Nuclear Magnetic Resonance (NMR) spectroscopy to detect and quantify lithium silicides (Li x Si) as they form and react within Si anodes in pouch cells during calendar aging. We provide direct experimental evidence of complex aging phenomena in the Si anodes, including both SEI growth and dissolution during storage. Formation of electrochemically isolated Li x Si is also observed, as indicated by the partial persistence of highly lithiated phases after the cell is discharged. Remarkably, we show that these isolated domains can themselves self-discharge over time, suggesting that their detection can be challenging in post-mortem studies. Finally, we show that aging outcomes depend heavily on the type of silicon particles contained within the electrode, and that certain surface coatings can help decrease the reactivity between lithium silicides and the electrolyte.

Li-ion battery↗
DOE OSTI2025

First simultaneous observation of co- and counter-current fast-ion losses in the ASDEX Upgrade tokamak

In ITER and future fusion power plants, the source of the fusion born alpha particles is almost isotropic in pitch angle, thus having co- and counter-current populations. For trapped ions, the co-current side of the orbit corresponds to its outer leg, while the counter-current side corresponds to the inner leg. Understanding the mechanisms responsible for the fast-ion losses (FILs) is critical for future magnetically confined fusion power plants. To further study the interplay of fast ions with plasma instabilities, a double pinhole collimator has been developed for a Fast-Ion Loss Detector (FILD) in the ASDEX Upgrade tokamak (AUG). This new FILD opens the operational window to simultaneous measurements of the co- and counter-current ion velocity-space. In this paper, the first results for the AUG double collimator FILD detector are shown. The commissioning of this new probe is carried out in H-mode plasmas with an on-axis magnetic field $B_0 = -2.5$ T, and a plasma current $I_{\textrm{p}} = 0.7$ MA. Simultaneous co- and counter-current FILs have been measured. Both have shown a similar dependence on Ion Cyclotron Resonance Heating (ICRH) power, where the main difference is the intensity of the losses, with the co-losses being an order of magnitude larger. Toroidal Alfvén eigenmode-coherent ICRH-only losses have been identified for the co-current ions. Additionally, the presence of Edge Localized Modes during the discharge were shown to increment Neutral Beam Injection prompt losses, while partially mitigating ICRH-driven losses on both co- and counter- sides of the velocity-space. Finally, a very trapped and high gyroradius losses, with an unclear origin, have been measured in the co- and counter-current velocity-space. The computed ion trajectories show that these ions remain permanently near the vessel wall, suggesting that they are accelerated within the scrape-off layer.

ELM↗
DOE OSTI2026

Performance Characterization of InCharge™ ICE-66 V2X Bidirectional DC Fast Charger

Vehicle-to-grid (V2G) technology extends the role of Plug-in Hybrid Vehicle’s (PHEV) and Battery Electric Vehicle’s (BEV) batteries beyond transportation by enabling bidirectional power transfer between the vehicle's onboard energy storage and the utility grid. Modern battery-powered vehicles are equipped with high-capacity battery packs that remain stationary and underutilized for the majority of their operational life. A vehicle used for daily commuting may be parked and connected to charging infrastructure for 18–20 hours per day, representing a significant untapped energy resource. When considered at scale, the aggregated storage capacity of a modest fleet of 10–15 vehicles within a single parking facility can reach the MWh range, sufficient to partially offset peak demand for a mid-size commercial building or contribute meaningful ancillary services to the local grid. The ability to charge during off-peak periods when electricity prices are low and discharge during peak demand when prices are high positions EV batteries as distributed energy arbitrage assets, with the potential to offset vehicle ownership and charging costs. Beyond energy arbitrage, V2G-capable assets can provide ancillary grid services through active and reactive power injections. Active power supports grid frequency regulation, while reactive power supports local voltage regulation. Together, these capabilities establish V2G as a technically promising and economically relevant pathway toward greater integration of battery-powered vehicles into the broader energy system.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2026

Partially Ionized Plasma Physics and Technological Applications

Partially ionized plasma physics has attracted increased attention recently due to numerous technological applications made possible by the increased sophistication of computer modelling, the depth of the theoretical analysis, and the technological applications to a vast field of manufacturing for computer components. Partially ionized plasma is characterized by a significant presence of neutral particles in contrast to the fully ionized plasma. The theoretical analysis is based upon solutions of the kinetic Boltzmann equation, yielding the non-Maxwellian electron energy distribution function (EEDF), thereby emphasizing the difference with a fully ionized plasma. The impact of the effect on discharges in inert and molecular gases is described in detail, yielding the complex nonlinear phenomena resulting in plasma selforganization. A few examples of such phenomena are given, including the non-monotonic EEDFs in the discharge afterglow in a mixture of argon with the molecular gas NF3; the explosive generation of cold electron populations in capacitive discharges, hysteresis of EEDF in inductively coupled plasmas. Recently, highly advanced computer codes were developed in order to address the outstanding challenges in plasma technology. These developments are briefly described in general terms.

