Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “extraterrestrial”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Mutual Detectability: A Targeted SETI Strategy That Avoids the SETI Paradox

As our ability to undertake searches for extraterrestrial intelligence (SETI) grows, so does interest in the controversial endeavor of messaging extraterrestrial intelligence (METI). METI proponents point to the SETI Paradox—if all civilizations refrain from METI then SETI is futile. I introduce mutual detectability as a game-theoretic strategy to increase the success potential of targeted SETI. Mutual detectability comprises four laws that establish how SETI participants can engage each other based on mutual evidence of mutual existence. I argue that the party whom both SETI participants can judge to have better quality evidence, or common denominator information (CDI), has an onus to transmit to avoid the SETI Paradox. Transiting exoplanets within the Earth Transit Zone form a target subset that satisfies mutual detectability requirements. I identify the intrinsic time-integrated transit signal strength, which for Earth is 10{sup 3} L{sub ⊙} ppm hours yr{sup −1}, as suitable CDI. Civilizations on habitable-zone planets of radius R{sub p}/R{sub ⊕}≲(L{sub ∗}/L{sub ⊙}){sup −1/7} have superior CDI on us, and so under the mutual detectability framework have game-theory incentive (onus) to transmit. While the onus to transmit falls on us for habitable planets around L{sub *} > L{sub ⊙} stars, considerations of relative stellar frequency, main-sequence lifetime and planet occurrence rates mean that such systems are likely to be in a small minority. Surveys of the Earth Transit Zone for Earth-analog transiting planets around subsolar luminosity hosts would facilitate targeted SETI programs for civilizations who have game-theory incentive to transmit signals to us. A choice to remain silent, by not engaging in METI toward such systems, does not in this case fuel concerns of a SETI Paradox.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

The Breakthrough Listen Search for Intelligent Life: Searching for Technosignatures in Observations of TESS Targets of Interest

Exoplanetary systems are prime targets for the Search for Extraterrestrial Intelligence (SETI). With the recent uptick in the identification of candidate and confirmed exoplanets through the work of missions like the Transiting Exoplanet Survey Satellite (TESS), we are beginning to understand that Earth-like planets are common. In this work, we extend the Breakthrough Listen (BL) search for extraterrestrial intelligence to include targeted searches of stars identified by TESS as potential exoplanet hosts. We report on 113 30 minute cadence observations collected for 28 targets selected from the TESS Input Catalog from among those identified as containing signatures of transiting planets. The targets were searched for narrowband signals from 1 to 11 GHz using the turboSETI pipeline architecture modified for compatibility with the Google Cloud environment. Data were searched for drift rates of ±4 Hz s{sup −1} above a minimum signal-to-noise threshold of 10, following the parameters of previous searches conducted by Price et al. and Enriquez et al. The observations presented in this work establish some of the deepest limits to date over such a wide band (1–11 GHz) for life beyond Earth. We determine that fewer than 12.72% of the observed targets possess transmitters operating at these frequencies with an equivalent isotropic radiated power greater than our derived threshold of 4.9×10{sup 14} W.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Integration of Total-Sky Imager Data with a Physics-Based Smart Persistence Model for Intra-Hour Forecasting of Solar Radiation

Short-term solar forecasting models based solely on global horizontal irradiance (GHI) measurements are often unable to discriminate the forecasting of the factors affecting GHI from those that can be precisely computed by atmospheric models. Our previous study introduced a Physics-based Smart Persistence model for Intra-hour forecasting of solar radiation (PSPI) that decomposed the forecasting of GHI into the computation of extraterrestrial solar radiation and solar zenith angle and the forecasting of cloud albedo and cloud fraction. The extraterrestrial solar radiation and solar zenith angle were accurately computed by the Solar Position Algorithm (SPA) developed at the National Renewable Energy Laboratory (NREL). A cloud retrieval technique was used to estimate cloud albedo and cloud fraction from surface-based observations of GHI. With the assumption of persistent cloud structures, the cloud albedo and cloud fraction were predicted for future time steps using a two-stream approximation and a 5-minute exponential weighted moving average, respectively. The model evaluation indicated the estimation and forecast of cloud fraction mostly contributed to the uncertainty of the PSPI though it overcame the persistence and smart persistence models in all forecast time horizons between 5 and 60 minutes. This study aims to enhance the PSPI by ingesting surface-based observations of cloud fraction from a total sky imager (TSI). The estimation and forecast of cloud albedo is correspondingly improved by utilizing the cloud fraction observations and thus leads to more accurate GHI forecast. Various time-series analysis methods are also investigated on the forecasting of cloud fraction and cloud albedo for further improving the GHI forecast. These improvements are valuable for many applications, such as forecasting energy use for buildings, grid operations, and ultimately bringing down the cost of solar energy.

