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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Soil organic carbon accrual due to more efficient microbial utilization of plant inputs at greater long-term soil moisture

High long-term soil moisture may either stimulate or inhibit soil organic carbon (SOC) losses through changes to mineral and chemical composition, and resultant organo-mineral interactions. Yet, the trade-off between mineralization and accrual of SOC under long-term variation in unsaturated soil moisture remains uncertain. We tested the underexplored relationships between long-term soil moisture and organo-mineral chemical composition and its implications for SOC persistence in an experimental field in New York, USA, with differences in long-term mean soil volumetric water content (0–0.15 m depth) ranging from 0.40 to 0.63 (v/v) during the growing season. Long-term soil moisture across 20 subplots on four fallow plots were positively correlated with SOC (R 2 = 0.23; P = 0.019, n = 20), mineral-associated organic matter (MAOM) content (g fraction/g soil) (R 2 = 0.44; P = 0.001; n = 20) and occluded particulate organic matter (oPOM) content (R 2 = 0.18; P = 0.033; n = 20). Higher long-term soil moisture was associated with a decrease in the relative content of sodium pyrophosphate extractable Fe (R 2 = 0.33; P < 0.005; n = 20), an increase in sodium dithionite extractable Fe (R 2 = 0.44; P < 0.001; n = 20), and an increase in SOC retention by non-crystalline Al pools (R 2 = 0.51; P = 0.0002 for sodium pyrophosphate extracts, R 2 = 0.41; P = 0.0014 for hydroxylamine hydrochloride extracts; n = 20 for both). Increasing long-term soil moisture was associated with a four-fold increase in microbial biomass C (per unit SOC) and lower metabolic quotient (R 2 = 0.56, P < 0.001). MAOM fractions of high-moisture soils had lower C:N (from C:N 9.5 to 9.0, R 2 = 0.27, P = 0.011, n = 20). Consistent with decreasing C:N, increasing decomposition with increasing moisture was reflected by a 15% and 10% greater proportion of oxidized carboxylic-C to aromatic-C and O-alkyl C, respectively, as measured with 13 C NMR, and a more pronounced FTIR signature of N-containing proteinaceous compounds in high-moisture MAOM fractions, indicative of microbial metabolites and transformation products. A partial least squares regression showed that SOC content increased with greater long-term moisture (P = 0.019), pyrophosphate-extractable Al (P = 0.0001), and exchangeable Ca (P = 0.013). Here our results show that higher long-term soil moisture resulted in SOC accrual by enhancing conversion of plant inputs into microbial biomass that interacts with reactive minerals.

58 GEOSCIENCES↗
NASA NTRS1989

Relativistic magnetospheric electrons: Lower ionospheric conductivity and long-term atmospheric variability

Long term observations of relativistic electrons in the earth's outer magnetosphere show a strong solar cycle dependence with a prominent intensity maximum during the approach to solar minimum. This population therefore closely corresponds to the presence of high speed solar wind streams emanating from solar coronal holes. Using a numerical code, the precipitating electron energy deposition in the earth's upper and middle atmosphere were calculated. Observed events (typically persisting several days) would have maximum effect in the 40 to 60 km altitude range with peak energy depositions greater than 110 keV/cu cm-s. It is suggested that this electron population could play an important long term role in modulating lower D region ionization and middle atmospheric ozone chemistry. Methods are described of observing middle atmospheric and lower ionospheric effects of the electrons including balloon, riometer, and space-based ozone sensor systems. A particularly promising approach may involve the monitoring of global Schumann resonance modes which are sensitive to global changes in the properties of the earth-ionosphere cavity. Present work indicates that Schumann resonance properties are moderately correlated with the flux of precipitating relativistic electrons thus offering the possibility of continuously monitoring this aspect of magnetosphere-atmosphere coupling.

