Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “nonequilibrium”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

The Development of a Nonequilibrium Radiative Heat Transfer Computational Model for High Altitude Entry Vehicle Flowfield Methods

This final report will attempt to concisely summarize the activities and accomplishments associated with NASA Grant and to include pertinent documents in an appendix. The project initially had one primary and several secondary objectives. The original primary objective was to couple into the NASA Johnson Space Center (JSC) nonequilibrium chemistry Euler equation entry vehicle flowfield code, INEQ3D, the Texas A&M University (TAMU) local thermodynamic nonequilibrium (LTNE) radiation model. This model had previously been developed and verified under NASA Langley and NASA Johnson sponsorship as part of a viscous shock layer entry vehicle flowfield code. The secondary objectives were: (1) to investigate the necessity of including the radiative flux term in the vibrational-electron-electronic (VEE) energy equation as well as in the global energy equation, (2) to determine the importance of including the small net change in electronic energy between products and reactants which occurs during a chemical reaction, and (3) to study the effect of atom-atom impact ionization reactions on entry vehicle nonequilibrium flowfield chemistry and radiation. For each, of these objectives, it was assumed that the code would be applicable to lunar return entry conditions, i.e. altitude above 75 km, velocity greater, than 11 km/sec, where nonequilibrium chemistry and radiative heating phenomena would be significant. In addition, it was tacitly assumed that as part of the project the code would be applied to a variety of flight conditions and geometries.

Carlson, Leland A.↗

Rotational Relaxation in Nonequilibrium Freejet Expansions of Heated Nitrogen

Rotational temperatures have been measured in rarefied, nonequilibrium, heated freejet expansions of nitrogen using the electron beam fluorescence technique at the University of California at Berkeley Low Density Wind Tunnel facility. Spectroscopic measurements of the (0,0) band of the first negative system of nitrogen reveal the nonequilibrium behavior in the flowfield upstream of, and through the Mach disk, which forms as the freejet expands into a region of finite back pressure. Results compare well with previous freejet expansion data and computations regarding location of the Mach disk and terminal rotational temperature in the expansion. Measurements are also presented for shock thickness based on the rotational temperature changes in the flow. Thickening shock layers, departures of rotational temperature from equilibrium in the expansion region, and downstream rotational temperature recovery much below that of an isentropic normal shock provide indications of the rarefied, nonequilibrium flow behavior. The data are analyzed to infer constant values of the rotational-relaxation collision number from 2.2 to 6.5 for the various flow conditions. Collision numbers are also calculated in a consistent manner for data from other investigations for which is seen a qualitative increase with increasing temperature. Rotational-relaxation collision numbers are seen as not fully descriptive of the rarefied freejet flows. This may be due to the high degree of nonequilibrium in the flowfields, and/or to the use of a temperature-insensitive rotational-relaxation collision number model in the data analyses.

Gochberg, Lawrence A.↗

Multiple Boundary Layer Instability Modes with Nonequilibrium and Wall Temperature Effects Using LASTRAC

Prediction and control of boundary layer transition from laminar to turbulent is important to many flow regimes and vehicle designs, including vehicles operating at hypersonic conditions where nonequilibrium effects may be encountered. Wall cooling is known to affect the instability characteristics of the boundary layer and subsequently the transition location. Design considerations, including material failure and fuel chemistry, require the use of actively cooled walls in hypersonic vehicles, further motivating the study of wall temperature effects on top of the considerations of reducing heat flux, drag, and uncertainty. In this work, we analyze the stability of a boundary layer with chemical and thermal nonequilibrium on a Mach 20, 6 wedge. We investigate the effects of wall temperature on multiple unstable modes individually and on the integrated growth of disturbances along the surface. We use the LAngley Stability and TRansition Analysis Code (LASTRAC) to evaluate boundary layer stability, using capabilities implemented by the authors. Included are results that address chemical nonequilibrium with both thermal equilibrium and nonequilibrium.