14 SOLAR ENERGY↗
DOE OSTI2020

Thermal Management by Engineering the Alignment of Nanocellulose

One of the grand current research challenges is to improve the energy efficiency of residential and commercial buildings, which cumulatively consume more than 40% of the energy generated globally. In addition to improving the comfort of the inhabitants and mitigating the growing energy consumption problem, new building materials and technologies could provide a safe strategy for geoengineering to mitigate global climate change. Herein, recent progress in developing such advanced materials from nanocellulose, which is often derived from wood or even dirty feedstocks like waste, is reviewed. By using chemical and bacteria-enabled processing, nanocellulose can be used to fabricate broadband photonic reflectors, thermally super-insulating aerogels, solar gain regulators, and low-emissivity coatings, with potential applications in windows, roofs, walls, and other components of buildings envelopes. These material developments draw inspiration from advanced energy management found in nature, such as the nanoporous photonic structures that evolved in cuticles of beetles. Fabrication of such materials takes advantage of mesoscale liquid crystalline self-assembly, which allows for pre-designed control of cellulose nanoparticle orientations at the mesoscale. Finally, with the potential fully realized, such materials could one day transform the current energy-lossy buildings into energy plants on Earth and possibly even enable extraterrestrial habitats.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Machine Learning for Optical Scanning Probe Nanoscopy

Abstract The ability to perform nanometer‐scale optical imaging and spectroscopy is key to deciphering the low‐energy effects in quantum materials, as well as vibrational fingerprints in planetary and extraterrestrial particles, catalytic substances, and aqueous biological samples. These tasks can be accomplished by the scattering‐type scanning near‐field optical microscopy (s‐SNOM) technique that has recently spread to many research fields and enabled notable discoveries. Herein, it is shown that the s‐SNOM, together with scanning probe research in general, can benefit in many ways from artificial‐intelligence (AI) and machine‐learning (ML) algorithms. Augmented with AI‐ and ML‐enhanced data acquisition and analysis, scanning probe optical nanoscopy is poised to become more efficient, accurate, and intelligent.

Chen, Xinzhong↗
DOE OSTI2023

One Collision—Two Substituents: Gas–Phase Preparation of Xylenes under Single–Collision Conditions

The fundamental reaction pathways to the simplest dialkylsubstituted aromatics—xylenes (C 6 H 4 (CH 3 ) 2 )—in high-temperature combustion flames and in low-temperature extraterrestrial environments are still unknown, but critical to understand the chemistry and molecular mass growth processes in these extreme environments. Exploiting crossed molecular beam experiments augmented by state-of-the-art electronic structure and statistical calculations, this study uncovers a previously elusive, facile gas-phase synthesis of xylenes through an isomer-selective reaction of 1-propynyl (methylethynyl, CH 3 CC) with 2-methyl-1,3-butadiene (isoprene, C 5 H 8 ). The reaction dynamics are driven by a barrierless addition of the radical to the diene moiety of 2-methyl-1,3-butadiene followed by extensive isomerization (hydrogen shifts, cyclization) prior to unimolecular decomposition accompanied by aromatization via atomic hydrogen loss. This overall exoergic reaction affords a preparation of xylenes not only in high-temperature environments such as in combustion flames and around circumstellar envelopes of carbon-rich Asymptotic Giant Branch (AGB) stars, but also in low-temperature cold molecular clouds (10 K) and in hydrocarbon-rich atmospheres of planets and their moons such as Triton and Titan. Furthermore, our study established a hitherto unknown gas-phase route to xylenes and potentially more complex, disubstituted benzenes via a single collision event highlighting the significance of an alkyl-substituted ethynyl-mediated preparation of aromatic molecules in our Universe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

One Collision—Two Substituents: Gas–Phase Preparation of Xylenes under Single–Collision Conditions

