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NEVADA NATIONAL SECURITY SITE 2020 DATA REPORT- GROUNDWATER MONITORING PROGRAM AREA 5 RADIOACTIVE WASTE MANAGEMENT SITE

This report presents groundwater and leachate sample results from the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada National Security Site in Nye County, Nevada. Since 1993, groundwater samples have been collected and static groundwater depths have been measured from the aquifer immediately below the Area 5 RWMS. The data are evaluated for evidence of effects on the aquifer related to the Area 5 RWMS. Leachate from the Cell 18 lined mixed waste cell has been sampled since 2011, and leachate from the Cell 25 lined mixed waste cell was first sampled in 2019 after it began receiving waste in August 2018. Leachate data are analyzed for hazardous contaminants to determine appropriate leachate handling and disposal. This report includes five years of data from 2016 through 2020.

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Long-Term Groundwater Monitoring Report Industrial Area Kennedy Space Center, Florida

This report presents the 2023 groundwater sampling results from the National Aeronautics and Space Administration (NASA) Industrial Area (IA) Long-Term Monitoring (LTM) activities. Due to the project contract ending in 2023, this report presents one year of LTM activities instead of the two-year timeframe presented in previous reports. The NASA IA LTM Program includes the following 12 sites: - Ransom Road Landfill (RRLF) – Solid Waste Management Unit (SWMU) 003 - Building M7-0505 Treatment Tank Area (M505) – SWMU 039 - Operations and Checkout Building (O&C) – SWMU 076 - Vertical Processing Facility (VPF) – SWMU 077 - Environmental Health Facility (EHF) – SWMU 079 - Kennedy Athletic, Recreation, and Social Park 1 (KARS Park 1) – SWMU 084 - Engineering Development Laboratory (EDL) – SWMU 085 - Launch Equipment Test Facility (LETF) – SWMU 091 - Mobil Service Station (MOBIL) – SWMU 093 - General Services Administration Seized Property (GSSP) – SWMU 095 - Space Station Processing Facility (SSPF) – SWMU 098 - Fuel Storage Area #1 Underground Storage Tank [Building 1044] (FSA1) – Potential Release Location (PRL) 157 Sampling events for the IA LTM Program are conducted seasonally during the dry and wet seasons, which occur in May and November, respectively. The sites in the NASA IA LTM Program are sampled on annual, biennial, or 5-year sampling frequencies based on historical trends. The current sampling frequencies for the NASA IA LTM sites are as follows: - FSA1 is sampled annually, alternating between wet and dry seasons. - GSSP is sampled annually during the wet season. - Seven sites are sampled biennially, alternating between the wet and dry seasons (RRLF, M505, O&C, VPF, LETF, MOBIL, and SSPF). - EHF and EDL are sampled biennially during the wet season. - KARS Park 1 is sampled once every 5 years.

remediation↗

2021-2022 Long-Term Groundwater Monitoring Report Industrial Area Kennedy Space Center, Florida

This report presents the groundwater sampling results from the National Aeronautics and Space Administration (NASA) Industrial Area (IA) 2021-2022 Long-Term Monitoring (LTM) activities and results of the 2023 DPT activities at three of the sites. The NASA IA LTM Program includes the following 14 sites: - Ransom Road Landfill (RRLF) – Solid Waste Management Unit (SWMU) 003 - Orsino Storage Yard (ORSY) – SWMU 004 - Building M7-0505 Treatment Tank Area (M505) – SWMU 039 - Hypergol Maintenance Facility Hazardous Waste South Staging Area (HMF South) – SWMU 070 - Operations and Checkout Building (O&C) – SWMU 076 - Vertical Processing Facility (VPF) – SWMU 077 - Environmental Health Facility (EHF) – SWMU 079 - Kennedy Athletic, Recreation, and Social Park 1 (KARS Park 1) – SWMU 084 - Engineering Development Laboratory (EDL) – SWMU 085 - Launch Equipment Test Facility (LETF) – SWMU 091 - Mobil Service Station (MOBIL) – SWMU 093 - General Services Administration Seized Property (GSSP) – SWMU 095 - Space Station Processing Facility (SSPF) – SWMU 098 - Fuel Storage Area #1 Underground Storage Tank (UST) [Building 1044] (FSA1) – Potential Release Location (PRL) 157 Groundwater levels were gauged at each site during the 2021 and 2022 LTM field activities. Sampling events for the IA LTM Program are conducted seasonally during the dry and wet seasons, which occur in May and November, respectively. The sites in the NASA IA LTM Program are sampled on annual, biennial, or 5-year sampling frequencies based on historical trends. Due to contract transitions and monitoring well installations, 2021 dry season activities were conducted during September 2021, while dry season activities for 2022 resumed in May 2022.

