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Electrification 2021 Annual Progress Report

During fiscal year 2021 (FY 2021), the U.S. Department of Energy (DOE) Vehicle Technologies Office (VTO) funded early-stage research, development, demonstration, & deployment (RDD&D) projects that address Batteries and Electrification of the U.S. transportation sector. The VTO Electrification Sub-Program is composed of Electric Drive Technologies, and Grid Integration activities. The Electric Drive Technologies group conducts R&D projects that advance electric motors and power electronics technologies. The Grid and Charging Infrastructure group conducts R&D projects that advance grid modernization and electric vehicle charging technologies. This document presents a brief overview of the Electrification Sub-Program and progress reports for its R&D projects. Each of the progress reports provide a project overview and highlights of the technical results that were accomplished in fiscal year (FY) 2021.

33 ADVANCED PROPULSION SYSTEMS↗

Analysis Program 2021 Annual Progress Report

During fiscal year 2021 (FY 2021), the U.S. Department of Energy Vehicle Technologies Office (VTO) funded analysis projects supportive of VTO’s goals to pursue early-stage research in vehicle and mobility system technologies to reduce petroleum dependence, increase energy reliability and security, improve transportation affordability, and promote economic growth. VTO analysis projects result in a foundation of data, analytical models, and applied analyses that provide insights into critical transportation energy problems and assist in research investment prioritization and portfolio planning. This document presents a brief overview of VTO analysis efforts and progress for projects funded in FY 2021. Each of the progress reports includes project objectives, approach, and highlights of the technical results that were accomplished during the fiscal year (FY).

33 ADVANCED PROPULSION SYSTEMS↗

ESIF 2021

This annual report highlights research done at the Energy Systems Integration Facility (ESIF) in Fiscal Year 2021.

Advanced Research on Integrated Energy Systems↗

ESGF project plan for ramping down development activities and transition the project and data to a new team

This document summarizes the current software development activities carried by the ESGF team with planned delivery dates before the transition of the project to a new team. The work we started on the publishing, search and retrieval, and the backend for indexing and data management that can be deployed using Kubernetes are planned to be delivered within the next three months; however, this assumes that the current team members will continue to work on the project. The activities are listed in Table 1 by priority and in case we lose team members, development of lower priority tasks can be paused and passed to the new team with its current status. Team members can be re-assigned based on their availability and transition work needed. Table 2 below describe activities necessary to help project transition to the new team. Deadlines for these activities are before October 1 st of 2022 or the completion of a successful transition. Support during the transition period assumes that we will have 3 key ESGF members and the ESGF PI supported at the 50% level or less for the duration of the transition. The level of support is an estimate, and it depends on several factors that cannot be decided at this time. The total cost of the proposed work and support activities for fiscal year 2021 is $1,270K with $230K carry over to fiscal year 2022. The cost for the support work listed in Table 2 is the sum of the two rows “HW support” and “project support, maintenance, and transition efforts”, colored blue, in Table1 which adds up to $720K. This cost is included in the $1,270K cost in table 1.

97 MATHEMATICS AND COMPUTING↗

MSIPP-NNSA 2021 Annual Report

This report highlights fiscal year 2021 programmatic and intern activities on the Minority-Serving Institution Partnership Program - National Nuclear Security Administration program.

99 GENERAL AND MISCELLANEOUS↗

2021 Annual Report: Atmospheric Radiation Measurement

In fiscal year 2021 (FY2021), the COVID-19 pandemic continued to have an impact on activities within the Atmospheric Radiation Measurement (ARM) user facility. Travel was limited, which affected field activities and forced the continuation of virtual meetings. However, the ability to travel expanded significantly through the year, bringing some return to normalcy, and throughout the year, there was a great deal of activity dedicated to advancing the facility. Because of COVID, ARM twice delayed the TRacking Aerosol Convection interactions ExpeRiment (TRACER) in the Houston, Texas, area. Originally planned to launch in the spring, TRACER started October 1, 2021, one month after the Surface Atmosphere Integrated Field Laboratory (SAIL) campaign began near Crested Butte, Colorado. ARM teams worked onsite and remotely to make sure both campaigns could launch on this new schedule that was set early in the year. Data from SAIL and TRACER will be critical to improving earth system models, each contributing to different sets of issues. SAIL measurements will provide insights into how precipitation forms and water travels through the Upper Colorado River Basin. TRACER scientists want to know whether tiny atmospheric particles can influence the severity of thunderstorms. In October 2020, the Multidisciplinary Drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition ended after 13 months. MOSAiC data from ARM and other organizations are already helping scientists better understand how ice, atmosphere, and ocean systems are connected in the central Arctic. This report discusses some early investigations from MOSAiC, along with other ARM campaigns and activities generating prolific research. In this report, you will also learn how research activities moved forward during the pandemic at ARM’s fixed-location atmospheric observatories. There were important science applications from measurements across the facility. ARM spent a significant amount of FY2021 looking back—and ahead. In November 2020, ARM had its Triennial Review. This review is held every three years to evaluate ARM’s effectiveness in science, operations, and management. Overall, the reviewers had positive feedback regarding the breadth and impact of science activities using ARM data and the way ARM strives to meet changing user needs. The reviewers also provided some recommendations for strengthening ARM going forward. Incorporating feedback from the review, we finalized an updated Decadal Vision document that will help guide ARM priorities in the coming years. This report describes the four themes driving ARM’s Decadal Vision.