non-Maxwellian electron energy distribution functi↗
DOE OSTI2025

Toward Stable, High‐Energy, Partially Disordered Mn‐Rich Spinel Cathodes by Revealing and Mitigating Surface Degradation

Mn-rich cathodes balance performance and sustainability but suffer from limited cyclability due to Mn dissolution and cathode-to-anode crosstalk. The Jahn-Teller (J-T) effect of Mn 3+ is often linked to the above phenomena, such as in spinel LiMn 2 O 4 . However, in typical voltage ranges, significant Mn 3+ only appears near the end of discharge, highlighting the need to reassess its role in driving Mn dissolution, structural degradation, and battery performance. Here, the spinel cathode's degree of disorder is tailored to expand the Mn redox range, enabling segmentation into J-T active and less active voltage ranges. Cycling at segmented voltage windows reveals surface degradation mechanisms with and without the major J-T effect. Despite a stronger J-T effect below 3.6 V vs. Li/Li + , Mn dissolution is less significant than above 3.6 V. Expanding the cycling window to 2.0–4.3 V causes severe degradation as the J-T active range induces a tetragonal phase and Mn 2+ -rich surface, driving Mn dissolution and consuming Li-ion inventory in full cells. Reducing electrolyte acidity minimizes Mn 3+ disproportionation, enabling a stable dopant-free Mn-only cathode with a 250 mAh g −1 specific capacity. These findings demonstrate that full cells using Mn-rich cathodes have the potential to avoid the notorious crosstalk problem through electrolyte engineering.

25 ENERGY STORAGE↗
DOE OSTI2026

pCAM precursor produced from electroextraction technology and its application in synthesis of NMC 811 cathode material

The synthesis and characterization of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (LNMC811) cathodes produced from recycled hydroxide precursors obtained from spent lithium-ion batteries is evaluated. Two precursor batches (Sample 1 and Sample 2) are prepared using modified recycling processes to examine how residual impurities and processing conditions influence the properties of the regenerated materials. Structural and compositional characterization by X-ray diffraction, ICP and SEM shows that the recycled precursors exhibit layered hydroxide structures containing both α Ni(OH) 2 and β Ni(OH) 2 phases. Trace impurities including sodium, boron, and aluminum are detected and partially mitigated during processing, with boron found to play a beneficial role in electrochemical behavior. Following lithiation with lithium carbonate and lithium hydroxide at 800 °C under an oxygen rich atmosphere, the resulting LNMC811 materials show electrochemical performance comparable to conventionally synthesized cathodes. Sample 2, which contains higher boron levels and improved cation ordering, delivers an initial discharge capacity of 174 mAh g -1 and retains more than 93 percent of its capacity after 50 cycles. The stable cycling behavior and structural integrity of these materials demonstrate that recycled precursors can be converted into high performance layered cathodes and support recycling as a practical and sustainable route for lithium-ion battery manufacturing.

25 ENERGY STORAGE↗
DOE OSTI2024

Simulation of metal nanoparticles growth in methane atmosphere of arc discharge: comparison to experiment

A direct current arc discharge in a methane atmosphere is a scalable and sustainable method to produce metal-carbon core–shell nanoparticles and single-walled carbon nanotubes, where a metal catalyst can be continuously supplied through evaporation of an anode made from the catalyst material. The size of catalyst particles is of critical importance as it can affect the synthesis yield and properties of nanotubes and core–shell nanoparticles. This study presents a numerical model describing the formation and growth of metal particles for the conditions representative of the arc discharge with an evaporating iron anode at near-atmospheric pressure of a methane-rich atmosphere. The model incorporates carbon adsorption to the metal surface and explains the limiting effect of carbon coverage on the size of metal nanoparticles. The predicted particle sizes are compared with experimental observations. The model also predicts higher concentrations of metal particles with the increasing partial pressure of methane.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

Tuning Cation (Dis)Order in Cr‐Based Li‐Excess Oxide Cathode Materials to Improve Li+ Transport Properties

