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At least 37 records · Page 2

Theoretical performance of lithium and fluorine as a rocket propellant

Theoretical performance for liquid lithium and liquid fluorine as a rocket propellant was calculated with assumptions both of equilibrium and frozen composition during expansion. Parameters included were specific impulse, combustion-chamber temperature, nozzle-exit temperature, composition, mean molecular weight, characteristic velocity, coefficient of thrust, and ratio of nozzle-exit area to throat area. For chamber pressure of 300 pounds per square inch absolute and expansion to 1 atmosphere, the maximum equilibrium specific impulse calculated was 335.5 pound-seconds per pound. The effect of ionization on calculated performance was shown to be negligible by comparison of values of various parameters calculated both with and without ionized products of combustion.

FUELS -ROCKETS (INCLUDES FUELS AND OXIDANT)

Corrosion of oxygen-doped tantalum by lithium

The increase in the penetration of tantalum by liquid lithium with increasing oxygen content of tantalum results from the ability of lithium to extract oxygen from tantalum oxides and/or from regions of high oxygen concentrations, accompanied by the creation of minute channels. At low oxygen concentration, oxides are present primarily at the grain boundaries and the lithium penetration is primarily intergranular. At high oxygen concentration, oxides and/or regions of high oxygen concentration are present both at the grain boundaries and within the grains; lithium penetration is both intergranular and transgranular. For a specific oxygen concentration, the severity of corrosion decreases with increasing temperature because (1) the oxygen solubility increases with temperature, decreasing the number of oxide particles and/or regions of high oxygen concentration, and (2) the diffusivity of oxygen in tantalum increases, allowing more rapid oxygen removal at the tantalum lithium interface.

Stecura, S.

INFUSE:FLARED (Final Technical Report)

This report summarizes the final outcomes of the INFUSE:FLARED collaboration between Tokamak Energy (TE), the University of Illinois Urbana-Champaign (UIUC), and the Department of Energy (DOE). The project aimed to experimentally determine and model the pumping, absorption, and separation behavior of deuterium in flowing liquid lithium under gas and plasma exposure conditions. The work supports the development of lithium-based plasma-facing components (PFCs) and tritium management strategies for next-generation fusion plants.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Thermochemistry of tantalum-wall cooling system with lithium and sodium working fluids

Plots are presented which show the distribution of oxygen between liquid lithium and tantalum or niobium, and between liquid sodium and tantalum at elevated temperatures. Additional plots showing the composition of the gas phase above the solutions of oxygen and alkali metal are presented. The use of the plots is illustrated by an example tantalum heat pipe filled with lithium.

Tower, L. K.

Preparation of refractory cermet structures for lithium compatibility testing

High-purity nitride and carbide cermets were synthesized for compatability testing in liquid lithium. A process was developed for the preparation of high-purity hafnium nitride powder, which was subsequently blended with tungsten powder or tantalum nitride and tungsten powders and fabricated into 3 in diameter billets by uniaxial hot pressing. Specimens were then cut from the billets for compatability testing. Similar processing techniques were applied to produce hafnium carbide and zirconium carbide cermets for use in the testing program. All billets produced were characterized with respect to chemistry, structure, density, and strength properties.

Heestand, R. L.

Effects of negative triangularity on microinstabilities in a low-recycling lithium-wall spherical tokamak

