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At least 37 records · Page 2

Develop Accurate Techniques for Passive SiC Temperature Monitoring of Miniature Samples for Cross-Cutting Applications

Passive thermometry is critically important because most fuels and materials irradiation experiments are not instrumented, and it is necessary to understand the irradiation temperature to properly interpret any post-irradiation examination data, including evolving properties and/or microstructures. The standard passive thermometry approach uses continuous dilatometry to evaluate changes in the instantaneous coefficient of thermal expansion during post-irradiation thermal annealing. This approach has limitations in terms of sample size (minimum length requirements) and the maximum irradiation temperature that can be accurately determined, which is limited by the reduced swelling (and therefore recovery) following higher temperature irradiation and limitations on the furnaces used with push-rod dilatometers. This work evaluates two new proposed techniques for post-irradiation evaluation of passive SiC temperature monitors: differential scanning calorimetry (DSC) and Raman spectroscopy. DSC is an extremely sensitive technique that can be used for any specimen geometry and is capable of higher temperature operation. Raman spectroscopy is similar in that it is a surface technique capable of examining extremely small samples (submillimeter), can be used with a heated stage up to 1,500°C (planned for future work), and is capable of mapping local irradiation temperatures throughout a sample. Existing SiC samples that were previously irradiated over a wide range of temperatures were cut into multiple pieces to allow for annealing studies using multiple different techniques: dilatometry, DSC, and Raman spectroscopy. This approach mitigates the concern that samples analyzed using one technique may have a slightly different irradiation history than those analyzed using a different technique. Recovery was clearly observed during annealing using both DSC and dilatometry. In some cases, a direct comparison could not be made due to some of the DSC runs accidentally including material from multiple specimens and issues with using an alternative DSC sample holder for the highest temperature annealing studies. Nevertheless, one trend was clear: the DSC runs resulted in higher irradiation temperatures compared to those of the dilatometry runs. Part of this could be attributed to the higher temperature ramp rates used during the DSC runs, which are often preferred to reduce noise in the measurements. By comparison, dilatometry has previously been shown to produce better data at lower ramp rates. Future work should further investigate the ideal ramp rate for both techniques to produce consistent results. Additional work should evaluate the best holder material to use for DSC runs exceeding 1,000°C to provide reliable data while preventing interactions between SiC and the holder.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Develop Accurate Techniques for Passive SiC Temperature Monitoring of Miniature Samples for Cross-Cutting Applications

Passive thermometry is critically important because most fuels and materials irradiation experiments are not instrumented, and it is necessary to understand the irradiation temperature to properly interpret any post-irradiation examination data, including evolving properties and/or microstructures. The standard passive thermometry approach uses continuous dilatometry to evaluate changes in the instantaneous coefficient of thermal expansion during post-irradiation thermal annealing. This approach has limitations in terms of sample size (minimum length requirements) and the maximum irradiation temperature that can be accurately determined, which is limited by the reduced swelling (and therefore recovery) following higher temperature irradiation and limitations on the furnaces used with push-rod dilatometers. This work evaluates two new proposed techniques for post-irradiation evaluation of passive SiC temperature monitors: differential scanning calorimetry (DSC) and Raman spectroscopy. DSC is an extremely sensitive technique that can be used for any specimen geometry and is capable of higher temperature operation. Raman spectroscopy is similar in that it is a surface technique capable of examining extremely small samples (submillimeter), can be used with a heated stage up to 1,500°C (planned for future work), and is capable of mapping local irradiation temperatures throughout a sample. Existing SiC samples that were previously irradiated over a wide range of temperatures were cut into multiple pieces to allow for annealing studies using multiple different techniques: dilatometry, DSC, and Raman spectroscopy. This approach mitigates the concern that samples analyzed using one technique may have a slightly different irradiation history than those analyzed using a different technique. Recovery was clearly observed during annealing using both DSC and dilatometry. In some cases, a direct comparison could not be made due to some of the DSC runs accidentally including material from multiple specimens and issues with using an alternative DSC sample holder for the highest temperature annealing studies. Nevertheless, one trend was clear: the DSC runs resulted in higher irradiation temperatures compared to those of the dilatometry runs. Part of this could be attributed to the higher temperature ramp rates used during the DSC runs, which are often preferred to reduce noise in the measurements. By comparison, dilatometry has previously been shown to produce better data at lower ramp rates. Future work should further investigate the ideal ramp rate for both techniques to produce consistent results. Additional work should evaluate the best holder material to use for DSC runs exceeding 1,000°C to provide reliable data while preventing interactions between SiC and the holder.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Energy Dependence Analysis of Neutrino-Nucleus Interactions in Scintillator for MINERvA