Abstract Li‐excess disordered rocksalts (DRXs) hold promise as next‐generation cathodes for Li‐ion batteries due to their high capacity and energy density, along with the potential to eliminate the need for Co and Ni. However, due to their low Li + diffusivity, DRXs need to be pulverized into nanoparticles to achieve high performance. Herein, a new strategy for overcoming this limitation is demonstrated, involving the design of as‐synthesized partially disordered oxides with a structure that lies between ordered layered and fully disordered, exhibiting a varying degree of local (dis)order. This unique structure activates new Li + diffusion channels, improving percolation and transport properties. This strategy allows a large content of Li + to be accessed in material with large, micron‐sized particles through highly reversible Cr 3+/6+ and O redox, yielding a first discharge capacity of 286 mAh g −1 (881 Wh kg −1 ). The Li + percolation network is further improved by substituting Ti with a mixture of multiple metals, which appears to locally decrease the migration barrier through lattice distortion. Proper tuning of the chemical composition, especially the content of metals with empty d orbitals, is established as a crucial factor for controlling the degree of disorder and mitigating voltage fade and hysteresis growth upon cycling.

Moździerz, Maciej↗
DOE OSTI2026

Enhancing photoionization rate calculations in low-temperature plasmas using spectral methods

Photoionization plays a central role in the development of streamer discharges and other non-equilibrium plasma phenomena. It creates seed electrons, which are essential for positive streamer propagation, allowing the ionization front to move forward. Because of this, accurate modeling of photoionization is very important for predicting streamer behavior and plasma evolution. The photoionization process in air (N 2 – O 2 mixture) is often described by the Zheleznyak model (1982). This model is usually solved through Helmholtz-type equations that approximate the Zheleznyak photoionization model (Zheleznyak et al. 1982) as Partial Differential Equations (PDEs). Conventional numerical methods, such as the Finite Difference Method (FDM) or Finite Volume Method (FVM), are widely used to solve these equations. Although they are prevalent, the computational cost of these methods due to their need for matrix operations and iterative solver is demanding. To address this challenge, this work develops a spectral solver based on the Fast Fourier Transform (FFT) combined with Discrete Cosine Transform (DCT) and Discrete Sine Transform (DST) to calculate the photoionization rate efficiently in an axisymmetric cylindrical domain. This method naturally satisfies the boundary conditions used in the model and converts the PDE into algebraic ones in spectral space. Thus, avoids the need for iterative matrix solvers. When compared with FDM results, it is demonstrated that the new solver not only maintains accuracy, but also reduces the computational cost, showing a performance increase of approximately 100 compared to FDM over a wide range of problem sizes. The method is parallelized using Message Passing Interface (MPI) and has been integrated into a fluid plasma model for streamer simulation. Here, this FFT-based approach provides a fast and reliable alternative for calculating photoionization in fluid models, helping large-scale plasma simulations run faster and efficiently, and allows higher-resolution simulation without extra computational cost.

Axisymmetric system↗
DOE OSTI2024

Overview of recent experimental results on the EAST Tokamak

Since the last IAEA-FEC in 2021, significant progress on the development of long pulse steady state scenario and its related key physics and technologies have been achieved, including the reproducible 403 s long-pulse steady-state H-mode plasma with pure radio frequency (RF) power heating. A thousand-second time scale (~1056 s) fully non-inductive plasma with high injected energy up to 1.73 GJ has also been achieved. The EAST operational regime of high β P has been significantly extended (H 98y2 > 1.3, β P ~ 4.0, β N ~ 2.4 and n e /n GW ~ 1.0) using RF and neutral beam injection (NBI). The full edge localized mode suppression using the n = 4 resonant magnetic perturbations has been achieved in ITER-like standard type-I ELMy H-mode plasmas with q 95 ≈ 3.1 on EAST, extrapolating favorably to the ITER baseline scenario. The sustained large ELM control and stable partial detachment have been achieved with Ne seeding. The underlying physics of plasma-beta effect for error field penetration, where toroidal effect dominates, is disclosed by comparing the results in cylindrical theory and MARS-Q simulation in EAST. Breakdown and plasma initiation at low toroidal electric fields (<0.3 V m -1 ) with EC pre-ionization is developed. A beneficial role on the lower hybrid wave injection to control the tungsten concentration in the NBI discharge is observed for the first time in EAST suggesting a potential way toward steady-state H-mode NBI operation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

Simultaneous ELM suppression and divertor detachment via synergistic boron powder and neon injection in EAST