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Contractors Road Heavy Equipment Area (SWMU 055) 2022 Annual Groundwater Monitoring Report

This document presents a summary of activities completed at the Contractors Road Heavy Equipment (CRHE) Area, located at Kennedy Space Center (KSC), Florida, from June through December 2022. The activities conducted at the CRHE Area include: - Annual groundwater sampling activities associated with sitewide plume monitoring and Underground Injection Control (UIC) monitoring in the former bioremediation Interim Measures (IM) Hot Spot 1 (HS1) area; - Direct push technology (DPT) groundwater investigation; - Semiannual vapor intrusion (VI) evaluation activities. This facility is designated Solid Waste Management Unit (SWMU) Number 055 (SWMU 055) under KSC’s Resource Conservation and Recovery Act (RCRA) Corrective Action program. HydroGeoLogic, Inc. (HGL) prepared this report for the National Aeronautics and Space NASA) under contract number 80KSC019F0096/80KSC019D0012, Technical Directive-03. An Advance Data Package (ADP) presentation of the elements of this report received Team (KSCRT) agreement at the April 5, 2023, KSCRT meeting. The chlorinated volatile organic compound plume appears to be stable vertically and horizontally. Additional DPT groundwater sampling will be completed to support a remedial alternatives evaluation for potential means to expedite groundwater cleanup. There are per- and polyfluorinated alkyl substances in site groundwater, and assessment is planned in the future. Sub-slab soil gas monitoring results do not indicate any concerns with indoor vapor intrusion. Based on the 2022 annual groundwater sampling results, it is recommended that annual sampling continue to alternate with the wet and dry season, with the next sampling event planned for December 2023.

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Contractors Road Heavy Equipment Area (SWMU 055) 2021 Annual Groundwater Monitoring Report

This document presents a summary of activities completed at the Contractors Road Heavy Equipment (CRHE) Area, located at Kennedy Space Center (KSC), Florida, from January through December 2021. The activities conducted at the CRHE Area include: - Annual groundwater sampling activities associated with site-wide plume monitoring and Underground Injection Control (UIC) monitoring in the former bioremediation Interim Measures (IM) Hot Spot 1 (HS1) area; - Direct push technology (DPT) groundwater investigation; and - Semi-annual vapor intrusion (VI) evaluation activities. This facility is designated Solid Waste Management Unit (SWMU) Number 055 (SWMU 055) under KSC’s Resource Conservation and Recovery Act Corrective Action program. This report was prepared by HydroGeoLogic, Inc. (HGL) for the National Aeronautics and Space Administration (NASA) under contract number 80KSC019F0096. The annual groundwater sampling results demonstrated that the footprint where chlorinated volatile organic compounds (VOC) are present above their State of Florida groundwater cleanup target levels (GCTLs) is not expanding overall. One non-chlorinated VOC (1,4-dioxane) is found above its GCTL at isolated points within the chlorinated VOC plume. The DPT groundwater investigation is being used to delineate the horizontal and vertical boundaries where chlorinated VOCs are present at levels above natural attenuation default concentrations. That data supports an evaluation of potential additional remedial actions. The potential for VI into the CRHE Area Office (K6-1996H) is evaluated by collected sub-slab vapor samples from four locations twice a year (once in the wet season and once in the dry season). The results for 2021 were all below the Environmental Protection Agency's vapor intrusion screening levels (VISLs) for both commercial and residential settings. The path forward for the site is to continue annual monitoring for chlorinated VOCs and 1,4-dioxane until additional remedies are implemented or the site is transitioned to long-term monitoring.

