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NASA NTRS1987

Synthesis and characterization of processable polyimides with enhanced thermal stability

Many of the emerging applications of polymers on space vehicles require materials with outstanding thermal stability. These polymers must also be readily processable in order to facilitate their use. The syntheses and polymerization of a cardo dianhydride were investigated. This monomer was prepared via the reaction of N-methyl 4-nitrophthalimide with a cardo diol. Polyimides containing oxyalkylene linkages were studied. The effects of two additional structural modifications on the polymers' properties were investigated. The effects of carrying out the preparation of poly(amic acid)s under non-equilibrium conditions were examined. Approaches that were investigated included the in-situ neutralization of the generated amic acid and its in-situ esterification.

Harris, Frank W.↗

NASA NTRSDate not supplied

Enhanced Thermal Stability of High Yttria Concentration YSZ Aerogels

Aerogels demonstrate extraordinarily low thermal conductivity and low density, presenting a promising form of lightweight insulation for aerospace applications. The primary challenge is stabilization of the highly porous structure at temperatures to 1200 °C. Upon collapse of the pore structure, the favorable thermal properties and low density are diminished. Yttria-stabilized zirconia (YSZ) aerogels are synthesized to investigate the effect of composition on morphology, phase behavior, and thermal stability (specific surface area, pore size distribution). This work demonstrates the improvement in thermal stability of zirconia aerogels with increased yttria content. Furthermore, changes in structure and surface chemistry of YSZ aerogels are studied in both oxidizing and inert atmospheres. With an improved understanding of aerogel structure and performance, metal oxide aerogels can be developed to withstand the extreme environments of space exploration.

Nathaniel Olson↗

NASA NTRS1988

A spectral collocation solution to the compressible stability eigenvalue problem

A newly developed spectral compressible linear stability code (SPECLS) (staggered pressure mesh) is presented for analysis of shear flow stability, and applied to high speed boundary layers and free shear flows. The formulation utilizes the first application of a staggered mesh for a compressible flow analysis by a spectral technique. An order of magnitude less number of points is needed for equivalent accuracy of growth rates compared to those calculated by a finite difference formulation. Supersonic disturbances which are found to have oscillatory structures were resolved by a spectral multi-domain discretization, which requires a factor of three fewer points than the single domain spectral stability code. It is indicated, as expected, that stability of mixing layers is enhanced by viscosity and increasing Mach number. The mean flow involves a jet being injected into a quiescent gas. Higher temperatures of the injected gas is also found to enhance stability characteristics of the free shear layer.

Macaraeg, Michele G.↗

NASA NTRS2015

Improved Discrete Ordinate Solutions in the Presence of an Anisotropically Reflecting Lower Boundary: Upgrades of the DISORT Computational Tool

A successor version 3 of DISORT (DISORT3) is presented with important upgrades that improve the accuracy, efficiency, and stability of the algorithm. Compared with version 2 (DISORT2 released in 2000) these upgrades include (a) a redesigned BRDF computation that improves both speed and accuracy, (b) a revised treatment of the single scattering correction, and (c) additional efficiency and stability upgrades for beam sources. In DISORT3 the BRDF computation is improved in the following three ways: (i) the Fourier decomposition is prepared "off-line", thus avoiding the repeated internal computations done in DISORT2; (ii) a large enough number of terms in the Fourier expansion of the BRDF is employed to guarantee accurate values of the expansion coefficients (default is 200 instead of 50 in DISORT2); (iii) in the post processing step the reflection of the direct attenuated beam from the lower boundary is included resulting in a more accurate single scattering correction. These improvements in the treatment of the BRDF have led to improved accuracy and a several-fold increase in speed. In addition, the stability of beam sources has been improved by removing a singularity occurring when the cosine of the incident beam angle is too close to the reciprocal of any of the eigenvalues. The efficiency for beam sources has been further improved from reducing by a factor of 2 (compared to DISORT2) the dimension of the linear system of equations that must be solved to obtain the particular solutions, and by replacing the LINPAK routines used in DISORT2 by LAPACK 3.5 in DISORT3. These beam source stability and efficiency upgrades bring enhanced stability and an additional 5-7% improvement in speed. Numerical results are provided to demonstrate and quantify the improvements in accuracy and efficiency of DISORT3 compared to DISORT2.

