Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “kinetic distributions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

Excitation of the OI (3s 5S0-3p 5P; lambda 7774 A) multiplet by electron impact on O2

Electron impact on O2 has been employed to ascertain the absolute cross-section value and emission linewidths of the OI (3s 5S0-3p 5P; 7774 A) multiplet. The emission linewidths are highly Doppler-broadened in dissociative excitation, and display two distinct kinetic energy distributions: which indicate that both purely repulsive and discrete, bound, excited molecular states, which then predissociate, are involved in the dissociation process that leads to the excitation of OI 7774 A. The magnitude of the measured cross-section and the fragment kinetic energy distribution both indicate that the previous time-of-flight studies of the metastable OI (5S0) state require reinterpretation.

Erdman, P. W.↗

On the discontinuity in kinetic solutions of the collisionless polar wind

The use of a Maxwellian ion velocity distribution in kinetic solutions of the collisionless polar wind regime results in a velocity distribution and associated moments that display sharp discontinuities at the boundary, which quantitatively affects the solution at high altitudes. This paper investigates the causes of this discontinuity, using both analytical and numerical approaches; it is shown that the choice of appropriate boundary conditions will eliminate the discontinuity.

Khoyloo, A.↗

Spectral study of wintertime kinetic energy of the Northern Hemisphere in the troposphere

Characteristics of the kinetic energy of wind fields at various pressure levels were analyzed, and significant wavenumbers in the wavenumber-frequency domain were identified. The nonlinear interaction terms of the kinetic energy equation were examined, and the distribution of the kinetic energy at the 850 mb, 500 mb, and 200 mb levels was calculated. A 5 deg latitude-longitude square grid was used, with NMC data for the 1975-1976 winter in the 20-60 deg N at 500 mb and 20-85 deg N for the 200 mb and 850 mb levels. The kinetic energy distribution was determined to be geography-dependent, with wavenumbers 6-9 westerly waves in the midfrequency range contributing significantly to kinetic energy maxima over the North Pacific and the east coast of North America. The contribution of the nonlinear interactions of these waves, which correspond to the longitudinal convergence of the kinetic energy flux, was found to be larger than the meridional convergence of the kinetic energy flux, and to occur mainly between 30-50 deg N. The nonlinear interactions were a negative contribution over the North Pacific at the 200 mb level.

Lee, H. N.↗

A Detailed Level Kinetics Model of NO Vibrational Energy Distributions

Several contemporary problems have pointed to the desirability of a detailed level kinetics approach to modeling the distribution of vibrational energy in NO. Such a model is necessary when vibrational redistribution reactions are insufficient to maintain a Boltzmann distribution over the vibrational energy states. Recent calculations of the rate constant for the first reaction of the Zeldovich mechanism (N2 + O (goes to) NO + N) have suggested that the product NO is formed in high vibrational states. In shock layer flowfields, the product NO molecules may experience an insufficient number of collisions to establish a Boltzmann distribution over vibrational states, thus necessitating a level kinetics model. In other flows, such as expansions of high temperature air, fast, near-resonance vibrational energy exchanges with N2 and O2 may also require a level specific model for NO because of the relative rates of vibrational exchange and redistribution. The proposed report will integrate computational and experimental components to construct such a model for the NO molecule.

Sharma, Surendra P.↗

Numerical integration of kinetic equations.

Relaxation to Maxwellian of Balescu-Lenard equation solved numerically as initial value problem for isotropic distributions of electrons in background of positive charge

MAXWELL DISTRIBUTION↗

The seasonal cycle of energetics from the GLAS/UMD climate GCM

The annual cycle of atmospheric energetics from a 2-year integration of the GLAS/UMD Climate GCM is computed and compared to results from the European Centre analyses of the GWE year, and to previously published results on a global basis. All calculations are done in the mixed space-time domain. The main conclusions are: (1) the seasonal cycle of today's eddy kinetic energy (in both hemispheres), and of the transient eddy available potential energy and the potential-to-kinetic energy conversions (mean and eddy) in the Northern Hemisphere are well simulated by the GCM; (2) the GCM's tendency to have anomalously large mean u-winds at upper levels in high latitudes leads to excessive wintertime values of mean kinetic and available potential energies, and causes distortions in the GCM latitude-height distribution of kinetic energy and of many of the conversions; (3) the eddy conversion of available potential-to-kinetic energy obtained from the ageostrophic wind in these analyses; and (4) the conversions in the Southern Hemisphere are not well simulated by the GCM, although the observations are somewhat questionable.