The fundamental reaction pathways to the simplest dialkylsubstituted aromatics—xylenes (C 6 H 4 (CH 3 ) 2 )—in high-temperature combustion flames and in low-temperature extraterrestrial environments are still unknown, but critical to understand the chemistry and molecular mass growth processes in these extreme environments. Exploiting crossed molecular beam experiments augmented by state-of-the-art electronic structure and statistical calculations, this study uncovers a previously elusive, facile gas-phase synthesis of xylenes through an isomer-selective reaction of 1-propynyl (methylethynyl, CH 3 CC) with 2-methyl-1,3-butadiene (isoprene, C 5 H 8 ). The reaction dynamics are driven by a barrierless addition of the radical to the diene moiety of 2-methyl-1,3-butadiene followed by extensive isomerization (hydrogen shifts, cyclization) prior to unimolecular decomposition accompanied by aromatization via atomic hydrogen loss. This overall exoergic reaction affords a preparation of xylenes not only in high-temperature environments such as in combustion flames and around circumstellar envelopes of carbon-rich Asymptotic Giant Branch (AGB) stars, but also in low-temperature cold molecular clouds (10 K) and in hydrocarbon-rich atmospheres of planets and their moons such as Triton and Titan. Furthermore, our study established a hitherto unknown gas-phase route to xylenes and potentially more complex, disubstituted benzenes via a single collision event highlighting the significance of an alkyl-substituted ethynyl-mediated preparation of aromatic molecules in our Universe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Space environment considerations for perovskite solar cell operations: A review

Designing new technology for extraterrestrial applications certainly presents unique challenges. The environmental stressors perovskite-based photovoltaics must overcome will vary with the environment in which they are deployed. One must consider mission requirements when designing photovoltaic devices and packaging. Different space "theaters" can have dramatically different stressors needing consideration for designing panels for solar power generation. Here, in this article, we review the relevant space environmental conditions that must be considered when designing perovskite-based photovoltaic devices for implementation in space. We specifically consider thermal, radiation, gaseous, weather, and other phenomena most relevant to photovoltaic operation for specific theaters such as Low Earth Orbit, Geosynchronous Orbit, Lunar surface, Mars (orbit and surface), and interplanetary exploration pathways.

14 SOLAR ENERGY↗
DOE OSTI2026

Scaling considerations for supercritical carbon dioxide cycles including turbomachinery loss models

A modeling framework for the supercritical carbon dioxide recompressed closed Brayton cycle was developed. Unlike typical models, this effort incorporated generalized empirical turbomachinery loss models. Aerodynamic, windage, and leakage losses were considered in order to address the limitations of conventional constant-efficiency turbomachinery assumptions without relying on machine-specific or computationally expensive simulations. The model enables system-level exploration of optimal cycle design across a range of power scales, including smaller scales that are relevant to microreactors and extraterrestrial power applications. Parametric studies and multi-objective optimizations are used to evaluate the trade-offs between thermal efficiency and system compactness based on an analytical heat exchanger scaling model, yielding Pareto-optimal fronts across a range of operating pressures. Results reveal that at small power scales, the Pareto-optimal compressor inlet pressure becomes subcritical due to the increasing influence of density-dependent turbomachinery losses. Here, the relative contributions of each loss mechanism are quantified, and design recommendations are provided for key parameters such as recompression split ratio and generator cavity pressure across varying power scales.

Multi-objective optimization↗
DOE OSTI2023

Measurements of sound propagation in Mars' lower atmosphere

Acoustics has become extraterrestrial and Mars provides a new natural laboratory for testing sound propagation models compared to those ones on Earth. Owing to the unique combination of a microphone and two sound sources, the Ingenuity helicopter and the SuperCam laser-induced sparks, the Mars 2020 Perseverance rover payload enables the in situ characterization of unique sound propagation properties of the low-pressure CO 2 -dominated Mars atmosphere. In this study, we show that atmospheric turbulence is responsible for a large variability in the sound amplitudes from laser-induced sparks. This variability follows the diurnal pattern of turbulence. In addition, acoustic measurements acquired over one Martian year reveal a variation of the sound intensity by a factor of 1.8 from a constant source due to the seasonal cycle of pressure and temperature that significantly modifies the acoustic impedance and shock-wave formation. Finally, we show that the evolution of the Ingenuity tones and laser spark amplitudes with distance is consistent with one of the existing sound absorption models, which is a key parameter for numerical simulations applied to geophysical experiments on CO 2 -rich atmospheres. Overall, these results demonstrate the potential of sound propagation to interrogate the Mars environment and will therefore help in the design of future acoustic-based experiments for Mars or other planetary atmospheres such as Venus and Titan.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Mars: new insights and unresolved questions