54 ENVIRONMENTAL SCIENCES↗

2021 LDRD Annual Report

This summary report provides an overview of all LDRD projects at Argonne that concluded in Fiscal Year 2021. Many projects are funded for multiple years, the initial fiscal year for each project is indicated by the first four digits of the LDRD project number.

25 ENERGY STORAGE↗

U.S. Department of Energy Hydrogen Program: 2021 Annual Merit Review and Peer Evaluation Report; June 7-11, 2021

This document summarizes peer review comments and scores for the fiscal year 2021 U.S. Department of Energy (DOE) Hydrogen Program Annual Merit Review and Peer Evaluation Meeting (AMR), held virtually June 7-11, 2021. In response to direction from various stakeholders, including the National Academies, this review process provides project- and program-level evaluations of DOE-funded research, development, demonstration, and analysis of hydrogen and fuel cell technologies.

AMR↗

FY 2021 Site Sustainability Plan

The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) Fiscal Year 2021 Site Sustainability Plan details the laboratory's current performance status relative federal mandates and goals pertaining to water, waste, fleet, and energy management; clean and renewable energy; green buildings; acquisition and procurement; measures, funding, and training; electronic stewardship; and organizational resilience. It also provides a road map for future site planning and development that support NREL's commitment to business operations that 1) demonstrate the incorporation of clean energy practices and 2) promote the development of a sustainable and resilient campus while growing greater technological capabilities to advance the national renewable energy marketplace.

ENERGY PLANNING, POLICY, AND ECONOMY↗

Advanced Engine and Fuel Technologies 2021 Annual Progress Report

This report highlights progress achieved by the Advanced Engine and Fuel Technologies Program during fiscal year 2021. The nature, current focus, and recent progress of the Program are described together with summaries of National Laboratory, industry, and university projects that provide an overview of the exciting work being conducted to address critical technical barriers and challenges to commercializing higher-efficiency engine, emissions control, and fuel technologies for passenger and commercial vehicles.

33 ADVANCED PROPULSION SYSTEMS↗

Batteries (2021 Annual Progress Report)

This document summarizes the progress of VTO battery R&D projects supported during the fiscal year 2021 (FY 2021). In FY 2021, the DOE VTO battery R&D funding was approximately $\$$115 million. Its R&D focus was on the development of high-energy batteries for EVs as well as very high-power devices for hybrid vehicles. The electrochemical energy storage roadmap (which can be found at the EERE Roadmap web page2) describes ongoing and planned efforts to develop electrochemical storage technologies for EVs. To advance battery technology, which can in turn improve market penetration of PEVs, the program investigates various battery chemistries to overcome specific technical barriers, e.g., battery cost, performance, life (both the calendar life and the cycle life), its tolerance to abusive conditions, and its recyclability/sustainability. VTO R&D has had considerable success, lowering the cost of EV battery packs to $\$$185/kWh in 2019 (representing more than 80% reduction since 2008) yet even further cost reduction is necessary for EVs to achieve head-to-head cost competitiveness with ICEs (without Federal subsidies). In addition, today’s batteries also need improvements in such areas as their ability to accept charging at a high rate, referred to as extreme fast charging (XFC) (15 minute charge) – to provide a “refueling” convenience similar to ICEs, and the ability to operate adequately at low temperatures. Research into “next-gen lithium-ion” batteries which would provide such functionalities is one of the R&D focus areas. VTO is funding research on both “next gen” chemistries (which employ an alloy anode and/or a high voltage cathode) and beyond lithium-ion (BLI) chemistries (which can, for example, employ a lithium metal anode).