This thesis is on the intrinsic energy dependence in neutrino-nucleus interaction models, especially quasielastic scattering and 2p2h process, and the implications for understanding data from MINERvA, NOvA, and DUNE. Neutrino-nucleus interactions are modeled using fve structure functions, W1, W2, W3, W4 and W5, and each structure function contributes diferently to the energy dependence once it enters the cross-section calculations. The energy independent term in the calculations contains only W2 and the next lower order term (of the order 1/E) contains W3 also. In this thesis, we show that W2 is good enough to describe MINERvA data and energy dependence coming from the cross-section directly is small. However, W3 will be signifcant for lower energy experiments such as NOvA and DUNE (especially at and below the oscillation maximum). We have also developed a method to extract structure functions directly from MINERvA data though we find that systematic uncertainties present in the data are too big to successfully determine 1/E Term. In addition to this, we have applied muon angle cuts on MINERvA data and MC, which have their own energy dependent effects. An apparent energy dependent discrepancy comes from known shortcomings especially in the pion production model. Finally, because the energy dependence analysis has similarities to the low-$\nu$ method, we have evaluated discrepancies between the data and MC in light of diferent fux constraint techniques. The results suggest including MINERvA s low-$\nu$ method constraint is an improvement.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Improved light yield and growth of large-volume ultrafast single crystal scintillators Cs 2 ZnCl 4 and Cs 3 ZnCl 5

Due to their reported fast decay times, Cs 2 ZnCl 4 and Cs 3 ZnCl 5 are promising candidates for detection of gamma rays and X-rays in high count rate and fast timing applications. In this work, we show that single crystals with better optical quality than previously demonstrated – and larger in size – can be grown via the vertical Bridgman method. Highly transparent Ø7 mm crystals of undoped Cs 2 ZnCl 4 and Cs 3 ZnCl 5 are grown and measured to have light yields surpassing those previously reported, achieving 1980 ± 100 ph/MeV and 1460 ± 70 ph/MeV at 662 keV – a 55% and 232% improvement, respectively. We observe single-component scintillation decay times for both Cs 2 ZnCl 4 (1.66 ns) and Cs 3 ZnCl 5 (0.82 ns) and radioluminescence emission with maximum intensity at ~290 nm. Scalability of these materials is also evaluated based on growth of Ø22 mm crystals. Minimal cracking is observed, and the fast decay times are maintained at this size. Coincidence time resolution of 3 × 3 × 5 mm 3 and 7 × 7 × 10 mm 3 pixels cut from Ø22 mm Cs 2 ZnCl 4 are measured to be 148 ± 1 ps FWHM and 175 ± 1 ps FWHM, respectively. Here, the improved performance and ability to be fabricated in large sizes now place Cs 2 ZnCl 4 and Cs 3 ZnCl 5 on the map as potential contenders for radiation detection applications where BaF 2 – the most commonly used ultrafast inorganic scintillator – is typically considered.

