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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Contrasting Target, Stray-Light, and Other Performance Metrics for MISR

The Multi-angle Imaging Spectrometer (MISR) is an Earth-observing sensor to be flown as part of the Earth Observing System (EOS) in 1998. The radiometric and spectral calibration of the nine cameras which compose this instrument will be done using targets which are uniform in space and in angle, unpolarized, and lacking in absorption lines. A calibration uncertainty will also be determined for this configuration. This allows one to estimate the accuracy of measured radiances, assuming the scene is likewise featureless with respect to these parameters. In addition to these calibrations, the MISR engineering team will be responsible for verification of certain performance specifications which assure data products can be produced for a range of target types.

Multi-angle Imaging Spectrometer MISR Earth Observ↗
DOE OSTI2025

Molecular insights into Yb(III) speciation in sulfate-bearing hydrothermal fluids from X-ray absorption spectra informed by ab initio molecular dynamics

Rare earth elements (REEs) are critical for advanced technologies, yet in hydrothermal aqueous solutions the molecular level details of their interaction with ligands that control their geochemical transport and deposition remain poorly understood. Here, this study elucidates the coordination behavior of Yb 3+ in sulfate-rich hydrothermal fluids using in situ extended X-ray absorption fine structure (EXAFS) spectroscopy and ab initio molecular dynamics (AIMD) simulations. By integrating multi-angle EXAFS with AIMD-derived constraints, we precisely resolve Yb 3+ coordination structures and ligand interactions under hydrothermal conditions. At room temperature, Yb 3+ is coordinated by five water molecules and two sulfate ligands (coordination number, CN = 8), forming a distorted square antiprism geometry. Increasing temperature induces progressive dehydration, reducing the hydration shell and favoring stronger sulfate complexation. At 200°C, sulfate ligands reorganize around Yb 3+ , shifting its geometry to a capped octahedron (CN = 7). At 300 °C, sulfate binding dominates, leading to structural reorganization that parallels the onset of sulfate mineral precipitation, consistent with the retrograde solubility of REE sulfates. These findings provide direct molecular-scale evidence that sulfate acts as both a transport and deposition ligand, critically influencing REE mobility in geochemical environments. Our results can also help to refine thermodynamic models of REE speciation in high-temperature hydrothermal fluids and improve our understanding of REE ore formation processes in nature.

AIMD↗
DOE OSTI2025

Harnessing Satellite Data Alone for Mapping Global Thermal Anisotropy

Mapping thermal anisotropy across global lands is critical for advancing a wide range of Earth science studies. However, a comprehensive understanding of global thermal anisotropy intensity (TAI) and its governing factors remains missing. We introduce a novel data-driven methodology to quantify global TAI exclusively using multi-angle MODIS land surface temperature time series observations. Our analysis reveals distinct seasonal and diurnal TAI patterns, with global mean summertime TAI exceeding 2.9°C. Furthermore, we identify strong associations between TAI and key surface and atmospheric parameters, such as leaf area index and downward shortwave radiation. Our findings advocate for a paradigm shift from model-based to data-driven approaches in correcting thermal anisotropy, thereby addressing a critical bottleneck in Earth observation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Towards retrieving cloud top entrainment velocities from MISR cloud motion vectors

Although important, direct retrievals of entrainment rates in cloud-topped planetary boundary layer (PBL) remain elusive. Here we present a novel technique for retrieving cloud-top entrainment velocities using only Multi-angle Imaging Spectro-Radiometer (MISR) stereoscopic retrievals of cloud-motion vectors (CMVs) and cloud-top heights (CTHs). Mesoscale vertical air velocity at CTH is diagnosed from the continuity equation and then used to derive entrainment velocities from the PBL mass-budget equation. The algorithm is demonstrated through a case of marine stratocumulus deck off the California coast, with comparisons made against data from the European Centre for Medium-range Weather Forecasts (ECMWF) reanalysis (ERA5) and the data from other satellites. MISR low-cloud CTH for this case were lower than the ERA5 reported PBL depth by 189 ± 87 m. These differences in cloud top heights partly modulate the differences in the ERA5 and MISR horizontal winds, with larger differences in meridional over zonal wind components. Average difference between ERA5 and MISR derived mesoscale vertical air motion at cloud top was 0.14 ± 0.73 cm s −1 , while the same for entrainment rate was −0.09 ± 0.46 cm s −1 . The uncertainties in the utilized CTHs and CMVs are propagated to derive systematic and random retrieval uncertainties. Fractional uncertainty is lower than 25 % when the retrieved mesoscale vertical air motion is stronger than ±0.04 cm s −1 and entrainment velocities are stronger than ±0.03 cm s −1 . These results showcase the ability to derive mesoscale vertical air motion and entrainment rates from MISR observations and motivate its extension to generate a global climatology leveraging its full 23-year record (2000–2022). Nonetheless comprehensive validation of the retrievals is warranted through comparisons with estimates from an independent dataset across diverse weather conditions.