A novel approach for simultaneous power exhaust and edge-localized mode (ELM) control is presented in the Experimental Advanced Superconducting Tokamak discharges, which utilize an ITER-like tungsten divertor. Real-time injection of boron (B) powder and neon (Ne) gas overcomes their limitations encountered when used separately. Pure Ne seeding leads to a narrow operational window constrained by core impurity accumulation and H-mode to L-mode back transitions, while pure solid B injection (SBI) is insufficient for effective divertor cooling. In comparison, their combined use achieves a stable, stationary, ELM-suppressed H-mode with adequate power exhaust. This synergistic scenario features partial energy detachment at the outer divertor while maintaining good plasma confinement (H 98 ∼ 1) with minimal degradation. Two key features of this scenario are: (1) the SBI triggers a persistent Edge Harmonic Mode (EHM), which provides a crucial continuous particle transport channel, preventing Ne and tungsten/molybdenum accumulation without flushing out by ELM, and (2) the B + Ne mixture allows for active optimization of the radiated power profile. Core radiation can be reduced by substituting a portion of the Ne with B, leveraging their complementary non-coronal equilibrium radiation efficiencies. This combined B + Ne injection scheme presents a promising pathway toward integrated core-edge scenarios, offering the potential to minimize total impurity throughput while leveraging an actuator (powder injection) already being considered for ITER.

Boron↗
DOE OSTI2025

Transition metal vacancy and position engineering enables reversible anionic redox reaction for sodium storage

Triggering the anionic redox reaction is an effective approach to boost the capacity of layered transition metal (TM) oxides. However, the irreversible oxygen release and structural deterioration at high voltage remain conundrums. Herein, a strategy for Mg ion and vacancy dual doping with partial TM ions pinned in the Na layers is developed to improve both the reversibility of anionic redox reaction and structural stability of layered oxides. Both the Mg ions and vacancies (□) are contained in the TM layers, while partial Mn ions (~1.1%) occupy the Na-sites. The introduced Mg ions combined with vacancies not only create abundant nonbonding O 2p orbitals in favor of high oxygen redox capacity, but also suppress the voltage decay originated from Na–O–□ configuration. The Mn ions pinned in the Na layers act as “rivets” to restrain the slab gliding at extreme de-sodiated state and thereby inhibit the generation of cracks. The positive electrode, Na 0.67 Mn 0.011 [Mg 0.1 □ 0.07 Mn 0.83 ]O 2 , delivers an enhanced discharge capacity and decent cyclability. This study provides insights into the construction of stable layered oxide positive electrode with highly reversible anionic redox reaction for sodium storage.

Cai, Congcong [Wuhan Univ. of Technology (China)]↗
DOE OSTI2026

Fluorinated Glyme Solvents to Extend Lithium-Sulfur Battery Life (Final Technical Report, Unlimited)

This project investigated a number of partially fluorinated glymes (PFGs) as electrolyte cosolvents to improve the performance of lithium-sulfur (Li-S) batteries. A major issue in Li-S cells is the electrochemical reaction of sulfur in the cathode to form lithium polysulfides (LPS) that dissolve in the electrolyte. Those LPS are electrochemically and chemically reactive at the lithium anode, resulting in lithium sulfide deposition on the anode and also electrochemical reaction at both the anode and cathode, leading to a “polysulfide shuttle” and reduced coulombic efficiency (CE) and self-discharge of the cell. PFGs reduce the solubility of LPS while maintaining good solubility of lithium salts such as LiTFSI. By adjusting the amount of PFG as cosolvent in the electrolyte, we showed that the solubility of LPS in the electrolyte can be tuned. (It is not desirable to completely eliminate LPS in the electrolyte, as they facilitate electrochemical reaction of the electrically insulating S 8 and Li 2 S within the cathode by shuttling charge between them and the conductive carbon.) Another issue in Li-S cells is degradation of the Li anode over many cycles of stripping (discharge) and plating (charge). We showed that PFGs have a beneficial effect on the physical morphology of the Li anode, SEI formation, and the CE of a Li-Li cell. Among the many PFGs tested, we found the best performance from PFGs designated PFG2 and PFG5, and these two PFGs were thoroughly studied. A systematic coin-cell study of electrolyte solvents of 90:10, 80:20, or 70:30 DME:PFG (DME = 1,2-dimethoxyethane) revealed some systematic trends: a higher percentage of PFG solvent led to substantially longer cycle life, but at the same time reduced specific capacity (mAh/g(S)) and cell capacity at higher rates. These studies used LiFSI as the electrolyte salt, as it was found to extend cycle life compared to LiTFSI. Finally, the addition of a small amount of 1,3-dioxolane (DOL) to the electrolyte was found to be beneficial. The overall optimal electrolyte solution was found to be 0.6 M LiFSI + 0.5 M LiNO 3 in 75:5:20 DME/DOL/PFG (either PFG2 or PFG5).