Contractors Road Heavy Equipment↗

2019 Groundwater Monitoring Report Project Shoal Area: Subsurface Corrective Action Unit 447

The Project Shoal Area is a site in Nevada where an underground nuclear test was conducted in 1963. It later came to be known as the Shoal, Nevada, Site. Surface contamination at the site has been remediated, but investigation of groundwater contamination resulting from the test is still in the corrective action process. Annual sampling and water-level monitoring are conducted as part of the subsurface corrective action strategy, which has focused on revising the site conceptual model and evaluating the adequacy of the monitoring well network. It has also included enhancements to the monitoring well network to address uncertainties in the groundwater flow direction and the cause of rising water levels in site wells west of the shear zone since the first hydrologic characterization (HC) wells were installed in 1996. Revisions to the site conceptual model and enhancements to the monitoring strategy were provided to Nevada Division of Environmental Protection (NDEP) in the Addendum to: Corrective Action Decision Document/Corrective Action Plan (CADD/CAP) for the Subsurface Corrective Action Unit 447 Shoal, Nevada, Site. NDEP approved the addendum to the CADD/CAP, which included an expanded contaminant boundary and compliance boundary for the site.

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2019 Corrective Measures Implementation and Intermim Measures Annual Status Report: Summary of Biosparge System Operation and Maintenance, and Interim Groundwater Monitoring Mobile Launch Platform / Vehicle Assembly Building Area (SWMU 056) Kennedy Space Center, Florida

This report presents a summary of the Corrective Measures Implementation (CMI) and Interim Measure (IM) implementation activities that occurred from May 2019 through December 2019 at the Mobile Launch Platform/Vehicle Assembly Building (MLPV) Area, Solid Waste Management Unit 056 (SWMU 056), located at the John F. Kennedy Space Center, Florida.

MOBILE LAUNCH PLATFORM / VEHICLE ASSEMBLY BUILDING↗

Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada: For Calendar Year 2020 (Rev. 2)

This report serves as the combined annual report for post-closure activities in compliance with the requirements listed in Resource Conservation and Recovery Act (RCRA) Permit Number NEV HW0101 associated with the following closed corrective action units (CAUs): 1) CAU 90, Area 2 Bitcutter Containment; 2) CAU 91, Area 3 U-3fi Injection Well; 3) CAU 92, Area 6 Decon Pond Facility; 4) CAU 110, Area 3 WMD U-3ax/bl Crater; 5) CAU 111, Area 5 WMD Retired Mixed Waste Pits; 6) CAU 112, Area 23 Hazardous Waste Trenches The locations of the sites are shown in Figure ES-1. This report covers calendar year 2020. The post-closure requirements for these sites are described in RCRA Permit NEV HW0101 and are summarized in each CAU-specific section of this report. The results of the inspections, a summary of maintenance activities, and an evaluation of monitoring data are presented in this report. Site inspections are conducted annually at CAUs 90, 91, and 112; semiannually at CAUs 92 and 110; and quarterly at CAU 111. Additional inspections are conducted at CAUs 92 and 111 if precipitation occurs in excess of 1.0 inch in a 24-hour period. Inspections include an evaluation of the condition of the units, including covers, fences, signs, gates, and locks. At CAUs 110 and 111, soil moisture monitoring and subsidence surveys are conducted in addition to the visual inspections. At CAU 110, the site fence, gate, lock, and use restriction signs are evaluated. At CAU 111, an ecological survey, direct radiation monitoring, air monitoring, radon flux monitoring, and groundwater monitoring are also conducted. This report will address all monitoring item notes above except groundwater monitoring. Groundwater monitoring is documented in the Nevada National Security Site Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site. All required inspections, maintenance, and monitoring were conducted in accordance with the post-closure requirements of the permit. Revision 6 of RCRA Permit NEV HW0101 was issued effective December 10, 2015, and remained in effect until December 10, 2020. At the time of this report submittal, the new RCRA permit application was in review.