Mitra, Arka [Argonne National Laboratory (ANL), Ar↗
NASA NTRS1986

Aerosol studies in mid-latitude coastal environments in Australia

The results of the evaluation of several inversion procedures that were used to select one which provides the most accurate atmospheric extinction profiles for small aerosol extinction coefficients (that often predominate in the maritime airmass) are presented. Height profiles of atmospheric extinction calculated by a two component atmospheric solution to the LIDAR equation will be compared with corresponding in-situ extinction profiles based on the size distribution profiles obtained in Western Australia. Values of the aerosol backscatter to extinction ratio obtained from multi-angle LIDAR measurements will be used in this solution.

Young, S. A.↗
NASA NTRS1986

Multiple incidence angle SIR-B experiment over Argentina

The Shuttle Imaging Radar (SIR-B), the second synthetic aperture radar (SAR) to fly aboard a shuttle, was launched on October 5, 1984. One of the primary goals of the SIR-B experiment was to use multiple incidence angle radar images to distinguish different terrain types through the use of their characteristic backscatter curves. This goal was accomplished in several locations including the Chubut Province of southern Argentina. Four descending image acquisitions were collected providing a multiple incidence angle image set. The data were first used to assess stereo-radargrammetric techniques. A digital elevation model was produced using the optimum pair of multiple incidence angle images. This model was then used to determine the local incidence angle of each picture element to generate curves of relative brightness vs. incidence angle. Secondary image products were also generated using the multi-angle data. The results of this work indicate that: (1) various forest species and various structures of a single species may be discriminated using multiple incidence angle radar imagery, and (2) it is essential to consider the variation in backscatter due to a variable incidence angle when analyzing and comparing data collected at varying frequencies and polarizations.

Cimino, Jobea↗
NASA NTRS1989

Low-pass spatial filtering of satellite radar data

Thirty-four low-pass spatial filter treatments were applied to a multi-angle SIR-B data set to reduce speckle effects and improve classification performance. These treatments were based on four algorithms: square mean, separable mean, square median, and separable recursive median. The filtered images were evaluated using both quantitative and qualitative techniques. It was determined that the square median algorithm implemented at two iterations with a window size of 3 by 3 produced the best overall results with the 28.5-m SIR-B data.

Mueller, Paul W.↗
NASA NTRS1990

Eos visible imagers

Some of the proposed Earth Observing System (Eos) optical imagers are examined. These imagers include: moderate resolution imaging spectrometer (MODIS); geoscience laser ranging system (GLRS); high resolution imaging spectrometer (HIRIS); the intermediate thermal infrared spectrometer (ITIR); multi-angle imaging spectrometer (MISR); earth observing scanning polarimeter (EOSP); and the lightening imaging sensor (LIS).

Barnes, W. L.↗
NASA NTRS1992

Development of a versatile laser light scattering instrument

NASA Lewis Research Center is providing and coordinating the technology for placing a compact Laser Light Scattering (LLS) instrument in a microgravity environment. This will be accomplished by defining and assessing user requirements for microgravity experiments, coordinating needed technological developments, and filling technical gaps. This effort is striving to brassboard and evaluate a miniature multi-angle LLS instrument. The progress of the program is reported.