Baker, D. N.↗
NASA NTRSDate not supplied

Abrasive Effects of Lunar Regolith on Material Wear for Long-Term Lunar Applications

Long-term operations on the Moon’s surface require materials that can withstand the harsh lunar environment. Lunar dust and regolith pose significant threats to the long-term durability of materials used in lunar applications. Lunar dust, easily perturbed and dispersed, adheres and abrades materials due to its rough and irregular grain morphology. More closely representing this abrasion action through experimental laboratory testing is critical in assessing the durability of potential lunar candidate materials used in mechanical, sensor, and human-based systems. In this study, the performance of materials using Taber abrasive wheels made from lunar regolith simulant was assessed and compared to results obtained using standard ceramic-based abrasion materials. The results highlight a difference in the abrasive wear rates between the lunar regolith simulant and the standard ceramic-based abrasive. Utilizing the mechanisms and testing capabilities of this two-body abrasive interaction leveraging regolith-based abrasives may more closely represent the interplay between materials and lunar dust, which is vital for assessing the long-term viability of materials for extended lunar missions. Improved lunar testing capabilities may also enhance evaluations of the long-term performance degradation of passive and active dust mitigation methods.

Zachary Stein↗
DOE OSTI2023

Long-term ultrasonic monitoring of concrete affected by alkali-silica reaction

This article presents continuous monitoring results of alkali-silica reaction (ASR) development in concrete specimens for over 400 days using ultrasonic testing and expansion measurements. Eight concrete specimens with nonreactive aggregate (Control), reactive coarse aggregate, and reactive fine aggregates were cast with two reinforced confinement conditions. The specimens were conditioned in an environmental chamber with high temperature and humidity (38°C and 90% relative humidity) to accelerate the ASR development. A multichannel ultrasonic monitoring system was developed to collect ultrasonic signals automatically, and the expansions in three directions were measured periodically. Results showed that the relative velocity change could detect the ASR initiation in all reactive specimens and show a correlation with expansion in the early stage. However, these correlations are inconsistent for different ASR specimens, and the velocity change becomes less sensitive to ASR damage in the late stage (after 300 days). Irrecoverable velocity drop was observed during every chamber shutdown period, especially in specimens with higher levels of ASR damage. This phenomenon suggests that the nonlinear ultrasonic response caused by the ambient temperature variation may indicate the ASR damage.

Engineering↗
NASA NTRSDate not supplied

Homogenization of Satellite Based Hyperspectral Infrared Sounder Data To Build Long Term Climate Record

Building long term climate record using data from multiple hyperspectral Infrared (IR)sounders requires the homogenization of different data record to ensure the consistency andcontinuity. Such a requirement comes from two perspectives: 1) the need to adjust theoverlapping measurements of different sounders to ensure the radiometric consistency in thespectral radiance domain; 2) the need for a rigorously defined scheme to ensure the radiometricconsistency being transferred to the essential climate variables derived from the radiance record.We develop a solution that uses a spectral fingerprinting scheme to derive anomalies of keyclimate variables from long term spectral radiance data record constructed using both AIRS andCrIS observations aboard AQUA, SNPP and JPSS satellites. The fingerprinting scheme usescommon radiative kernels for all sounder measurements and therefore effectively avoids thealgorithm introduced inconsistency in retrieved geophysical variables. Our approach uses aunified sampling scheme to match AIRS and CrIS observations in both spectral and spatial-temporal domain, facilitating the intercomparison of spectral radiances from different sensors(platforms). The optimized liner inversion scheme allows the direct quantification and thereforethe adjustment for the impact on the derived climate anomalies imposed by potential radiometricinconsistency between the overlapping measurements. Such a scheme also enables the low-latency data processing of long term hyperspectral sounder data records. This paper provides a detailed introduction of the spectral fingerprinting methodology.Also introduced here is the climate fingerprinting Sounder Product (ClimFiSP) developed basedon the fingerprinting methodology. ClimFiSP products include the space-time averagedproperties of key climate variables that are derived from the long-term, space-time averagedradiances from AQUA-AIRS, SNPP-CrIS, and JPSS1-CrIS. ClimFiSP will be available to usersthrough NASA'sGoddard Earth Sciences Data and Information Services Center (GES DISC).