Lin, Z.↗

NASA NTRS2002

Analysis of High Order Difference Methods for Multiscale Complex Compressible Flows

Accurate numerical simulations of complex multiscale compressible viscous flows, especially high speed turbulence combustion and acoustics, demand high order schemes with adaptive numerical dissipation controls. Standard high resolution shock-capturing methods are too dissipative to capture the small scales and/or long-time wave propagations without extreme grid refinements and small time steps. An integrated approach for the control of numerical dissipation in high order schemes with incremental studies was initiated. Here we further refine the analysis on, and improve the understanding of the adaptive numerical dissipation control strategy. Basically, the development of these schemes focuses on high order nondissipative schemes and takes advantage of the progress that has been made for the last 30 years in numerical methods for conservation laws, such as techniques for imposing boundary conditions, techniques for stability at shock waves, and techniques for stable and accurate long-time integration. We concentrate on high order centered spatial discretizations and a fourth-order Runge-Kutta temporal discretizations as the base scheme. Near the bound-aries, the base scheme has stable boundary difference operators. To further enhance stability, the split form of the inviscid flux derivatives is frequently used for smooth flow problems. To enhance nonlinear stability, linear high order numerical dissipations are employed away from discontinuities, and nonlinear filters are employed after each time step in order to suppress spurious oscillations near discontinuities to minimize the smearing of turbulent fluctuations. Although these schemes are built from many components, each of which is well-known, it is not entirely obvious how the different components be best connected. For example, the nonlinear filter could instead have been built into the spatial discretization, so that it would have been activated at each stage in the Runge-Kutta time stepping. We could think of a mechanism that activates the split form of the equations only at some parts of the domain. Another issue is how to define good sensors for determining in which parts of the computational domain a certain feature should be filtered by the appropriate numerical dissipation. For the present study we employ a wavelet technique introduced in as sensors. Here, the method is briefly described with selected numerical experiments.

Sjoegreen, Bjoern↗

NASA NTRS1983

Some lessons from NACA/NASA aerodynamic studies following World War II

An historical account is presented of the new departures in aerodynamic research conducted by NACA, and subsequently NASA, as a result of novel aircraft technologies and operational regimes encountered in the course of the Second World War. The invention and initial development of the turbojet engine furnished the basis for a new speed/altitude regime in which numerous aerodynamic design problems arose. These included compressibility effects near the speed of sound, with attendant lift/drag efficiency reductions and longitudinal stability enhancements that were accompanied by a directional stability reduction. Major research initiatives were mounted in the investigation of swept, delta, trapezoidal and variable sweep wing configurations, sometimes conducted through flight testing of the 'X-series' aircraft. Attention is also given to the development of the first generation of supersonic fighter aircraft.

Spearman, M. L.↗

NASA NTRS1996

Interface Morphology During Crystal Growth: Effects of Anisotropy and Fluid Flow

The effect of a parallel shear flow and anisotropic interface kinetics on the onset of instability during growth from a supersaturated solution is analyzed. The model used for anisotropy is based on the microscopic picture of step motion. A shear flow (linear Couette flow or asymptotic suction profile) parallel to the crystal solution interface in the same direction as the step motion decreases interface stability. A shear flow counter to the step motion enhances stability and for sufficiently large shear rates the interface is absolutely morphologically stable. For large wave numbers, the perturbed flow field can be neglected and a simple analytic approximation for the stability-instability demarcation is found.

Coriell, S. R.↗

NASA NTRS2010

Optimized Li-Ion Electrolytes Containing Fluorinated Ester Co-Solvents

A number of experimental lithium-ion cells, consisting of MCMB (meso-carbon microbeads) carbon anodes and LiNi(0.8)Co(0.2)O2 cathodes, have been fabricated with increased safety and expanded capability. These cells serve to verify and demonstrate the reversibility, low-temperature performance, and electrochemical aspects of each electrode as determined from a number of electrochemical characterization techniques. A number of Li-ion electrolytes possessing fluorinated ester co-solvents, namely trifluoroethyl butyrate (TFEB) and trifluoroethyl propionate (TFEP), were demonstrated to deliver good performance over a wide temperature range in experimental lithium-ion cells. The general approach taken in the development of these electrolyte formulations is to optimize the type and composition of the co-solvents in ternary and quaternary solutions, focusing upon adequate stability [i.e., EC (ethylene carbonate) content needed for anode passivation, and EMC (ethyl methyl carbonate) content needed for lowering the viscosity and widening the temperature range, while still providing good stability], enhancing the inherent safety characteristics (incorporation of fluorinated esters), and widening the temperature range of operation (the use of both fluorinated and non-fluorinated esters). Further - more, the use of electrolyte additives, such as VC (vinylene carbonate) [solid electrolyte interface (SEI) promoter] and DMAc (thermal stabilizing additive), provide enhanced high-temperature life characteristics. Multi-component electrolyte formulations enhance performance over a temperature range of -60 to +60 C. With the need for more safety with the use of these batteries, flammability was a consideration. One of the solvents investigated, TFEB, had the best performance with improved low-temperature capability and high-temperature resilience. This work optimized the use of TFEB as a co-solvent by developing the multi-component electrolytes, which also contain non-halogenated esters, film forming additives, thermal stabilizing additives, and flame retardant additives. Further optimization of these electrolyte formulations is anticipated to yield improved performance. It is also anticipated that much improved performance will be demonstrated once these electrolyte solutions are incorporated into hermetically sealed, large capacity prototype cells, especially if effort is devoted to ensure that all electrolyte components are highly pure.