Meyer, William V.↗
NASA NTRS1991

Reflectance stability analysis of Spectralon diffuse calibration panels

The Multi-angle Imaging SpectroRadiometer (MISR) plans to use deployable diffuse reflectance panels to provide periodic radiometric calibrations of its nine cameras while in-flight. Near-Lambertian reflectance characteristics are desirable to facilitate flat-field camera intercomparisons. Also required is panel spatial and spectral uniformity, and stability with time. Spectralon, a commercially available polytetrafluoroethylene (PTFE) compound, has been baselined in the MISR design. To assess the suitability of this material, a series of degradation tests were planned and implemented. These included UV vacuum exposure and proton bombardment tests which simulated the exposure levels to be encountered during the mission life. Proton levels are now considered too low to be of concern, but UV vacuum tests demonstrate sensitivity to material contamination. Material investigations have concluded that hydrocarbons are present in the bulk of the material, and that plastic packaging materials can introduce additional surface-layer contamination. It is found however, that these unwanted elements can be eliminated through vacuum pumping at elevated temperatures. Exposure to a UV source, while in vacuum, is again planned for a set of targets which have been vacuum baked. This will assess the stability of the pure PTFE form.

Bruegge, Carol J.↗
NASA NTRS1992

Moderate resolution imaging spectroradiometer (MODIS) and observations of the land surface

The moderate resolution imaging spectroradiometer (MODIS) is a NASA facility instrument that is being designed for flight on the Earth Observing System (EOS) series of missions. It is designed to measure biophysical states and dynamics of the land, atmosphere, and ocean. Plans are required for use of other instruments that will be accompanying MODIS on the EOS missions, such as the High-Resolution Imaging Spectrometer (HIRIS) and the Multi-angle Imaging Spectro-Radiometer (MISR). The HIRIS instrument, a spectrometer operating in the visible to shortwave infrared parts of the spectrum, would be employed in combination with the MODIS to understand the impact of sampling the spectrum and the effects of land cover mixtures within the MODIS pixel. The MISR will help in understanding the effects of anisotropy in reflected solar radiation. Both instruments will work in combination with MODIS to better quantify the effects of the atmosphere on observations of surface properties.

Salomonson, V. V.↗
NASA NTRS1993

Convective flow effects on protein crystal growth

The experimental setup for the in-situ high resolution optical monitoring of protein crystal growth/dissolution morphologies was substantially improved. By augmenting the observation system with a temperature-controlled enclosure, laser illumination for the interferometric microscope, and software for pixel by pixel light intensity recording, a height resolution of about two unit cells for lysozyme can now be obtained. The repartitioning of Na(+) and Cl(-) ions between lysozyme solutions and crystals was studied. Quite unexpectedly, it was found that the longer crystals were in contact with their solution, the lower was their ion content. The development of a model for diffusive-convective transport and resulting distribution of the growth rate on facets was completed. Results obtained for a realistic growth cell geometry show interesting differences between 'growth runs' at 1g and 0g. The kinematic viscosity of lysozyme solutions of various supersaturations and salt concentrations was monitored over time. In contrast to the preliminary finding of other authors, no changes in viscosity were found over four days. The experimental setup for light scattering investigations of aggregation and nucleation in protein solutions was completed, and a computer program for the evaluation of multi-angle light scattering data was acquired.

Rosenberger, Franz↗
NASA NTRS1993

Laser light scattering instrument advanced technology development

The objective of this advanced technology development (ATD) project has been to provide sturdy, miniaturized laser light scattering (LLS) instrumentation for use in microgravity experiments. To do this, we assessed user requirements, explored the capabilities of existing and prospective laser light scattering hardware, and both coordinated and participated in the hardware and software advances needed for a flight hardware instrument. We have successfully breadboarded and evaluated an engineering version of a single-angle glove-box instrument which uses solid state detectors and lasers, along with fiber optics, for beam delivery and detection. Additionally, we have provided the specifications and written verification procedures necessary for procuring a miniature multi-angle LLS instrument which will be used by the flight hardware project which resulted from this work and from this project's interaction with the laser light scattering community.