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Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada (CY2021)

This report serves as the combined annual report for post-closure activities in compliance with the requirements listed in Resource Conservation and Recovery Act (RCRA) Permit Number NEV HW0101 associated with the following closed corrective action units (CAUs): CAU 90, Area 2 Bitcutter Containment, CAU 91, Area 3 U-3fi Injection Well, CAU 92, Area 6 Decon Pond Facility, CAU 110, Area 3 WMD U-3ax/bl Crater, CAU 111, Area 5 WMD Retired Mixed Waste Pits, and CAU 112, Area 23 Hazardous Waste Trenches. This report covers calendar year 2021. The post-closure requirements for these sites are described in RCRA Permit NEV HW0101 and are summarized in each CAU-specific section of this report. The results of the inspections, a summary of maintenance activities, and an evaluation of monitoring data are presented in this report. This report will address all monitoring requirements noted in the RCRA Permit NEV HW0101, except groundwater monitoring. Groundwater monitoring is documented in the Nevada National Security Site Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site. All required inspections, maintenance, and monitoring were conducted in accordance with the post-closure requirements of the permit. Revision 6 of RCRA Permit NEV HW0101 was issued effective December 10, 2015, and remained in effect until December 10, 2020. At the time of this report submittal, the new RCRA permit application was in review.

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Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada, For Calendar Year 2021 (Revision 1)

This report serves as the combined annual report for post-closure activities in compliance with the requirements listed in Resource Conservation and Recovery Act (RCRA) Permit Number NEV HW0101 associated with the following closed corrective action units (CAUs): CAU 90, Area 2 Bitcutter Containment; CAU 91, Area 3 U-3fi Injection Well; CAU 92, Area 6 Decon Pond Facility; CAU 110, Area 3 WMD U-3ax/bl Crater; CAU 111, Area 5 WMD Retired Mixed Waste Pits; and CAU 112, Area 23 Hazardous Waste Trenches. This report will address all monitoring requirements noted in the RCRA Permit NEV HW0101, except groundwater monitoring. Groundwater monitoring is documented in the Nevada National Security Site Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site.

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Guidance for Monitoring Passive Groundwater Remedies Over Extended Time Scales

Passive remediation can be appropriate where natural processes and actions such as institutional controls mitigate exposure to contaminated groundwater, achieving remedial action objectives and protectiveness of human health and the environment. Monitored natural attenuation (MNA) is a prevalent passive remediation strategy supported by a regulatory framework and monitoring design guidance. However, long-term passive remedies are usually selected in combination with at least one active remedy, such as source removal, in situ treatment, or pump-and-treat, functioning as a complementary method for achieving remediation objectives and meeting the applicable statutory and regulatory requirements. However, MNA and existing monitoring guidance primarily target situations where the remedial action objectives are met within a few decades. When time scales for passive remediation extend to many decades (50 years or more), a corresponding change in monitoring strategy is needed to adapt to the extended time scale. This document provides guidance for implementing an extended-scale monitoring (ESM) approach appropriate for long-duration passive remediation. Extended-scale is defined in this document with respect to time (i.e., a long duration of remediation) and a large enough physical scale such that downstream receptors will not be impacted within the remediation timeframe. ESM applies to slow-moving groundwater contaminant plumes and emphasizes monitoring primarily for potential exposure pathways. For this approach, the primary monitoring objective is to demonstrate that the plume diminishes before reaching the receptor zone or point of compliance and/or a receptor does not receive concentrations above the compliance limit. While the overall objectives of protecting human health and the environment are the same as for plumes where remediation can occur over a shorter time period, the time scales between decisions are longer and the dynamics of plume evolution are slower. To this end, a scenario-based strategy is described for different plume and source conditions, defining a containment and receptor zones. The containment zone is the area where the risk of exposure to groundwater contamination can be mitigated (e.g., through institutional controls) during the remediation time period. The receptor zone is defined as the area where exposure to groundwater contamination cannot be mitigated and compliance concentration standards must be met. Within the containment zone, slow plume migration may occur, leading to concentrations that exceed compliance standards. However, where distance to the receptor zone is large relative to plume migration and attenuation rate, this approach can be protective of the receptor zone. Selection of a long-duration passive remedy needs to be based on sufficient understanding of contaminant sources, hydrogeology, and contaminant plumes. A strong technical basis, supported by predictive analysis, is recommended to substantiate that contamination is expected to stay within the containment zone during the active remediation and attainment phase of the remedy, and diminish to meet compliance standards within the extended timeframe prior to reaching the receptor zone (e.g., many decades or even centuries). The ESM approach is based on verification of plume behavior and not on detailed plume dynamics. Monitoring is conducted to confirm expected behavior with an emphasis on exposure pathways to verify that plumes remain contained in areas where the protectiveness objectives can be met. ESM should not be adopted if there is significant risk of the plume extending beyond the containment zone. Given the slow movement within the containment zone, less frequent sampling is required relative to approaches used for conventional-scale remediation.