Prakash, G. K. Surya↗

NASA NTRS1987

Time-marching solution of incompressible Navier-Stokes equations for internal flow

Primitive variables with central differencing on a staggered grid are used in the present, factored ADI finite-difference scheme for artificial compressibility method solution of the incompressible Navier-Stokes equations, leading to a close coupling between velocity and pressure that both enhances stability and eliminates the need for artificial damping. Computational efficiency is enhanced through the use of a spatially variable, fixed Courant number-based time-step. The numerical results obtained for a driven cavity at Re of 10,000, with local cell Re as high as 100, exhibits no flow variable spatial oscillations on a 40 x 40 stretched grid solution.

Soh, W. Y.↗

NASA NTRS1985

Interactive aircraft flight control and aeroelastic stabilization

An analytical model of a 3-D airfoil was used to study an optimization procedure formulated to enhance stability of an airfoil through integrated structural and control synthesis. This procedure is discussed together with preliminary results. These results show that a sensitivity derivative approach utilizing structural parameters, weighting matrix parameters and optimal control parameters (in this case, the design airspeed) is effective in determining the best structural/control design.

Weisshaar, T. A.↗

NASA NTRS1992

Computational study of transition front on a swept wing leading-edge model

The e(N) method is employed with Navier-Stokes calculations to study 3D supersonic boundary layers at the leading-edge region of swept wings with attention given to the conditions for linear stability. Mean-flow profiles are computed as solutions to the Navier-Stokes equations, and the e(N) method is used to identify the onset of the transition. Specific treatment is given to the identification of parameters which affect the transition such as free-stream Reynolds number, wall cooling, and boundary-layer suction levels. The boundary layer can be stabilized to below N=10 levels in all locations by utilizing distributed suction, and enhanced stabilization can also be achieved by employing wall cooling and reduced free-stream Reynolds numbers. This study presents key calculations for corresponding experimental investigations by shedding light on requirements for test conditions and measurement requirements.

Iyer, Venkit↗

NASA NTRS1989

Etalons Help Select Modes Of Laser Diodes

Stability under changes of temperature and current increased. External etalon aligned with laser diode provides optical feedback enhancing stability of operation in one or few of longitudinal laser modes. Provides amount of feedback varying periodically with wavelength. Also helps to increase stability by reducing sensitivity to minor feedback from external objects other than etalon.

Maynard, William L.↗

NASA NTRS1984

The Effect of Solidification Rate on Morphological Stability

At low solidification rates, the criterion for the onset of morphological instability parallels closely the criterion of constitutional supercooling. At somewhat larger rates of solidification, however, the results of the perturbation theory of morphological instability differ significantly from the predictions of constitutional supercooling. This arises because the critical wave length for instability decreases as solidification rate increases and thus the effects of capillarity (solid-liquid surface tension) play a strong stabilizing role. This gives rise to the concept of absolute stability, according to which the system will always be stable for a sufficiently large rate of solidification. This enhanced stabilization by capillarity is present only so long as local equilibrium is maintained at the solid-liquid interface. If the interfacial temperature drops below its equilibrium value by an amount dependent on growth rate, oscillatory morphological instabilities can occur. The differences among these various stability criteria are illustrated by means of some simple two-dimensional diagrams that should supplant the conventional plots of (temperature gradient)/(growth rate) vs. alloy concentration.

Sekerka, R. F.↗

NASA NTRS1982

Stabilized Acoustic Levitation of Dense Materials Using a High-Powered Siren

Stabilized acoustic levitation and manipulation of dense (e.g., steel) objects of 1 cm diameter, using a high powered siren, was demonstrated in trials that investigated the harmonic content and spatial distribution of the acoustic field, as well as the effect of sample position and reflector geometries on the acoustic field. Although further optimization is possible, the most stable operation achieved is expected to be adequate for most containerless processing applications. Best stability was obtained with an open reflector system, using a flat lower reflector and a slightly concave upper one. Operation slightly below resonance enhances stability as this minimizes the second harmonic, which is suspected of being a particularly destabilizing influence.