Kline, H. L.↗

Chemical nonequilibrium effects on the flow in the windward plane of symmetry of a blunted delta orbiter

The extent, and some of the consequences, of nonequilibrium effects in the inviscid orbiter flow field are examined. Calculations have been made for the reacting flow along selected streamlines in the windward plane of symmetry of a blunted delta shape representative of a shuttle orbiter. An approximate model of the pressure field in the windward plane of symmetry of a blunted delta wing was constructed from wind tunnel measurements of the body surface pressure distribution and approximate calculations of the shock shape and streamline locations. Numerical solutions for the flow along streamlines were obtained for this pressure distribution, and solutions were obtained for both equilibrium and finite-reaction rate, nonequilibrium chemical reactions. Since the streamtube solutions are much easier to compute than fully three-dimensional, reacting flows, results were obtained for a wide range of conditions. The validity of this approach is based on the assumptions that the pressure field is insensitive to nonequilibrium effects and that the flow along streamlines is quasi-one dimensional. Numerical solutions have been used to verify this approach for other blunted slender shapes such as spherically blunted cones.

Lordi, J. A.↗

Probe and radar electron temperatures in an isotropic nonequilibrium plasma.

Electron temperatures measured by electrostatic probes and radar backscatter are distinct physical quantities, the temperature from each technique determined from a different moment of the electron-distribution function. Numerical inequality of temperatures results from a non-Maxwellian electron-distribution function or, equivalently, from a nonequilibrium electron plasma. Probe and backscatter electron temperatures are studied for low- and high-energy (isotropic) distortions of the distribution function. The nonequilibrium plasma generally produces higher probe than backscatter temperatures; however, the temperature difference is small for distortions due to realistic photoelectron populations. If the ionosphere is in a highly nonequilibrium state, probe and backscatter temperatures would differ from the temperature characterizing the average electron kinetic energy, and a single temperature applicable to a variety of physical processes would no longer exist.

Hoegy, W. R.↗

Nonequilibrium combustion effects in supersonic streams

This research program is a theoretical and experimental investigation of the effect of nonequilibrium conditions upon the performance of combustors employing supersonic flows. Calculations and experiments are made regarding the effects on the ignition of hydrogen of the nonequilibrium species (free radicals, atoms, water vapor, etc.) obtained using vitiated air. Results of this investigation show that the nonequilibrium free-radical content from a supersonic vitiated air source will cause early ignition of the hydrogen. An analysis of heated air expended from a high temperature source to test section conditions also indicates that there is sufficient free radical content in the incoming flow to cause early ignition. Water vapor, an inherent contaminant in the generation of vitiated air, was found to reduce the ignition delay period under the experimental conditions considered.

Jensen, R. M.↗

Chemical nonequilibrium effects on the inviscid flow in the windward plane of symmetry of two simplified shuttle configurations

A theoretical study was made to delineate the effects of thermochemical nonequilibrium in the inviscid flow field of a representative space shuttle orbiter configuration. The study was based on experimental pressure data which was used as an input to a stream tube computer program. The pressure data from two configurations are tabulated. Calculations were restricted to the windward plane of symmetry and the calculations covered an altitude range from 200,000 to 250,000 feet at velocities of 16,000 to 24,000 feet per second respectively. Angles of attack of 20 and 40 degrees were included. The calculations show that the nonequilibrium effects are confined largely to the entropy layer expect at the highest altitude, where significant nonequilibrium effects are observed in the entire inviscid flow field.

Lordi, J. A.↗

Nonequilibrium chemistry boundary layer integral matrix procedure

The development of an analytic procedure for the calculation of nonequilibrium boundary layer flows over surfaces of arbitrary catalycities is described. An existing equilibrium boundary layer integral matrix code was extended to include nonequilibrium chemistry while retaining all of the general boundary condition features built into the original code. For particular application to the pitch-plane of shuttle type vehicles, an approximate procedure was developed to estimate the nonequilibrium and nonisentropic state at the edge of the boundary layer.