In this work, we present a linear gyrokinetic study of the impact of negative triangularity (NT) on microinstabilities in the Lithium Tokamak eXperiment-β (LTX-β), a low-recycling spherical tokamak with liquid lithium plasma-facing components that produce flat electron-temperature profiles [Elliott et al., IEEE Trans. Plasma Sci. 48, 1382 (2020)]. While NT is widely recognized as a stabilizing mechanism and often associated with improved confinement in conventional tokamaks, this study reveals that its effect is not universally stabilizing in the parameter regime of LTX-β and is shown to be highly sensitive to local equilibria. Using local linear simulations with the GS2 code [Kotschenreuther et al., Comput. Phys. Commun. 88, 128 (1995)] at ρ=0.3, 0.5, and 0.8 for two representative discharges (#103955 and #109355), and employing the Miller equilibrium model to isolate shaping effects, we find that NT can transition from stabilizing to destabilizing depending on magnetic shear, safety factor, and electron-temperature gradient. In shot #103955, NT reduces growth rates across radii, with strongest stabilization at the edge, whereas in shot #109355, it is stabilizing in the core but destabilizing at mid-radius and edge under experimental conditions. Parametric scans show that flattening the electron-temperature profile, increasing magnetic shear, and reducing the safety factor recover NT stabilization. These results demonstrate that NT stabilization is tunable rather than intrinsic and requires coordinated control of magnetic geometry and gradient drive.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Aerospace Gas/Liquid Separator for Terrestrial Applications

The space gas/liquid separator, a key component in the heat transport subsystem of a space reactor power system, was developed to remove helium gas from liquid lithium in zero gravity. This application is opposite from the space application in that it is removing a liquid from a gas rather than a gas from a liquid.

space

Self-consistent modeling of tokamak edge plasma transport with lithium sources

Magnetic confinement fusion devices require effective heat and particle exhaust solutions on the divertor plates to operate sustainably, especially under reactor-relevant conditions. Liquid lithium divertors have been proposed to address two major challenges: control of excessive heat flux to plasma-facing components through vapor shielding and minimization of core plasma contamination from impurities. The National Spherical Torus Experiment-Upgrade (NSTX-U) will explore lithium as a divertor material due to its potential to meet both objectives. We present a self-consistent coupling framework between the plasma boundary transport code UEDGE and the lithium wall transport code Wall–Li to evaluate the feasibility and operational limits of lithium-based divertors. The model aims to optimize lithium sourcing levels to prevent core plasma contamination via fuel dilution while ensuring divertor protection through vapor shielding. This integrated framework, applicable to any tokamak with lithium sources, dynamically adjusts lithium sourcing based on local plasma conditions and surface temperature. The coupled model is tested using NSTX-like geometry and plasma conditions to assess its performance and reliability. Wall–Li calculates lithium fluxes from plasma-facing components, incorporating physical sputtering, thermally enhanced sputtering, and evaporation driven by surface temperature and ion flux. These fluxes are reintroduced into UEDGE as neutral lithium atoms, enabling simulation of their transport and distribution within the plasma. UEDGE computes plasma and neutral transport, surface heat flux, and iteratively feeds this information back to Wall–Li. A small time step is employed to ensure numerical stability and convergence, enabling accurate simulations over typical tokamak discharge durations. This integrated modeling approach provides a robust tool for identifying operational regimes that balance effective lithium sourcing with minimal core plasma contamination, offering critical insights for optimizing lithium-based divertor systems in current and future fusion devices.

Magnetic confinement fusion

Impact of nitrogen on lithium-induced corrosion and cracking of RAFM steel

The emergence of private fusion enterprises, combined with advancements in U.S. and EU ITER-TBM as well as EU DEMO liquid breeder blanket concepts, has renewed focus on the materials challenges. This study examines the compatibility of reduced activation ferritic/martensitic (RAFM) steel in liquid Lithium (Li) containing various Nitrogen (N) concentrations, tested at 600 and 700 °C for 500 and 1000 h under static conditions. Microstructural characterization revealed the corrosion-induced dissolution and precipitation in Li containing 0.082 and 0.17 wt.% N at 600 °C, while limited dissolution and precipitation were observed in N-gettered Li using zirconium (Zr) and titanium (Ti) foils at 600 °C. Tensile testing at room temperature after Li exposure revealed a decrease in strength and ductility of the RAFM steel as a function of N content in Li. Severe embrittlement was observed after 500 h in Li containing 0.17 wt.% N at 600 °C and after 500 h in hot-gettered Li at 700 °C. Chromium (Cr) depletion from the steel matrix was observed, leading to the formation of M6C-type carbides on the surface identified by electron microscopy (SEM), X-ray diffraction (XRD), in agreement with thermodynamic calculations. These findings highlight the critical materials challenges posed by liquid Li breeder blanket concepts, emphasizing the need for improved strategies to address Li-induced dissolution, precipitation, and steel embrittlement due to N contamination of the coolant.