Gammell, P. M.↗

NASA NTRS2024

Intrastep, Stage-Value Predictors for Diagonally-Implicit Runge-Kutta Methods

To better identify the necessary attributes of good stage-value predictors (SVPs), numerous SVPs are designed for an existing: ESDIRK4(3)7L[2]SA [26] and a new: ESDIRK4(3)8L[2]SA scheme.1 Both are stifflyaccurate, stage-order two, explicit, singly-diagonally implicit Runge–Kutta (ESDIRK) schemes. Tradeoffs are studied in the parameter spaces enforcing the constraints on accuracy, linear stability, nonlinear stability and coefficient size to determine which objectives correlate with effective predictors. The SVPs are tested on three challenging external aerodynamics problems [107 − 108 degrees of freedom (DoFs)], each with a different level of stiffness. The problems include two 3D airfoils simulations and one canonical turbulence simulation. All simulations use the compressible Navier-Stokes equations (CNSE). An entropy stable spectral collocation formulation is used for discretizing the spatial terms in the equations. Simulations are performed at a wide variety of temporal error tolerances. Problems that are sufficiently stiff (e.g., lax temporal error tolerances) benefit from SVPs designed with second-order accuracy and stability properties: A-stability, and L-stability, rather than high accuracy constraints. Simulations with modest stiffness (e.g., strict error tolerances) are better suited for SVPs designed using high accuracy constraints. Designing SVPs with enhanced stability properties is tedious but worthwhile. Simulation times are reduced with optimal SVPs by as much as 100% on some stages, with combined stepwise improvements of between 50 − 100% for both methods. A comparative study is performed with the two aforementioned methods as well as four other ESDIRKs. The newly designed ESDIRK4(3)8L[2]SA with γ ≈ 1/10, proves to be the most efficient of the six tested ESDIRK schemes simulating the CNSE.

Diagonally-Implicit Runge-Kutta↗

NASA NTRS1986

Low-speed wind-tunnel investigation of the effect of strakes and nose machines on lateral-directional stability of a fighter configuration

A series of low-speed static wind-tunnel force tests were conducted on a 0.15-scale model of a modern high-performance fighter aircraft. The tests identified the use of nose chines to enhance stability at high angles of attack. Results of this investigation showed that the strake was the major contributor to directional instability. The destabilizing forces were created by two mechanisms: (1) adverse flow in the region of the vertical tail, and (2) forces generated on the fuselage ahead of the center of gravity. Properly designed nose chines effectively negated the adverse flow near the vertical tail and created stabilizing forces on the forebody in the range of the stall angle of attack.

Brandon, J. M.↗

NASA NTRS1993

Inherent stability of central element coaxial liquid-liquid injectors

Most TRW liquid bi-propellant rocket engines built over the past thirty-plus years have employed a central element coaxial pintle injector and have operated with liquid/liquid propellant injection. This injector is a patented design exclusive to TRW and has unique features that make the rocket engine combustion characteristics different from those of other types of injector engine designs. Its many benefits include excellent combustion performance, efficient deep throttling, adaptability to low cost manufacturing, and high reliability. Approximately 200 pintle injector engines of various sizes and operating on a variety of propellants have been flown without a single inflight failure. An especially important feature of the pintle injector engine is its apparent inherent combustion stability. In over thirty years of development, testing, and production, TRW has never experienced combustion instability in any of its pintle injector engine designs. This has been true of engines operating over a range of thrust from 5 to 250,000 lbs. on earth-storable hypergolic propellants and a large number of smaller engines operating on a variety of propellants (21 combinations) in long duration-firing, pulsing (down to 2 msec), and deep throttling (as much as 19:1) modes. Operating chamber pressures have ranged from 10 to 3,500 psia. This record is particularly impressive given that typical TRW design practice does not consider combustion instability as an issue and no pintle engine has ever employed stability-enhancing features, such as baffles or acoustically resonant chambers. In spite of this, TRW engines have operated stably in regimes not possible with other types of injectors. Various physical explanations and combustion process models for this favorable stability characteristic have been postulated. However, a definitive study that unequivocally establishes the important stabilizing mechanisms still remains to be conducted.

Stoddard, Frank J.↗

NASA NTRS2007

Dispersive Elements for Enhanced Laser Gyroscopy and Cavity Stabilization

We analyze the effect of a highly dispersive element placed inside a modulated optical cavity on the frequency and amplitude of the modulation to determine the conditions for cavity self-stabilization and enhanced gyroscopic sensitivity. We find an enhancement in the sensitivity of a laser gyroscope to rotation for normal dispersion, while anomalous dispersion can be used to self-stabilize an optical cavity. Our results indicate that atomic media, even coherent superpositions in multilevel atoms, are of limited use for these applications, because the amplitude and phase filters work against one another, i.e., decreasing the modulation frequency increases its amplitude and vice-versa. On the other hand, for optical resonators the dispersion reversal associated with critical coupling enables the amplitude and phase filters to work together. We find that for over-coupled resonators, the absorption and normal dispersion on-resonance increase the contrast and frequency of the beat-note, respectively, resulting in a substantial enhancement of the gyroscopic response. Under-coupled resonators can be used to stabilize the frequency of a laser cavity, but result in a concomitant increase in amplitude fluctuations. As a more ideal solution we propose the use of a variety of coupled-resonator-induced transparency that is accompanied by anomalous dispersion.

Smith, David D.↗