25 ENERGY STORAGE↗

2021 Report - SRNL Aging and Lifetimes program tritium aging studies on structural alloys

This report documents work performed in fiscal year 2021 at SRNL in support of the Aging and Lifetimes program. This work is part of an on-going collaboration between SRNL and SNL to understand tritium embrittlement of structural metals used in Gas Transfer System reservoirs, thereby informing lifetime assessments and predictions. In this effort, test coupons are pre-charged with tritium and allowed to age in a freezer to minimize tritium diffusion and off-gassing while allowing for born-in helium levels to systematically increase. Coupons are then removed periodically and tested to develop an understanding of how mechanical properties degrade as helium levels increase. This report summarizes test results from coupons which are in various stages of aging as they were tritium pre-charged in previous years. Tests were performed on 304L that was previously tritium pre-charged and allowed to age to nominally 300 appm helium. Specimens from this study were previously tested at 100 appm nominal helium content, and this new test point expands that study. Tensile testing of these heat treated 304L tubes (and welded tubes) aged to 100 appm helium were completed which provided a unique study of a diverse set of microstructures and yield strengths ranging from 200-800 MPa. Additionally, 304L notched and smooth tensile specimens aged to 300 appm helium were tensile tested to predetermined strains to provide for a systematic microscopy investigation of aging effects on microstructural damage in partnership with SNL. Testing was performed on 304L electron beam (EB) weld coupons as well as 21-6-9 annealed coupons that were thermally pre-charged in 2020. Tests on the EB welds were completed at 100 appm helium contents, and tests on the annealed 21-6-9 material were completed at 100, 200, and 300 appm helium. Table 0-1 provides the status of the ongoing tritium coupon aging studies. The table includes the year tritium pre-charging took place, the material, and the targeted helium concentrations (appm) for testing.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Performance Assessment for the Environmental Restoration Disposal Facility (Annual Status Report FY 2021)

DOE O 435.1 and DOE M 435.1-1 require that a determination of continued adequacy of the performance assessment (PA) (CP-60089), composite analysis (CA), and disposal authorization statement (DAS) be made on an annual basis, and that the determination must consider the results of data collection and analysis from research, field studies, and monitoring as well as the need to update any Radioactive Waste Management Basis (RWMB) documents. Beginning in 1996, the Environmental Disposal Facility (ERDF) started accepting low-level radioactive, hazardous, and mixed wastes that were generated during cleanup activities at the Hanford Site. ERDF is composed of a series of cells or disposal areas and can accommodate future design expansions as needed. Currently, there are eight cells and two supercells in ERDF. Each supercell is the equivalent of two cells. During this reporting period (fiscal year 2021, extending from October 1, 2020, through September 30, 2021), approximately 9.14E+04 metric tons (1.01E+05 U.S. tons) of waste was disposed at ERDF. From ERDF inception through September 30, 2021, approximately 16.9 million metric tons (18.9 U.S. tons) of waste has been disposed of at ERDF, which equates to consumption of approximately 88.7% of the currently constructed disposal volume. According to the design of ERDF, the facility has the ability to be expanded as needed. As a condition of the DAS, disposal operation within ERDF must be in accordance with the waste acceptance criteria (ERDF-00011) that provide specific radionuclide disposal limits, waste form restrictions, and descriptions of acceptable waste packages in compliance with the requirements of DOE M 435-1.1. The ERDF waste acceptance criteria stipulate that waste destined for disposal at ERDF be controlled based on source, physical form, and contaminant concentration and activity levels. There have been no changes to the physical configuration of ERDF or to the waste forms (source, physical form, etc.). No new unreviewed disposal question screenings or evaluations have been generated in this reporting period. Therefore, there are no noted impacts to the PA, CA, DAS, or RWMB resulting from the evaluations and screenings. Sum-of-fractions analysis shows that the disposed inventory meets both the concentration and inventory threshold requirements. A sum-of-fractions value is computed for ERDF sensitive radionuclides contributing to the all pathways and the air pathway inventory limits. Computed values were 7.63E-03 and 1.49E-03, respectively. The disposed waste inventory remained well under the PA imposed limits, as shown in Table 4 and Table 5 in the main text of this report. Required monitoring was satisfactorily completed during the fiscal year reporting period. Compliance with performance objectives were met as each of the reported values were well below the established limit. Overall, there are no substantive changes to primary PA assumptions or changes to the PA analysis conclusion; therefore, compliance with DOE O 435.1 and the DAS is maintained.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Quantitative Highlights of 20 years Aqua Data Archive and Data Usage