Tong, H.↗

Estimates of nonequilibrium radiation for Venus entry

The present investigation is an analysis of the radiation from the chemical nonequilibrium region in the shock layer about a vehicle during Venus entry. The radiation and the flow were assumed to be uncoupled. An inviscid, nonequilibrium flowfield was calculated and an effective electronic temperature was determined for the predominant radiating species. Species concentrations and electronic temperature were then input into a radiation transport code to calculate heating rates. The present results confirm earlier investigations which indicate that the radiation should be calculated using electronic temperatures for the radiating species. These temperatures are not related in a simple way to the local translational temperature. For the described mission, the nonequilibrium radiative heating rate is approximately twice the corresponding equilibrium value at peak heating.

Grose, W. L.↗

Computation of nonequilibrium three-dimensional inviscid flow over blunt-nosed bodies flying at supersonic speeds

A computer code based on the method of characteristics is described and applied to the study of two- and three-dimensional chemical nonequilibrium flow over sharp and blunt-nosed bodies. Nonequilibrium flow over a wedge is used to show the approach to equilibrium flow, and to demonstrate the nature of the reaction zone behind the bow shock wave. The structure and development of a blunt-body entropy layer in nonequilibrium flow is examined for a blunt cone at zero incidence. Three-dimensional computations for the space shuttle body at 30 deg angle of attack are presented. A nondimensional scaling parameter, the Damkoehler number, which is the ratio of flow time to chemical reaction time, is calculated and its significance discussed.

Rakich, J. V.↗

Effects of precursor heating on chemical and radiative nonequilibrium viscous flow around a Jovian entry body

The influence of precursor heating on viscous chemical nonequilibrium radiating flow around a Jovian entry body is investigated. Results obtained for a 45 deg hyperboloid blunt body entering the Jupiter's nominal atmosphere at zero angle of attack indicate that the nonequilibrium radiative heating rate is significantly higher than the corresponding equilibrium heating. The precursors heating, in general, increases the radiative and convective heating to the body and this increase is slightly higher for the nonequilibrium conditions.

Tiwari, S. N.↗

Effects of precursor heating on chemical and radiation nonequilibrium viscous flow around a Jovian entry body

The influence of precursor heating on viscous chemical nonequilibrium radiating flow around a Jovian entry body is investigated. Results obtained for a 45-degree hyperboloid blunt body entering Jupiter's nominal atmosphere at zero angle of attack indicate that the nonequilibrium radiative heating rate is significantly higher than the corresponding equilibrium heating. The precursor heating, in general, increases the radiative and convective heating to the body, and this increase is slightly higher for the nonequilibrium conditions.

Tiwari, S. N.↗

Chemical nonequilibrium effects on flowfields for aeroassist orbital transfer vehicles

Acceptable altitude and velocity ranges for the perigee of aeroassist orbital transfer vehicles (AOTV) have been determined for various values of ballistic coefficient and lift-to-drag ratio. The chemical nonequilibrium effect on the flowfield of a simple but representatively high-drag, blunt configuration was investigated for these perigee conditions, ranging from 73 to 90 km in altitude and 8 to 9.3 km/s in velocity. The analysis was performed using a two-dimensional viscous-shock-layer code which had previously demonstrated good success in predicting nonequilibrium heating on the Space Shuttle. The results indicate lower ratio of nonequilibrium/equilibrium heating for the present AOTV perigee conditions than for the Shuttle flight conditions, due to higher velocity. The trend for the degree of nonequilibrium with the effect of varying wall catalycity and configuration was determined over the altitude range. Some implications to future design consideration are stated.