Straus, David M.↗

Studies in electron phenomena in MOS structures: The pulsed C-V method

The pulse hysteresis capacitance voltage (C-V) provides a straight forward technique for measuring the change of various charges in MOS structures and a tool for investigating the kinetics of various electron phenomena is developed and described. The method can be used for measuring the energy distribution and kinetics of surface states with the resolution of about 1/5 x 10 to the -9 power cm eV. Some transients in an MOS structure, particularly, the thermal generation of minority charge carriers via surface states and the relaxation of minority charge carriers supplied from the inversion layer outside the MOS structure are theoretically investigated. Analytical expressions which clearly present the physics of those electron phenomena are derived.

Kaplan, G.↗

Line Profile of H Lyman (alpha) from Dissociative Excitation of H2 with Application to Jupiter

Observations of the H Lyman(alpha) (Ly-alpha) emission from Jupiter have shown pronounced emissions, exceeding solar fluorescence, in the polar aurora and equatorial "bulge" regions. The H Ly-alpha line profiles from these regions are broader than expected, indicating high-energy processes producing fast atoms as determined from the observed Doppler broadening. Toward understanding that process a high-resolution ultraviolet (UV) spectrometer was employed for the first measurement of the H Ly-alpha emission Doppler profile from dissociative excitation of H2 by electron impact. Analysis of the deconvolved line profile reveals the existence of a narrow central peak of 40 +/- 4 mA full width at half maximum and a broad pedestal base about 240 mA wide. Two distinct dissociation mechanisms account for this Doppler structure. Slow H(2p) atoms characterized by a distribution function with peak energy near 80 meV produce the peak profile, which is nearly independent of the electron impact energy. Slow H(2p) atoms arise from direct dissociation and predissociation of singly excited states which have a dissociation limit of 14.68 eV. The wings of H Ly-alpha arise from dissociative excitation of a series of doubly excited states which cross the Franck-Condon region between 23 and 40 eV. The profile of the wings is dependent on the electron impact energy, and the distribution function of fast H(2p) atoms is therefore dependent on the electron impact energy. The fast atom kinetic energy distribution at 100 eV electron impact energy spans the energy range from 1 to 10 eV with a peak near 4 eV. For impact energies above 23 eV the fast atoms contribute to a slightly asymmetric structure of the line profile. The absolute cross sections of the H Ly-alpha line peak and wings were measured over the range from 0 to 200 eV. Analytic model coefficients are given for the measured cross sections which can be applied to planetary atmosphere auroral and dayglow calculations. The dissociative excitation process, while one contributing process, appears insufficient by itself to explain the line broadening observed at Jupiter.

Ajello, Joseph M.↗

Dissociative excitation of H2, HD, and D2 by electron impact

Time-of-flight techniques have been used to investigate the electron-impact dissociation of H2, HD, and D2 in order to determine the effect of isotopic mass variation in the target molecule on the dissociative excitation process. At incident electron energies near 100 eV, the time-of-flight spectrum produced from each molecule consists of atoms in the metastable 2s state and in high-lying long-lived Rydberg levels. The individual time-of-flight distributions, kinetic-energy spectra, and relative differential cross sections for these two species resulting from each molecule have been measured. The kinetic-energy spectrum of the Rydberg atoms produced from dissociative excitation of H2 was notably dissimilar in shape from the corresponding distributions produced from HD and D2. Also the 2s and Rydberg production cross sections differed between the three molecules. In the dissociation of the heteronuclear HD molecule, the ratio of fast H(2s) atoms to D(2s) atoms was about 1 to 1, while the same ratio comparing the Rydberg atoms was nearly 2 to 1. These differences indicate the influence of the mass variation on the position of the Franck-Condon region in the production of 2s atoms and on the competition between autoionization and dissociation in the formation of Rydberg fragments.

Carnahan, B. L.↗

The vibrational distribution of N2(+) in the terrestrial ionosphere

The densities and vibrational distributions of N2(+) in the X2sigma g +, A2Pi u and B2sigma u + states in the daytime terrestrial ionosphere are computed for both low and high solar activity. Altitude profiles of the relative populations of the vibrational levels of N2(+) X2sigma g + are presented. The fraction of vibrationally excited N2(+) varies from 5 percent at 100 km to 50 percent at 450 km. Several models are examined in which loss of N2(+)(v) is enhanced for v greater than 0 and in which various assumptions are made about the vibrational distributions produced in charge transfer reactions. The N2(+) densities are significantly reduced if N2(+)(v) reacts with O at rates which are near gas-kinetic. Vibrational distributions of the A2pi u and B2sigma u + states are also presented, as well as volume emission rates and integrated overhead intensities of the major bands of the Meinel and first negative systems.