NASA’s Aqua satellite carries six Earth-observing instruments Atmospheric Infrared Sounder (AIRS), Advanced Microwave Scanning Radiometer for EOS (AMSR-E), Advanced Microwave Sounding Unit (AMSU), Clouds and the Earth’s Radiant Energy System (CERES), Humidity Sounder for Brazil (HSB) and Moderate Resolution Imaging Spectroradiometer (MODIS). Currently only four of six instruments are collecting data, two instruments that stopped transmitting data are AMSR-E that suffered a major anomaly in October 2011 and was powered off in March 2016 while as HSB failed in February 2003. NASA’s Earth Science Data and Information System (ESDIS) Project makes these data, along with derived products, available to worldwide data users. Since the launch of Aqua on May 4, 2002, more than 10,000 data products have been archived and distributed by NASA-funded Distributed Active Archive Centers (DAACs) that are part of NASA’s Earth Observing System Data and Information System (EOSDIS). At the end of the 2021 Fiscal Year with over 100,000 orbits data, about 1,000 Aqua data products constituted almost 16.5 % of the entire EOSDIS data archive volume (8.6 PB out of approximately 55.2 PB), and 7.5 PB of Aqua data were distributed to over half-a-million public users worldwide. By categorizing the Aqua data products and their distribution, we can get a quantitative assessment of Aqua data usage. NASA’s ESDIS Project has collected archive, distribution, and user information from EOSDIS data users since February 2000. These metrics are available through the ESDIS Metrics System (EMS). EMS information is stored in a relational database from which quantitative metrics of Aqua data use can be retrieved and analyzed. The purposes of this study are to: 1) perform a comprehensive investigation of the 20-year trend in the archive and distribution of Aqua data products; 2) identify and characterize data product usage over the last 20 years; and 3) identify and characterize the global user community for these data. In addition to revealing how Aqua data use has evolved over time, the results of this study provide insights on identifying the various user communities for different kinds of Earth science data products. Also, because of the enormous quantity of data handled by EOSDIS DAACs, the study provides guidance of the requirements for future data systems that will be needed to effectively and efficiently handle the ever-increasing amounts of Earth science data produced by future (and ongoing) Earth science missions.

Lalit Wanchoo↗

Sodium Fire Collaborative Study Progress -- CNWG Fiscal Year 2020

This report discusses the progress on the collaboration between Sandia National Laboratories (Sandia) and Japan Atomic Energy Agency (JAEA) on the sodium fire research in fiscal year 2020. First, the current sodium pool fire model in MELCOR, which is adapted from CONTAIN-LMR code, is discussed. The associated sodium fire input requirements are also presented. These input requirements are flexible enough to permit further model development via control functions to enhance the current model without modifying the source code. The theoretical pool fire model improvement developed at Sandia is discussed. A control function model has been developed from this improvement. Then, the validation study of the sodium pool fire model in MELCOR carried out by both Sandia and JAEA’s staff is described. To validate this pool fire model with the enhancement, a JAEA sodium pool fire experiment (F7-1 test) is used. The results of the calculation are discussed as well as suggestions for further model improvement. Finally, recommendations are made for new MELCOR simulations for next fiscal year, 2021.

36 MATERIALS SCIENCE↗

U.S. Efforts in Support of Examinations at Fukushima Daiichi- November 2020 Meeting Notes with Updated Information Requests

Much is still not known about the end-state of core materials in each unit that was operating on March 11, 2011 at the Fukushima Daiichi Nuclear Power Station (Daiichi). Information obtained from Daiichi is required to inform Decontamination and Decommissioning (D&D) activities, improving the ability of the Tokyo Electric Power Company Holdings, Incorporated (TEPCO Holdings) to characterize potential hazards and to ensure the safety of workers involved with cleanup activities. This information also has important implications for the safety and operation of U.S. commercial nuclear power plants. This document summarizes results from the Fiscal Year 2021 (FY2021) U.S. effort to review Daiichi information and extract insights to enhance the safety of existing and future nuclear power plant designs. This U.S. effort, which was initiated in 2014 by the Department of Energy Office of Nuclear Energy (DOE-NE), is completed by a group of experts in reactor safety and plant operations that identify examination needs and evaluate recent Daiichi examination data to address these needs. Since its inception, annual reports were issued that document significant safety insights being obtained in areas of special emphasis: system and component performance, radionuclide surveys and sampling, debris end-state location, combustible gas effects, and plant operations and maintenance. In addition to reducing uncertainties related to severe accident modeling progression, these insights have and continue to be used to update guidance for severe accident prevention, mitigation, and emergency planning. Reduced uncertainties in modeling the events at Daiichi improve the realism of reactor safety evaluations that inform future D&D activities. A key aspect of prior U.S. efforts, the updated list of information requests, is included in this FY2021 report to ensure that they are transmitted to organizations within Japan. This report also continues to emphasize how information obtained from the affected reactors at Daiichi has been and will continue to be used to update severe accident management strategies and reduce uncertainties in systems analysis code models. In addition, recommendations are included that would expand the use of this information to provide insights regarding maintenance, radiation protection, design, and siting activities for existing and new reactors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