Shinn, J. L.↗

The hydrodynamics of magnetic nonequilibrium

Because the dynamical nonequilibrium of closely packed twisted flux tubes is essentially the problem of two-dimensional MHD turbulence, the extensive literature on two-dimensional turbulence represents the hydrodynamics of magnetic nonequilibrium. Many features of the turbulence can conversely be understood as a consequence of the dynamical nonequilibrium. Attention is presently given to the dynamics of the strong fluid jets, issuing from reconnection points, that are exhibited by numerical simulations of two-dimensional turbulence. Simple examples are given which show that the uniformity of jet width observed is a consequence of the form of the pressure of the magnetic fields between which the jets are confined. The general hydrodynamics of a layer of fluid confined by steady pressures is reducible to a quadrature, so that a variety of effects may be considered, including gravitation. The dissipation of the solar corona is discussed.

Parker, E. N.↗

Calculation of nonequilibrium radiation in the flight regimes of aeroassisted orbital transfer vehicles

A computer code has been developed that calculates radiative properties of nonequilibrium air in the low-density regimes expected during the flight of aeroassisted, orbital transfer vehicles. From the given nonequilibrium thermodynamic state variables, the code calculates number densities of internal states and the accompanying emission and absorption characteristics. In addition, the code calculates the number density of the hypothetical gas in radiative equilibrium that produces the same radiation emission as the given nonequilibrium gas. Sample results are shown to demonstrate how the code predicts the nonlinear variation of radiation with density at low densities.

Park, C.↗

On the computation of shock shapes in nonequilibrium hypersonic flows

Several models using different descriptions of high temperature air are used to compute the bow shock shapes on experimental model configurations. The test conditions result in nonequilibrium chemical reaction and thermal excitation of the gas which has a first-order effect on the shock shapes. The computed results are compared to experiment and demonstrate that the model using seven chemical species and six temperatures predicts the experimental shock shapes very well. The other gas models, including perfect gas, equilibrium gas and one-temperature chemical nonequilibrium models are less accurate. The results illustrate the necessity of including both thermal and chemical nonequilibrium in the description of the gas. The use of these experimental data makes it possible to verify aspects of current and future chemically reacting flow algorithms.

Candler, Graham↗

Rotational and vibrational nonequilibrium effects in rarefied, hypersonic flow

Results are reported for an investigation into the methods by which energy transfer is calculated in the Direct Simulation Monte Carlo method. Description is made of a recently developed energy exchange model that deals with the translational and rotational modes. A new model for simulating the transfer of energy between the translational and vibrational modes is also explained. This model allows the vibrational relaxation time to follow the temperature dependence predicted by the Landau-Teller theory at moderate temperatures. For temperatures in excess of about 8000K the vibrational model is extended to include an empirical result for the relaxation time. The effect of introducing these temperature dependent collision numbers into the DSMC technique is assessed by making calculations representative of the stagnation streamline of a hypersonic space vehicle. Both thermal and chemical nonequilibrium effects are included while the flow conditions have been chosen such that ionization and radiation may be neglected. The introduction of these new models is found to significantly affect the degree of thermal nonequilibrium observed in the flowfield. Larger, and more widely ranging, differences in the results obtained with the different energy exchange probabilities are found when a significant amount of internal energy is included in the calculation of chemical nonequilibrium.

Boyd, Iain D.↗

Model gases for the detailed study of microscopic chemical nonequilibrium in diatomic gas flows

It is shown that chlorine (Cl2) and iodine (I2) are suitable model diatomic gases to use in theoretical studies of chemical nonequilibrium that account for rotational and vibrational as well as electronic processes in a gas. Because of the low temperature at which significant dissociation can be achieved in iodine, it is a particularly attractive candidate for the study of relatively low temperature chemically reacting flows, permitting detailed knowledge of the nonequilibrium populations of translational, rotational, vibrational and electronic energy levels. A preliminary investigation indicates that a useful iodine flow facility can be constructed and that diagnostic techniques are available to validate in detail prediction techniques for nonequilibrium flows.

Kunc, Joseph A.↗