Improved Heat-Engine Solar-Energy System
Heat engine solar-energy system improved by installing overcapacity heat exchanger and buffer loop between engine fluid and solar heated fluid.
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Heat engine solar-energy system improved by installing overcapacity heat exchanger and buffer loop between engine fluid and solar heated fluid.
The Phase 1 Final Technical Report describes the results of the work completed during the “Advanced Modular Sub-Atmospheric Hybrid Heat Engine” project. A key part of the Phase 1 work was the completion of a thermodynamic cycle analysis for the MHHE at the selected module size. The hybrid heat engine has been developed as a modular unit (sized in the range of 500kW – 60MW) that can be used with modular coal or biomass gasifiers, with distributed power generation systems, with large power plants comprised of multiple generating units, and with natural gas compression stations. The MHHE will provide cleaner, more efficient, and lower cost generation with better load following capabilities than existing competing technologies with a singular generating source such as solar farm, gas turbine, or combustion engine. The drivers of the MHHE technology are: benefits of modular power generation (reduced equipment cost, construction cost and implementation time, connection ready on delivery, flexible scalability, serviceability), fuel flexibility, lowest cost power generation and reduced emissions.A logical progression of work and a clear path forward toward meeting the FOA goals and objectives have been established. Namely, a preliminary market analysis and primary fuel identification was completed first and then the modularity of the system was defined. The benefits of the proposed hybrid and modular heat engine were described when applied to modular coal gasifiers, distributed power generators, and larger power plants. Based on the market analysis, modularity, and chosen primary fuel, a conceptual design and layout of the hybrid heat engine was developed, analyzed, and characterized. The technology gaps already identified have been reviewed and expanded upon, and a test plan to address these gaps through bench scale testing in Phase 2 has been developed. Cost estimate methodology and considerations in support of a potential Phase 2 project have been described.
In Sterling-cycle heat engine, pneumatic system is used to drive displacer/regenerator, eliminating mechanical linkages and valves.
The principal objective of this Phase 2 SBIR program was to develop and demonstrate a practically insoluble coating for nickel-based superalloys for Stirling engine heat pipe applications. Specific technical objectives of the program were: (1) Determine the solubility corrosion rates for Nickel 200, Inconel 718, and Udimet 72OLI in a simulated Stirling engine heat pipe environment, (2) Develop coating processes and techniques for capillary groove and screen wick structures, (3) Evaluate the durability and solubility corrosion rates for capillary groove and screen wick structures coated with an insoluble coating in cylindrical heat pipes operating under Stirling engine conditions, and (4) Design and fabricate a coated full-scale, partial segment of the current Stirling engine heat pipe for the Stirling Space Power Convertor program. The work effort successfully demonstrated a two-step nickel aluminide coating process for groove wick structures and interior wall surfaces in contact with liquid metals; demonstrated a one-step nickel aluminide coating process for nickel screen wick structures; and developed and demonstrated a two-step aluminum-to-nickel aluminide coating process for nickel screen wick structures. In addition, the full-scale, partial segment was fabricated and the interior surfaces and wick structures were coated. The heat pipe was charged with sodium, processed, and scheduled to be life tested for up to ten years as a Phase 3 effort.
A heat engine includes a first rotatable pulley and a second rotatable pulley spaced from the first rotatable pulley. A shape memory alloy (SMA) element is disposed about respective portions of the pulleys at an SMA pulley ratio. The SMA element includes a first wire, a second wire, and a matrix joining the first wire and the second wire. The first wire and the second wire are in contact with the pulleys, but the matrix is not in contact with the pulleys. A timing cable is disposed about respective portions of the pulleys at a timing pulley ratio, which is different than the SMA pulley ratio. The SMA element converts a thermal energy gradient between the hot region and the cold region into mechanical energy.