Wallace, J. F.↗
NASA NTRS1994

Convective flow effects on protein crystal growth

The long-term stability of the interferometric setup for the monitoring of protein morphologies has been improved. Growth or dissolution of a crystal on a 100 A scale can now be clearly distinguished from dimensional changes occurring within the optical path of the interferometer. This capability of simultaneously monitoring the local interfacial displacement at several widely-spaced positions on the crystal surface with high local depth resolution, has already yielded novel results. We found with lysozyme that (1) the normal growth rate is oscillatory, and (2) the mean growth step density is greater at the periphery of a facet than in its center. The repartitioning of Na(+) and Cl(-) ions between lysozyme solutions and crystals was studied for a wide range of crystallization conditions. A nucleation-growth-repartitioning model was developed to interpret the large body of data in a unified way. The results strongly suggests that (1) the ion to lysozyme ratio in the crystal depends mostly on kinetic rather than crystallographic parameters, and (2) lysozyme crystals possess a salt-rich core with a diameter on the order of 10 microns. The computational model for diffusive-convective transport in protein crystallization (see the First Report) has been applied to a realistic growth cell geometry, taking into account the findings of the above repartitioning studies. These results show that some elements of a moving boundary problem must be incorporated into the model in order to obtain a more realistic description. Our experimental setup for light scattering investigations of aggregation and nucleation in protein solutions has been extensively tested. Scattering intensity measurements with a true Rayleigh scatterer produced systematically increased forward scattering, indicating problems with glare. These have been resolved. Preliminary measurements with supersaturated lysozyme solutions revealed that the scatterers grow with time. Work has begun on a computer program for the unified evaluation of simultaneously obtained, multi-angle static and dynamic light scattering data.

Rosenberger, Franz↗
NASA NTRS1993

Modeling Spectralon's Bidirectional Reflectance for In-flight Calibration of Earth-Orbiting Sensors

The in-flight calibration of the EOS Multi-angle Imaging SpectroRadiometer (MISR) will be achieved, in part, by observing deployable Spectralon panels. This material reflects light diffusely, and allows all cameras to view a near constant radiance field. This is particularly true when a panel is illuminated near the surface normal. To meet the challenging MISR calibration requirements, however, very accurate knowledge of the panel reflectance must be known for all utilized angles of illumination, and for all camera and monitoring photodiode view angles. It is believed that model predictions of the panels Bidirectional Reflectance Distribution Function (BRDF) can be used in conjunction with a measurements program to provide the required characterization. This paper describes the results of a model inversion which was conducted using measured Spectralon BRDF data at several illumination angles. Four physical parameters of the material were retrieved, and are available for use with the model to predict reflectance for any arbitrary illumination or view angle. With these data the root mean square difference between the model and the observations is currently of the order of the noise in the data, at about +/- l%. With this success the model will now be used in a variety of future studies, including the development of a measurements test plan, the validation of these data, and the prediction of a new BRDF profile, should the material degrade in space.

Flasse, Stephane P.↗
DOE OSTI2025

Aqueous Self‐Assembly of Cylindrical and Tapered Bottlebrush Block Copolymers

The self‐assembly of amphiphilic bottlebrush block copolymers (BCPs), featuring backbones densely grafted with two types of side chains, is less well understood compared to linear BCPs. In particular, the solution self‐assembly of tapered bottlebrush BCPs—cone‐shaped BCPs with hydrophilic or hydrophobic tips—remains unexplored. This study investigates eight tapered and four cylindrical bottlebrush BCPs with varied ratios of hydrophobic polystyrene (PS) and hydrophilic poly(acrylic acid) (PAA) side chains, synthesized via sequential addition of macromonomers using ring‐opening metathesis polymerization (SAM‐ROMP). Self‐assembled nanostructures formed in water were analyzed using cryogenic transmission electron microscopy, small‐angle neutron scattering, and dynamic light scattering. Most BCPs generated multiple nanostructures with surface protrusions, including spherical micelles, cylindrical micelles, and vesicles, alongside transitional forms like ellipsoids and semi‐vesicles. Coarse‐grained molecular dynamics simulations supported the experimental findings, which revealed two distinct self‐assembly pathways. The first involved micelle fusion, producing elliptical and cylindrical aggregates, sometimes forming Y‐junctions. The second pathway featured micelle maturation into semivesicles, which developed into vesicles or large compound vesicles. This work provides the first experimental evidence of vesicle formation via semivesicles in bottlebrush BCPs and demonstrates the significant influence of cone directionality on self‐assembly behavior in these cone‐shaped polymeric amphiphiles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