36 MATERIALS SCIENCE↗

Air quality impacts from the development of unconventional oil and gas well pads: Air toxics and other volatile organic compounds

Unconventional oil and natural gas development (UOGD) has expanded rapidly across the United States in recent decades and raised concerns about associated air quality impacts. While significant effort has been made to quantify methane emissions, relatively few observations have been made of Volatile Organic Compounds (VOCs), especially during drilling and completion of new wells. Extensive air monitoring during development of several large, multi-well pads in Broomfield, Colorado, in the Denver-Julesburg Basin, provides a novel opportunity to examine changes in local air toxics and other VOC concentrations during well drilling and completions and production. These operations offer an especially useful case to study as several management practices were implemented to reduce emissions (e.g., electrified, grid-powered drill rigs and closed loop fluid handling systems to reduce truck traffic and limit fluid handling on the pad). With simultaneous measurements of methane and 50 VOCs from October 2018 to December 2022 at as many as 19 sites near well pads, in adjacent neighborhoods, and at a more distant reference location, we identify impacts from each phase of well development and production. Use of weekly, time-integrated canisters, a Proton Transfer Reaction Mass Spectrometer (PTR-MS), continuous photoionization detectors (PID) to trigger canister collection upon detection of VOC-rich plumes, and an instrumented vehicle, provided a powerful suite of measurements to characterize both transient plumes and longer-term changes in air quality. Prior to the start of well development, VOC gradients were small across Broomfield. Once drilling commenced, concentrations of oil and gas (O&G) related VOCs, including alkanes and aromatics, increased around active well pads. Concentration increases were clearly apparent during certain operations, including drilling, coil tubing/millout operations, and production tubing installation. Emissions of C 8 –C 10 n-alkanes during drilling operations highlighted the importance of VOC emissions from synthetic drilling mud chosen to reduce odor impacts. More than 90 samples were collected of transient plumes. Using composition measurements, meteorological data, and information about well pad activities, these plumes were connected with specific UOGD operations including drilling, flowback, and production equipment maintenance. The chemical signatures of these plumes differed by operation type (e.g., C 8 –C 10 n-alkanes constituted a larger fraction of measured VOCs in drilling-related plumes). Concentrations of individual, oil and gas-related VOCs in these plumes were often several orders of magnitude higher than in background air, with maximum ethane and benzene concentrations of 79,600 and 819 ppbv, respectively. Because these plumes typically impact a monitoring site for just several minutes, they are easily missed by slower-responding instruments. Study measurements highlight future emission mitigation opportunities during UOGD operations, including better control of emissions from shakers that separate drill cuttings from drilling mud, production separator maintenance operations, and periodic emptying of sand cans during flowback operations.

54 ENVIRONMENTAL SCIENCES↗

Shock initiation of low density polymer bonded explosive LX-14: A study of two morphologies

A series of six shock initiation experiments have been carried out on low density LX-14 powder in order to simulate a shock insult on the heavily damage polymer bonded explosive, LX-14. Two distinct morphologies were studied (tap density molding powder and machined swarf), both at the same density of 0.942 g/cm 3 , or 50.1% theoretical maximum density. The purpose of these experiments was to provide data to help make an assessment of the effects that damage has on the material sensitivity to a planar shock. This was achieved primarily by providing shock sensitivity data in the form of a Pop plot, and also reactants equation of state data, which aids in the determination of input conditions for both the experiments performed in this work and also future experiments of this material type. The experiments were of a cut-back format, consisting of four sample heights on each shot and diagnosed with optical velocimetry. The experiments were carried out at the Technical Area 40 Chamber 9 gas gun facility at the Los Alamos National Laboratory, where the LX-14 targets were subjected to Al 6061 and Oxygen Free High Conductivity copper impactors launched to velocities up to 2.14 km/s. Time corrected reactive growth wave profiles are presented in this paper along with the derivation of the following Hugoniot parameters for this explosive, where the molding powder and machine swarf are represented by the following linear equations, respectively, U s = 1.64 (±0.64)u p + 2.25 (±0.49) and U s = 0.87 (±.0.60)u p + 4.08 (±0.49). The results show that the steady increase in shock sensitivity with increasing void fraction reaches an inflection point beyond which the shock sensitivity begins to decease. This inflection point lies between 65% and 50% of the theoretical maximum density of the LX-14. In both cases, the damaged LX-14 was not as sensitive as expected, with a relative shock sensitivity of the molding powder being less than the pressed LX-14, and the machined swarf having a shock sensitivity that is comparable to pressed LX-14.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Estimation of cutting tool wear using an elastomeric tactile sensor