Mars exploration motivates the search for extraterrestrial life, the development of space technologies, and the design of human missions and habitations. Here, we seek new insights and pose unresolved questions relating to the natural history of Mars, habitability, robotic and human exploration, planetary protection, and the impacts on human society.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Vibrational Bands of the 2-Butyn-1-yl Radical

This article reports the spectroscopic signature of the 2-butyn-1-yl radical. The radical is an isomer of C 4 H 5 and is is likely to be significant to reactions that occur during combustion of fuels, as well as reactions in extraterrestrial environments. In this work, the radical was formed by heating a mixture of 1-bromo-2-butyne and argon to 800 K in a pulsed, microtubular reactor. The resultant radicals and other trace products were trapped in a low-temperature argon matrix. Fourier-transform infrared spectroscopy was used to record seven vibrational bands of the 2-butyn-1-yl radical. In conclusion, the experimentally observed frequencies and intensities of the seven vibrational bands were found to be consistent with computational predictions from the literature and also new calculations done in this work.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

An Aromatic Universe–A Physical Chemistry Perspective

This Perspective presents recent advances in our knowledge of the fundamental elementary mechanisms involved in the low- and high-temperature molecular mass growth processes to polycyclic aromatic hydrocarbons in combustion systems and in extraterrestrial environments (hydrocarbon-rich atmospheres of planets and their moons, cold molecular clouds, circumstellar envelopes). Molecular beam studies combined with electronic structure calculations extracted five key elementary mechanisms: Hydrogen Abstraction – Acetylene Addition, Hydrogen Abstraction – Vinylacetylene Addition, Phenyl Addition – DehydroCyclization, Radical-Radical Reactions, and Methylidyne Addition – Cyclization – Aromatization. Furthermore, these studies, summarized here, provide compelling evidence that key classes of aromatic molecules can be synthesized in extreme environments covering low temperatures in molecular clouds (10 K) and hydrocarbon-rich atmospheres of planets and their moons (35–150 K) to high temperature environments like circumstellar envelopes of carbon rich Asymptotic Giant Branch Stars stars and combustion systems at temperatures above 1,400 K thus shedding light on the aromatic universe we live in.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Behavior of Long-Chain Hydrocarbons at High Pressures and Temperatures

Although long-chain aliphatic hydrocarbons are documented in meteorites, their origin is poorly understood. A key question is whether they are pristine or a byproduct of terrestrial alteration? Thus, to understand if these long-chain hydrocarbons are indigenous, it will be important to explore their thermodynamic and mechanical stability at conditions experienced by extraterrestrial objects during atmospheric entry and passage. Extreme pressures and temperatures experienced by meteorites are likely to alter the molecular organization of these long-chain hydrocarbons. These structural changes associated with extreme conditions are often documented via laboratory-based Raman spectroscopic measurements. So far, Raman spectroscopic measurements have investigated the effect of static compression on the aliphatic hydrocarbons. The effect of temperature on the structural changes remains poorly explored. To bridge this gap, in this study, we have explored the behavior of two aliphatic hydrocarbons at simultaneously high pressures and temperatures. We have used a resistively heated diamond anvil cell. On compression to moderate pressures, the appearance of new vibrational modes in the low-energy region confirms prior studies and is related to the bending of the linear chains. Upon heating to ~220 °C, we note that the new low-energy mode undergoes softening. The mode softening is likely due to the combination of unbending of the alkane chain and mode anharmonicity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Sub-Nanometer Nanoclusters of Copper Atop Single-Atom Copper Moieties toward Electrochemical CO 2 Hydrogenation to Methane

The electrochemical CO 2 reduction (eCO 2 R) offers a compelling route for converting CO 2 into value-added fuels and chemicals. Among CO 2 -derived products, methane (CH 4 ) occupies a distinct position, serving both as a key intermediate for emerging cascade electro-oxidation to oxygenates and as a strategically important extraterrestrial fuel that can be generated in situ from off-planet CO 2 resources. Although Cu-based catalysts capable of selectively producing CH 4 have been reported, they seldom sustain high selectivity at practically relevant current densities. Here, we created a single-step co-pyrolysis strategy toward generating and anchoring Cu sub-nanometer clusters (Cu SNC ) atop Cu-N x single-atom (SA) motifs embedded within N-doped carbon (NC), with controllable nanostructures through tuning of the synthesis parameters. Complementary spectroscopic analyses and density functional theory (DFT) calculations help reveal a structure−activity correlation that could guide the catalyst design. The Cu SNC @NC sample synthesized at 550 °C pyrolysis temperature (best described and modeled as Cu 3 -CuN 4 domains) represents the most effective combination of cluster size, metal-nitrogen coordination, and adsorption energetics needed to selectively promote CH 4 generation versus other eCO 2 R products. Incorporating pulsed electrolysis and hydrophobicity-modulated transport tuning at the triple-phase boundary (TPB) further enhanced CH 4 production achieving a partial CH 4 current density of ∼321 mA cm −2 , 53% Faradaic efficiency (FECH 4 ), and less than 4% combined FE for other eCO 2 R products, simplifying downstream CH 4 purification or upgrading. This work establishes generalizable principles for controlling Cu cluster atomicity and metal−nitrogen coordination, both of which are recognized determinants of CH 4 -efficient eCO 2 R.