Wan Wu↗
DOE OSTI2025

Assessing the Long-Term Stability of Anion Exchange Membranes for Electrochemical CO 2 Reduction

Materials and cell components used in CO 2 electrolysis have largely been adapted from technologies initially developed for water electrolysis and fuel cells. However, electrochemical CO 2 reduction introduces distinct material challenges due to the unique chemical environment in this process. Here, in this study, we conducted ex-situ 1000 h stability tests on commonly used anion exchange membranes, exposing them exclusively to electrolytes and organic molecules used or produced during CO 2 electrolysis, at concentrations relevant to and compatible with postseparation processes. Notably, 15% w/w n-propanol and 5 M acetic acid caused complete dissolution or partial disintegration of the membranes unless cross-linking was present and remained stable throughout the test. When the membranes stayed physically intact, most of them exhibited excellent chemical stability in alkaline medium containing alcohols or formic acid, which was confirmed by vibrational spectroscopy and ion exchange capacity measurements. However, exposure to alcohol-and acid-containing solutions led to a substantial increase in swelling and water uptake, with potential implications for mechanical stability, ion/product crossover, and compression management of adjacent components. The potential effects of CO 2 electroreduction products on membrane stability, their subsequent impact on electrolyzer performance, and mitigation strategies are discussed.

CO2RR↗
NASA NTRS2004

Common Calibration Source for Monitoring Long-term Ozone Trends

Accurate long-term satellite measurements are crucial for monitoring the recovery of the ozone layer. The slow pace of the recovery and limited lifetimes of satellite monitoring instruments demands that datasets from multiple observation systems be combined to provide the long-term accuracy needed. A fundamental component of accurately monitoring long-term trends is the calibration of these various instruments. NASA s Radiometric Calibration and Development Facility at the Goddard Space Flight Center has provided resources to minimize calibration biases between multiple instruments through the use of a common calibration source and standardized procedures traceable to national standards. The Facility s 50 cm barium sulfate integrating sphere has been used as a common calibration source for both US and international satellite instruments, including the Total Ozone Mapping Spectrometer (TOMS), Solar Backscatter Ultraviolet 2 (SBUV/2) instruments, Shuttle SBUV (SSBUV), Ozone Mapping Instrument (OMI), Global Ozone Monitoring Experiment (GOME) (ESA), Scanning Imaging SpectroMeter for Atmospheric ChartographY (SCIAMACHY) (ESA), and others. We will discuss the advantages of using a common calibration source and its effects on long-term ozone data sets. In addition, sphere calibration results from various instruments will be presented to demonstrate the accuracy of the long-term characterization of the source itself.

Kowalewski, Matthew↗
DOE OSTI2022

Negative hydrogen ion sources for particle accelerators: Sustainability issues and recent improvements in long-term operations

High brightness, negative hydrogen ion sources are used extensively in scientific facilities operating worldwide. Negative hydrogen beams have become the preferred means of filling circular accelerators and storage rings as well as enabling efficient extraction from cyclotrons. Several well-known facilities now have considerable experience with operating a variety of sources such as RF-, filament-, magnetron- and Penning-type H- ion sources. These facilities include the US Spallation Neutron Source (SNS), Japan Proton Accelerator Research Complex (J-PARC), Rutherford Appleton Laboratory (RAL-ISIS), Los Alamos Neutron Science Center (LANSCE), Fermi National Accelerator Laboratory (FNAL), Brookhaven National Laboratory (BNL), numerous installations of D-Pace (licenced by TRIUMF) ion sources used mainly on cyclotrons and, most recently, the CERN-LINAC-1 injector. This report first summarizes the current performance of these ion sources in routine, daily operations with attention toward source service-periods and availability metrics. Sustainability issues encountered at each facility are also reported and categorized to identify areas of common concern and key issues. Recent ion source improvements to address these issues are also discussed as well as plans for meeting future facility upgrade requirements.