Fox, J. L.↗

High-resolution optical and ultraviolet absorption-line studies of interstellar gas

Recent progress in the characterization of the interstellar medium (ISM) by means of optical and UV spectral data is summarized. The gas is studied by focusing on background stars whose spectra can be accurately modeled to provide the light source for the absorption-line scans. The capabilities of earth- and space-based instruments which have been and are used for the surveys are delineated. The distributions of diffuse gas densities and characteristics of the cold, warm and hot gas in the Galaxy are described in terms of the elemental abundances, kinetics and distributions of the gas. Particular note is taken of gas in the solar neighborhood and around SNR, and of absorption-line data of cosmological significance.

Cowie, Lennox L.↗

Wavelet and Fractal Analysis of Remotely Sensed Surface Temperature with Applications to Estimation of Surface Sensible Heat Flux Density

Wavelet and fractal analyses have been used successfully to analyze one-dimensional data sets such as time series of financial, physical, and biological parameters. These techniques have been applied to two-dimensional problems in some instances, including the analysis of remote sensing imagery. In this respect, these techniques have not been widely used by the remote sensing community, and their overall capabilities as analytical tools for use on satellite and aircraft data sets is not well known. Wavelet and fractal analyses have the potential to provide fresh insight into the characterization of surface properties such as temperature and emissivity distributions, and surface processes such as the heat and water vapor exchange between the surface and the lower atmosphere. In particular, the variation of sensible heat flux density as a function of the change In scale of surface properties Is difficult to estimate, but - in general - wavelets and fractals have proved useful in determining the way a parameter varies with changes in scale. We present the results of a limited study on the relationship between spatial variations in surface temperature distribution and sensible heat flux distribution as determined by separate wavelet and fractal analyses. We analyzed aircraft imagery obtained in the thermal infrared (IR) bands from the multispectral TIMS and hyperspectral MASTER airborne sensors. The thermal IR data allows us to estimate the surface kinetic temperature distribution for a number of sites in the Midwestern and Southwestern United States (viz., San Pedro River Basin, Arizona; El Reno, Oklahoma; Jornada, New Mexico). The ground spatial resolution of the aircraft data varied from 5 to 15 meters. All sites were instrumented with meteorological and hydrological equipment including surface layer flux measuring stations such as Bowen Ratio systems and sonic anemometers. The ground and aircraft data sets provided the inputs for the wavelet and fractal analyses, and the validation of the results.

Schieldge, John↗

Particle acceleration near X-type magnetic neutral lines

The behavior of charged particles near X-type magnetic neutral lines is investigated. The magnetic field is taken to be hyperbolic and time stationary, with a uniform electric field perpendicular to the magnetic field. The general properties of the orbits of noninteracting particles in that field geometry are examined. Approximate analytic solutions to the orbit equations are derived by considering a magnetic-insulation picture where there is a hole in the magnetic insulation around the neutral line. Scaling laws for the dependence of the energy gain on strengths of the magnetic and electric fields are derived. The kinetic-energy distribution function for accelerated particles is derived for particles flowing past the neutral line. These analytic derivations are supported by computer simulations, in which the relativistic equations of motion for single test particles are numerically solved and the orbits and kinetic-energy gains of the particles are obtained. A number of simulations were performed and one parameter at a time was varied. Applications of the results to magnetic-neutral-line regions in space physics and astrophysics are possible.

Deeg, Hans-Jorg↗

Thermodynamics and statistical mechanics

The basic thermodynamic properties of gases are reviewed and the relations between them are derived from the first and second laws. The elements of statistical mechanics are then formulated and the partition function is derived. The classical form of the partition function is used to obtain the Maxwell-Boltzmann distribution of kinetic energies in the gas phase and the equipartition of energy theorem is given in its most general form. The thermodynamic properties are all derived as functions of the partition function. Quantum statistics are reviewed briefly and the differences between the Boltzmann distribution function for classical particles and the Fermi-Dirac and Bose-Einstein distributions for quantum particles are discussed.

Source record↗

Kinetic model for the vibrational energy exchange in flowing molecular gas mixtures

The present study is concerned with the development of a computational model for the description of the vibrational energy exchange in flowing gas mixtures, taking into account a given number of energy levels for each vibrational degree of freedom. It is possible to select an arbitrary number of energy levels. The presented model uses values in the range from 10 to approximately 40. The distribution of energy with respect to these levels can differ from the equilibrium distribution. The kinetic model developed can be employed for arbitrary gaseous mixtures with an arbitrary number of vibrational degrees of freedom for each type of gas. The application of the model to CO2-H2ON2-O2-He mixtures is discussed. The obtained relations can be utilized in a study of the suitability of radiation-related transitional processes, involving the CO2 molecule, for laser applications. It is found that the computational results provided by the model agree very well with experimental data obtained for a CO2 laser. Possibilities for the activation of a 16-micron and 14-micron laser are considered.

Offenhaeuser, F.↗