Romedenne, Marie [ORNL] (ORCID:0000000317936561)

Large-Eddy Simulation of Conductive Flows at Low Magnetic Reynolds Number

In this paper we study the LES method with dynamic procedure in the context of conductive flows subject to an applied external magnetic field at low magnetic Reynolds number R(sub m). These kind of flows are encountered in many industrial applications. For example, in the steel industry, applied magnetic fields can be used to damp turbulence in the casting process. In nuclear fusion devices (Tokamaks), liquid-lithium flows are used as coolant blankets and interact with the surrounding magnetic field that drives and confines the fusion plasma. Also, in experimental facilities investigating the dynamo effect, the flow consists of liquid-sodium for which the Prandtl number and, as a consequence, the magnetic Reynolds number is low. Our attention is focused here on the case of homogeneous (initially isotropic) decaying turbulence. The numerical simulations performed mimic the thought experiment described in Moffatt in which an initially homogeneous isotropic conductive flow is suddenly subjected to an applied magnetic field and freely decays without any forcing. Note that this flow was first studied numerically by Schumann. It is well known that in that case, extra damping of turbulence occurs due to the Joule effect and that the flow tends to become progressively independent of the coordinate along the direction of the magnetic field. Our comparison of filtered direct numerical simulation (DNS) predictions and LES predictions show that the dynamic Smagorinsky model enables one to capture successfully the flow with LES, and that it automatically incorporates the effect of the magnetic field on the turbulence. Our paper is organized as follows. In the next section we summarize the LES approach in the case of MHD turbulence at low R(sub m) and recall the definition of the dynamic Smagorinsky model. In Sec. 3 we describe the parameters of the numerical experiments performed and the code used. Section 4 is devoted to the comparison of filtered DNS results and LES results. Conclusions are presented in Sec. 5.

Knaepen, B.

Understanding NBI heating and fueling in LTX-β tokamak

My work on the contract DE-SC=0023274 (July, 2022 - July, 2025) was focused on understanding the plasma fueling by NBI. On Dec. 1998 with Sergei Krasheninnikov (UCSD, San Diego, CA) we initiated the Li Wall Fusion (LiWFusion) as a new concept of magnetic fusion [1]. The new 1 2 plasma 3 4 5 6 2.1 Overview of rate coefficients, mean-free paths λH0 , and diffusions coefficients 6 2. GSV code for ⟨σv⟩ analysis of NBI fueling concept was a reaction of the lack of luck of tokamak fusion with QDT = 1 on TFTR and JET. We recognized the edge plasma cooling by recycling to be the route reason of the tokamak problems on the way to burning plasma. LiWFusion relies on plasma pumping by a lithium layer on the inner walls of the plasma chamber, combined with the plasma heating and fueling by the Neutral Beam Injection (NBI). These two innovations eliminate the route problem of the tokmak fusion. The concept became theoretically mature in 2006. In 2012, the technology of continuously Flowing Liquid Lithium (24/7-FLiLi) was invented by me for the future implementations of the LWFusion concept. At the same time, my every presentation on LiWFusion to International Symposium on Lithium Applications since 2010 was objected by some person with words “Everybody since the 1970s knows that plasma fueling by NBI is impossible”. I dropped the name of the author of this objection and ignored his views. My work on the current grant on NBI fueling of LTX-β not only clarified the issue but resolved it in an astonishing way. The NBI fueling was fully understood (thus humiliating the current dogmatic fusion community). The new future of LTX-β dedicated for decades to Li in tokamaks, as well as of the entire magnetic fusion program was envisioned, in sharp contrast with the fallure of OFES in the post-TFTR era of 21st century.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Evolution of systems concepts for a 100 kWe class Space Nuclear Power System