Welton, Robert F.↗
DOE OSTI2020

Transcriptomic Profiles of Zymomonas mobilis 8b to Furfural Acute and Long-Term Stress in Both Glucose and Xylose Conditions

Zymomonas mobilis 8b is an ethanologenic bacterium engineered to utilize both glucose and xylose. The impacts of lignocellulosic hydrolyzate inhibitors on the growth of Zymomonas mobilis 8b have been investigated. However, the molecular responses of these inhibitors have not been completely elucidated yet. In this study, molecular responses to furfural were investigated using transcriptomic approaches of both chip-based microarray and a directional mRNA-Seq. Furfural acute shock time-course experiment with 3 g/L furfural supplemented when cells reached exponential phase and stress response experiment in the presence of 2 g/L furfural from the beginning of fermentation were carried out to study the physiological and transcriptional profiles of short-term and long-term effects of furfural on 8b. Furfural negatively affected 8b growth in terms of final biomass and the fermentation time. Transcriptomic studies indicated that the response of 8b to furfural was dynamic and complex, and differences existed between short-term shock and long-term stress responses. However, the gene function categories were similar with most down-regulated genes related to translation and biosynthesis, while the furfural up-regulated genes were mostly related to general stress responses. Several gene candidates have been identified and genetic studies indicated that expression of ZMO0465 and cysteine synthase operon ZMO0003-0006 driven by its native promoter in a shuttle vector enhanced the furfural tolerance of 8b. In addition, the relationship between microarray and mRNA-Seq was compared with good correlations. The directional mRNA-Seq data not only provided the gene expression profiling, but also can be applied for transcriptional architecture improvement to identify and confirm operons, novel transcripts, hypothetical gene functions, transcriptional start sites, and promoters with different strength.

09 BIOMASS FUELS↗
DOE OSTI2020

Multi-year incubation experiments boost confidence in model projections of long-term soil carbon dynamics

Abstract Global soil organic carbon (SOC) stocks may decline with a warmer climate. However, model projections of changes in SOC due to climate warming depend on microbially-driven processes that are usually parameterized based on laboratory incubations. To assess how lab-scale incubation datasets inform model projections over decades, we optimized five microbially-relevant parameters in the Microbial-ENzyme Decomposition (MEND) model using 16 short-term glucose (6-day), 16 short-term cellulose (30-day) and 16 long-term cellulose (729-day) incubation datasets with soils from forests and grasslands across contrasting soil types. Our analysis identified consistently higher parameter estimates given the short-term versus long-term datasets. Implementing the short-term and long-term parameters, respectively, resulted in SOC loss (–8.2 ± 5.1% or –3.9 ± 2.8%), and minor SOC gain (1.8 ± 1.0%) in response to 5 °C warming, while only the latter is consistent with a meta-analysis of 149 field warming observations (1.6 ± 4.0%). Comparing multiple subsets of cellulose incubations (i.e., 6, 30, 90, 180, 360, 480 and 729-day) revealed comparable projections to the observed long-term SOC changes under warming only on 480- and 729-day. Integrating multi-year datasets of soil incubations (e.g., > 1.5 years) with microbial models can thus achieve more reasonable parameterization of key microbial processes and subsequently boost the accuracy and confidence of long-term SOC projections.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Comparison of Quinone-Based Catholytes for Aqueous Redox Flow Batteries and Demonstration of Long-Term Stability with Tetrasubstituted Quinones

Quinones are appealing targets as organic electrolytes for aqueous redox flow batteries (RFBs), but their utility continues to be constrained by limited stability under operating conditions. The present study evaluates the stability of a series water-soluble quinones, with redox potentials ranging from 605–885 mV vs. NHE, under acidic aqueous conditions (1 M H2SO4). Four of the quinones are examined as cathodic electrolytes in an aqueous RFB, paired with anthraquinone-2,7-disulfonate (AQDS) as the anodic electrolyte. The RFB data complement the solution stability measures and show that the most stable electrolyte is a tetrasubstituted quinone containing four sulfonated thioether substituents. The results highlight the importance of substituting all C–H positions of the quinone in order to maximize the quinone stability and set the stage for design of improve organic electrolytes for aqueous RFBs. The authors thank Joseph Fourie for assisting in the synthesis of compound 8. Financial support for this work was provided by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (SSS, TWR, JBG, CWA, YP), with supplemental contributions by the Wisconsin Alumni Research Foundation (WARF) through the WARF Accelerator Program (YQ and partial support for JBG, CWA, YP). NMR spectroscopy facilities were partially supported by the NSF (CHE-0342998 and CHE-1048642), a UW Madison Instructional Laboratory Modernization Award, and a gift from Paul J. and Margaret M. Bender.