Machining performance of cutting tools and part quality are affected by the geometric condition of the cutting edge, which is influenced by thermomechanical loads experienced during the process. Tool condition monitoring (TCM) systems provide insight for timely replacement of cutting tools. However, existing TCM systems are expensive and require specialized equipment or sensors, hindering widespread adoption. A novel TCM system is developed herein using an elastomeric tactile sensor. Sensor images of the cutting edge are used to quantify wear using two distinct algorithms. In the first algorithm, the unworn and worn edges are identified based on Canny edge detect. In the second, the unworn edge is identified using edge detection while the region of wear is identified using a relative intensity method. In both cases, the maximum wear width is calculated based on an experimentally determined pixel to-physical distance scale. The TCM system is first used to estimate flank wear on a solid carbide helical end mill before evaluating its robustness by employing it to estimate insert wear of an indexable helical end mill. Measurements are also performed manually using an optical microscope and a high-resolution focus variation microscope for verification. The novel technique estimates flank wear in the solid carbide tool with a high accuracy of 98%. Larger discrepancies are observed for the inserts, however, with overlapping uncertainties. In conclusion, the technique shows promise in adaptability, automation, and closed loop control of machine tools.

Machining↗

Analytical insights into the interplay of momentum, multiplicity, and the speed of sound in heavy-ion collisions

We introduce a minimal model of ultracentral heavy-ion collisions to study the relation between the speed of sound of the produced plasma and the final particles' energy and multiplicity. We discuss how the particles' multiplicity N tot and average energy E tot / N tot is related to the speed of sound c s by c s 2 = d ln ( E tot / N tot ) / d ln N tot if the fluid is inviscid, its speed of sound is constant and all final particles can be measured. We show that finite rapidity cuts on the particles' multiplicity N and energy E introduce corrections between c s 2 and d ln ( E / N ) / d ln N that depend on the system's lifetime. We study analytically these deviations with the Gubser hydrodynamic solution, finding that, for ultrarelativistic bosons, they scale as the ratio of the freeze-out temperature T FO over the maximum initial temperature of the fluid T 0 ; the nonthermodynamic aspect of these corrections is highlighted through their dependence on the system's initial conditions. Published by the American Physical Society 2024

Physics↗

Applications of Lifted Nonlinear Cuts to Convex Relaxations of the AC Power Flow Equations

Here, we demonstrate that valid inequalities, or lifted nonlinear cuts (LNC), can be projected to tighten the Second Order Cone (SOC), Convex DistFlow (CDF), and Network Flow (NF) relaxations of the AC Optimal Power Flow (AC-OPF) problem. We conduct experiments on 38 cases from the PGLib-OPF library, showing that the LNC strengthen the SOC and CDF relaxations in 100% of the test cases, with average and maximum differences in the optimality gaps of 6.2% and 17.5% respectively. The NF relaxation is strengthened in 46.2% of test cases, with average and maximum differences in the optimality gaps of 1.3% and 17.3% respectively. We also study the trade-off between relaxation quality and solve time, demonstrating that the strengthened CDF relaxation outperforms the strengthened SOC formulation in terms of runtime and number of iterations needed, while the strengthened NF formulation is the most scalable with the lowest relaxation quality improvement due to these LNC.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Efficient Computation of Doppler-Broadened Elastic Scattering Kernel Moments Using Ladder-Operator Formulation

Anefficient routine for computing Legendre moments of the Doppler-broadened elastic scattering kernel, including resonance scattering effects, has been implemented in the ISOXML module of Griffin. Isotropic scattering in the center-of-mass system and the ideal gas model for target motion are assumed. A ladder-operator formulation is introduced to compute all Legendre moments from order 0 to N simultaneously, enabling near-linear scaling of computational cost with respect to the maximum Legendre order. A physics-based strategy for constructing outgoing energy grids has also been developed, in which a tailored base grid is combined with adaptive refinement to maintain accuracy while limiting the number of outgoing energy points. For energies between resonances, a constant cross-section model is employed to further reduce computational cost. In addition, a quantitative criterion is derived to determine isotope-wise cut-off incident energies based on a prescribed up-scattering probability coverage. For 238U, up to incident energies of approximately 75, 230, and 661 eV at 294, 900, and 2500 K (corresponding to a 2% up-scattering probability threshold), computation of P0 kernels requires 1–8 s and computation of P0–P5 kernels requires 0.4–4 min using a single thread, while maintaining 1–3% relative error in up-scattering probability. These results demonstrate that the proposed formulation enables accurate and computationally practical Doppler-broadened kernel generation for online multigroup cross-section production in Griffin.