The technical status of three heat engines (Stirling, high-temperature Brayton, and Combined cycle) for use in solar thermal power systems is presented. Performance goals necessary to develop a system competitive with conventional power requirements include an external heated engine output less than 40 kW, and efficiency power conversion subsystem at least 40% at rated output, and a half-power efficiency of at least 37%. Results show that the Stirling engine can offer a 39% efficiency with 100 hours of life, and a 20% efficiency with 10,000 hours of life, but problems with seals and heater heads exist. With a demonstrated efficiency near 31% at 1500 F and a minimum lifetime of 100,000 hours, the Brayton engine does not offer sufficient engine lifetime, efficiency, and maintenance for solar thermal power systems. Examination of the Rankine bottoming cycle of the Combined cycle engine reveals a 30 year lifetime, but a low efficiency. Additional development of engines for solar use is primarily in the areas of components to provide a long lifetime, high reliability, and low maintenance (no more than $0.001/kW-hr).
A solar power satellite is the energy-converting element of a system that can deliver some 10 GW of power to utilities on the earth's surface. We evaluated heat engines and solar cells for converting sunshine to electric power at the satellite. A potassium Rankine cycle was the best of the heat engines, and 50 microns thick single-crystal silicon cells were the best of the photovoltaic converters. Neither solar cells nor heat engines had a clear advantage when all factors were considered. The potassium-turbine power plant, however, was more difficult to assemble and required a more expensive orbital assembly base. We therefore based our cost analyses on solar-cell energy conversion, concluding that satellite-generated power could be delivered to utilities for around 4 to 5 cents a kWh.
The parabolic dish solar collector systems for converting sunlight to electrical power through a heat engine will, require a small heat engine of high performance long lifetime to be competitive with conventional power systems. The most promising engine candidates are Stirling, high temperature Brayton, and combined cycle. Engines available in the current market today do not meet these requirements. The development of Stirling and high temperature Brayton for automotive applications was studied which utilizes much of the technology developed in this automotive program for solar power engines. The technical status of the engine candidates is reviewed and the components that may additional development to meet solar thermal system requirements are identified.
The Phase 1 Final Report describes the results of the work completed during the “Advanced Modular Sub-Atmospheric Hybrid Heat Engine” project. The objectives of Phase 1 work were to develop a conceptual design of the turbine-based modular hybrid heat engine (MHHE), including thermodynamic cycle analysis, define the nominal engine component boundary conditions, identify technology gaps, and develop a detailed test plan to address these gaps through bench scale testing in a potential subsequent Phase 2 project. To achieve the project objective, the following activities were performed in Phase 1 work: (1) Market analysis and primary fuel selection, (2) Conceptual design and integrated layout development, (3) Design support and key components characterization, (4) Planning to move technology to pre-commercial demonstration.
A quantum heat engine (QHE) based on the interaction driving of a many-particle working medium is introduced. The cycle alternates isochoric heating and cooling strokes with both interaction-driven processes that are simultaneously isochoric and isentropic. When the working substance is confined in a tight waveguide, the efficiency of the cycle becomes universal at low temperatures and governed by the ratio of velocities of a Luttinger liquid. We demonstrate the performance of the engine with an interacting Bose gas as a working medium and show that the average work per particle is maximum at criticality. We further discuss a work outcoupling mechanism based on the dependence of the interaction strength on the external spin degrees of freedom.
This is the second annual technical report entitled, Improved Silicon Carbide for Advanced Heat Engines, and includes work performed during the period February 16, 1986 to February 15, 1987. The program is conducted for NASA under contract NAS3-24384. The objective is the development of high strength, high reliability silicon carbide parts with complex shapes suitable for use in advanced heat engines. The fabrication methods used are to be adaptable for mass production of such parts on an economically sound basis. Injection molding is the forming method selected. This objective is to be accomplished in a two-phase program: (1) to achieve a 20 percent improvement in strength and a 100 percent increase in Weibull modulus of the baseline material; and (2) to produce a complex shaped part, a gas turbine rotor, for example, with the improved mechanical properties attained in the first phase. Eight tasks are included in the first phase covering the characterization of the properties of a baseline material, the improvement of those properties and the fabrication of complex shaped parts. Activities during the first contract year concentrated on two of these areas: fabrication and characterization of the baseline material (Task 1) and improvement of material and processes (Task 7). Activities during the second contract year included an MOR bar matrix study to improve mechanical properties (Task 2), materials and process improvements (Task 7), and a Ford-funded task to mold a turbocharger rotor with an improved material (Task 8).