Conceptual designs for the SP-100 Space Nuclear Power System have been prepared that meet baseline, backup and growth program scenarios. Near-term advancement in technology was considered in the design of the Baseline Concept. An improved silicon-germanium thermoelectric technique is used to convert the heat from a fast-spectrum, liquid lithium cooled reactor. This system produces a net power of 100 kWe with a 10-year end of life, under the specific constraints of area and volume. Output of the Backup Concept is estimated to be 60 kWe for a 10-year end of life. This system differs from the Baseline Concept because currently available thermoelectric conversion is used from energy supplied by a liquid sodium cooled reactor. The Growth Concept uses Stirling engine conversion to produce 100 kWe within the constraints of mass and volume. The Growth Concept can be scaled up to produce a 1 MWe output that uses the same type reactor developed for the Baseline Concept. Assessments made for each of the program scenarios indicate the key development efforts needed to initiate detailed design and hardware program phases. Development plans were prepared for each scenario that detail the work elements and show the program activities leading to a state of flight readiness.

Katucki, R.

Upgrades to the Thomson Scattering Diagnostic on the Lithium Tokamak eXperiment-Beta (LTX-$β$)

We describe the upgrades to the Thomson scattering (TS) diagnostic on the Lithium Tokamak eXperiment-beta (LTX- β ) to provide complete radial coverage of the plasma. LTX- β is a spherical tokamak with plasma limited at a major radius of R = 14 cm and R = 66 cm. Flat temperature profiles with peaked density were observed in LTX- β using an existing multipoint TS diagnostic with radial coverage of the plasma core. There is a need for more comprehensive core and edge TS measurements to thoroughly examine beam fueling, beam heating, and transport under low recycling conditions with liquid lithium walls and a lower collisionality scrape-off layer (SOL). The core TS set up provides plasma profiles from R = 40–60 cm. To extend the TS diagnostic coverage: 1) we added a TS viewing optics to cover the SOL region at five radial points from R = 57–64 cm, and 2) another TS viewing optics in the HFS region from R = 15–45 cm to obtain TS data from ten radial positions while making use of the original laser beam. The main focus of this article is on the new HFS TS setup that is equipped with better-matched collection optics located in the horizontal midplane where the laser polarization lies and views from a scattering angle of 130°–150° with respect to the laser path. A set of unequal-length Y-branched fiber bundles transports the TS light from two radial points to each polychromator. The new HFS view is better matched in spot size, scattering angle, and throughput to the laser and polychromators and has new V-grooved style viewing dumps. The new HFS TS view, along with the core and SOL TS views, will provide a full radial measurement coverage from R = 15–64 cm to explore the flat temperature profiles.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Design and Analysis of the Open-Surface Slow Li Flow Divertor and Comparison to the Fast Li Flow Divertor

In the ongoing U.S. project, “Liquid Metal Plasma Facing Components,” sponsored by the U.S. Department of Energy, efforts have been taken to develop two open-surface divertor designs for the Fusion Nuclear Science Facility using liquid lithium (Li) as a heat and particle flux removal media. The main focus of this study is the design and analysis of a slow (~1 mm/s) and thin (<1 mm) open-surface Li flow divertor with a Li-cooled substrate, which is then compared with an earlier design of a fast (up to 10 m/s) and thick (~0.5 cm) Li flow divertor with the substrate cooled with helium. The slow Li flow divertor design is based on the original LiWall concept developed at the Princeton Plasma Physics Laboratory. Such a thin and slow Li layer can remove the particle flux by reducing the recycling flux, while the heat flux is removed mainly through the heat sink located beneath. In the present study, the heat sink is provided through a Li cooling flow inside the substrate of reduced activation ferritic/martensitic steel. By performing a multiphysics analysis with COMSOL that included liquid-metal magnetohydrodynamics (MHD), heat transfer, and structural mechanics, the impact of various factors on the divertor heat removal capability, such as Li flow velocity, MHD effects, and inlet velocity boundary condition, were examined. Based on comparisons of the two divertor designs, it was shown that the fast-flow divertor significantly outperformed the slow-flow design, whose heat removal capability was limited to ~1 to 2 MW/m2.

Jiang, Yuchen [ORNL] (ORCID:0000000283280284)