Doppler-broadening↗

Method for optimization of huff-n-puff gas injections in hydrocarbon reservoirs

Methods for optimization of liquid oil production by huff-n-puff in shale reservoirs to achieve an improved (and optimal) oil recovery factor. The process determines and utilizes the optimum huff and puff times, number of cycles and soaking time under practical operation and reservoir conditions. The huff time in the process is a period so long that the pressure near the wellbore reaches the set maximum injection pressure during the huff period. The puff time in the process is the time required for the pressure near the wellbore to reach the set minimum production pressure during the puff period. Soaking is typically not necessary during the huff-n-puff gas injection in shale oil reservoirs. The number of huff-n-puff cycles is determinable by the time in which the economic rate cut-off is reached.

Sheng, James J.↗

Method for optimization of huff-n-puff gas injection in hydrocarbon reservoirs

Methods for optimization of liquid oil production by huff-n-puff in shale reservoirs to achieve an improved (and optimal) oil recovery factor. The process determines and utilizes the optimum huff and puff times, number of cycles and soaking time under practical operation and reservoir conditions. The huff time in the process is a period so long that the pressure near the wellbore reaches the set maximum injection pressure during the huff period. The puff time in the process is the time required for the pressure near the wellbore to reach the set minimum production pressure during the puff period. Soaking is typically not necessary during the huff-n-puff gas injection in shale oil reservoirs. The number of huff-n-puff cycles is determinable by the time in which the economic rate cut-off is reached.

Sheng, James J.↗

Quaternary slip rates and most recent surface rupture of the Bitterroot fault, western Montana

The Bitterroot fault is a ~100-km-long Quaternary active normal fault that bounds the eastern margin of the north–south-trending Bitterroot Mountains and accommodates extension near the Intermountain Seismic Belt. Here, new detailed mapping using high-resolution topographic data derived from light detection and ranging (lidar) along the southern Bitterroot Range documents multiple generations of fault scarps in Holocene–Pleistocene deposits with vertical off sets that increase in magnitude with age. Fault mapping indicates a complex fault geometry characterized by an en echelon pattern of discontinuous segments of 41–78° east-dipping normal faults that appear to cut the older Eocene detachment fault, and locally 70–88° west-dipping antithetic normal faults. 10 Be cosmogenic exposure dating provides in situ age control for 32 surface boulders (>1 m) sampled in glacial deposits. Near Como Dam, two Pinedale-age glacial moraine sequences yield peak age distributions of 15.0 ± 0.4 ka and 16.4 ± 0.6 ka as apparent exposure ages (e = 0), and 15.4 ± 0.4 ka and 16.8 ± 0.6 ka based on the maximum allowed boulder surface erosion rate (e = 2 mm/ka). Vertical separation of 3.5 ± 0.2 m across the ~16–17 ka glacial moraine off set by the Bitterroot fault scarp yields a fault slip rate of 0.2–0.3 mm/yr. Glacial Lake Missoula highstand shorelines, inset into the ~15 ka glacial moraine and vertically off set 4.6 ± 1.6 m by an antithetic strand of the Bitterroot fault, yield fault slip rates of 0.2–0.5 mm/yr that overlap with fault slip rates on the main strand near Lake Como (0.2–0.3 mm/yr). At the Ward Creek fan located ~15 km to the north of Lake Como, two glacial debris fan sequences yield peak age distributions of 16.6 ± 0.4 ka and 62.8 ± 1.7 ka (e = 0), and 17.0 ± 0.4 ka and 69.9 ± 2.2 ka (e = 2 mm/ka). Vertical separations of 2.4 ± 0.3 m and 4.5 ± 0.2 m on the ~17 ka and ~63–70 ka fan surfaces off set by the Bitterroot fault yield fault slip rates of 0.2–0.3 mm/yr and 0.1 mm/yr, respectively. Our results indicate broadly consistent fault slip rates for the main fault segments at Lake Como (0.2–0.3 mm/yr) and the Ward Creek fan (0.1–0.3 mm/yr) with an along-strike range of 0.1–0.3 mm/yr for the southern Bitterroot fault. Fault scaling relations and evidence of multiple late Quaternary fault surface ruptures suggest the Bitterroot fault could produce a Mw ~7.2 earthquake. Structural model constraints and our slip rate results indicate both high-angle or low-angle fault geometries are possible at depth. A seismogenic low-angle fault model could generate a larger earthquake of Mw >7.2. Earthquake history is unknown for the Bitterroot fault, but fault scarps in young glacial deposits demonstrate its seismogenic potential. Data from this study suggest seismic hazards from the Bitterroot fault may pose a high level of risk to the Missoula metropolitan area, the State’s second most populous region, and major infrastructures across the Missoula and Bitterroot Valleys.