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Hypergol Maintenance Facility Hazardous Waste South Staging Areas, SWMU 070

The purpose of this CMI Year 9 AGWMR is to present the actions taken and results obtained during the ninth year of implementation of Corrective Measures (CM) at HMF. Groundwater monitoring activities were conducted in accordance with the CMI Work Plan (Tetra Tech, 2005a) and CMI Site-Specific Safety and Health Plan (Tetra Tech, 2005b). Groundwater monitoring activities detailed in this Year 9 report include pre-startup sampling in February 2014(prior to restarting the air sparging system) and quarterly performance monitoring in March, July, and September 2014.

Remediation↗

Alpha Spectrometry Results for Groundwater Samples Collected in Northern Iraq and a Summary of the Environmental Setting of the Adaya Burial Site

The Radiation Protection Center (RPC) of the Iraqi Ministry of Environment continues to evaluate the potential health impacts associated with the Adaya Burial Site, which is located 33 kilometers (20.5 miles) southwest of Mosul. This report documents the radiological analyses of 16 groundwater samples collected from wells located in the vicinity of the Adaya Burial Site and at other sites in northern Iraq. The Adaya Burial Site is a high-risk dump site because a large volume of radioactive material and contaminated soil is located on an unsecure hillside above the village of Tall ar Ragrag. The uranium activities for the 16 water samples in northern Iraq are considered to be naturally occurring and do not indicate artificial (man-made) contamination. With one exception, the alpha spectrometry results for the 16 wells that were sampled in 2019 indicate that the water quality concerning the three uranium isotopes (Uranium-233/234, Uranium-235/236, and Uranium-238) was acceptable for potable purposes (drinking and cooking). However, Well 7 in Mosul had a Uranium-233/234 activity concentration that slightly exceeded the World Health Organization guidance level. Eight of the 16 wells are located in the villages of Tall ar Ragrag and Adaya and had naturally occurring uranium concentrations. Wells in the villages of Tall ar Ragrag and Adaya are located near the Adaya Burial Site and should be sampled on an annual schedule. The list of groundwater analytes should include metals, total uranium, isotopic uranium, gross alpha/beta, gamma spectroscopy, organic compounds, and standard water quality parameters. Our current understanding of the hydrogeologic setting in the vicinity of the Adaya Burial Site is solely based on villager's domestic wells, topographic maps, and satellite imagery. To better understand the hydrogeologic setting, a Groundwater Monitoring Program needs to be developed and should include the installation of twelve groundwater monitoring wells in the vicinity of Tall ar Ragrag and the Adaya Burial Site. Characterization of the limestone aquifer and overlying alluvium is needed. RPC should continue to support health assessments for the villagers in Tall ar Ragrag and Adaya. Collecting samples for surface water (storm water), airborne dust, vegetation, and washway sediment should be conducted on a routine basis. Human access to the Adaya Burial Site needs to be strictly limited. Livestock access on or near the burial site needs to be eliminated. The surface-water exposure pathway is likely a greater threat than the groundwater exposure pathway. Installation of a surface-water diversion or collection system is recommended in order to reduce the potential for humans and livestock to come in contact with contaminated water and sediment. To reduce exposure to villagers, groundwater treatment should be considered if elevated uranium or other contaminants are detected in drinking water. Installing water-treatment systems would likely be quicker to accomplish than remediation and excavation of the Adaya Burial Site. The known potential for human exposure to uranium and metals (such as arsenic, chromium, selenium, and strontium) at the Adaya Burial Site is serious. Additional characterization , mitigation, and remediation efforts should be given a high priority.

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