25 ENERGY STORAGE↗
DOE OSTI2025

Experimental characterization of discharge plasma dynamics in a square capillary for prospective applications in laser wakefield acceleration

Research on plasma generated by electrical discharge in gas-filled capillaries plays an important role in advancing laser wakefield accelerators. We present a comprehensive study of the temporal and spatial distribution of plasma density within a short, 1 cm long, square-shaped capillary filled with hydrogen gas. Two transverse capillary sizes, 500 μm and 300 μm, were investigated achieving peak plasma densities of 0.9 × 10 18 cm −3 and 2.5 × 10 18 cm −3 , respectively, at the capillary center. In addition, we explore how these distributions depend on discharge parameters, specifically discharge current and gas flow through the capillary. Plasma density was determined by analyzing the Stark broadening of the hydrogen Balmer-alpha line. The results obtained were compared with the theoretical models and simulations. The comparison between the model predictions and the experimental data at the transient ionization stage of the discharge reveals a discrepancy of a factor of ∼1.3–2.1, depending on the capillary size, which is thoroughly discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Measurement of the properties of the dust acoustic wave in a magnetic field

We present the first experimental observations of the dust acoustic wave where the wave was observed to propagate in the directions of gravity and magnetic field when these directions were not aligned. The experiments were conducted in the Magnetized Dusty Plasma eXperiment facility using a novel electrode system that allows for the angle between gravity and the magnetic field to be varied in a controlled way. This letter reports on measurements in an rf glow discharge argon plasma environment where the angle between direction of gravity and the magnetic field is 45 $^{\circ }$ . When there was no applied magnetic field, the wave was observed to propagate in the direction of gravity. However, as the magnetic field increased and the ions transitioned from flowing in the direction of gravity to the direction of the magnetic field, a second wave emerged and two distinct waves were observed to simultaneously propagate, one in the direction of gravity and one in the direction of the magnetic field. As the magnetic field was further increased, the wave that propagated in the direction of gravity was suppressed and the wave was only observed to propagate in the direction of the applied magnetic field. We also observe that the speed and the kinetic temperature of the dust for the mode that propagated in the direction of gravity decreased with increasing magnetic field while the speed and the kinetic temperature of the dust for the mode that propagated in the direction of the magnetic field increased with increasing magnetic field. These measurements suggest that an ion-dust streaming instability is at least partially responsible for the high temperatures that have previously been observed in dusty plasmas when the dust acoustic wave is present.

Williams, J. D. (ORCID:000000025199707X)↗
DOE OSTI2025

Three-Dimensional Helical-Rotating Plasma Structures in Beam-Generated Partially Magnetized Plasmas

Azimuthal structures emerging in beam-generated partially magnetized plasmas are investigated using three-dimensional particle in cell-Monte Carlo collision simulations. Two distinct instability regimes are identified at low pressures. Furthermore, when the gas pressure is sufficiently high, quasineutrality is attained and 2D spiral-arm structures form as a result of the development of a lower-hybrid instability, resulting in enhanced cross-field transport. At lower pressures, quasineutrality is not achieved and a 3D helical-rotating plasma structure forms due to development of the diocotron instability. Analytical formulas are proposed for the critical threshold pressure between these regimes and for the rotation frequency of the helical structures. Preliminary experimental verification is provided.

Penning discharges↗
DOE OSTI2025

Measurement of partial vapor pressures of salt mixtures via combined horizontal transpiration and thermogravimetric analysis

A method combining thermogravimetric analysis (TGA) and horizontal transpiration with elemental analysis via inductively coupled plasma mass spectrometry or ion chromatography enabled calculation of partial pressures of individual salts in molten mixtures. TGA quantified total mass loss, while transpiration identified vapor-phase composition. Furthermore, two chloride (NaCl-MgCl 2 , NaCl-MgCl 2 + UCl 3 ) salts and one mixed halide (LiCl-LiF + Li 2 O) salt were analyzed at 750 °C and 550 °C, respectively. NaCl and MgCl 2 vapor pressures were 2.19–2.61 × 10 -4 atm and 2.47–2.48 × 10 -5 atm (dependent upon the identity of the invesitgated mixture); UCl 3 was 1.42 × 10 -7 atm. LiCl and LiF vapor pressures at 550 °C were 1.53 × 10 -6 and 6.32 × 10 -6 atm, respectively. Additionally, the TGA method was validated against values from the literature for unary LiCl and LiF.

36 MATERIALS SCIENCE↗