58 GEOSCIENCES↗

Magnon heat transport in a two-dimensional Mott insulator

Whether or not anomalies in the thermal conductivity in insulating cuprates can be attributed to antiferromagnetic order and magnons in a 2D Mott insulator remains an intriguing open question. To shed light on this issue, we investigate the thermal conductivity $\kappa$ and its relationship with the specific heat $c_v$ in the half-filled 2D single-band Hubbard model, using the numerically exact determinant quantum Monte Carlo algorithm and maximum entropy analytic continuation. At low temperatures where the charge degrees of freedom are gapped-out and $c_v$ exhibits a clear magnon peak, we observe that thermal conductivity $\kappa$ also tends to form a peak at similar temperatures. Reducing temperature further produces a sharp upturn in $\kappa$, associated with an increasing mean-free path. Here we identify this as the high-temperature side of the anomalous peak in insulating cuprates, where the mean-free path eventually is cut-off by other scattering effects, including phonons, disorder, and physical size. Different scattering effects in our model are identified and analyzed in the thermal diffusivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Enhanced heavy oil recovery by low salinity polymer flood combined with microgel treatment

“Heavy oil resources account for a large portion of the total oil reserves around the world. The target heavy oil reservoir is located on Alaska’s North Slope (ANS). Advantages of low-salinity HPAM polymer (LSP) over high-salinity polymer (HSP) were demonstrated. LSP could recover more oil with 40% less polymer consumption. No additional oil was recovered by HSP after LSP flood. The first-ever polymer flood pilot on ANS showed remarkable success regarding water cut reduction, oil production increase, delayed breakthrough, and projected oil recovery improvement. Polymer alone was insufficient to achieve satisfactory recovery as the reservoirs were highly heterogeneous. Microgels could improve the effectiveness of polymer flood by reducing water cut and increasing oil recovery. Favorable working conditions were identified. Microgel transport behavior was studied using superpermeable sandpacks (27-221 darcies) with multiple pressure sensors. The particle-to-pore matching size ratio significantly impacted the effectiveness of the gels. A threshold differential pressure (ΔPth) and critical pressure gradient (∇Pcr) were required to push the gels to penetrate and propagate through the channels. The ΔPth and ∇Pcr revealed the underlying mechanisms of selective penetration/placement behavior of microgels in heterogeneous reservoirs. Diagrams were developed to estimate the maximum propagation distance of the gels in channels in conceptual field applications. Sandwich-like channel models and methodologies were developed to comprehensively evaluate the effectiveness of gel materials. Gel retention in the channels was quantified. Results also indicated that the retained gels were dehydrated. Fluid diversion and sweep improvement after gel treatments were evaluated by tracer tests”--Abstract, page iv.