The interest of NASA in the application of ceramics in heat engines is reviewed. This interest started in the early 1950s with attempts to apply oxides, borides, and cermets as gas turbine components. These attempts, as other similar efforts around the world at that time, generally met with failure due to the brittle nature of the materials and a lack of understanding of how to accommodate brittleness by appropriate design approaches. More recent efforts of the 1970s have concentrated on the silicon nitride and silicon carbide family of ceramics. This class of materials demonstrated thermal stability and thermal shock resistance in gas turbine environments. Subsequent programs funded by the DOE and managed by NASA have demonstrated great strides in material fabricability and the application of FEM design concepts. However, the materials remain brittle and lacking in reliability and reproducibility. This reliability/reproducibility problem is viewed as the major current impediment to the application of ceramics in heat engines; approaches to its solution are discussed.
We present a hybrid osmotic heat engine (OHE) system that uses draw solutions with an organic solvent for enhanced thermal separation efficiency. The hybrid OHE system produces sustainable energy by combining pressure-retarded osmosis (PRO) as a power generation stage and membrane distillation (MD) utilizing low-grade heat as a separation stage. While previous OHE systems employed aqueous electrolyte draw solutions, using methanol as a solvent is advantageous because methanol is highly volatile and has a lower heat capacity and enthalpy of vaporization than water. Hence, the thermal separation efficiency of a draw solution with methanol would be higher than that of an aqueous draw solution. In this study, we evaluated the performance of LiCl-methanol as a potential draw solution for a PRO-MD hybrid OHE system. The membrane transport properties as well as performance with LiCl methanol draw solution were evaluated using thin-film composite (TFC) PRO membranes and compared to the results obtained with a LiCl water draw solution. Experimental PRO methanol flux and maximum projected power density of 47.1 L m(-2) h(-1) and 72.1 W m(-2), respectively, were achieved with a 3 M LiCl-methanol draw solution. The overall efficiency of the hybrid OHE system was modeled by coupling the mass and energy flows between the thermal separation (MD) and power generation (PRO) stages under conditions with and without heat recovery. The modeling results demonstrate higher ORE energy efficiency with the LiCl methanol draw solution compared to that with the LiCl water draw solution under practical operating conditions (i.e., heat recovery <90%). We discuss the implications of the results for converting low-grade heat to power.
This is the third annual technical report for the program entitled, Improved Silicon Carbide for Advanced Heat Engines, for the period February 16, 1987 to February 15, 1988. The objective of the original program was the development of high strength, high reliability silicon carbide parts with complex shapes suitable for use in advanced heat engines. Injection molding is the forming method selected for the program because it is capable of forming complex parts adaptable for mass production on an economically sound basis. The goals of the revised program are to reach a Weibull characteristic strength of 550 MPa (80 ksi) and a Weibull modulus of 16 for bars tested in 4-point loading. Two tasks are discussed: Task 1 which involves materials and process improvements, and Task 2 which is a MOR bar matrix to improve strength and reliability. Many statistically designed experiments were completed under task 1 which improved the composition of the batches, the mixing of the powders, the sinter and anneal cycles. The best results were obtained by an attritor mixing process which yielded strengths in excess of 550 MPa (80 ksi) and an individual Weibull modulus of 16.8 for a 9-sample group. Strengths measured at 1200 and 1400 C were equal to the room temperature strength. Annealing of machined test bars significantly improved the strength. Molding yields were measured and flaw distributions were observed to follow a Poisson process. The second iteration of the Task 2 matrix experiment is described.