aqueous flow batteries, quinones, organic, redox m↗
NASA NTRSDate not supplied

Conditions of the Toll-Like Receptors System of the Human Innate Immunity Cells During the Long-Term Isolation

During long duration missions onboard the International Space Station (ISS), alterations in T cell function and plasma cytokine profiles have been observed. Recent studies involving pattern recognition receptors (PRRs) have established that adaptation of innate immunity to long duration space flight occurs through changes in signal PRRs, Toll-like receptors (TLRs). Despite the fact that fundamental research of PRR molecular biology is far from complete, there are an increasing number of arguments confirming the important role of this system in regulating the initial stages of the adaptive immune response, as well as in the formation of autoimmune and allergic diseases. Long duration isolation is widely used by NASA as an analog for space flight with previous missions including several Antarctic bases, an undersea research station (NEEMO), and other isolation chambers. ‘SIRIUS’ is a multi-compartment pressurized facility at the IMBP in Moscow, Russia, in which subjects will spend 8 months executing tasks similar to those performed by astronauts in space. Prolonged isolation studies like SIRIUS replicate many of the influences expected to occur during long duration spaceflight missions including isolation, stress, confinement, and living in remote conditions. The immune study to be performed on the upcoming SIRIUS mission is being led by Dr. Sergey Ponomarev at the Institute of Biomedical Problems in Moscow, Russia. The NASA JSC Immunology lab will provide analysis of immune cell function, serum cytokines and stress hormones, and salivary cortisol, cytokines, and viruses. This study will be conducted with SIRIUS subjects under the auspices of the parent program. The goal of the study is to evaluate the effect of the 8-month isolation mission on components of human innate immunity at the molecular and cellular level. Successful implementation and completion of this project will provide a unique assortment of new data, significantly expanding the current understanding of the molecular and cellular changes in TLRs during long-term isolation. We hypothesize that mission-like isolation in the Russian NEK facility, consisting of circadian misalignment, isolation, stress, and ‘station lifestyle’, will result in a pattern of immune dysregulation similar to that observed in astronauts onboard ISS. This pattern of alterations can be summarized as phenotypic changes (altered distribution of peripheral cytotoxic, central memory, CD8+ T cell subsets), reductions in T cell function, alterations in plasma cytokine profiles (increased inflammatory and certain chemokines), and reductions in mitogen stimulated cytokine profiles (spans Th1, Th2, Th17). We further hypothesize that these immune changes will correlate with the reactivation of latent herpesviruses (which persists during orbital flight), to be used as measurable adverse clinical manifestation or with other observed symptomology. The SIRIUS-21 mission began in November of 2021 and successfully concluded with the crew emerging in July of 2022. Currently, the logistics of shipping the samples from Russia to the United States is being organized.

Cody L Gutierrez↗
DOE OSTI2021

An initial framework for the rapid qualification of long-term creep rupture strength via microstructural modeling

This report describes the development and testing of a new method for extrapolating short-term creep rupture test data to predict long-term rupture strength. The goal of this work is to reduce the time required to qualify new materials for nuclear service by reducing the lead time required for dedicated, long-term material testing to establish key long-term material properties. The new approach described here uses a physics-based model to predict the long-term creep rupture strength of 316H stainless steel using only short-term test data. The key idea is to use Bayesian inference to find the statistical distribution of the model parameters that best explain the short-term rupture data. Because the model is physics-based these parameters are all microstructural quantities that can be measured through detailed material characterization experiments. The Bayesian prior distributions provide a means for incorporating this characterization data into the final model to improve the accuracy of the long-term model predictions. However, where such data is not available the process still produces an accurate model based on an uniformed prior. Our hypothesis is that this approach more accurately extrapolates the short-term test data when compared to current, empirical methods. The report proves this hypothesis using actual long-term rupture data available for 316H, including tests with rupture times greater than 200,000 hours. The general approach developed here could be applied to other materials and other time-dependent material properties. Applying this new technique to develop long-term qualified material properties, potentially in conjunction with other accelerated qualification approaches like staggered qualification test programs, could greatly reduce the time required to qualify new materials for nuclear service.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