Zhao, Yang↗

Proton beam quality enhancement by spectral phase control of a PW-class laser system

We report on experimental investigations of proton acceleration from solid foils irradiated with PW-class laser-pulses, where highest proton cut-off energies were achieved for temporal pulse parameters that varied significantly from those of an ideally Fourier transform limited (FTL) pulse. Controlled spectral phase modulation of the driver laser by means of an acousto-optic programmable dispersive filter enabled us to manipulate the temporal shape of the last picoseconds around the main pulse and to study the effect on proton acceleration from thin foil targets. The results show that applying positive third order dispersion values to short pulses is favourable for proton acceleration and can lead to maximum energies of 70 MeV in target normal direction at 18 J laser energy for thin plastic foils, significantly enhancing the maximum energy compared to ideally compressed FTL pulses. The paper further proves the robustness and applicability of this enhancement effect for the use of different target materials and thicknesses as well as laser energy and temporal intensity contrast settings. We demonstrate that application relevant proton beam quality was reliably achieved over many months of operation with appropriate control of spectral phase and temporal contrast conditions using a state-of-the-art high-repetition rate PW laser system.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Net-Zero Carbon Microgrids

The microgrid concept has been effective in creating aggregations of distributed energy resources—generation, storage and loads—for resiliency, in the form of energy security. The success of microgrids in bringing energy security to a wide range of customers—from individual residences to commercial and industrial installations to military bases—has been exemplified during power disruptions and extended outages due to extreme weather events, cybersecurity attacks, and equipment failures. Now microgrids have an opportunity to meet the challenges of climate change and contribute to a carbon-free power delivery system. The transition to net-zero starts within microgrids themselves. In fact, today’s microgrids are largely dominated by generators using fossil fuels, natural gas and diesel, with high greenhouse gas emissions. In short, the transition to net-zero means replacing fossil fueled generators with renewable generation in microgrids. This transition is extended by including new dispatchable generation technologies that are 100% carbon-free and that offer additional advantage of a more-dependable and sustainable source of energy and power. Basically, the decarbonization of microgrids requires three elements: 1) maximizing generation from renewable energy resources, 2) management of storage and flexible loads to balance the variability and intermittency of renewable energy resources, and 3) introducing new clean power sources, including hydrogen-based generation and small modular reactors. This report affirms a need for specific focus by governmental agencies at national, regional, and local levels to establish technology, policy, and investment in this area. The intention of the Net-Zero Microgrid (NZM) Program is to inform these constituencies with cross-cutting research and tools for the reduction of GHG in microgrids – to net-zero in the near term eventually to zero in the longer term. The NZM Program is committed to achieving decarbonization for resiliency and for providing clean energy at the local or distribution level, from remote communities to underserved communities, and large industrial and military facilities. The NZM Planning and Design Platform is a core tool to be developed as an early deliverable of the NZM Program because only a fully integrated microgrid-design approach will ensure maximum carbon reduction in energy production.

13 HYDRO ENERGY↗

Genome-scale metabolic rewiring improves titers rates and yields of the non-native product indigoidine at scale

Abstract High titer, rate, yield (TRY), and scalability are challenging metrics to achieve due to trade-offs between carbon use for growth and production. To achieve these metrics, we take the minimal cut set (MCS) approach that predicts metabolic reactions for elimination to couple metabolite production strongly with growth. We compute MCS solution-sets for a non-native product indigoidine, a sustainable pigment, in Pseudomonas putida KT2440, an emerging industrial microbe. From the 63 solution-sets, our omics guided process identifies one experimentally feasible solution requiring 14 simultaneous reaction interventions. We implement a total of 14 genes knockdowns using multiplex-CRISPRi. MCS-based solution shifts production from stationary to exponential phase. We achieve 25.6 g/L, 0.22 g/l/h, and ~50% maximum theoretical yield (0.33 g indigoidine/g glucose). These phenotypes are maintained from batch to fed-batch mode, and across scales (100-ml shake flasks, 250-ml ambr®, and 2-L bioreactors).

59 BASIC BIOLOGICAL SCIENCES↗