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Historical Cost Curves for Hydrogen Masers and Cesium Beam Frequency and Timing Standards

Historical cost curves were developed for hydrogen masers and cesium beam standards used for frequency and timing calibration in the Deep Space Network. These curves may be used to calculate the cost of future hydrogen masers or cesium beam standards in either future or current dollars. The cesium beam standards are decreasing in cost by about 2.3% per year since 1966, and hydrogen masers are decreasing by about 0.8% per year since 1978 relative to the National Aeronautics and Space Administration inflation index.

Remer, D. S.

Levelized Cost of Dispensed Hydrogen for Heavy-Duty Vehicles

In this short technical report, we explore the range of levelized costs of dispensed hydrogen (H2) from hydrogen refueling (or fueling) stations (HRS) for H2 heavy-duty fuel cell electric vehicles (FCEVs) that are feasible in the 2030 timeframe. We explore different scenarios by varying hydrogen delivery distances, HRS sizes, HRS utilization rates, and economies of scale in the Hydrogen Delivery Scenario Analysis Model (HDSAM). Thus, we observe how the contribution to the levelized cost of each supply chain component changes.

30 DIRECT ENERGY CONVERSION

Recent progress in the NASA-Goddard Space Flight Center atomic hydrogen standards program

At NASA Goddard Space Flight Center and through associated contractors, a broad spectrum of work is being carried out to develop improved hydrogen maser frequency standards for field use, improved experimental hydrogen maser frequency standards, and improved frequency and time distribution and measurement systems for hydrogen maser use. Recent progress in the following areas is reported: results on the Nr masers built by the Applied Physics Laboratory of Johns Hopkins University, the development of a low cost hydrogen maser at Goddard Space Flight Center, and work on a low noise phase comparison system and digitally phase locked crystal oscillator called the distribution and measurement system.

Reinhardt, V. S.

Production cost comparisons of hydrogen from fossil and nuclear fuel and water decomposition

The comparative costs entailed in producing hydrogen by major technologies that rely on petroleum, natural gas, coal, thermochemical cycles, and electrolysis are examined. Techniques were developed for comparing these processes by formulating the process data and economic assessments on a uniform and consistent basis. These data were normalized to permit a meaningful comparative analysis of product costs of these processes.

Ekman, K. R.

Quantifying Sources of Long-Term Voltage Decay for Rutile Iridium Oxide Anodes in Proton Exchange Membrane Water Electrolysis

To achieve aggressive hydrogen cost targets for proton exchange membrane water electrolysis (PEMWE), it is necessary to develop catalyst systems that reduce precious metal loadings while maintaining performance over extended operation. While amorphous iridium (Ir) -based catalysts exhibit high initial activity, their long-term stability remains a key limitation. In this study, the behavior of a rutile IrO2 catalyst is investigated over 4000 h of durability testing and compared to past efforts evaluating a more amorphous material. This study finds that rutile IrO2 results in a smaller decay rate (4.9 ..mu..V h-1) than an amorphous catalyst (28 ..mu..V h-1); additionally, the rutile IrO2 results in a smaller degree of Ir migration (20% to the membrane and cathode) than an amorphous catalyst (35%). This research emphasizes rutile IrO2 as a promising avenue for the development of durable, low-iridium anodes that can meet lifetime and cost targets for next-generation electrolyzer systems.

08 HYDROGEN

Quantifying Sources of Voltage Decay in Long-Term Durability Testing for PEM Water Electrolysis

Meeting a competitive 1$/kg hydrogen cost target for polymer electrolyte membrane water electrolysis (PEMWE) will require advances to significantly reduce capital costs and precious metal catalyst usage, while simultaneously enabling 40,000–80,000 h stack lifetimes under dynamic use conditions. Minimizing cell voltage decay rates is therefore a key goal for PEMWE, although the fundamental processes governing voltage decay are not yet well understood. Here we present a quantitative approach to analyze the contributions to voltage decay in long-term PEMWE testing using polarization curves, impedance spectroscopy, and post-mortem electron microscopy. We apply this approach to analyze a 28 μV h −1 decay rate observed in a 4000 h durability test of a cell using 0.5 mg cm −2 total PGM catalyst loading (0.4 mg Ir cm −2 anode, 0.1 mg Pt cm −2 cathode) and 3 A cm −2 current density. We also analyze a comparative series of 1000 h tests under different conditions. These results provide valuable insights into anode catalyst degradation processes, as well as transferrable methodology for PEMWE durability research.

