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Morphology of cold-drawn nylon 66.

Nylon 66 spherulites morphology before and after cold drawing from X ray diffraction, light and electron microscopic examination

Crystal, R. G.

Stagnation region heating of a phenolic-nylon ablator during return from planetary missions

The results of a stagnation-line analysis of the radiative heating of a phenolic-nylon ablator are reported. The analysis includes flowfield coupling with the ablator surface, equilibrium chemistry, multicomponent or binary diffusion and a coupled line and continuum radiation calculations. Users manual and operating instructions for the computer programs listed in the report are included.

Esch, D. D.

Fracture Behavior in Nylon 6 Fibers

Electron paramagnetic resonance (EPR) techniques are used to determine the number of free radicals produced during deformation leading to fracture of nylon 6 fibers. A reaction rate molecular model is proposed to explain some of the deformation and bond rupture behavior leading to fracture. High-strength polymer fibers are assumed to consist of a sandwich structure of disordered and ordered regions along the fiber axis. In the disordered or critical flaw regions, tie chains connecting the ordered or crystalline block regions are assumed to have a statistical distribution in length. These chains are, therefore, subjected to different stresses. The effective length distribution was determined by EPR. The probability of bond rupture was assumed to be controlled by reaction-rate theory with a stress-aided activation energy and behavior of various loadings determined by numerical techniques. The model is successfully correlated with experimental stress, strain, and bond rupture results for creep, constant rate loadings, cyclic stress, stress relaxation and step strain tests at room temperature.

Lloyd, B. A.

Effects of pressure, oxygen concentration, and forced convection on flame spread rate of Plexiglas, Nylon and Teflon

Experiments were conducted in which the burning of cylindrical materials in a flowing oxidant stream was studied. Plexiglas, Nylon, and Teflon fuel specimens were oriented such that the flames spread along the surface in a direction opposed to flowing gas. Correlations of flame spread rate were obtained that were power law relations in terms of pressure, oxygen concentration, and gas velocity.

Notardonato, J. J.