CH4 production↗
DOE OSTI2020

A Monte Carlo Approach to Approximating the Effects of Pore Geometry on the Phase Behavior of Soil Freezing

Abstract Freezing in porous media is associated with a host of dynamic phenomena that stem from the presence and mobility of premelted liquid at subzero temperatures. Accurate assessments of the progressive liquid‐ice phase transition is required for predictive models of frost damage, glacier‐till coupling, and many other cold regions processes, as well as for evaluating the capacity for water storage in near‐surface extraterrestrial environments. We use a Monte Carlo approach to sample the pore space in a synthetic 3D packing of poly‐dispersed spherical particles and evaluate local geometrical constraints that allow us to assess changes in the relative proportions of pore fluid and ice. By approximating the phase boundary geometry in fine‐grained pores while considering both the curvature of the liquid‐ice interface and wetting interactions with matrix particles, our model predicts changes in phase equilibrium in granular media over a broad temperature range, where present accounting for the colligative effects of chloride and perchlorate solutes. In addition to formulating the constitutive behavior needed to better understand properties and processes in frozen soils, our results also provide insight into other aspects of phase equilibria in porous media, including the formation of methane hydrates in permafrost and marine sediments, and the partitioning between liquid water and vapor in the vadose zone.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Airborne Infrasound Makes a Splash

Natural and anthropogenic events may create low frequency sound waves, or infrasound, that can travel for vast distances in planetary atmospheres. They permit the remote monitoring of geophysical activity over local to global scales. Most studies have utilized ground-based recorders, but it is possible to deploy acoustic sensors to altitudes of over 50 km. Such elevated platforms can capture sounds that their surface analogs cannot access. High altitude balloons and low altitude aerostats are filling this observation gap, but key environments remain out of reach of both of these. Furthermore, recent work by den Ouden, Smets et al. (2021) addressed this with a new instrumentation platform—a large seabird flying just above the ocean's surface. Their work demonstrates that, infrasound sensing using heavier-than-air platforms in windy environments is possible, which has implications both terrestrially (e.g., extending sensor networks over the oceans) and extraterrestrially (proposed or planned missions to Venus and Titan).

47 OTHER INSTRUMENTATION↗
DOE OSTI2025

Revealing the Moon's Taurus‐Littrow Landslide via Integrated Analysis of Pristine Apollo 17 Soil Core 73001/2

The “light mantle” deposit at the base of South Massif in the Moon's Taurus‐Littrow Valley was a primary science target for the Apollo 17 exploration. The possibility that it was a landslide triggered by ejecta from Tycho Crater is critical for establishing the age of Tycho and constraining recent lunar impact chronology; however, the mechanism of emplacement of the deposit has recently been questioned. The newly opened 73001/73002 double drive tube from Station 3 sampled 70.6 cm deep into the regolith and represents the first stratigraphic section of an extraterrestrial landslide deposit returned to Earth. Here we provide an overview of the stratigraphy of the 73001/73002 core based on top to bottom variations revealed by coordinated laboratory analyses and explore constraints on the emplacement of the light mantle deposit. Briefly, the upper ∼10 cm of 73002 contains a disturbed zone from space weathering and emplacement of ejecta from a nearby crater that excavated and ejected basaltic material. Below 10 cm is a nearly uniform unit of immature regolith. These data support a single event for the emplacement of the deposit at this location, followed by weathering and mixing of materials from nearby crater ejecta in the upper 10 cm. Slight variations in chemistry and clast components may reflect the relative stratigraphy of the South Massif slope, with material toward the bottom of 73001 originating from lower slopes and material from higher up in the core representing regolith from higher up the South Massif slopes.

58 GEOSCIENCES↗