08 HYDROGEN

Comparative life-cycle assessments and techno-economic analysis of renewable natural gas production pathways from biogas

Renewable natural gas (RNG) offers a promising pathway for decarbonizing hard-to-abate sectors. This study shows that, relative to conventional upgrading technologies (i.e., membrane separation and pressure swing adsorption), the catalytic methanation reaction (CMR) at water resource recovery facilities doubles RNG output. When consuming lowcarbon hydrogen, the CMR reduces operational energy use and global warming potential. Techno-economic analysis indicates that the CMR is not yet competitive but will become viable if hydrogen reaches $1/kg. Heat integration and hydrogen cost are key drivers of overall performance.

03 NATURAL GAS

Reacting CO 2 with Light Alkanes to Value-Added Products

Catalytic conversion of anthropogenic carbon dioxide (CO 2 ) into value-added products is a promising strategy to mitigate global carbon emissions. Concurrently, the shale gas revolution has provided an abundant supply of light alkanes (methane, ethane, propane, and butane), presenting a unique opportunity to employ these underutilized hydrocarbons as an effective, low-cost hydrogen source for CO 2 reduction. In this Perspective, we summarize past efforts, current state, and future opportunities for reacting CO 2 with light alkanes to generate a diverse range of value-added products. Compared with direct alkane conversion, the introduction of CO 2 fundamentally alters reaction thermodynamics and kinetics, enabling selective C–H and C–C bond activation while suppressing catalyst deactivation from coke formation. Building on decades of research in dry reforming and CO 2 -assisted dehydrogenation, recent advances in catalyst design have enabled CO 2 -assisted dehydrogenation processes that approach chemical equilibrium for the selective production of olefins and syngas. Importantly, advances in catalyst design and reactor engineering have further expanded the product scope beyond gas-phase (syngas and olefins) to include liquid-phase (oxygenates and aromatics), and solid-phase products (carbon nanomaterials). We highlight key catalyst design principles for controlling reaction pathways and discuss major challenges and opportunities in developing selective and versatile platforms for the simultaneous upgrading of CO 2 and light alkanes.

CO2

Durable, pure water–fed, anion-exchange membrane electrolyzers through interphase engineering

Anion-exchange membrane water electrolyzers (AEMWEs) promise scalable, low-cost hydrogen production but are limited by the electrochemical instability of their anode ionomers. We report interphase engineering using inorganic-containing molecular additives that coassemble with ionomer, enabling pure water-fed AEMWEs to operate with a degradation rate <0.5 millivolt per hour at 2.0 amperes per square centimeter and 70°C-a >20-fold durability improvement. Analysis of different additives and ionomers shows that the stabilization mechanism involves cross-links between metal oxo/hydroxo oligomers and ionomers. Under operation, the inorganic additive enriches, forming an interphase near the water-oxidation catalyst that passivates the anode ionomer against continuous degradation while maintaining mechanical integrity and hydroxide conductivity. This additive-based interphase-engineering strategy provides a path to durable AEMWEs that operate without supporting electrolytes and is adaptable across diverse catalysts and ionomers for electrochemical technologies.

Hou, Shujin

The thermal efficiency and cost of producing hydrogen and other synthetic aircraft fuels from coal

A comparison is made of the cost and thermal efficiency of producing liquid hydrogen, liquid methane and synthetic aviation kerosene from coal. These results are combined with estimates of the cost and energy losses associated with transporting, storing, and transferring the fuels to aircraft. The results of hydrogen-fueled and kerosene-fueled aircraft performance studies are utilized to compare the economic viability and efficiency of coal resource utilization of synthetic aviation fuels.

Witcofski, R. D.

The thermal efficiency and cost of producing hydrogen and other synthetic aircraft fuels from coal

A comparison is made of the cost and thermal efficiency of producing liquid hydrogen, liquid methane and synthetic aviation kerosene from coal. These results are combined with estimates of the cost and energy losses associated with transporting, storing, and transferring the fuels to aircraft. The results of hydrogen-fueled and kerosene-fueled aircraft performance studies are utilized to compare the economic viability and efficiency of coal resource utilization of synthetic aviation fuels.

Witcofski, R. D.