Requirements and constraints are established for power conversion subsystems, including heat engine, alternator and auxiliaries, of dish concentrator solar thermal power systems. In order to be competitive with conventional power systems, it is argued that the heat engine should be of less than 40 kW rated output, in a subsystem with an efficiency of at least 40% at rated output and at least 37% at half power. An interval between major overhauls of 50,000 hours is also desirable, along with minor maintenance and lubrication not more than four times a year requiring no more than one man-hour each time, and optimal reliability. Also found to be important are the capability for hybrid operation using heat from a solar receiver, fuel-fired combustor or both simultaneously, operation at any attitude, stability to transients in input power and output loading, operation at ambient temperatures from -30 to 50 C, and compatibility with environmental and safety requirements. Cost targets include a price of $180/kWe, and operation, maintenance and replacement costs averaging $0.001/kWh for 30 years of operation.
We propose employing a quantum heat engine as a sensitive probe for thermal baths. In particular, we study a single-atom Otto engine operating in an open thermodynamic cycle. Owing to its cyclic nature, the engine is capable of translating small temperature differences between two baths into a macroscopic oscillation in a flywheel. We present analytical and numerical modeling of the quantum dynamics of the engine and estimate it to be capable of detecting temperature differences as small as 2 μK. This sensitivity can be further improved by utilizing quantum resources such as squeezing of the ion motion. The proposed scheme does not require quantum state initialization and is able to detect small temperature differences in a wide range of base temperatures.
We present that a sodium thermal electrochemical converter (Na-TEC) generates electricity directly from heat through isothermal expansion of sodium ions across a beta"-alumina solid-electrolyte. This heat engine has been considered for use with conventional concentrating solar power (CSP) systems before. However, unlike previous single-stage devices, the improved design uses two stages with an interstage reheat, allowing more economical and efficient conversion up to 29% at a hot side temperature of 850 °C. Herein, a cost-performance analysis for this improved design assesses opportunities for distributed-CSP in the context of micro-combined heat and power systems. A high-level techno-economic analysis (TEA) is presented that explores four scenarios where a Na-TEC is used as the heat engine for a distributed-CSP system. Overnight capital cost and levelized cost of electricity (LCOE) are estimated for a system lifetime of 30 years, revealing that overnight capital costs in a range from $3.57 to $17.71 per W e are feasible, which equate to LCOEs from 6.9 to 17.2 cents kWh e -1 . This analysis makes a significant contribution by concurrently quantifying the efficiency and unit costs for a range of multistage configurations, and demonstrating that a Na-TEC may be a promising alternative to Stirling engines for distributed-CSP systems at residential scale of 1–5 kW e .
High strength at elevated temperatures, low density, resistance to wear, and abundance of nonstrategic raw materials make structural ceramics attractive for advanced heat engine applications. Unfortunately, ceramics have a low fracture toughness and fail catastrophically because of overload, impact, and contact stresses. Ceramic matrix composites provide the means to achieve improved fracture toughness while retaining desirable characteristics, such as high strength and low density. Materials scientists and engineers are trying to develop the ideal fibers and matrices to achieve the optimum ceramic matrix composite properties. A need exists for the development of failure models for the design of ceramic matrix composite heat engine components. Phenomenological failure models are currently the most frequently used in industry, but they are deterministic and do not adequately describe ceramic matrix composite behavior. Semi-empirical models were proposed, which relate the failure of notched composite laminates to the stress a characteristic distance away from the notch. Shear lag models describe composite failure modes at the micromechanics level. The enhanced matrix cracking stress occurs at the same applied stress level predicted by the two models of steady state cracking. Finally, statistical models take into consideration the distribution in composite failure strength. The intent is to develop these models into computer algorithms for the failure analysis of ceramic matrix composites under monotonically increasing loads. The algorithms will be included in a postprocessor to general purpose finite element programs.