Hydrogen from coal cost estimation guidebook

In an effort to establish baseline information whereby specific projects can be evaluated, a current set of parameters which are typical of coal gasification applications was developed. Using these parameters a computer model allows researchers to interrelate cost components in a sensitivity analysis. The results make possible an approximate estimation of hydrogen energy economics from coal, under a variety of circumstances.

Billings, R. E.

Efficiency and cost advantages of an advanced-technology nuclear electrolytic hydrogen-energy production facility

The concept of an advanced-technology (viz., 1985 technology) nuclear-electrolytic water electrolysis facility was assessed for hydrogen production cost and efficiency expectations. The facility integrates (1) a high-temperature gas-cooled nuclear reactor (HTGR) operating a binary work cycle, (2) direct-current (d-c) electricity generation via acyclic generators, and (3) high-current-density, high-pressure electrolyzers using a solid polymer electrolyte (SPE). All subsystems are close-coupled and optimally interfaced for hydrogen production alone (i.e., without separate production of electrical power). Pipeline-pressure hydrogen and oxygen are produced at 6900 kPa (1000 psi). We found that this advanced facility would produce hydrogen at costs that were approximately half those associated with contemporary-technology nuclear electrolysis: $5.36 versus $10.86/million Btu, respectively. The nuclear-heat-to-hydrogen-energy conversion efficiency for the advanced system was estimated as 43%, versus 25% for the contemporary system.

Donakowski, T. D.

Dedicated nuclear facilities for electrolytic hydrogen production

An advanced technology, fully dedicated nuclear-electrolytic hydrogen production facility is presented. This plant will produce hydrogen and oxygen only and no electrical power will be generated for off-plant use. The conceptual design was based on hydrogen production to fill a pipeline at 1000 psi and a 3000 MW nuclear base, and the base-line facility nuclear-to-shaftpower and shaftpower-to-electricity subsystems, the water treatment subsystem, electricity-to-hydrogen subsystem, hydrogen compression, efficiency, and hydrogen production cost are discussed. The final conceptual design integrates a 3000 MWth high-temperature gas-cooled reactor operating at 980 C helium reactor-out temperature, direct dc electricity generation via acyclic generators, and high-current density, high-pressure electrolyzers based on the solid polymer electrolyte approach. All subsystems are close-coupled and optimally interfaced and pipeline hydrogen is produced at 1000 psi. Hydrogen costs were about half of the conventional nuclear electrolysis process.

Foh, S. E.

Techno-economic Model and Analysis for Hydrogen (H2) Pipeline Transportation

Presentation at the 9th ELAEE (Latin American Energy Economics Meeting) July 28th – 30th, 2024 in PUC-Rio, Rio de Janeiro, Brazil. The presentation highlights the FECM/NETL Hydrogen Pipeline Cost Model (H2_P_COM). The model estimates costs for transporting gaseous hydrogen in a pipeline from a source, such as a hydrogen production facility, to a final destination which may be a user of the hydrogen or a distribution center where hydrogen in the pipeline is diverted to multiple end users.

Cunha, Luciane

Fuel cells for single-aisle regional aircraft: System configuration, performance and cost

A hydrogen fuel cell propelled electric aircraft can compete with incumbent turbofan technologies for single-aisle regional aircraft by coupling design of stack, air handling, thermal management, propulsion, and airframe to optimize performance. The stack operates at 95°C to facilitate heat rejection during take-off and below 75°C during cruise to extend lifetime and is oversized to satisfy power requirements at end of life. A multi-stage turbocompressor with a compression ratio >10 is selected to reach high stack power density at 11,300-m cruise altitude. The propulsion system is configured to accommodate air handling within the core duct, an inclined heat exchanger in the outer duct to limit the nacelle size, and variable area nozzles to independently control mass flows through the core and bypass ducts. The airframe is modified for maximum lift coefficient and longer balanced field length for dramatically reduced thrust during take-off, and the fuselage is stretched by 20% to store liquid hydrogen (LH 2 ). Modularization of power systems promotes safety in one engine inoperative scenarios and allows reaching specific power metrics for stack, balance-of-plant and fuel cell system (FCS), necessary for acceptable take-off weight. In conclusion, cost parity requires increase in FCS lifetime, LH 2 cost reduction, and improved FCS specific power.

Catalyst durability